CN1756894A - 用于在隧道钻进机处进行注射的方法和组合物 - Google Patents
用于在隧道钻进机处进行注射的方法和组合物 Download PDFInfo
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- CN1756894A CN1756894A CN200480005542.2A CN200480005542A CN1756894A CN 1756894 A CN1756894 A CN 1756894A CN 200480005542 A CN200480005542 A CN 200480005542A CN 1756894 A CN1756894 A CN 1756894A
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- 238000000034 method Methods 0.000 title claims abstract description 9
- 238000002347 injection Methods 0.000 title claims abstract description 7
- 239000007924 injection Substances 0.000 title claims abstract description 7
- 239000000203 mixture Substances 0.000 title description 9
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000007864 aqueous solution Substances 0.000 claims abstract description 12
- 229920000642 polymer Polymers 0.000 claims abstract description 12
- 239000006260 foam Substances 0.000 claims description 14
- 239000000243 solution Substances 0.000 claims description 10
- 239000004094 surface-active agent Substances 0.000 claims description 9
- 238000005303 weighing Methods 0.000 claims description 7
- -1 sulphate ethers Chemical class 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 4
- 238000005187 foaming Methods 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 3
- FKKAGFLIPSSCHT-UHFFFAOYSA-N 1-dodecoxydodecane;sulfuric acid Chemical group OS(O)(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC FKKAGFLIPSSCHT-UHFFFAOYSA-N 0.000 claims description 2
- 239000003945 anionic surfactant Substances 0.000 claims description 2
- 125000001033 ether group Chemical group 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 239000002689 soil Substances 0.000 abstract description 22
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 238000009412 basement excavation Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 125000005702 oxyalkylene group Chemical group 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 239000006265 aqueous foam Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000012770 industrial material Substances 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000001118 alkylidene group Chemical group 0.000 description 1
- 150000001412 amines Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/38—Gaseous or foamed well-drilling compositions
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21D—SHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
- E21D9/00—Tunnels or galleries, with or without linings; Methods or apparatus for making thereof; Layout of tunnels or galleries
- E21D9/06—Making by using a driving shield, i.e. advanced by pushing means bearing against the already placed lining
