The layer/polyaniline conductive tackiness agent
Technical field
The invention belongs to the electro-conductive adhesive field.Be used for electrical equipment and electronic assemblies process and need to connect the place of circuit, with sticking generation weldering.
Background technology
Electro-conductive adhesive is to adapt to the tackiness agent kind that the electronic industry development need occurs, and it is used for the place that electrical equipment and electronic assemblies process need to connect circuit, with sticking generation weldering.Electro-conductive adhesive is made up of tackiness agent, electroconductive stuffing, solvent and additive.At present, many electronic components begin microminiaturization, and use some materials that are difficult to weld and the not high macromolecular material of thermotolerance, as adopt traditional welding process, very easily damage components and parts, and the also very difficult control of accurate miniature welding, not prison welding can be caused, the components and parts distortion, use properties descends.Conductive resin is more satisfactory method of attachment, not only can replace welding, can also be coated with, print on the circuit version as the conducting wire.Electroconductive stuffing commonly used has metal powder, Graphite Powder 99 etc., all belongs to inorganic materials.Its shortcoming is the cost height, easily oxidation, easily surface shortcoming such as come off.
Summary of the invention
The invention provides a kind of layer/polyaniline conductive tackiness agent, solving the cost height that present electro-conductive adhesive adopts inorganic materials to exist, easily oxidation, easily surface problem such as come off.The technical scheme that the present invention takes is: the component by following weight part is formed:
Tackiness agent: 90~110 parts
Electroconductive stuffing: 8~10 parts of electrically conductive polyanilines
Dispersion agent: 2~40 parts
Defoamer: 3~12 parts of N-BUTYL ACETATEs
Siccative: 0~2 part in dibutyl two lauryl alcohol tin.
Wherein: tackiness agent is Resins, epoxy, urethane resin, water soluble resin or silicone resin;
Dispersion agent is: dimethylbenzene, butanols, ethanol, ester class or water.
The invention has the advantages that and selected organic materials first for use: electrically conductive polyaniline is as electroconductive stuffing, solved the cost height that present electro-conductive adhesive adopts inorganic materials to exist, easily oxidation, easily surface problem such as come off.The key technical indexes of the present invention: color and outward appearance: black viscous fluid, proportion g/cm
3: 1.08, surface resistivity Ω/cm:10
2-10
5, solid content %:55-60,25 ℃/Pa ' of viscosity s:40-50.
Embodiment
Embodiment 1
Tackiness agent: Resins, epoxy E-51:100 gram
Electroconductive stuffing: electrically conductive polyaniline: 8 grams
Dispersion agent: dimethylbenzene: 40 grams
Defoamer: N-BUTYL ACETATE: 10 grams
Mix more than inciting somebody to action, grind 3-5 time, sneak into solidifying agent then: Ka Delai N75 40 grams that U.S. Ka Delai company produces with colloidal mill.Record surface resistivity 10
3Ω/cm.
Embodiment 2
Tackiness agent: urethane resin A-160:100 gram
Electroconductive stuffing: electrically conductive polyaniline: 8 grams
Dispersion agent: dimethylbenzene: 30 grams
Defoamer: N-BUTYL ACETATE: 12 grams
Mix more than inciting somebody to action, grind 3-5 time, and then add solidifying agent with colloidal mill: Ka Delai N75 32 grams,
Test surfaces resistivity 10
2Ω/cm.
Embodiment 3
Tackiness agent: terminal hydroxy group dimethyl silicone rubber emulsion: 90 grams
Electroconductive stuffing: electrically conductive polyaniline: 10 grams
Dispersion agent: propyl carbinol: 5 grams
Defoamer: N-BUTYL ACETATE: 11 grams
Siccative: dibutyl tin dilaurate: 0.5 gram
Above component is mixed, grind 3-5 time at colloidal mill, promptly obtaining surface resistivity is 10
3The electro-conductive adhesive of Ω/cm.
Embodiment 4:
Tackiness agent: water-based acrylic acid emulsion: 110 grams
Electroconductive stuffing: electrically conductive polyaniline: 9 grams
Dispersion agent: ethanol: 2 grams
Dispersion agent: deionized water 8 grams
Defoamer: N-BUTYL ACETATE: 3 grams
Will more than mix, heat to 80 degree, kept 20~30 minutes, after 10 hours dryings of normal temperature, colloidal mill grinding 3-5 time, surveying its surface resistivity is 10
4Ω/cm.