CN1715339A - Cation dye for dyeing and finishing wool real silk textile - Google Patents

Cation dye for dyeing and finishing wool real silk textile Download PDF

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Publication number
CN1715339A
CN1715339A CN 200410041153 CN200410041153A CN1715339A CN 1715339 A CN1715339 A CN 1715339A CN 200410041153 CN200410041153 CN 200410041153 CN 200410041153 A CN200410041153 A CN 200410041153A CN 1715339 A CN1715339 A CN 1715339A
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Prior art keywords
dyeing
dye
och
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wool
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CN 200410041153
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CN100348672C (en
Inventor
肖学俊
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YANCHENG DONGWU CHEMICAL Co.,Ltd.
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SUZHOU DONGWU DYESTUFF CO Ltd
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Abstract

The cationic dye for dyeing and finishing wool and silk textile contains compound with structure as shown. The dye has sym-triazine compound as core, which has one end connected to color part in ion bond form and the other end with radical capable of reacting with the amino in wool and other protein fiber to reach dyeing effect. The dye is used for dyeing and finishing wool and silk textile and blending wool and silk textile and has bright color, high color fastness, simple dyeing and finishing process, and environment friendship.

Description

The cationic dyestuff that is used for dyeing and finishing hairs silk textiles
Technical field
The present invention relates to a kind of cationic dyestuff that is used for dyeing and finishing hairs silk textiles.
Background technology
At the beginning of last century, the dyestuff that is used for hair fibre has four classes: matching stain, mordanting dye, chrome dye, natural and vat dyes.In these dyestuffs, chrome dye is because the dyeing color and luster withers secretly, and environmental pollution is serious, thereby from the fifties, its market consumption just begins to descend.Natural dyestuff output is few, and kind is few, the vat dyes complex manufacturing, thereby this three classes dyestuff all successively is eliminated.Matching stain had the period of full bloom, but poor to woolen dyed fastness, and dyeing acidity is strong excessively, and fiber is caused damage, and environmental pollution is serious, and has quite a few to belong to the forbidding dyestuff, and its consumption is just on a declining curve.Successively developed 1:1 metallized dye, 1:2 metallized dye and reactive dye for wool later on again, the someone proposes to answer used additives to impel dyeing wool on the cationic dyestuff with dispersed dye dyeing and finishing wool again in recent years; Though these dyestuffs that developed afterwards can solve some old problems, also brought new problem simultaneously, mainly be that the 1:1 metallized dye is big to fibre-tendering; 1:2 metallized dye level-dyeing property is poor, and chromatogram is incomplete; Though the reactive dye for wool that development in recent years is got up has the degree of fixation height, colour fastness is better, advantages such as kind increase, but its level-dyeing property is very poor, because the wool high-quality green tea is different with the hair root dyeing property, and solution irregular, the irreversible dyeability of dyestuff has hindered dissolving and diffusion process, can't improve irregular phenomenon by moving to dye, add that used reactive dyestuffs price is higher, thereby be difficult to promote the use of.Dispersed dye almost do not have substantivity to protein fibre, answer used additives can impel dyeing wool on the dispersed dye, but the wet fastness of dyeing wool is very poor.Cationic dyestuff is a class water-soluble dye, be mainly used in the dyeing of acrylic fiber, it is good to have complete, bright in colour, the wet fastness of chromatogram, advantage such as dye uptake height, " inexpensive ", but it is difficult to the substantive dyeing of hydrophilic natural protein fibre, though someone makes dyeing wool on the positively charged ion by auxiliary agent, also increased painted cost and the complicacy that has increased dyeing simultaneously, fail formally to apply.
The existence of these problems all influences further developing of wool industry, and therefore exploitation is fit to woolen dyed dedicated dye.Just seem very important and urgent.
Summary of the invention
At the existing problem of above-mentioned dyestuff, the purpose of this invention is to provide a kind of cationic dyestuff that is applicable to dyeing and finishing hairs (comprising camel hair, the rabbit hair etc.), silk fabric, it need not to adopt just energy substantive dyeing of auxiliary agent, to simplify wool, silk dyeing, improve the dyeing quality of wool, silk.
The cationic dyestuff of dyeing and finishing hairs silk fabric of the present invention is the compound that contains following structural formula:
In the above-mentioned (a) and (b) formula:
R 1Be selected from Cl, F;
R 2Be selected from following groups:
Figure A20041004115300201
NHCH 2CH 2OH(Na)
D in the above-mentioned (a) and (b) formula is selected from following positively charged ion:
Figure A20041004115300221
Wherein: R 3Be selected from H, Br;
R 4Be selected from H, Br, CH 3, OCH 3, OC 2H 5
R 5Be selected from H, Br;
R 6: be selected from CH 3, C 2H 4CONH 2
R 7Be selected from following each group:
R wherein 8: be selected from H, CH 3
R 9Be selected from H, CH 3
R 10Be selected from H, CH 3, C 2H 5, C 2H 4CN, O, C 2H 4Cl;
R 11Be selected from H, O, CH 3, C 2H 5, C 2H 4OH, C 2H 4CN,
C 2H 4Cl、C 2H 4N(CH 3) 3、CH 2CH(OCH 3)CH 2OCH 3
Figure A20041004115300231
Wherein: R 12Be selected from H, CH 3, C 2H 5
R 13Be selected from H, CH 3, C 2H 5
R 14Be selected from H, CH 3, C 2H 5
R 15Be selected from H, CH 3, C 2H 5
R 16Be selected from H, CH 3
R 17Be selected from H, CH 3
Figure A20041004115300232
Wherein: R 19Be selected from H, CH 3, C 2H 5
R 20: be selected from CH 3, C 2H 5,
Figure A20041004115300233
R 21Be selected from CH 3, C 2H 5
R 22Be selected from CH 3, C 2H 5
Wherein: R 23Be selected from H, Cl, COOCH 3
R 24Be selected from following group:
Figure A20041004115300235
Figure A20041004115300236
Figure A20041004115300237
Figure A200410041153002310
Figure A20041004115300241
Wherein:
R 25Be selected from H, OCH 3
R 26Be selected from H, CH 3, C 2H 5
R 27Be selected from H, CH 3, C 2H 5, C 2H 4CN, C 2H 4N (CH 3) 2, C 2H 4Cl,
Figure A20041004115300242
R 28Be selected from H, CH 3
Figure A20041004115300243
Wherein: R 29Be selected from H, CH 3, NH 2, OCH 3
R 30Be selected from H, OCH 3
Wherein: R 31Be selected from CH 3, C 2H 5
R 32Be selected from following group:
Figure A20041004115300251
Figure A20041004115300252
Wherein: R 33Be selected from H, NO 2, SO 2N (CH 3) 2,
Figure A20041004115300253
R 34Be selected from Cl, N (CH 3) 3, H;
R 35Be selected from H, Cl, CN:
R 36Be selected from H, Cl:
R 37Be selected from CH 3, OCH 3, H, NH 2
R 38Be selected from Cl, OCH 3, H;
R 39Be selected from H, CH 3, C 2H 5
R 40Be selected from H, C 2H 4N (CH 3) 3, C 2H 4CN and following group:
Wherein: R 41Be selected from following group:
Figure A20041004115300256
Wherein: R 18: be selected from H, CH 3
R 42Be selected from CH 3, CH (CH 3) 2, C 2H 5
R 43Be selected from CH 3, CH (CH 3) 2, C 2H 5
R 44Be selected from H, CH 3
Wherein: R 45Be selected from CH 3, C 2H 5
R 46Be selected from CH 3, C 2H 5
Figure A20041004115300264
Wherein: R 47Be selected from H, NH 2
R 48Be selected from H, NO 2, OCH 3
R 49Be selected from H, CH 3
R 50Be selected from following group:
Figure A20041004115300272
Figure A20041004115300273
Wherein: R 51Be selected from Cl,
Figure A20041004115300275
R 52Be selected from NH 2, OH;
Figure A20041004115300281
Figure A20041004115300282
Wherein: R 53Be selected from H, C 2H 5
R 54Be selected from following group:
Figure A20041004115300292
Wherein: R 55Be selected from CH 3, C 2H 5
R 56Be selected from CH 3, C 2H 5
R 57Be selected from CH 3, C 2H 5
R 58Be selected from CH 3, C 2H 5
R 59Be selected from C 2H 4COOH,
Figure A20041004115300293
Figure A20041004115300295
Wherein: R 60Be selected from following group:
R 61Be selected from H, OCH 3, CH 3
R 62: be selected from following group:
Wherein: R 63Be selected from H, NH 2,
Figure A20041004115300303
R 65Be selected from H, CH 3, C 2H 5
R 66Be selected from following group:
Figure A20041004115300305
Figure A20041004115300306
Figure A20041004115300307
Figure A20041004115300308
Figure A20041004115300309
Figure A20041004115300311
Wherein: R 67Be selected from H, CH 3
R 68Be selected from CH 3,
Figure A20041004115300312
R 69Be selected from H, CH 3
R 71Be selected from H, CH 3
Wherein: R 72Be selected from H, NH 2, N (CH 3) 2
R 73Be selected from H, CH 3
R 74Be selected from H, CH 3
R 75Be selected from H, CH 3
R 76Be selected from H, CH 3
R 77Be selected from H, CH 3
R 78Be selected from H, CH 3
Figure A20041004115300314
Figure A20041004115300322
Figure A20041004115300323
Wherein: R 79Be selected from CH 3, C 2H 5
R 80Be selected from CH 3, C 2H 5
R 81Be selected from H, NH 2,
Wherein: R 82Be selected from CH 3, C 2H 5
R 83Be selected from CH 3, C 2H 5
R 84Be selected from CH 3, C 2H 5
R 85Be selected from CH 3, C 2H 5
R 86Be selected from following group:
NHC 2H 5、
Figure A20041004115300331
Figure A20041004115300332
Wherein: R 87Be selected from CH 3, C 2H 5
R 88Be selected from CH 3, C 2H 5
R 89Be selected from CH 3, C 2H 5
R 90Be selected from CH 3, C 2H 5
Wherein: R 91Be selected from H, CH 3
R 92Be selected from H, C 2H 5
R 93Be selected from H, C 2H 5
R 94Be selected from H, CH 3
R 95Be selected from following group:
Figure A20041004115300334
Wherein: R 96Be selected from CH 3, C 2H 4OH;
R 97Be selected from CH 3, C 2H 5, C 2H 4OH;
R 98Be selected from CH 3, C 2H 4OH;
R 99Be selected from CH 3, C 2H 4OH;
R 100Be selected from H, CH 3
R 101Be selected from H, CH 3, Cl;
R 102Be selected from H, CH 3
R 103Be selected from CH 3, C 2H 5,
R 104Be selected from H, CH 3
Figure A20041004115300343
Wherein: R 106Be selected from H, CH 3,
R 107Be selected from H, SC 2H 4N (CH 3) 3
R 108Be selected from following group:
Figure A20041004115300345
C 3H 6N(CH 3) 3
Figure A20041004115300351
Wherein: R 109Be selected from CH 3, C 3H 7
R 110Be selected from CH 3, C 3H 7
R 111Be selected from CH 3, C 3H 7
Be to be basic kernel on the dye structure of the present invention with s-triazine, one end of this basic structure partly links with the form and the color development of ionic linkage, the form that has kept cationic dyestuff " to form " by colored ion that has positive charge and anionic structure, the other end group of this structure then can with wool (silk, the rabbit hair, camel hair ...) etc. the amino reaction of protein fibre, reach the effect of dyeing wool on the dyestuff.It has the following advantages as hair, silk goods or the dyestuff of blending fabric that contains hair, silk:
1. this cationic dyestuff great variety of goods, lovely luster, dyefastness is good;
2. can be to hair/nitrile, BLENDED FABRIC such as silk/nitrile are once dyed, needn't be stage by stage, gradation dyeing, reduced operation steps;
3. in dyeing course, adjust the PH of dye liquor with soda acid except that adding this dye well, not needing additionally to add other auxiliary agents (as levelling agent, dispersion agent, permeate agent, dyeing auxiliaries etc.) can reduce production costs on the one hand, minimizing is to the corrosion of equipment, simplify dyeing and finishing technology, the pollution of various auxiliary compounds to environment also can be avoided in the aspect in addition, reduces a large amount of dischargings poisonous, hazardous compound;
4. in dyeing course, except that adding hair fibre and dyestuff of the present invention, only need to add the soda acid that is used to transfer PH on a small quantity in the dye vat, therefore, dye liquor can repeatedly repeat to apply mechanically, and has greatly reduced the quantity discharged of dye liquor, thereby alleviates the pollution to environment greatly; It is a kind of environmental protection type dye.
5. the intensity height of this cationic dyestuff, consumption is significantly less than the consumption of matching stain, has reduced mao cost that dyes of dyeing.
Cationic dyestuff compound of the present invention (a) prepares with following reaction formula:
Wherein:
Figure A20041004115300372
Can prepare with same reaction process:
Above D +X -Be the general formula of traditional basic dyestuff (cationic dyestuff), expression basic dyestuff (cationic dyestuff); D +Be positively charged ion coloured moiety, X -Be anionicsite, can be selected from CH 3SO 4 -, Cl -, ZnCl 3 -, HSO 4 -, H 2PO 4 -, CH 3COO -, Br -, NO 3 -
R1: be Cl or F;
R2: for containing naphthylamino, naphthyloxy, phenoxy group, phenylamino and contain amino or the group of hydroxyl (above reaction only is example with the naphthyloxy).
Y: be K or Na;
Among the above reaction formula I, compound (A) is a cationic dyestuff, makes it be dissolved in water by adjusting suitable temperature; Compound (B) is Sulphanilic Acid (or its sodium salt) or m-sulfanilic acid (or its sodium salt), and the two mixes with A: B=1: 1-10 (molecular ratio), react compound (E);
Press reaction formula II, add the reaction of compound (C) cyanuric chloride and compound (E), add-on is B: C=1～1.3: 1 (molecular ratio), stirs 4-6 hour, in the process of insulation, the mixed solution that adds catalyzer sodium hydroxide (or potassium hydroxide) and acetic acid simultaneously, the adding proportioning is sodium hydroxide (or potassium hydroxide): acetic acid=1: 0.5-3.0 (molecular ratio), when the PH of reaction mass greater than 5, and remain unchanged, just can obtain reaction intermediate (F) by filtering.
By the reaction formula III, the filter cake making beating back of intermediate product (F) is added compound (G), temperature is controlled under the 5-60 ℃ of condition, stirring reaction 4-6 hour, in the process that stirs insulation, the mixture that adds catalyzer sodium hydroxide (or hydrogen-oxygen potassium) and acetic acid adds proportioning and is: sodium hydroxide or potassium: acetic acid=1: 0.5-3.0, when the PH of reactant at 6-7, and when keeping half an hour constant, then reaction finishes, and obtains reaction product (H) or (I), after reaction finishes, by filtering, drying is pulverized, and finally obtains needed dyestuff.
More than the compound (G) in the reaction formula III is by reaction formula IV, by compound (D) and sodium hydroxide or potassium hydroxide (being YOH) reaction and get, the amount of D is pressed D: C=1-1.25: 1 (molecular ratio) adds, the amount of YOH is pressed D: YOH=1: 1-2 (molecular ratio) adds, after stirring half an hour, be heated to suitable temperature, (D) is all dissolved to compound, promptly changes into compound (G).
The preparation method of compound of the present invention can be illustrated by following example.
Embodiment
Example 1:
Add 400 in the flask and restrain water, stir the former powder that adds 20 gram Basic Orange 2 1# down, stirring is warmed up to Basic Orange 2 1# and all dissolves, be cooled to 20 degree, add 30 gram Sodium sulfanilate salt, stirred 1 hour, add 20 gram cyanuric chlorides again, finish 25 degree insulations 6 hours, obtain (F).
Add 100 gram water in the flask, add 18.7 gram beta naphthals, stirring slowly adds sodium hydroxide 32 grams (concentration expressed in percentage by weight is 30%) down, and being warming up to beta naphthal all dissolves, and is cooled to normal temperature again, adds 100 gram water (G).
In the flask, add 400 gram water and intermediate products (F), under 25 degree, add (G), finish and be warming up to 50 degree, stirring reaction 5 hours when PH=6-7 keeps half an hour constant, reduces temperature to normal temperature, vacuum filtration, oven dry is pulverized, and gets 32 gram dyestuff of the present invention, i.e. chemical formulas (I).
Embodiment 2
Hair of the present invention is directly used in the dyeing of wool (silk, camel hair, the rabbit hair etc.) with cationic dyestuff, also can be used for fur dyeing, and dyeing quality detects as table one:
The woolen dyed fastness detected result of table one
Project Unit Test method Textile industry acceptable end product standard Detection level of the present invention
Red Yellow Blue Green (colorant match)
Water-fast washing (37 ± 2 ℃) Color and luster changes Level GB/T5713 Be not less than 3 4-5 4-5 4 4-5
Felt staining Level GB/T5713 Be not less than 3 3 3 3-4 3
Cotton staining Level GB/T5713 Be not less than 3 3 3 3 3
Anti-soaping (40 ± 2 ℃) Color and luster changes Level GB/T3921.1 Be not less than 3 3-4 3-4 3 2-3
Felt staining Level GB/T3921.1 Be not less than 3 4 4 4 4
Cotton staining Level GB/T3921.1 Be not less than 3 4 4 4-5 4
Perspiration resistance (37 ± 2 ℃) Color and luster changes Level GB/T3922 acid Be not less than 3-4 4 4 4 4
GB/T3922 alkali 4 4 4 4
Felt staining Level GB/T3922 acid Be not less than 3 2-3 3 2-3 3
GB/T3922 alkali 3 3 2 3
Cotton staining Level GB/T3922 acid Be not less than 3 3 3 3-4 3
GB/T3922 alkali 3-4 3 3-4 3
Rub resistance Metal to-metal contact Level GB/T3920 Be not less than 3-4 4-5 4-5 4 4-5
Wet friction Level GB/T3920 Be not less than 2-3 3 3-4 3 3
Heat-resisting pressure (200 ℃) Color and luster changes Level GB/T6152 4 4-5 4-5 4
Cotton staining Level GB/T6152 4-5 4-5 4-5 4-5
Fast light Xenon arc Level GB/T8427 Be not less than 3-4 3 5-6 3 3
Embodiment 3
Hair of the present invention is directly used in the blended fabric dyeing of wool and acrylic fibers with cationic dyestuff, and its dyeing quality detects as table two:
Table two. acrylic fibres dyeing fastness detected result
Project Unit Test method Detection level of the present invention
Anti-soaping (60 ± 2 ℃) Color and luster changes Level GB/3921.3 4-5
Cotton staining Level GB/3921.3 4-5
Acrylic fibers staining Level GB/3921.3 4-5
Perspiration resistance (37 ± 2 ℃) Color and luster changes Level GB/T3922 acid 4
GB/T3922 alkali 4
Cotton staining Level GB/T3922 acid 4-5
GB/T3922 alkali 4-5
Acrylic fibers staining Level GB/T3922 acid 4-5
GB/T3922 alkali 4-5
Rub resistance Metal to-metal contact Level GB/T3920 4-5
Wet friction Level GB/T3920 4
Heat-resisting pressure (200 ℃) Color and luster changes Level GB/T6152 4
Cotton staining Level GB/T6152 4-5
Fast light Xenon arc Level GB/T8427 5

Claims (41)

  1. The cationic dyestuff that is used for dyeing and finishing hairs silk textiles is characterized in that containing the compound of following structural formula:
    Figure A2004100411530002C1
    In the above-mentioned (a) and (b) formula:
    R 1Be selected from Cl, F;
    R 2Be selected from following groups:
    Figure A2004100411530002C2
    Figure A2004100411530003C2
    NHCH 2CH 2OH(Na)
    D in the above-mentioned (a) and (b) formula is selected from following positively charged ion:
    (1)
    Figure A2004100411530004C1
    Wherein: R 3Be selected from H, Br;
    R 4Be selected from H, Br, CH 3, OCH 3, OC 2H 5
    R 5Be selected from H, Br;
    R 6: be selected from CH 3, C 2H 4CONH 2
    R 7Be selected from following each group:
    Figure A2004100411530004C2
    R wherein 8: be selected from H, CH 3
    R 9Be selected from H, CH 3
    R 10Be selected from H, CH 3, C 2H 5, C 2H 4CN, O, C 2H 4Cl;
    R 11Be selected from H, O, CH 3, C 2H 5, C 2H 4OH, C 2H 4CN, C 2H 4Cl, C 2H 4N (CH 3) 3, CH 2CH (OCH 3) CH 2OCH 3
  2. (2)
    Wherein: R 12Be selected from H, CH 3, C 2H 5
    R 13Be selected from H, CH 3, C 2H 5
    R 14Be selected from H, CH 3, C 2H 5
    R 15Be selected from H, CH 3, C 2H 5
    R 16Be selected from H, CH 3
    R 17Be selected from H, CH 3
  3. (3)
    Figure A2004100411530005C2
    Wherein: R 19Be selected from H, CH 3, C 2H 5
    R 20: be selected from CH 3, C 2H 5,
    Figure A2004100411530005C3
    R 21Be selected from CH 3, C 2H 5
    R 22Be selected from CH 3, C 2H 5
  4. (4)
    Wherein: R 23Be selected from H, Cl, COOCH 3
    R 24Be selected from following group:
    Figure A2004100411530005C6
    Figure A2004100411530005C10
    Wherein:
    R 25Be selected from H, OCH 3
    R 26Be selected from H, CH 3, C 2H 5
    R 27Be selected from H, CH 3, C 2H 5, C 2H 4CN, C 2H 4N (CH 3) 2, C 2H 4Cl,
    Figure A2004100411530006C2
    R 28Be selected from H, CH 3
  5. (5)
    Figure A2004100411530006C3
    Wherein: R 29Be selected from H, CH 3, NH 2, OCH 3
    R 30Be selected from H, OCH 3
  6. (6)
    Figure A2004100411530006C4
    Wherein: R 31Be selected from CH 3, C 2H 5
    R 32Be selected from following group:
    Figure A2004100411530007C1
  7. (7)
    Figure A2004100411530007C2
    Wherein: R 33Be selected from H, NO 2, SO 2N (CH 3) 2,
    Figure A2004100411530007C3
    R 34Be selected from Cl, N (CH 3) 3, H;
    R 35Be selected from H, Cl, CN;
    R 36Be selected from H, Cl;
    R 37Be selected from CH 3, OCH 3, H, NH 2
    R 38Be selected from Cl, OCH 3, H;
    R 39Be selected from H, CH 3, C 2H 5
    R 40Be selected from H, C 2H 4N (CH 3) 3, C 2H 4CN and following group:
    Figure A2004100411530007C4
  8. (8)
    Figure A2004100411530007C5
    Wherein: R 41Be selected from following group:
  9. (9)
    Figure A2004100411530008C1
    Wherein: R 18: be selected from H, CH 3
    R 42Be selected from CH 3, CH (CH 3) 2, C 2H 5
    R 43Be selected from CH 3, CH (CH 3) 2, C 2H 5
    R 44Be selected from H, CH 3
  10. (10)
  11. (11)
    Figure A2004100411530008C3
    Wherein: R 45Be selected from CH 3, C 2H 5
    R 46Be selected from CH 3, C 2H 5
  12. (12)
    Figure A2004100411530008C4
    Wherein: R 47Be selected from H, NH 2
    R 48Be selected from H, NO 2, OCH 3
    R 49Be selected from H, CH 3
    R 50Be selected from following group:
  13. (13)
  14. (14)
    Figure A2004100411530009C3
  15. (15)
    Wherein: R 51Be selected from Cl,
    R 52Be selected from NH 2, OH;
  16. (16)
    Figure A2004100411530010C1
  17. (17)
  18. (18)
  19. (19)
    Figure A2004100411530010C4
  20. (20)
    Wherein: R 53Be selected from H, C 2H 5
    R 54Be selected from following group:
  21. (21)
  22. (22)
    Figure A2004100411530011C3
    Wherein: R 55Be selected from CH 3, C 2H 5
    R 56Be selected from CH 3, C 2H 5
    R 57Be selected from CH 3, C 2H 5
    R 58Be selected from CH 3, C 2H 5
    R 59Be selected from C 2H 4COOH,
    Figure A2004100411530011C5
  23. (23)
    Figure A2004100411530011C6
  24. (24)
    Figure A2004100411530012C1
    Wherein: R 60Be selected from following group:
    R 61Be selected from H, OCH 3, CH 3
    R 62: be selected from following group:
    Figure A2004100411530012C3
  25. (25)
    Wherein: R 63Be selected from H, NH 2,
    Figure A2004100411530012C5
    R 65Be selected from H, CH 3, C 2H 5
    R 66Be selected from following group:
    Figure A2004100411530012C6
    Figure A2004100411530012C7
    Figure A2004100411530012C8
    Figure A2004100411530013C1
  26. (26)
  27. (27)
    Wherein: R 67Be selected from H, CH 3
    R 68Be selected from CH 3,
    R 69Be selected from H, CH 3
    R 71Be selected from H, CH 3
  28. (28)
    Wherein: R 72Be selected from H, NH 2, N (CH 3) 2
    R 73Be selected from H, CH 3
    R 74Be selected from H, CH 3
    R 75Be selected from H, CH 3
    R 76Be selected from H, CH 3
    R 77Be selected from H, CH 3
    R 78Be selected from H, CH 3
  29. (29)
  30. (30)
    Figure A2004100411530014C2
  31. (31)
    Figure A2004100411530014C3
  32. (32)
    Figure A2004100411530014C4
    Wherein: R 79Be selected from CH 3, C 2H 5
    R 80Be selected from CH 3, C 2H 5
    R 81Be selected from H, NH 2,
  33. (33)
    Figure A2004100411530015C2
    Wherein: R 82Be selected from CH 3, C 2H 5
    R 83Be selected from CH 3, C 2H 5
    R 84Be selected from CH 3, C 2H 5
    R 85Be selected from CH 3, C 2H 5
    R 86Be selected from following group:
    NHC 2H 5、
    Wherein: R 87Be selected from CH 3, C 2H 5
    R 88Be selected from CH 3, C 2H 5
    R 89Be selected from CH 3, C 2H 5
    R 90Be selected from CH 3, C 2H 5
  34. (35)
    Wherein: R 91Be selected from H, CH 3
    R 92Be selected from H, C 2H 5
    R 93Be selected from H, C 2H 5
    R 94Be selected from H, CH 3
    R 95Be selected from following group:
  35. (36)
    Wherein: R 96Be selected from CH 3, C 2H 4OH;
    R 97Be selected from CH 3, C 2H 5, C 2H 4OH;
    R 98Be selected from CH 3, C 2H 4OH;
    R 99Be selected from CH 3, C 2H 4OH;
    R 100Be selected from H, CH 3
    R 101Be selected from H, CH 3, Cl;
    R 102Be selected from H, CH 3
    R 103Be selected from CH 3, C 2H 5,
    Figure A2004100411530016C4
    R 104Be selected from H, CH 3
  36. (37)
    Figure A2004100411530017C1
    Wherein: R 106Be selected from H, CH 3,
    R 107Be selected from H, SC 2H 4N (CH 3) 3
    R 108Be selected from following group:
    C 3H 6N(CH 3) 3
  37. (38)
    Figure A2004100411530017C4
  38. (39)
  39. (40)
    Figure A2004100411530018C1
  40. (41)
    Wherein: R 109Be selected from CH 3, C 3H 7
    R 110Be selected from CH 3, C 3H 7
    R 111Be selected from CH 3, C 3H 7
  41. (42)
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CN103147322A (en) * 2013-03-26 2013-06-12 无锡新德印染制品有限公司 Assistant for printing and dyeing
CN103147320A (en) * 2013-03-26 2013-06-12 无锡新德印染制品有限公司 Assistant for printing and dyeing
CN103147319A (en) * 2013-03-26 2013-06-12 无锡新德印染制品有限公司 Assistant for printing and dyeing
CN103147321A (en) * 2013-03-26 2013-06-12 无锡新德印染制品有限公司 Assistant for printing and dyeing
CN103225217A (en) * 2013-04-28 2013-07-31 佛山市名洲纺织有限公司 Silk fiber knitted fabric dyeing method for achieving fluorescent color
CN104047167A (en) * 2014-06-26 2014-09-17 马鞍山纽泽科技服务有限公司 Wool modifier and preparation method of wood modifier
CN104074048A (en) * 2014-06-26 2014-10-01 马鞍山纽泽科技服务有限公司 Wool modifying and dyeing process
CN106894248A (en) * 2017-04-13 2017-06-27 江南大学 A kind of method that utilization Maillard reaction improves wool cationic dyeing performance

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CN1250830A (en) * 1998-10-12 2000-04-19 王志 Method for dyeing animal protein fibre, such as wool,with cationic dye
CN1250831A (en) * 1998-10-12 2000-04-19 王志 Method for dyeing silk and its fabrics with cationic dye
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CN103147322A (en) * 2013-03-26 2013-06-12 无锡新德印染制品有限公司 Assistant for printing and dyeing
CN103147320A (en) * 2013-03-26 2013-06-12 无锡新德印染制品有限公司 Assistant for printing and dyeing
CN103147319A (en) * 2013-03-26 2013-06-12 无锡新德印染制品有限公司 Assistant for printing and dyeing
CN103147321A (en) * 2013-03-26 2013-06-12 无锡新德印染制品有限公司 Assistant for printing and dyeing
CN103225217A (en) * 2013-04-28 2013-07-31 佛山市名洲纺织有限公司 Silk fiber knitted fabric dyeing method for achieving fluorescent color
CN104047167A (en) * 2014-06-26 2014-09-17 马鞍山纽泽科技服务有限公司 Wool modifier and preparation method of wood modifier
CN104074048A (en) * 2014-06-26 2014-10-01 马鞍山纽泽科技服务有限公司 Wool modifying and dyeing process
CN104047167B (en) * 2014-06-26 2016-04-13 马鞍山纽泽科技服务有限公司 Wool modifying agent and preparation method thereof
CN106894248A (en) * 2017-04-13 2017-06-27 江南大学 A kind of method that utilization Maillard reaction improves wool cationic dyeing performance

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