Landscapes
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Mining & Mineral Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Excavating Of Shafts Or Tunnels (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Earth Drilling (AREA)
Abstract
一种借助于地压平衡隧道钻进机钻进隧道的方法，其包括在切割机头处注射发泡的水溶液和水溶性丙烯酸基聚合物的水溶液。该方法使在柔软的粘性土壤中钻进隧道比较容易。
Description
本发明涉及地压平衡屏蔽隧道钻进机和在其中使用的组合物。
包括大直径切割机头的隧道钻进机(TBM)是众所周知和被广泛使用的。为了在软土中钻进，通常使用的类型是屏蔽TBM。在这种机器中，TBM和其辅助装置被装在圆柱体(被称为“屏蔽”)中。在屏蔽内，在切割机头后面头的是工作室，其容纳挖掘的土壤和将土壤输送走的传送带。屏蔽TBM的另一个变体是地压平衡TBM(EPBM)。在这种机器中，通过注射含水泡沫将钻进面保持，该含水泡沫既保持钻进面，又带走土壤。在钻进面处的压力被保持在这样一种程度，其能够保持所述面，但不会引起地表上土壤上升而引起对地表上的建筑物的破坏，由此得名“地压平衡”。压力通过TBM的速度、泡沫注射速率和压力以及通过借助于传送带运送土壤的速率进行控制。此外，泡沫有助于防止切割圆盘的止动(这在软土中是常见问题)。
现在已经发现，在使用EPBM时，通过注射附加的物质能够实质上提高性能。因此，本发明提供了借助于地压平衡TBM钻进隧道的方法，其包括在切割机头处注射发泡的水溶液和水溶性丙烯酸基聚合物的水溶液。
所述泡沫可以通过至少一种表面活性剂的水溶液的发泡产生。能够发泡的任何表面活性剂均适合用于本发明，但是优选的表面活性剂包括硫酸盐酯、硫酸盐醚和磺酸盐。
适合的表面活性剂的优选例子包括聚氧亚烷基烷基醚硫酸盐，其中所述聚氧亚烷基链具有1-3个氧化烯单元的平均链长。如果表面活性剂是月桂基醚硫酸盐，优选醚部分由不多于两个氧乙基单元组成。
典型的工业材料包括Toho化学工业公司的“Alscope”(商标)系列。
其他特别优选的类型包括单异丙醇铵月桂醇硫酸盐(可作为例如“Sulfetal”(商标)Cjot 60得到，α-烯烃磺酸盐(CAS登记号68439-57-6)，可以例如“Rhodocal”(商标)A-246-L得到，和C8-22脂肪醇硫酸盐，以及C8-22脂肪醇醚硫酸盐，所述脂肪醇优选是月桂醇，所述醚是与具有1-3个氧化烯单元的氧化烯(优选环氧乙烷)链形成的醚，并且成盐阳离子优选选自碱金属、镁和烷醇胺。
水溶性丙烯酸基聚合物是众所周知的工业材料。用于本发明的材料具有相对低的分子量，2,000-20,000，优选2,000-10,000，并且更优选4,000-6,000。虽然除丙烯酸以外的小比例(不多于10％重量)的单体可能是允许的，但是优选所述聚合物是100％的丙烯酸。本发明中使用的术语“丙烯酸”不仅包括酸本身，而且包括其盐。优选的丙烯酸是一价阳离子的盐，例如钠、钾、铵或者叔或者季胺的盐。
丙烯酸基聚合物溶液和可发泡的表面活性剂溶液可以作为独立的溶液使用，或者它们可以混合使用。因此，本发明还提供了供地压平衡隧道钻进机使用的发泡溶液，其包括丙烯酸基聚合物的水溶液和选自硫酸盐酯、硫酸盐醚和磺酸盐的阴离子表面活性剂的水溶液。
所述表面活性剂溶液可以被发泡并且通过切割机头注入。表面活性剂优选以0.2-4、更优选0.5-2、最优选0.5-1.5千克干燥材料每立方米挖掘的土壤的速度注入，并且丙烯酸基聚合物以0.05-2.0、优选0.1-1.0、更优选0.2-0.5千克干燥聚合物每立方米挖掘的土壤的速度注入。
本发明的方法相对于先前的在EPBM中使用泡沫的方法具有大量优点。已经发现，丙烯酸基聚合物在这种情况下起土壤的增塑剂的作用。这具有三个重要结果。首先，其能够更容易地获得最适合于容易地取出的土壤稠性。其次，获得最佳的土壤稠性导致在切割机头处获得降低的扭矩，或者导致在规定的扭矩下获得较高的挖掘速度。第三，其使得增塑土壤所需的水减少。这进而意味着土壤能够被更容易地处理。优选的是在填埋场中处理土壤，但是如果含水量过高(通常是这样的)，这将是不可能的，因此需要使用辅助的脱水过程或者使用替代的处理方法，两种情况都是更昂贵和不太方便的。
本发明进一步参考以下非限制性实施例进行描述。
实施例
将具有120毫米的展开(spread)(根据DIN 18555-2)的标准土壤样品与30％FIR(泡沫注射速率)的泡沫混合，该泡沫具有10的FER(泡沫膨胀速率)。使用的发泡液体的量是30克每立方分米土壤。
使用的泡沫是：
a)由工业上可得的发泡剂(MEYCOFIX SLF 20)的3％(重量)的溶液制造的泡沫；
b)由包含以下成分的溶液制造的泡沫：
3％的MEYCOFIX SLF 20和
2％的45％的聚丙烯酸钠盐的溶液，所述聚丙烯酸的重均MW为5000。
| 标准土壤 | 标准土壤+泡沫a) | 标准土壤+泡沫b) | |
| 根据DIN 18555-2的展开(毫米) | 120 | 170 | 260 |
这清楚地显示出用于本发明中的组合物的增塑效果。在没有发泡组合物的情况下，为了获得通过本发明组合物获得的260毫米的展开，需要每立方分米土壤170克的额外的水。在挖掘隧道的应用中存在这种量的水，意味着在土壤可用于填埋场之前需进行脱水或者需要其他处理手段。
Claims (4)
1.一种借助于地压平衡隧道钻进机钻进隧道的方法，其包括在切割机头处注射发泡的水溶液和水溶性丙烯酸基聚合物的水溶液。
2.权利要求1的方法，其中用于发泡的水溶液和水溶性丙烯酸基聚合物的水溶液作为单一的材料加入。
3.一种供地压平衡隧道钻进机使用的发泡的溶液，其包括丙烯酸基聚合物和选自硫酸盐酯、硫酸盐醚和磺酸盐的阴离子表面活性剂的水溶液。
