CN1772832A - Oil absorbing quick curing adhesive - Google Patents
Oil absorbing quick curing adhesive Download PDFInfo
- Publication number
- CN1772832A CN1772832A CNA2005100952034A CN200510095203A CN1772832A CN 1772832 A CN1772832 A CN 1772832A CN A2005100952034 A CNA2005100952034 A CN A2005100952034A CN 200510095203 A CN200510095203 A CN 200510095203A CN 1772832 A CN1772832 A CN 1772832A
- Authority
- CN
- China
- Prior art keywords
- oil
- bonding
- curing adhesive
- quick curing
- oil absorbing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 14
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 17
- 239000004593 Epoxy Substances 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 4
- 239000003921 oil Substances 0.000 abstract description 36
- 239000003822 epoxy resin Substances 0.000 abstract description 8
- 229920000647 polyepoxide Polymers 0.000 abstract description 8
- 239000002283 diesel fuel Substances 0.000 abstract description 3
- 239000003502 gasoline Substances 0.000 abstract description 3
- 239000003350 kerosene Substances 0.000 abstract description 3
- 238000007789 sealing Methods 0.000 abstract description 3
- 239000000314 lubricant Substances 0.000 abstract 1
- 230000014759 maintenance of location Effects 0.000 abstract 1
- 239000010705 motor oil Substances 0.000 abstract 1
- 238000003860 storage Methods 0.000 abstract 1
- 235000015927 pasta Nutrition 0.000 description 12
- -1 container Substances 0.000 description 8
- 238000004513 sizing Methods 0.000 description 8
- 239000003292 glue Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- NFVPEIKDMMISQO-UHFFFAOYSA-N 4-[(dimethylamino)methyl]phenol Chemical compound CN(C)CC1=CC=C(O)C=C1 NFVPEIKDMMISQO-UHFFFAOYSA-N 0.000 description 4
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 4
- 239000000292 calcium oxide Substances 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical class CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000002828 fuel tank Substances 0.000 description 1
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The oil absorbing quick curing adhesive as one kind of oily surface adhesive consists of epoxy resin 40-60 wt%, oil absorbing resin 10-16 wt%, oil absorbing stuffing 4-10 wt%, curing agent 16-22 wt% and promoter 10-15 wt%. The adhesive adheres and cures the oily surface quickly into one integral, and has two functions of adhering and sealing. It may be used in adhering surface of product with leaking gasoline, kerosene, diesel oil, engine oil, lubricant oil, transformer oil etc. and for emergency adhering of various leaking oil storages, container, truck, etc. without needing stopping and oil unloading.
Description
One, technical field
Oil absorbing quick curing adhesive of the present invention belongs to the bonding sizing agent of pasta.
Two, background technology
The at present domestic tackiness agent that has only two types of the bonding sizing agent of pasta and fast setting tackiness agent.The domestic bonding sizing agent of pasta that begins one's study at the beginning of the nineties in previous generation, Changchun Automobile Materials Research Inst's Li Shusheng carried out roundup to pasta glue in 1991, Shanghai Inst. of Materials had developed the solvent-free pasta functional structure of US-1 sizing agent afterwards, Shandong Zibo city chemical institute has been developed oil absorbency SGA sizing agent, HeFei University of Technology has developed EA-1 pasta glue, these tackiness agent belong to fast curing reactive acrylate class tackiness agent basically, though have the bonding function of pasta, but can only carry out bonding on the surface that micro oil is arranged, the surface oil mass is many slightly just can't be bonding, and curing speed is very slow or do not solidify.Also there is patent domestic pasta glue aspect, as invention disclosed patent on June 7th, 1989 (application number 87101409.2, publication number CN1633289A) pasta sizing agent, can carry out bonding at band oil meter face, but set time is explanation not, goes up analysis from filling a prescription and does not belong to fast curing type.
