CN1721335A - Photo-catalytic water purification post - Google Patents

Photo-catalytic water purification post Download PDF

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Publication number
CN1721335A
CN1721335A CN 200410068952 CN200410068952A CN1721335A CN 1721335 A CN1721335 A CN 1721335A CN 200410068952 CN200410068952 CN 200410068952 CN 200410068952 A CN200410068952 A CN 200410068952A CN 1721335 A CN1721335 A CN 1721335A
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China
Prior art keywords
water
chamber
photo
water purification
photochemical catalysis
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CN 200410068952
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Chinese (zh)
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CN100406094C (en
Inventor
张俊英
潘锋
郝维昌
王天民
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Beihang University
Beijing University of Aeronautics and Astronautics
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Beihang University
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Priority to CNB2004100689523A priority Critical patent/CN100406094C/en
Publication of CN1721335A publication Critical patent/CN1721335A/en
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Publication of CN100406094C publication Critical patent/CN100406094C/en
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Abstract

The water purifying photocatalyst column includes one middle part photocatalytic chamber, which has quartzite supporting high photocatalytic activity titania as photocatalyst, light source in the middle and guide partition board; one bearing ring below the photocatalytic chamber, one active carbon barrier layer, one porous partition plate and one water accumulating deposition cavity with water exhaust set successively below the photocatalytic chamber; one primary filtering layer, one porous partition plate and one buffering cavity with water inlet set successively above the photocatalytic chamber; and sealing thread structures on two ends. The water purifying photocatalyst column of the present invention can kill bacteria, viruses and microbes in water permanently and decompose toxic and harmful matter in water completely, and has stable performance and no pollution caused by catalyst carrier bits.

Description

Photo-catalytic water purification post
Technical field
The present invention relates to a kind ofly can kill microorganism in the water, bacterium, virus, the water-purification plant, particularly photo-catalytic water purification post of the poisonous and harmful molecule of effectively degrading.
Background technology
Traditional water purifier has generally adopted media filtration and ultraviolet and ozone sterilizing unit to realize the purification of water body.Yet there is the absorption saturation problem in media filtration, adsorbs the not only water permeability reduction of saturated filtrate, also becomes bacteriophage probably and assembles the hotbed that grows.In addition, filtrate is not strong for the effect of filtered water dissolubility poisonous and harmful molecule.The frequent replacing of filtrate not only can cause the increase of water purifier use cost, but also can bring the inconvenience of maintenance.
The water purifier that the ultraviolet and ozone device is housed can be killed bacterium, virus and the microorganism in the water to a certain extent, but these life entities can discharge intracellular toxin after death, cause the secondary pollution of water body.
Someone has utilized titania oxide supported glass fibre to make photocatalyst reaction formula water purifier (CN95244568.9) as photocatalyst, yet glass fibre itself has very strong sorption to UV-light, has weakened the light source utilization ratio of photocatalyst.And glass fibre ruptures easily, and the fragment that the micron order glass fibre that adopts in order to obtain bigger serface forms after fracture is as easy as rolling off a log sneaks into current and not easily separated, if be inhaled into human body, extreme is detrimental to health.
Summary of the invention
Technology of the present invention is dealt with problems: overcome the deficiencies in the prior art, a kind of stable performance is provided, can kill bacterium in the water, virus, microorganism lastingly, poisonous and harmful molecule in the thorough water of decomposition of energy, the photo-catalytic water purification post of catalyst-free carrier fragment pollution, this photo-catalytic water purification post can utilize source light efficiently, and active photocatalyst can efficiently be killed the disease caused by infectious water bacteria microorganism and its toxic substance is resolved into water and carbonic acid gas under illumination.The present invention can reach the purpose of thoroughly falling dirt, deep purifying water quality.
Technical solution of the present invention: photo-catalytic water purification post, be column structure, its characteristics are: the cylinder middle part is the photochemical catalysis chamber, the indoor photocatalyst body of photochemical catalysis adopts load that the quartz sand of high efficiency photocatalysis activity titanium oxide is arranged, the centre of photochemical catalysis chamber is a light source, the indoor diaphragm that also is provided with of photochemical catalysis, the diaphragm outer edge closely contacts with the photochemical catalysis chamber interior walls, leaves the space between hole and the light source in the middle of it; The following of photochemical catalysis chamber is the load-bearing ring, leave the slit between load-bearing ring and the fluorescent tube, load-bearing ring bottom is filled with the gac blocking layer, porous barrier (descending) is equipped with in bottom, gac blocking layer, it below the porous barrier (descending) retaining precipitation chamber, water port is located on this chamber, and retaining precipitation chamber links to each other with the bottom by screwed lid; The top of photochemical catalysis chamber is the primary filter floor, the top of primary filter layer be porous barrier (on), porous barrier (on) and last spiral cover between be cushion chamber, water inlet is located on this cushion chamber; Cylinder two ends is up and down taked the sealing of spiral cover helicitic texture, and the interface of last screwed lid and light source is added with the leakproof rubber, and the leakproof rubber above the cylinder is pressed tight envelope by gland, and following leakproof rubber is pressed tight envelope by base.
The sidewall of described photochemical catalysis chamber scribbles the ultraviolet reflectance coating of energy high reflection of waterproof.
Described primary filter layer is sandwich structure, by the activated carbon felt at two ends and the zeolite granular that is clipped in the middle are formed up and down.
Described cylinder can use with a plurality of parallel connections of array way or series connection according to purification speed and purification purity requirement, and its cylinder hull shape can be designed to the shape of circle, regular hexagon or other needs according to the requirement of arrayed.
Described porous barrier (on) or multiple hole metal sheet or the plastic plate of porous barrier (descending) for having intensity, and it can become regular hexagon or other shape according to the shaped design of pole section.
Described load-bearing ring is the inclined-plane, and the stainless steel metal ring of intensity is arranged, by threaded engagement from the water purification post cylinder of packing into.
The present invention's advantage compared with prior art is as follows:
(1) the present invention can not only kill bacterium in the water, virus, microorganism lastingly, poisonous and harmful molecule in the thorough water of decomposition of energy, catalyst-free carrier fragment pollution, and stable performance;
(2) can utilize source light efficiently, active photocatalyst can efficiently be killed the disease caused by infectious water bacteria microorganism and its toxic substance is resolved into water and carbonic acid gas under illumination;
(3) can reach the purpose of thoroughly falling dirt, deep purifying water quality.
Description of drawings
Figure 1 shows that sectional structure chart of the present invention.
Among the figure by the 1-base, the 2-water outlet, 3-porous barrier (descending), 4-adsorption filtration layer (descending), 5-load-bearing ring, the 6-photocatalyst, the 7-ultraviolet source, the 8-diaphragm, 9-internal reflection film, 10-adsorption filtration layer (on), the 11-porous barrier (on), the last spiral cover of 12-, the 13-gland, the 14-terminal stud (on), the 15-water inlet, 16-leakproof rubber (on), the 17-cushion chamber, 18-zeolite adsorption layer, 19-decontaminating column body skin, 20-retaining precipitation chamber, 21-leakproof rubber (descending), the 22-screwed lid, 23-terminal stud (descending).
Embodiment
As shown in Figure 1, the present invention adopts the setting shown in this figure to place.Sewage enters this refining plant from water inlet 15, flows out from water outlet 2, obtains the cleaning current of handling through sterilizing and purifying.This place's sewage refers to through rough purification, the sanitary sewage that does not contain suspended particle and heavy metal ion or industrial dye waste water.What be used to purify also can be well water or spring etc.Sanitary sewage or industrial dye waste water can reach safety dumping even domestic water standard through refining plant of the present invention; Domestic water (tap water, well water, spring etc.) can reach direct standard for drinking through refining plant of the present invention.
Flow dynamic of the present invention derives from the hydraulic pressure of water inlet and the gravity of current self.At first enter the cushion chamber 17 of photo-catalytic water purification post of the present invention from the current of water inlet 15 inflows, cushion chamber be the last spiral cover 12 of this refining plant and porous barrier (on) the 11 one section cavity that is divided into, this cavity can cushion the impact of current, and the reactive force of current is evenly spread on the porous barrier 11 with the pressure form, allow current evenly enter light catalytic purifying district below the cylinder by dividing plate.
Porous barrier 11 can become regular hexagon or other shape according to the shaped design of pole section.Porous barrier is multiple hole metal sheet or the plastic plate with certain intensity, play to sorbing material isolate, spacing effect, the hole on the dividing plate can allow the current freedom unimpeded.
Evenly infiltrate the primary filter layer of this refining plant through the current of porous barrier 11.The primary filter layer is sandwich structure, by the activated carbon felt 10 at two ends and the zeolite granular 18 that is clipped in the middle are formed up and down.Zeolite granular has very strong adsorption, and the micro-deleterious metallic element in can planar water prevents the photocatalyst poison deactivation.The effect of two-layer activated carbon felt mainly is in order to isolate zeolite granular.
Then infiltrate the light catalytic purifying unit of photo-catalytic water purification post of the present invention by the current of primary filter layer.The photochemical catalysis carrier of this part adopts the titania oxide supported quartzy sand grains of high catalytic activity.Quartzy do not have sorption to UV-light, therefore adopts the quartz sand of particle diameter about 20 orders, and printing opacity is permeable preferably.Help the efficient utilization of photocatalyst to light source.The purity that can regulate current seepage velocity and purification of water quality by the particle diameter that changes quartz sand as required; This catalytic unit is also taked photocatalyst (load has the quartz sand of titanium oxide), water and the direct way of contact of fluorescent tube making under the evenly stressed condition of fluorescent tube, this structure can make full use of the radius of light source on the one hand, also the heating flow heated water and the photocatalyst of available fluorescent tube on the other hand, improve the activity of photocatalyst, simultaneously fluorescent tube is lowered the temperature.
The sidewall of photochemical catalysis chamber, it is the ultraviolet reflectance coating 9 of energy high reflection that the inner walls of photo-catalytic water purification post scribbles waterproof, this coating also can be high reflecting metal film or other film, the light reflection that penetrates optical catalyst carrier can be utilized once more, improves the utilising efficiency of light source.
Also have diaphragm 8 in the photochemical catalysis chamber of this photo-catalytic water purification post, be the plastic sheet or the quartz plate of the saturating ultraviolet of wide-angle taper, outer edge closely contacts with photochemical catalysis chamber 19, and 7 of middle hole and fluorescent tubes leave the space, and current can infiltrate.The effect of diaphragm is the light-catalyzed reaction that current deflecting is strengthened near the strong ultraviolet radiation zone of light source, improves catalyticing purifying effect.Diaphragm can also form obstacle and prolong the residence time of current in catalytic chamber, helps sewage is carried out purifying treatment fully.The number of diaphragm can be set according to the speed of current infiltration and the purity requirement of purification of water quality.
Be load-bearing ring 5 below the photochemical catalysis chamber, the load-bearing ring is the stainless steel metal ring that the certain intensity in certain inclined-plane is arranged, and from the water purification post cylinder of packing into, its effect is a weight of bearing quartz sand in the cylinder, primary filter layer and water by threaded engagement.Leave the slit between load-bearing ring and the fluorescent tube 7, the structure on inclined-plane can guide current to flow through between the slit.
Between the slit of load-bearing ring and fluorescent tube and bottom is filled with gac blocking layer 4, and the charcoal felt of aperture less than quartz sand particle size adopted on the blocking layer, and main effect is to stop quartz sand and leaches pure water.
Porous barrier 3 is equipped with in the bottom of activated carbon filter layer, and it acts on dividing plate 11.
Be retaining precipitation chamber 20 below the porous barrier 3, water port 2 is located at the position of certain altitude at the bottom of the chamber, like this can the water body of preliminary precipitation through purifying, and allow the solid impurity that may exist in the water be deposited at the bottom of the chamber, clear liquid then can flow out from cavity.
The sealing of spiral cover helicitic texture is taked at the two ends up and down of cylinder of the present invention, and sealing place all has the leakproof rubber.Last screwed lid 22 and 12 and the interface of fluorescent tube be added with leakproof rubber 16 and 21, press tight envelope by gland 13 above the leakproof rubber 16, press tight envelope by base 1 below the leakproof rubber 21.This sealed structure can guarantee that the cavity sealing is tight, the absence of liquid seepage.
The present invention can use with a plurality of parallel connections of array way or series connection according to purification speed and purification purity requirement.Parallel connection is that a plurality of decontaminating column water-ins are intake together, and water outlet is water outlet together, can improve the water treatment amount of unit time; Series connection is the mutual cascade of a plurality of decontaminating column water-in water outlet, can improve the purity that water purifies.Decontaminating column hull shape of the present invention can be designed to circle, regular hexagon or other shape according to the requirement of arrayed, is convenient to form array and puts.
Generally all flow to external water-storing device through pure water of the present invention.
In sum, photo-catalytic water purification post of the present invention can be used for drinking the purification of water purification and industrial dye waste water.
More than be described with regard to embodiments of the present invention, but the present invention also can other mode implement, the present invention can do various changes in design in the contained claim scope of the application's claims.

Claims (8)

1, photo-catalytic water purification post, be column structure, it is characterized in that: the cylinder middle part is the photochemical catalysis chamber, the indoor photocatalyst body of photochemical catalysis adopts load that the quartz sand of high efficiency photocatalysis activity titanium oxide is arranged, the centre of photochemical catalysis chamber is a light source, the indoor diaphragm that also is provided with of photochemical catalysis, the diaphragm outer edge closely contacts with the photochemical catalysis chamber interior walls, leaves the space between hole and the light source in the middle of it; The following of photochemical catalysis chamber is the load-bearing ring, leave the slit between load-bearing ring and the fluorescent tube, load-bearing ring bottom is filled with the gac blocking layer, porous barrier (descending) is equipped with in bottom, gac blocking layer, it below the porous barrier (descending) retaining precipitation chamber, water port is located on this chamber, and retaining precipitation chamber links to each other with the bottom by screwed lid; The top of photochemical catalysis chamber is the primary filter floor, the top of primary filter layer be porous barrier (on), porous barrier (on) and last spiral cover between be cushion chamber, water inlet is located on this cushion chamber; Cylinder two ends is up and down taked the sealing of spiral cover helicitic texture, and the interface of last screwed lid and light source is added with the leakproof rubber, and the leakproof rubber above the cylinder is pressed tight envelope by gland, and following leakproof rubber is pressed tight envelope by base.
2, photo-catalytic water purification post according to claim 1 is characterized in that: the sidewall of described photochemical catalysis chamber scribbles the ultraviolet reflectance coating of energy high reflection of waterproof.
3, photo-catalytic water purification post according to claim 1 is characterized in that: described primary filter layer is sandwich structure, by the activated carbon felt at two ends and the zeolite granular that is clipped in the middle are formed up and down.
4, photo-catalytic water purification post according to claim 1, it is characterized in that: described cylinder can use with a plurality of parallel connections of array way or series connection according to purification speed and purification purity requirement, and its cylinder hull shape can be designed to the shape of circle, regular hexagon or other needs according to the requirement of arrayed.
5, photo-catalytic water purification post according to claim 1, it is characterized in that: described porous barrier (on) or multiple hole metal sheet or the plastic plate of porous barrier (descending) for having intensity, and it can become regular hexagon or other shape according to the shaped design of pole section.
6, photo-catalytic water purification post according to claim 1 is characterized in that: described load-bearing ring is the inclined-plane, and the stainless steel metal ring of intensity is arranged, by threaded engagement from the water purification post cylinder of packing into.
7, photo-catalytic water purification post according to claim 1 is characterized in that: the aperture on described filtration blocking layer is less than quartz sand particle size.
8, photo-catalytic water purification post according to claim 1 is characterized in that: described quartz sand particle size is at the 15-25 order.
CNB2004100689523A 2004-07-15 2004-07-15 Photo-catalytic water purification post Expired - Fee Related CN100406094C (en)

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CN100406094C CN100406094C (en) 2008-07-30

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101939261A (en) * 2007-09-27 2011-01-05 生命之水有限责任公司 Ultraviolet water purification system
CN104193055A (en) * 2014-09-18 2014-12-10 中国科学院生态环境研究中心 Reclaimed water reusing device integrating ultrafiltration membrane filtration and photocatalytic reaction
CN105565469A (en) * 2015-12-17 2016-05-11 浙江科技学院 Flow-control-theory-based composite catalytic oxidation device
CN105833605A (en) * 2016-05-05 2016-08-10 亿丰洁净科技江苏股份有限公司 Water filter
CN106746079A (en) * 2016-12-15 2017-05-31 衡阳中重机械装备有限公司 A kind of Simple sewage processing unit
CN108079781A (en) * 2017-12-22 2018-05-29 南京工大环境科技南通有限公司 A kind of foul waste gas controlling device antagonistic substance and its application
CN110258163A (en) * 2019-07-02 2019-09-20 蚌埠市海峰印刷有限责任公司 A kind of pulp purifiation system

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2517874B2 (en) * 1993-09-30 1996-07-24 工業技術院長 Method for producing titanium oxide thin film photocatalyst
JPH11151486A (en) * 1997-09-22 1999-06-08 Nkk Corp Advanced water purifying basin and photocatalyst used therefor
JP3791167B2 (en) * 1997-12-26 2006-06-28 東芝ライテック株式会社 Photocatalyst, lamp and lighting fixture
CN1245147A (en) * 1998-08-19 2000-02-23 株式会社太白环境 Photocatalytic reaction system for treating waste water
CN1107650C (en) * 1999-12-27 2003-05-07 广东省生态环境与土壤研究所 Light catalytic treatment method for organic waste water and its device

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101939261A (en) * 2007-09-27 2011-01-05 生命之水有限责任公司 Ultraviolet water purification system
CN104193055A (en) * 2014-09-18 2014-12-10 中国科学院生态环境研究中心 Reclaimed water reusing device integrating ultrafiltration membrane filtration and photocatalytic reaction
CN104193055B (en) * 2014-09-18 2016-04-13 中国科学院生态环境研究中心 Light-catalysed reclaimed water reuse device combined by a kind of ultra-filtration membrane
CN105565469A (en) * 2015-12-17 2016-05-11 浙江科技学院 Flow-control-theory-based composite catalytic oxidation device
CN105565469B (en) * 2015-12-17 2018-01-12 浙江科技学院 A kind of compound catalytic oxidizing equipment based on flow control principle
CN105833605A (en) * 2016-05-05 2016-08-10 亿丰洁净科技江苏股份有限公司 Water filter
CN106746079A (en) * 2016-12-15 2017-05-31 衡阳中重机械装备有限公司 A kind of Simple sewage processing unit
CN108079781A (en) * 2017-12-22 2018-05-29 南京工大环境科技南通有限公司 A kind of foul waste gas controlling device antagonistic substance and its application
CN110258163A (en) * 2019-07-02 2019-09-20 蚌埠市海峰印刷有限责任公司 A kind of pulp purifiation system

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