CN1757978A - A kind of hydrate high density latent heat is carried central air conditioner system - Google Patents
A kind of hydrate high density latent heat is carried central air conditioner system Download PDFInfo
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- CN1757978A CN1757978A CN 200510100814 CN200510100814A CN1757978A CN 1757978 A CN1757978 A CN 1757978A CN 200510100814 CN200510100814 CN 200510100814 CN 200510100814 A CN200510100814 A CN 200510100814A CN 1757978 A CN1757978 A CN 1757978A
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- refrigerating medium
- central air
- air conditioner
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- 239000002002 slurry Substances 0.000 claims abstract description 52
- 238000004781 supercooling Methods 0.000 claims abstract description 38
- 238000004378 air conditioning Methods 0.000 claims abstract description 23
- 230000005540 biological transmission Effects 0.000 claims abstract description 20
- 238000001816 cooling Methods 0.000 claims abstract description 18
- 239000000498 cooling water Substances 0.000 claims abstract description 17
- 238000005057 refrigeration Methods 0.000 claims abstract description 17
- 150000003863 ammonium salts Chemical class 0.000 claims abstract description 5
- 239000007864 aqueous solution Substances 0.000 claims description 9
- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 claims description 4
- ODJZWVFLHZHURI-UHFFFAOYSA-M [Br-].C(CCC)[P+](CCCC)(CCCC)CCCC.[NH4+].[Br-] Chemical compound [Br-].C(CCC)[P+](CCCC)(CCCC)CCCC.[NH4+].[Br-] ODJZWVFLHZHURI-UHFFFAOYSA-M 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 3
- 230000007306 turnover Effects 0.000 claims description 2
- 230000008901 benefit Effects 0.000 abstract description 8
- 239000003507 refrigerant Substances 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 43
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 15
- RKHXQBLJXBGEKF-UHFFFAOYSA-M tetrabutylphosphanium;bromide Chemical compound [Br-].CCCC[P+](CCCC)(CCCC)CCCC RKHXQBLJXBGEKF-UHFFFAOYSA-M 0.000 description 15
- 239000012071 phase Substances 0.000 description 14
- 239000007788 liquid Substances 0.000 description 12
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 229910001220 stainless steel Inorganic materials 0.000 description 7
- 239000010935 stainless steel Substances 0.000 description 7
- 230000007704 transition Effects 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 5
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- 238000005516 engineering process Methods 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
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- 238000000034 method Methods 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 239000007790 solid phase Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- JCHOVTKTIUCYQR-UHFFFAOYSA-M tetrabutylazanium;bromide;hydrate Chemical compound O.[Br-].CCCC[N+](CCCC)(CCCC)CCCC JCHOVTKTIUCYQR-UHFFFAOYSA-M 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
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- 238000010586 diagram Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
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- 238000003475 lamination Methods 0.000 description 1
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- 201000009240 nasopharyngitis Diseases 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
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Abstract
The invention provides a kind of hydrate slurry and carry central air conditioner system as the high density latent heat of refrigerating medium with ammonium salt.Comprise refrigeration unit, refrigerating medium circulating pump 8, air conditioning terminal heat transmission equipment 7 and refrigerating medium, the evaporimeter 11 of refrigeration unit, condenser 13, compressor 4 and choke valve 12 are connected to form refrigeration cycle, condenser 13 is connected to form cooling water circulation loop through cooling water pump 14 with cooling tower 1, it is characterized in that: also comprise evaporimeter 11, ultrasonic wave supercooling remover 10, the continuously quick generating apparatus of the hydrate slurry that preheater 5 and refrigerating medium circulating pump 8 connect and compose successively, the continuously quick generating apparatus of this hydrate slurry is connected to form the refrigerating medium closed circuit with air conditioning terminal heat transmission equipment 7; Described refrigerating medium is the hydrate slurry of ammonium salt.The present invention adopts novel secondary refrigerant, and the refrigerating medium circulation that can be central air-conditioning with its highdensity cold conveying capacity brings huge energy-saving benefit.
Description
Technical field
The present invention relates to a kind of central air conditioner system, particularly a kind of latent heat type central air conditioner system of utilizing hydrate slurry as refrigerating medium.
Background technology
Existing various big-and-middle-sized central air conditioner system nearly all with the chilled water of liquid state as the storage and the conveying of carrying cold media implementation cold, promptly so-called cold water formula central air-conditioning.In this cold water formula central air conditioner system, cold water obtains cold in the refrigeration unit evaporimeter after, temperature reduces (generally dropping to 7 ℃), be transported in each air conditioning terminal heat transmission equipment (as fan coil etc.) by water pump and insulated piping again and discharge cold, temperature rising (generally rising to 12 ℃), sent back to the evaporimeter of refrigeration unit then again, finished a circulation.Therefore, in big-and-middle-sized central air conditioner system, transmission nearly all circulates by cold water and finishes from refrigeration unit to the cold each terminal heat transmission equipment.Though that cold water has is nontoxic, corrosivity is little, stable in properties, plurality of advantages such as cheap, but carry (promptly not having phase transformation takes place) because cold water carries the mode of cold to belong to sensible heat, its cold carries density (refrigerating medium that is exactly specific discharge utilizes following the cold that can carry of the temperature difference in unit) very low.So the cold that the unit volume fluid can be stored or carry is very limited.For the very high big-and-middle-sized central air conditioner system of various cold water formulas of cold delivery requirements, the flow of required refrigerating medium (cold water) is also very big, and this not only needs thick line size, and the delivery pump merit that is consumed also can be very high.For common central air conditioner system, keep the pump merit that cold water circulation consumed and in the comprehensive energy consumption of whole air-conditioning system, can reach 30% ratio.On the other hand, the transmission of sensible heat heat needs the bigger temperature difference, this problem with regard to having caused the heat-exchange system efficiency to descend.
Compare with sensible heat heat transfer, follow the latent heat of phase-state change to conduct heat then to have the cold transmission density is big, heat transfer temperature difference is little advantages such as (even can realize the constant temperature heat exchange).Up to the present, all there be many application ice is starched to carry out the research report that cold is carried both at home and abroad.These research and propose application ice slurry, and---being the mixed muddy suspension body of solid-liquid two-phase that solid ice pellets and aqueous water form under 0 ℃ by a certain percentage---carries as the high density cold in the refrigerating medium realization central air-conditioning.Because the ice slurry contains solid-state ice, so it can carry cold by the latent heat of phase change of ice.The latent heat of phase change of ice is 80kcal/kg, and is bigger 80 times than the sensible heat (1kcal/kg) of water under 1 ℃ of temperature difference, and therefore the ice slurry utilizes the cold under the temperature to carry density far above cold water identical.On the other hand, because the ice slurry is a kind of muddy suspension body that contains aqueous water, be a kind of fluid with good fluidity, therefore can carry with pump and pipeline easily as common cold water.If can starch refrigerating medium---the cold water that replaces in the existing central air-conditioning with ice, then the cold of refrigerating medium carries density to be greatly improved, this just means that the circular flow of refrigerating medium in pipes system can reduce significantly, therefore the energy consumption of keeping the refrigerating medium circulation also will significantly reduce thereupon, simultaneously the circulating line downsizing be can also make, material cost and space saved.This shows, utilize the solid-liquid two-phase of ice slurry or other similar ice slurry to mix the refrigerating medium that slurry is carried as cold, will bring huge energy-saving benefit for various central air conditioner systems.
Though the application prospect of ice slurry high density latent heat conveying technology in central air conditioner system is considerable, also is faced with many intrinsic defectives and a technical difficult problem.At first, the generation temperature of ice slurry is on the low side (being below 0 ℃, by the freezing point decision of water).In order to produce out the ice slurry, the evaporating temperature of refrigeration machine must drop to below-5 ℃ usually, low like this evaporating temperature makes that the Energy Efficiency Ratio (COP) of refrigeration system is very low, can only reach about 60% of common handpiece Water Chilling Units usually, has increased the energy resource consumption of refrigeration compressor significantly; Secondly, solid ice particles and the density difference between the aqueous water in the ice slurry are bigger, occur the frozen water lamination in course of conveying easily, and this distribution to the conveying of ice slurry and cold is all unfavorable; The 3rd, between ice pellets and the ice pellets once contacting, very easily be incorporated into bigger particle, therefore the ice slurry is easy to harden and blocking pipe equipment with regard to ice cube occurring in pipe conveying procedure, and this also is to restrict ice slurry high density latent heat conveying technology at present to move towards one of practical major obstacle.
Based on above technical background, the present invention proposes the refrigerating medium carried as cold with a kind of hydrate slurry of ammonium salt, replace refrigerating medium---the cold water in the existing cold water formula central air conditioner system, thereby make central air conditioner system realize the energy-saving benefit of cutting down significantly by the refrigerating medium circulation power consumption that the high density latent heat conveying technology brings
Summary of the invention
The object of the present invention is to provide a kind of hydrate slurry to carry central air conditioner system as the high density latent heat of refrigerating medium with ammonium salt.The refrigerating medium circulation that this novel refrigerating medium can be a central air-conditioning with its highdensity cold conveying capacity brings huge energy-saving benefit.
Hydrate high density latent heat of the present invention carries central air conditioner system to comprise evaporimeter, condenser, compressor, choke valve, the continuously quick generating apparatus of hydrate slurry, air conditioning terminal heat transmission equipment (fan coil), the ammonium salt hydrate, evaporimeter, condenser, compressor and choke valve head and the tail connect and compose refrigeration cycle successively, evaporimeter, ultrasonic wave supercooling remover, preheater and refrigerating medium circulating pump connect and compose the continuously quick generating apparatus of hydrate slurry successively, and the continuously quick generating apparatus of this hydrate slurry is connected to form the refrigerating medium closed circuit with air conditioning terminal heat transmission equipment (fan coil); Warm-up cycle water pump, preheater and auxiliary thermal source are connected to form the warm-up cycle loop.
In the described refrigerating medium closed circuit, between preheater and the evaporimeter, the outlet of evaporator outlet, ultrasonic wave subcooler remover respectively is equipped with a temperature sensor, the inlet of refrigerating medium circulating pump is equipped with expansion tank.
Described ammonium salt hydrate can be the tetrabutyl phosphonium bromide aqueous ammonium, and (chemical molecular formula is (C by the tetrabutyl phosphonium bromide ammonium salt
4H
9)
4NBr) formulated with water, wherein the mass concentration of TBAB in the described aqueous solution is 16.8%～40.5% (kg/kg).Phase transition temperature when this aqueous solution generates the solid water compound can change between 0～12 ℃ according to the mass concentration difference of TBAB, phase transition temperature and wherein have the corresponding relation of determining between the mass concentration of tetrabutyl phosphonium bromide ammonium salt, when mass concentration is 20% (kg/kg), phase transition temperature is 8.5 ℃, when mass concentration is 25% (kg/kg), phase transition temperature is 10 ℃, and when mass concentration was 35% (kg/kg), phase transition temperature was 11.3 ℃.The hydrate slurry that the tetrabutyl phosphonium bromide aqueous ammonium generates is carried the refrigerating medium of central air conditioner system as hydrate high density latent heat of the present invention, stores in described refrigerating medium closed circuit and circulation.
The type of cooling of described condenser can be that water-cooled also can be air-cooled.If water-cooled is connected to form cooling water circulation loop through cooling water pump with cooling tower with condenser, this moment warm-up cycle water pump, preheater being linked to each other with the feed pipe of described cooling tower constitutes the warm-up cycle loop, and thermal source is provided by the feed pipe of cooling tower; If it is air-cooled, then a cooling fan directly is contained on the described condenser, this moment, heat can be obtained from the high temperature cooling hot blast of condenser by increasing heat exchanger in described warm-up cycle loop, also can obtain heat by other thermal source (as electrical heating, environment hot water etc.) outside system, constitute a closed circuit separately.
Hydrate slurry device for continuously fast preparing of the present invention comprises preheater, evaporimeter (supercooling heat exchanger), ultrasonic wave supercooling remover and refrigerating medium circulating pump that head and the tail connect successively.
Described supercooling heat exchanger is a plate type heat exchanger.
Connecting leg between described evaporimeter (supercooling heat exchanger) and the ultrasonic wave supercooling remover is provided with a temperature sensor.
On the outlet connecting leg of described ultrasonic wave supercooling remover refrigerating medium circulating pump is housed.
Described preheater is plate type heat exchanger or shell-and-tube heat exchanger or double pipe heat exchanger, and the connecting leg between preheater and the evaporimeter (supercooling heat exchanger) is provided with a temperature sensor.
Described ultrasonic wave supercooling remover comprises housing and is encapsulated in the ultrasonic oscillator box of described enclosure interior, described housing becomes an inner chamber with described ultrasonic oscillator box-like, this inner chamber connects with inlet tube and outlet respectively, described inlet tube connects the supercooling heat exchanger, and described outlet connects delivery pump.The built-in some ultrasonic oscillators that link to each other with power supply of described ultrasonic oscillator box, the formed ultrasonic wave surface of emission of described ultrasonic oscillator is over against the central shaft of described inner chamber.The inner chamber of described ultrasonic wave supercooling remover is exactly the place that supercooling is removed.Housing is respectively equipped with inlet tube and outlet in two ends up and down, and the center, top is provided with blast pipe.
Hydrate slurry device for continuously fast preparing of the present invention can be applicable to make hydrate slurry.Aqueous water or hydrate soln at first are admitted to preheating in the preheater, enter then in the evaporimeter (supercooling heat exchanger) by supercooling, cooled liquid directly enters ultrasonic wave supercooling remover after coming out from evaporimeter (supercooling heat exchanger), in ultrasonic wave supercooling remover, generate hydrate slurry rapidly through action of ultrasonic waves, be transported to air conditioning terminal heat transmission equipment (fan coil) by refrigerating medium circulating pump at last, the refrigerating medium (liquid tetrabutyl phosphonium bromide aqueous ammonium) of returning from the air conditioning terminal heat transmission equipment is sent to preheater again, finishes a circulation.Hydrate slurry device for continuously fast preparing of the present invention has thus been realized the efficient quick and continuous circulation manufacture process of hydrate slurry.
As refrigerating medium, this refrigerating medium can generate the mixed hydrate slurry (the mixed ice of similar solid-liquid two-phase is starched) of solid-liquid two-phase that contains a large amount of tiny solid water compound crystal grain by the continuously quick generating apparatus of described hydrate slurry to hydrate high density latent heat conveying central air conditioner system of the present invention continuously fast with the tetrabutyl phosphonium bromide aqueous ammonium.Because having very high cold, this hydrate slurry with good fluidity carries density (Billy is that 7～12 ℃ cold water is high more than 3 times with temperature), so the refrigerating medium circular flow can reduce significantly, thereby the pump power consumption of carrying cold circulation can reduce about 75% than the cold water circulation of ordinary central air-conditioner, for existing cold water formula central air-conditioning brings huge energy-saving benefit, carry central air conditioner system to compare with potential ice slurry high density latent heat, though the cold of TBAB hydrate slurry of the present invention carries density high not as good as the ice slurry, but make the required refrigeration evaporator temperature of described TBAB hydrate slurry (7 ℃) far above ice slurry (2 ℃), therefore refrigeration unit can have very considerable energy saving benefit equally in the high energy efficiency that meets or exceeds common handpiece Water Chilling Units than (COP) following operation.
Description of drawings
Fig. 1 is that the described hydrate high density latent heat of the embodiment of the invention is carried the central air conditioner system schematic diagram;
Fig. 2 is the structural representation of embodiment of the invention ultrasonic wave supercooling remover 10;
Fig. 3 is the cutaway view of Fig. 2.
Description of reference numerals
1 cooling tower, 2 cooling tower feed pipes, 3 warm-up cycle water pumps, 4 compressors, 5 preheaters, 6 expansion tanks, 7 air conditioning terminal heat transmission equipments, 8 refrigerating medium circulating pumps, 9 temperature sensors, 10 ultrasonic wave supercooling removers, 11 evaporimeters, 12 choke valves, 13 condensers, 14 cooling water pumps
101 outlets, 102 housings, 103 inlet tubes, 104 stop valves, 105 blast pipes, 106 ultrasonic oscillator power supply lead wires, 107 power supply lead wire stainless steel sleeve pipes, 108 nuts, 109 seal gaskets, 1010 ultrasonic oscillator boxes, 1011 surface of emissions, 1012 inner chambers
The specific embodiment
Hydrate high density latent heat of the present invention carries central air conditioner system to comprise loops such as kind of refrigeration cycle, refrigerating medium circulation and warm-up cycle, as shown in Figure 1.If condenser is a water-cooled, then also comprise a cooling water circulation loop, as be air-cooled that then no-cooling-water circulation changes by condenser fan and replaces.Below with water cooled condenser, embodiments of the present invention are done specifying:
In mass concentration is that 22% ratio makes the refrigerating medium of tetrabutyl phosphonium bromide aqueous ammonium as present embodiment, and its phase transition temperature is 9 ℃.
Evaporimeter, condenser, compressor and choke valve head and the tail connect and compose refrigeration cycle successively, water circulation cooling is cooled in condenser 13 after compressed machine 4 compressions of cold-producing medium (fluorine Lyons), after choke valve 12 throttling step-downs, enter evaporation heat absorption in the evaporimeter 11 then, cold is passed to refrigerating medium.Low pressure refrigerant vapor after the evaporation is got back in the compressor once more, finishes a circulation.
Condenser is connected to form cooling water circulation loop through cooling water pump with cooling tower, cooling water is sent in the condenser 13 by cooling water pump 14, absorbed the condenser heat of cold-producing medium after cooling tower feed pipe 2 enters cooling in the cooling tower 1, cooled cooling water is got back to cooling water pump 14 again, finishes a circulation.
Evaporimeter 11, ultrasonic wave supercooling remover 10, preheater 5 and refrigerating medium circulating pump 8 together constitute the continuously quick generating apparatus system of hydrate slurry, and refrigerating medium is changed into hydrate slurry by liquid solution in the generating apparatus system continuously fast continuously fast at this hydrate slurry.The continuously quick generating apparatus of hydrate slurry is connected to form the refrigerating medium closed circuit with air conditioning terminal heat transmission equipment (fan coil), the refrigerating medium of returning from air conditioning terminal heat transmission equipment 7 is liquid tetrabutyl phosphonium bromide aqueous ammonium, liquid tetrabutyl phosphonium bromide aqueous ammonium directly enters preheater 5 after air conditioning terminal heat transmission equipment 7 comes out, the outlet of preheater 5 connects the inlet of evaporimeter 11.The effect of preheater 5 is to make the temperature that enters evaporimeter 11 liquid tetrabutyl phosphonium bromide aqueous ammonium before be not less than 10 ℃ all the time, because this temperature is higher than 9 ℃ of the phase transition temperatures of the described aqueous solution, so can guarantee no longer to contain in the described aqueous solution solid-state hydrate particle, thereby guarantee that the described aqueous solution that enters evaporimeter 11 can not generate the solid water compound in advance and stop up evaporimeter 11.10 ℃ described tetrabutyl phosphonium bromide aqueous ammonium directly enters evaporimeter 11 after preheater 5 comes out, in evaporimeter 11 by supercooling to 7 ℃.At this moment, the solid water compound does not generate as yet, but the described aqueous solution has been in supercooled state.The above-mentioned 7 ℃ supercooled state aqueous solution directly enters and flows through ultrasonic wave supercooling remover 10 with the＜flow velocity of 10m/s from evaporimeter 11 back of coming out, generate hydrate through hyperacoustic short brilliant effect therein, when arriving the outlet of ultrasonic wave supercooling remover 10, described tetrabutyl phosphonium bromide aqueous ammonium has become the hydrate slurry that contains 25% solid phase hydration thing composition, because the solid water compound that the inherent characteristic of tetrabutyl phosphonium bromide aqueous ammonium generates all is the following fine particles of particle diameter 100 μ m, and even particle size distribution, density is also very approaching with residue tetrabutyl phosphonium bromide aqueous ammonium, therefore under non-long-time static condition, phenomenons such as solid-liquid layering and solid phase harden can not occur, have the flow behavior that good suitable pipeline is carried.Above-mentioned hydrate slurry directly is sent to each air conditioning terminal heat transmission equipment 7 released cold quantities by refrigerating medium circulating pump 8 after coming out from ultrasonic wave supercooling remover 10.Temperature raises above-mentioned hydrate slurry discharges cold in air conditioning terminal heat transmission equipment 7 after, becomes 12 ℃ above-mentioned tetrabutyl phosphonium bromide aqueous ammonium, and then enters preheater, finishes a circulation.
The cold density of the above-mentioned hydrate slurry that comes out from ultrasonic wave supercooling remover 10 is 67kJ/kg (heat content with 12 ℃ tetrabutyl phosphonium bromide aqueous ammoniums is a benchmark), be 3 times of cold water cold density (21kJ/kg) that utilize temperature between 7～12 ℃, therefore the circular flow of whole refrigerating medium can reduce by 3 times, thereby brings the significantly reduction of refrigerating medium circulation power consumption.
In the refrigerating medium closed circuit, one temperature sensor A is installed between preheater and the evaporimeter, is used to control the above-mentioned TBAB aqueous temperature that enters evaporimeter 11 and is not less than 10 ℃, if be lower than 10 ℃ then send the preheating instruction, warm-up cycle starts, otherwise warm-up cycle does not start.Evaporator outlet is installed a temperature sensor B, is used to control the degree of supercooling of the above-mentioned tetrabutyl phosphonium bromide aqueous ammonium that comes out from evaporimeter 11.A temperature sensor C is installed in the outlet of ultrasonic wave supercooling remover, is used to control the temperature of the above-mentioned hydrate slurry that is sent to air conditioning terminal heat transmission equipment 7.
Cooling tower feed pipe 2 in preheater, warm-up cycle water pump and the cooling water circulation is connected to form the warm-up cycle loop.When needs started warm-up cycle, warm-up cycle water pump 3 was just extracted the cooling water that comes out from condenser 13 out a part and is sent to preheater 5 from cooling tower feed pipe 2, returned in the cooling tower feed pipe 2 behind the heating refrigerating medium in preheater 5, finished a circulation.
The inlet of refrigerating medium circulating pump is installed an expansion tank 6, is used for the pressure of balance refrigerating medium closed circuit.
As shown in Figure 3, the ultrasonic wave supercooling remover 10 of present embodiment comprises housing 102 and is encapsulated in the ultrasonic oscillator box 1010 of described housing 102 inside, described housing 02 and described ultrasonic oscillator box 1010 form an inner chamber 1012, this inner chamber 1012 connects with inlet tube 101 and outlet 103 respectively, described inlet tube 101 connects pervaporation device (supercooling heat exchanger) 11, and described outlet 103 connects refrigerating medium circulating pump 8.Described ultrasonic oscillator box 1010 built-in some ultrasonic oscillators that link to each other with power supply 1013, the described ultrasonic oscillator 1013 formed ultrasonic wave surface of emissions 1011 are over against the central shaft of described inner chamber 1012.The inner chamber 1012 of described ultrasonic wave supercooling remover 1010 is exactly the place that supercooling is removed.Housing is respectively equipped with inlet tube 103 and outlet 101 in two ends about in the of 102, and the center, top is provided with blast pipe 105.
Described ultrasonic oscillator box 1010 is made up of ultrasonic oscillator 1013, stainless steel casing and ultrasonic oscillator power supply lead wire 106.The equally spaced cuboid stainless steel casing inside that is arranged in the square-section of some ultrasonic oscillators, the surface of emission of all ultrasonic oscillators all is attached on the same inner surface of stainless steel casing, the pairing outer surface of this inner surface is exactly the surface of emission 1011 of ultrasonic oscillator box, it is 10 central shafts over against above-mentioned supercooling releasing place inner chamber 1012 in the supercooling remover, so that launch uniform ultrasonic wave in cylindrical cavity.The place is the opening except that the ultrasonic oscillator power supply lead wire, and the ultrasonic oscillator box is all sealings, and its inside and outside is isolated, invades the corrosion ultrasonic oscillator to prevent liquid.
The power supply lead wire place of described ultrasonic oscillator box is provided with power supply lead wire stainless steel sleeve pipe 107, and the sleeve outer wall face is processed with screw thread.The oscillator box overall package is in described housing, and power supply stainless steel sleeve pipe 107 is wrapped in the oscillator power supply lead wire and stretches out from the housing round hole, and makes housings close by seal gasket 109 and clamp nut 108.On the other hand, stainless steel power supply lead wire sleeve pipe and clamp nut also play the fixedly effect of oscillator box.
In the square cavity of described shell inner surface, arrange two identical above-mentioned ultrasonic oscillator boxes 1010.Ultrasonic oscillator box 1010 is vertically placed, and the ultrasonic oscillator box surface of emission 1011 is arranged on the circumference in enclosure interior cylindrical cavity 1012 cross sections, with the cylindrical shape of the maintenance inner chamber 1012 of maximum possible.Two ultrasonic oscillator boxes 1010 are 120 degree at upper edge, horizontal cross-section enclosure interior inner chamber 1012 circumference and distribute, the purpose of Bu Zhiing is in order to make two ultrasonic oscillator box ultrasonic waves transmitted mutual oblique in the housing inner chamber like this, to make in inner chamber not only strongly but also ultrasound field cavitation disturbance uniformly.
On the upper side of described housing, be furnished with an inlet tube 103, be furnished with an outlet 101 on the lower side.Import and export Guan Jun and draw, and the direction of rotation of current turnover is identical along the tangent to periphery direction level of enclosure interior inner chamber.Such import and export pipe arrangement is in order to make current rotate disturbance after entering the enclosure interior inner chamber, so that current are accepted ultrasonic wave radiation more uniformly in inner chamber.
Described case top has a blast pipe 105, and blast pipe is equipped with stop valve 104.Can get rid of foreign gas in the housing by stop valve, also can be used as the high-pressure security protection measure.
Claims (10)
1, a kind of hydrate high density latent heat is carried central air conditioner system, comprise refrigeration unit, refrigerating medium circulating pump (8), air conditioning terminal heat transmission equipment (7) and refrigerating medium, the evaporimeter of refrigeration unit (11), condenser (13), compressor (4) and choke valve (12) are connected to form refrigeration cycle, condenser (13) is connected to form cooling water circulation loop through the same cooling tower of cooling water pump (14) (1), it is characterized in that: also comprise evaporimeter (11), ultrasonic wave supercooling remover (10), the continuously quick generating apparatus of the hydrate slurry that preheater (5) and refrigerating medium circulating pump (8) connect and compose successively, the continuously quick generating apparatus of this hydrate slurry is connected to form the refrigerating medium closed circuit with air conditioning terminal heat transmission equipment (7); Described refrigerating medium is the hydrate slurry of ammonium salt.
2, a kind of hydrate high density latent heat as claimed in claim 1 is carried central air conditioner system, it is characterized in that: described hydrate can be the tetrabutyl phosphonium bromide ammonium salt aqueous solution, and wherein the mass concentration of TBAB in the described aqueous solution is 16.8%～40.5% (kg/kg).
3, a kind of hydrate high density latent heat as claimed in claim 1 is carried central air conditioner system, and it is characterized in that: in the described refrigerating medium closed circuit, the inlet of refrigerating medium circulating pump (8) is equipped with expansion tank (6).
4, a kind of hydrate high density latent heat as claimed in claim 1 is carried central air conditioner system, it is characterized in that: the device for continuously fast preparing of described hydrate slurry comprises preheater (5), evaporimeter (11), ultrasonic wave supercooling remover (10) and the refrigerating medium circulating pump (8) that head and the tail connect successively; Described ultrasonic wave supercooling remover (10) comprises housing (102) and is encapsulated in the inner ultrasonic oscillator box (1010) of described housing (102), described housing (102) and described ultrasonic oscillator box (1010) form an inner chamber (1012), this inner chamber (1012) connects with inlet tube (103) and outlet (101) respectively, described inlet tube (103) connects evaporimeter (11), and described outlet (101) connects refrigerating medium circulating pump (8); The built-in some ultrasonic oscillators that link to each other with power supply of described ultrasonic oscillator box (1010), the formed ultrasonic wave surface of emission of described ultrasonic oscillator (1011) is over against the central shaft of described inner chamber (1012).
5, carry central air conditioner system as claim 1 or 4 described a kind of hydrate high density latent heats, it is characterized in that: between described preheater (5) and the described evaporimeter (11) temperature sensor is housed, between described evaporimeter (11) and the described ultrasonic wave supercooling decontrol (10) temperature sensor is housed also.
6, carry central air conditioner system as claim 1 or 4 described a kind of hydrate high density latent heats, it is characterized in that: described evaporimeter (11) is a plate type heat exchanger.
7, carry central air conditioner system as claim 1 or 4 described a kind of hydrate high density latent heats, it is characterized in that: described preheater (5) is plate type heat exchanger or shell-and-tube heat exchanger or double pipe heat exchanger.
8, a kind of hydrate high density latent heat as claimed in claim 4 is carried central air conditioner system, it is characterized in that: it is cylindrical that described inner chamber (1012) is class, described ultrasonic oscillator box (1010) is two, and is 120 degree distributions at the described inner chamber in upper edge, horizontal cross-section (1012) circumference.
9, a kind of hydrate high density latent heat as claimed in claim 4 is carried central air conditioner system, it is characterized in that: described inlet tube (103) is arranged in the upper side of described housing (102), described outlet (101) is arranged in the lower side of described housing (102), both all draw along the tangent to periphery direction level of housing inner chamber (1012), and the direction of rotation of current turnover is identical.
10, a kind of hydrate high density latent heat as claimed in claim 4 is carried central air conditioner system, and it is characterized in that: described housing (102) top has a blast pipe (105), and described blast pipe (105) is equipped with stop valve (104).
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101008143A CN100342179C (en) | 2005-10-31 | 2005-10-31 | Hydrate high density latent heat transfer central air conditioning system |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101008143A CN100342179C (en) | 2005-10-31 | 2005-10-31 | Hydrate high density latent heat transfer central air conditioning system |
Publications (2)
| Publication Number | Publication Date |
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| CN1757978A true CN1757978A (en) | 2006-04-12 |
| CN100342179C CN100342179C (en) | 2007-10-10 |
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| Application Number | Title | Priority Date | Filing Date |
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| CNB2005101008143A Expired - Fee Related CN100342179C (en) | 2005-10-31 | 2005-10-31 | Hydrate high density latent heat transfer central air conditioning system |
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| CN (1) | CN100342179C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102449407A (en) * | 2009-04-03 | 2012-05-09 | 易通-威廉姆斯集团有限公司 | Cooling unit |
| CN103032980A (en) * | 2011-09-29 | 2013-04-10 | 艾默生网络能源有限公司 | Water chilling unit |
| CN103363635A (en) * | 2012-04-05 | 2013-10-23 | 王秀利 | Water cooling central air conditioner waste heat recovery device and method |
| CN103808068A (en) * | 2014-01-28 | 2014-05-21 | 华中科技大学 | Refrigerating system |
| CN110345665A (en) * | 2019-06-10 | 2019-10-18 | 湖北风神净化空调设备工程有限公司 | A kind of ice source heat pump system that ice content is controllable |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2020222255A1 (en) * | 2019-05-02 | 2020-11-05 | Shantnu Ajaykumar Jain | An air conditioner system with super critical fluid controlled operation |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4507458B2 (en) * | 2001-05-30 | 2010-07-21 | Ｊｆｅエンジニアリング株式会社 | Method for producing hydrate slurry |
| JP2004053171A (en) * | 2002-07-22 | 2004-02-19 | Jfe Engineering Kk | Air conditioning system and operation method for the same |
| JP2005265284A (en) * | 2004-03-18 | 2005-09-29 | Denso Corp | Brine type air-conditioner |
| CN1256541C (en) * | 2004-04-14 | 2006-05-17 | 中国科学院广州能源研究所 | Hidden heat type air conditioning system |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102449407A (en) * | 2009-04-03 | 2012-05-09 | 易通-威廉姆斯集团有限公司 | Cooling unit |
| CN102449407B (en) * | 2009-04-03 | 2015-04-22 | 易通-威廉姆斯集团有限公司 | Cooling unit |
| CN103032980A (en) * | 2011-09-29 | 2013-04-10 | 艾默生网络能源有限公司 | Water chilling unit |
| CN103032980B (en) * | 2011-09-29 | 2016-01-06 | 艾默生网络能源有限公司 | A kind of handpiece Water Chilling Units |
| CN103363635A (en) * | 2012-04-05 | 2013-10-23 | 王秀利 | Water cooling central air conditioner waste heat recovery device and method |
| CN103808068A (en) * | 2014-01-28 | 2014-05-21 | 华中科技大学 | Refrigerating system |
| CN103808068B (en) * | 2014-01-28 | 2017-05-10 | 华中科技大学 | Refrigerating system |
| CN110345665A (en) * | 2019-06-10 | 2019-10-18 | 湖北风神净化空调设备工程有限公司 | A kind of ice source heat pump system that ice content is controllable |
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|---|---|
| CN100342179C (en) | 2007-10-10 |
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Application publication date: 20060412 Assignee: China Guangdong Nuclear Energy Industry Development Co. Ltd. Assignor: Guangzhou Senyo Thermal Storage Technology Co., Ltd. Contract record no.: 2013440020424 Denomination of invention: Hydrate high density latent heat transfer central air conditioning system Granted publication date: 20071010 License type: Exclusive License Record date: 20131227 |
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Application publication date: 20060412 Assignee: China Guangdong Nuclear Energy Industry Development Co. Ltd. Assignor: Guangzhou Senyo Thermal Storage Technology Co., Ltd. Contract record no.: 2013440020424 Denomination of invention: Hydrate high density latent heat transfer central air conditioning system Granted publication date: 20071010 License type: Exclusive License Record date: 20131227 |
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