The domestic research of fast setting sizing agent started from the eighties in last century, the He Manluo of Dalian Inst of Chemicophysics, Chinese Academy of Sciences has developed fast solidified epoxy resin glue, Heilungkiang, Harbin petroleum chemistry has been developed quick-setting J-39 glue esters of acrylic acid tackiness agent, Tianjin synthetic materials Research Institute quick curing adhesives such as 914 fast cured epoxy resin class glue.Oil absorbing quick curing adhesive does not appear in the newspapers as yet.
Three, summary of the invention
The objective of the invention is to, developing does not a kind ofly need strict clean to repairing the surface, can carry out bonding repairing on the surface that oil arranged, and can solidify the oil absorbing quick curing adhesive that has two kinds of functions of adhering and sealing concurrently by PhastGel in several minutes again.
The weight percent of oil absorbing quick curing adhesive of the present invention:
Resins, epoxy (dihydroxyphenyl propane class) 40～60%
Oil-absorbing resin 10～16%
Oil suction filler 4～10%
Solidifying agent 16～22%
Promotor 10～15%
Oil absorbing quick curing adhesive of the present invention can be bonding with pasta, fast setting is integrated, have two kinds of functions of adhering and sealing, and can satisfy at the continuous gasoline of seepage, kerosene, diesel oil, machine oil, lubricating oil, the surface bonding of the various oils of transformer wet goods, even also can fast setting in these oil, can be at the basin of storing various oils, container, fuel tank, the continuous seepage of tank car etc., the pasta of leakage do not stop, do not drain the oil emergent bonding fast, and can repair by fast setting in several minutes.
Four, embodiment
By above-mentioned prescription as can be known, oil absorbing quick curing adhesive of the present invention is main colloidal materials with Resins, epoxy, oil absorption resin and material and fast solidifying agent in glue, have been added respectively, promotor etc., having solved existing sizing agent can only be in oil mass surface bonding seldom but can not fast setting, or can only solidify soon can not the bonding problem of pasta.
Oil absorbing quick curing adhesive design reaction principle is, tackiness agent can bonding primary condition be, the surface energy of tackiness agent must be less than by the surface energy of sticky object.Because gasoline, kerosene, diesel oil, lubricated wet goods hydrocarbon-type oil are C
7～C
12, C
12～C
16, C
15～C
18, C
16～C
20Long chain alkane class material, their surface energy is lower, and the surface energy of tackiness agent is higher relatively, thereby tackiness agent be difficult to carry out on the surface that oil is arranged bonding, therefore adopted can molten oil the cambic oligomer material with low surface energy, be exactly so-called oil-absorbing resin, its objective is the surface energy that reduces tackiness agent, make it the surface energy that surface energy is lower than oily substance, also adopted part oil absorption resin and filler simultaneously, to reduce the oil mass of gluing of surfaces effectively.Meanwhile, also adopted the fast solidifying agent and the accelerator system that contain hydroxyl,, can quicken curing reaction again because hydroxyl can either be participated in curing reaction.
The present invention can adopt following concrete weight percent:
Resins, epoxy such as E-44 or E-51 40～60%
Oil-absorbing resin 1 is as acrylic acid epoxy resin 6～8%
Oil-absorbing resin 2 is as the rare amide resins 4～8% of crosslinked polypropylene
Oil suction filler such as calcium oxide powder 4～10%
Solidifying agent such as hydroxy aliphatic amine 16～22%
Curing catalyst as 2,4,6-three (dimethylamino methyl) phenol 10～15%
Specific examples:
Example (1) carries out bonding to the less surface of oil:
In the E-44 of 60g Resins, epoxy, the acrylic acid epoxy resin that adds 6g respectively successively, the calcium oxide powder of 4g (about 100 orders), the hydroxy aliphatic amine of 16g, 10g 2,4,6-three (dimethylamino methyl) phenol, be applied on the bonding plane immediately after stirring, gel solidification about 10 minutes produces bonding strength.
