CN1742068B - 冷冻机制冷剂 - Google Patents
冷冻机制冷剂 Download PDFInfo
- Publication number
- CN1742068B CN1742068B CN200380109220.8A CN200380109220A CN1742068B CN 1742068 B CN1742068 B CN 1742068B CN 200380109220 A CN200380109220 A CN 200380109220A CN 1742068 B CN1742068 B CN 1742068B
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- CN
- China
- Prior art keywords
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- content
- weight
- component
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003507 refrigerant Substances 0.000 title claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 115
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 34
- 238000005057 refrigeration Methods 0.000 claims description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- 239000000314 lubricant Substances 0.000 claims description 11
- 239000003921 oil Substances 0.000 claims description 11
- KLZDCUBZWUSEGO-UHFFFAOYSA-N CC.F.F.F.F.F Chemical compound CC.F.F.F.F.F KLZDCUBZWUSEGO-UHFFFAOYSA-N 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 7
- 230000000996 additive effect Effects 0.000 claims description 7
- 238000001704 evaporation Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- -1 polyol ester Chemical class 0.000 claims description 5
- 229920001515 polyalkylene glycol Polymers 0.000 claims description 4
- 239000012190 activator Substances 0.000 claims description 3
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 238000009833 condensation Methods 0.000 claims description 3
- 230000005494 condensation Effects 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 claims description 3
- 230000007797 corrosion Effects 0.000 claims description 3
- 230000000994 depressogenic effect Effects 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 239000002480 mineral oil Substances 0.000 claims description 3
- 235000010446 mineral oil Nutrition 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 230000003449 preventive effect Effects 0.000 claims description 3
- 238000003786 synthesis reaction Methods 0.000 claims description 3
- 239000004034 viscosity adjusting agent Substances 0.000 claims description 3
- 239000005662 Paraffin oil Substances 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims description 2
- 229920002545 silicone oil Polymers 0.000 claims description 2
- 230000008020 evaporation Effects 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 abstract description 19
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 19
- 238000009835 boiling Methods 0.000 abstract description 13
- 229930195735 unsaturated hydrocarbon Natural products 0.000 abstract description 3
- GQUXQQYWQKRCPL-UHFFFAOYSA-N 1,1,2,2,3,3-hexafluorocyclopropane Chemical compound FC1(F)C(F)(F)C1(F)F GQUXQQYWQKRCPL-UHFFFAOYSA-N 0.000 abstract description 2
- WXGNWUVNYMJENI-UHFFFAOYSA-N 1,1,2,2-tetrafluoroethane Chemical compound FC(F)C(F)F WXGNWUVNYMJENI-UHFFFAOYSA-N 0.000 abstract description 2
- ACYQYBAHTSKBLM-UHFFFAOYSA-N difluoromethoxy(trifluoro)methane Chemical compound FC(F)OC(F)(F)F ACYQYBAHTSKBLM-UHFFFAOYSA-N 0.000 abstract description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 abstract description 2
- NCUVQJKPUJYKHX-UHFFFAOYSA-N 1,1,1,2,2-pentafluoro-2-(trifluoromethoxy)ethane Chemical compound FC(F)(F)OC(F)(F)C(F)(F)F NCUVQJKPUJYKHX-UHFFFAOYSA-N 0.000 abstract 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
- GTLACDSXYULKMZ-UHFFFAOYSA-N pentafluoroethane Chemical compound FC(F)C(F)(F)F GTLACDSXYULKMZ-UHFFFAOYSA-N 0.000 abstract 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 13
- 239000004215 Carbon black (E152) Substances 0.000 description 12
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 12
- 238000009834 vaporization Methods 0.000 description 10
- 230000008016 vaporization Effects 0.000 description 10
- 239000001273 butane Substances 0.000 description 9
- 238000002474 experimental method Methods 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- 230000001276 controlling effect Effects 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000006200 vaporizer Substances 0.000 description 3
- XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical compound FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 description 2
- 150000005826 halohydrocarbons Chemical class 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 101000609457 Trichosanthes kirilowii Trypsin inhibitor 1 Proteins 0.000 description 1
- 125000002015 acyclic group Chemical group 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000004773 chlorofluoromethyl group Chemical group [H]C(F)(Cl)* 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- CFBGXYDUODCMNS-UHFFFAOYSA-N cyclobutene Chemical compound C1CC=C1 CFBGXYDUODCMNS-UHFFFAOYSA-N 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- VNXBKJFUJUWOCW-UHFFFAOYSA-N methylcyclopropane Chemical compound CC1CC1 VNXBKJFUJUWOCW-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000010606 normalization Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Images
Landscapes
- Lubricants (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
说明 | SVP方程(见注1) | Glide方程(见注2) |
丁烷(3.5%)共混物R125/134a/600(65.0/31.5/3.5) | y=-2347.4682x+12.96325R<sup>2</sup>=0.99999 | y=-0.02618x+3.51740R<sup>2</sup>=0.99790 |
异丁烷(3.5%)共混物R125/134a/600a(64.9/31.7/3.4) | y=-2356.045324+12999729R<sup>2</sup>=0.999956 | y=-0.00001x<sup>3</sup>-0.000012x<sup>2</sup>+0.028998x+3.628716 |
R22 | (见注3) | 不能用 |
Claims (15)
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0227891.9 | 2002-11-29 | ||
GB0227891A GB0227891D0 (en) | 2002-11-29 | 2002-11-29 | Chiller refrigerants |
GB0228306A GB0228306D0 (en) | 2002-12-04 | 2002-12-04 | Chiller refrigerants |
GB0228306.7 | 2002-12-04 | ||
PCT/GB2003/005227 WO2004050787A1 (en) | 2002-11-29 | 2003-12-01 | Chiller refrigerants |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201010167086A Division CN101838519A (zh) | 2002-11-29 | 2003-12-01 | 冷冻机制冷剂 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1742068A CN1742068A (zh) | 2006-03-01 |
CN1742068B true CN1742068B (zh) | 2010-06-16 |
Family
ID=9948782
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200380109220.8A Expired - Fee Related CN1742068B (zh) | 2002-11-29 | 2003-12-01 | 冷冻机制冷剂 |
Country Status (3)
Country | Link |
---|---|
CN (1) | CN1742068B (zh) |
GB (1) | GB0227891D0 (zh) |
UA (1) | UA82345C2 (zh) |
-
2002
- 2002-11-29 GB GB0227891A patent/GB0227891D0/en not_active Ceased
-
2003
- 2003-01-12 UA UAA200506364A patent/UA82345C2/uk unknown
- 2003-12-01 CN CN200380109220.8A patent/CN1742068B/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN1742068A (zh) | 2006-03-01 |
UA82345C2 (en) | 2008-04-10 |
GB0227891D0 (en) | 2003-01-08 |
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US7410595B2 (en) | Refrigerant compositions | |
US20080128650A1 (en) | Refrigerant compositions | |
CN1742068B (zh) | 冷冻机制冷剂 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
ASS | Succession or assignment of patent right |
Owner name: E. I. DU PONT DE NEMOURS AND CO. Free format text: FORMER OWNER: RHODIA ORGANIQUE FINE LTD. Effective date: 20060721 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20060721 Address after: Wilmington, Delaware, USA Applicant after: E. I. du Pont de Nemours and Co. Address before: Hertfordshire, United Kingdom Applicant before: Rhodia Organique Fine Ltd. |
|
REG | Reference to a national code |
Ref country code: HK Ref legal event code: DE Ref document number: 1087429 Country of ref document: HK |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
REG | Reference to a national code |
Ref country code: HK Ref legal event code: GR Ref document number: 1087429 Country of ref document: HK |
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TR01 | Transfer of patent right |
Effective date of registration: 20171227 Address after: Delaware, USA Patentee after: Como Efsee Co.,Ltd. Address before: Wilmington, Delaware, USA Patentee before: E. I. du Pont de Nemours and Co. |
|
TR01 | Transfer of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20100616 Termination date: 20201201 |
|
CF01 | Termination of patent right due to non-payment of annual fee |