4.权利要求3的发泡溶液，其中表面活性剂是月桂基醚硫酸盐，其醚部分由最多两个氧乙基单元组成。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0304602.6A GB0304602D0 (en) | 2003-02-28 | 2003-02-28 | Method and composition |
| GB0304602.6 | 2003-02-28 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1756894A true CN1756894A (zh) | 2006-04-05 |
| CN100560938C CN100560938C (zh) | 2009-11-18 |
Family
ID=9953843
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004800055422A Expired - Lifetime CN100560938C (zh) | 2003-02-28 | 2004-02-10 | 用于在隧道钻进机处进行注射的方法和组合物 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US7709422B2 (zh) |
| EP (1) | EP1599654B1 (zh) |
| JP (1) | JP4469842B2 (zh) |
| CN (1) | CN100560938C (zh) |
| AT (1) | ATE399255T1 (zh) |
| AU (1) | AU2004215218B2 (zh) |
| CA (1) | CA2517420C (zh) |
| DE (1) | DE602004014594D1 (zh) |
| ES (1) | ES2305724T3 (zh) |
| GB (1) | GB0304602D0 (zh) |
| HK (1) | HK1088938A1 (zh) |
| TW (1) | TWI332053B (zh) |
| WO (1) | WO2004076817A1 (zh) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7725523B2 (en) * | 2000-04-11 | 2010-05-25 | Bolnick David A | System, method and computer program product for gathering and delivering personalized user information |
| JP4637113B2 (ja) * | 2003-11-28 | 2011-02-23 | キヤノン株式会社 | 階層データの好ましいビューを構築するための方法 |
| JP2007002168A (ja) * | 2005-06-27 | 2007-01-11 | Daiichi Kasei Sangyo Kk | 気泡シールド工法用起泡剤 |
| US8524641B2 (en) * | 2010-09-16 | 2013-09-03 | Momentive Performance Materials Inc. | Aqueous foaming compositions with high tolerance to hydrocarbons |
| JP5600288B2 (ja) * | 2010-12-08 | 2014-10-01 | 株式会社奥村組 | 泥土圧シールド工法及び泥土圧シールド掘進機 |
| JP6113449B2 (ja) * | 2012-09-28 | 2017-04-12 | 株式会社フジタ | 泥土圧シールド工法及び泥土圧シールド掘進機 |
| US20150193390A1 (en) * | 2012-12-03 | 2015-07-09 | Google Inc. | Visited hyperlink appearance based on user activity |
| RU2509096C1 (ru) * | 2013-02-11 | 2014-03-10 | Общество с ограниченной ответственностью "ВМПАВТО" | Пенообразующая водная композиция |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3215200A (en) * | 1960-10-31 | 1965-11-02 | Nalco Chemical Co | Production of aqueous foams and compositions therefor |
| US4013568A (en) * | 1975-12-11 | 1977-03-22 | Union Oil Company Of California | Composition and method for drilling formations containing geothermal fluid |
| US4442018A (en) * | 1982-11-01 | 1984-04-10 | The United States Of America As Represented By The United States Department Of Energy | Stabilized aqueous foam systems and concentrate and method for making them |
| CH683861A5 (de) * | 1991-10-30 | 1994-05-31 | Heierli & Co Patentverwertungs | Tunnelvortriebsmaschine. |
| FR2690709B1 (fr) | 1992-04-30 | 1997-07-25 | Seppic Sa | Procede d'excavation de tunnels, utilisation d'un agent moussant et nouvel agent moussant. |
| US5513712A (en) * | 1994-11-08 | 1996-05-07 | Marathon Oil Company | Polymer enhanced foam drilling fluid |
| DE69520407T2 (de) * | 1994-11-28 | 2001-09-06 | Rhodia Chimie, Courbevoie | Gel von nicht-polarem Mitteln, Verwendung bei Herstellung von Bohrspülungen auf Wasser-Basis |
| FR2728298A1 (fr) * | 1994-12-16 | 1996-06-21 | Condat Sa | Produit et procede pour la lubrification des surfaces metalliques d'un tunnelier a pression de terre |
| DE19521693A1 (de) * | 1995-06-14 | 1996-12-19 | Wolff Walsrode Ag | Verwendung von Cellulosemischethern als Additive für Erddruckschilde |
| GB9720846D0 (en) | 1997-10-02 | 1997-12-03 | Mbt Holding Ag | Composition |
| US6076997A (en) * | 1997-12-03 | 2000-06-20 | Mbt Holding Ag | Deep mix soil stabilization method |
| GB9918992D0 (en) | 1999-08-12 | 1999-10-13 | Mbt Holding Ag | Method |
-
2003
- 2003-02-28 GB GBGB0304602.6A patent/GB0304602D0/en not_active Ceased
-
2004
- 2004-02-10 EP EP04709623A patent/EP1599654B1/en not_active Expired - Lifetime
- 2004-02-10 AT AT04709623T patent/ATE399255T1/de active
- 2004-02-10 CA CA2517420A patent/CA2517420C/en not_active Expired - Lifetime
- 2004-02-10 ES ES04709623T patent/ES2305724T3/es not_active Expired - Lifetime
- 2004-02-10 WO PCT/EP2004/001229 patent/WO2004076817A1/en active IP Right Grant
- 2004-02-10 US US10/546,551 patent/US7709422B2/en active Active
- 2004-02-10 JP JP2006501794A patent/JP4469842B2/ja not_active Expired - Lifetime
- 2004-02-10 CN CNB2004800055422A patent/CN100560938C/zh not_active Expired - Lifetime
- 2004-02-10 DE DE602004014594T patent/DE602004014594D1/de not_active Expired - Lifetime
- 2004-02-10 AU AU2004215218A patent/AU2004215218B2/en not_active Expired
- 2004-02-12 TW TW093103348A patent/TWI332053B/zh not_active IP Right Cessation
-
2006
- 2006-08-21 HK HK06109235.0A patent/HK1088938A1/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| US7709422B2 (en) | 2010-05-04 |
| EP1599654B1 (en) | 2008-06-25 |
| US20070015667A1 (en) | 2007-01-18 |
| HK1088938A1 (en) | 2006-11-17 |
| JP2006519325A (ja) | 2006-08-24 |
| DE602004014594D1 (de) | 2008-08-07 |
| WO2004076817A1 (en) | 2004-09-10 |
| GB0304602D0 (en) | 2003-04-02 |
| CN100560938C (zh) | 2009-11-18 |
| TWI332053B (en) | 2010-10-21 |
| ATE399255T1 (de) | 2008-07-15 |
| AU2004215218B2 (en) | 2010-07-01 |
| EP1599654A1 (en) | 2005-11-30 |
| AU2004215218A8 (en) | 2004-09-10 |
| ES2305724T3 (es) | 2008-11-01 |
| AU2004215218A1 (en) | 2004-09-10 |
| CA2517420A1 (en) | 2004-09-10 |
| JP4469842B2 (ja) | 2010-06-02 |
| CA2517420C (en) | 2011-11-29 |
| TW200500547A (en) | 2005-01-01 |
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