Example (2) is bonding to there being more butyrous surface to carry out:
In the E-44 of 60g epoxy resins, the acrylic acid epoxy resin that adds 6g respectively successively, the calcium oxide powder of 6g (about 100 orders), the rare amide resins powder of 5g crosslinked polypropylene (about 100 orders), the hydroxy aliphatic amine of 18g, 12g 2,4,6-three (dimethylamino methyl) phenol, be applied to immediately after stirring on the bonding plane, gel solidification about 10 minutes produces bonding strength.
Example (3) to have a lot of oil or ceaselessly the surface of trickling oil carry out bonding:
In the E-44 of 55g Resins, epoxy, the acrylic acid epoxy resin that adds 8g respectively successively, the calcium oxide powder of 10g (about 100 orders), the rare amide resins powder of 8g crosslinked polypropylene, the hydroxy aliphatic amine of 22g, 15g 2,4,6-three (dimethylamino methyl) phenol, be applied to immediately after stirring on the bonding plane, gel solidification about 10 minutes produces bonding strength.
Claims (1)
1. an oil absorbing quick curing adhesive is characterized in that, the weight percent of composition is: Resins, epoxy 40-60%, oil-absorbing resin 10-16%, oil suction filler 4-10%, solidifying agent 16-22%, promotor 10-15%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2005100952034A CN1772832A (en) | 2005-11-03 | 2005-11-03 | Oil absorbing quick curing adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2005100952034A CN1772832A (en) | 2005-11-03 | 2005-11-03 | Oil absorbing quick curing adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1772832A true CN1772832A (en) | 2006-05-17 |
Family
ID=36759978
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2005100952034A Pending CN1772832A (en) | 2005-11-03 | 2005-11-03 | Oil absorbing quick curing adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1772832A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102477270A (en) * | 2010-11-23 | 2012-05-30 | 上海恩意材料科技有限公司 | Water-proof fast-curing adhesive |
| CN106221640A (en) * | 2016-08-31 | 2016-12-14 | 国网辽宁省电力有限公司丹东供电公司 | A kind of pasta bonding adhesive and use its restorative procedure |
| CN107603545A (en) * | 2017-09-19 | 2018-01-19 | 常州诺澜复合材料有限公司 | A kind of preparation method of waterproof heat-resisting fluid sealant |
| CN108701978A (en) * | 2016-02-25 | 2018-10-23 | 株式会社自动网络技术研究所 | Wire protective component and its manufacturing method and harness |
| CN109481964A (en) * | 2018-10-04 | 2019-03-19 | 南京航空航天大学溧水仿生产业研究院有限公司 | The preparation method of polyvinyl chloride oil suction fibre film |
-
2005
- 2005-11-03 CN CNA2005100952034A patent/CN1772832A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102477270A (en) * | 2010-11-23 | 2012-05-30 | 上海恩意材料科技有限公司 | Water-proof fast-curing adhesive |
| CN108701978A (en) * | 2016-02-25 | 2018-10-23 | 株式会社自动网络技术研究所 | Wire protective component and its manufacturing method and harness |
| CN108701978B (en) * | 2016-02-25 | 2020-03-27 | 株式会社自动网络技术研究所 | Wire protection member, method for manufacturing same, and wire harness |
| CN106221640A (en) * | 2016-08-31 | 2016-12-14 | 国网辽宁省电力有限公司丹东供电公司 | A kind of pasta bonding adhesive and use its restorative procedure |
| CN106221640B (en) * | 2016-08-31 | 2021-10-01 | 国网辽宁省电力有限公司丹东供电公司 | Oil surface adhesive and repairing method using same |
| CN107603545A (en) * | 2017-09-19 | 2018-01-19 | 常州诺澜复合材料有限公司 | A kind of preparation method of waterproof heat-resisting fluid sealant |
| CN109481964A (en) * | 2018-10-04 | 2019-03-19 | 南京航空航天大学溧水仿生产业研究院有限公司 | The preparation method of polyvinyl chloride oil suction fibre film |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |