CN1695813A - Method and system of electric projectile through high-speed liquid for preparing superfine material - Google Patents
Method and system of electric projectile through high-speed liquid for preparing superfine material Download PDFInfo
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- CN1695813A CN1695813A CN 200510040633 CN200510040633A CN1695813A CN 1695813 A CN1695813 A CN 1695813A CN 200510040633 CN200510040633 CN 200510040633 CN 200510040633 A CN200510040633 A CN 200510040633A CN 1695813 A CN1695813 A CN 1695813A
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Abstract
A method for preparing superfine material by spraying the electrically charged high-speed fluid includes fluidizing the material to be processed, electrically charging it, pressure spraying via nozzle, and collecting the resultant superfine material. Its system is composed of high-speed jet unit, electric charger, and collector.
Description
Technical field
The present invention relates to a kind of preparation method and system of super-fine material, especially a kind of method and system that the high-velocity fluid technology combined the preparation super-fine material with the Electrofluid Mechanics spraying technique.
Background technology
At present, comprise the super-fine material of superfines and superfine fibre owing to have characteristics such as high specific area, tiny hole thereby be with a wide range of applications, thereby be subjected to showing great attention to of people in fields such as medicine, catalysis, separation, protection, cosmetics, textiles.People comprise that by high-velocity fluid technology (comprising the percussion flow technology), Electrofluid Mechanics spraying technique EFI and electrospinning, colloidal sol-gel technique, gas phase codeposition technique, hydrothermal technique, ball grinding technique, self-assembling technique, sacrificial mold plate technique prepare super-fine material at present, wherein high-velocity fluid technology, electric jet technology, colloidal sol-gel technique, gas phase codeposition technique, hydrothermal technique and ball grinding technique are used widely in actual production, and technology such as electrospinning, self-assembling technique and sacrificial mold plate technique still are in development.Yet resulting super-fine material of high-velocity fluid technology or size are still too big at present, as passing through the prepared nonwoven of high-velocity fluid, the diameter dimension of its fiber is more than tens microns, perhaps preparation method's complexity needs the very system of complex and expensive as preparing superfine powder by high-velocity fluid collision gas-phase reaction deposition.Electric jet technology then is widely used in fields such as mass spectrum, engine, material drying, particle manufacturing, thin film fabrication, pesticide spraying; but the particle of preparation or size too big as adopt the high velocity fog technology or can not the mass preparation super-fine material as adopting the ullrasonic spraying technology; therefore application is confined within the certain limit; the superfine fibre of electrospinning preparation then yields poorly and can not combine with industrialized production owing to it, thereby still is difficult to obtain large-scale application.
Summary of the invention
The purpose of this invention is to provide and a kind of the high-velocity fluid technology is combined with the method and system of mass preparation ultra-fine grain or fiber with the Electrofluid Mechanics spraying technique.
Technical scheme of the present invention is:
A kind of preparation super-fine material electric projectile through high-speed liquid method is characterized in that may further comprise the steps:
A, at first make the machined material fluidisation;
B, secondly make the charged flow at high speed of above-mentioned fluidised machined material, comprise and make fluidised machined material obtain required ultra-fine formed material by the nozzle ejection that is applied with pressure, its volume flow rate is between 10 milliliters/hour～10 liters/second, linear flow speed is between 1.5 mm/second～1000 meter per seconds, and the linear flow speed of fluid is the speed flow at high speed greater than 0.5 meter per second at least one time period, and charged in all or part of time period of the flow process of fluidised machined material, electric charge field is between 0.1V/ millimeter～1000kV/ millimeter;
C, collect by the machined material of gathering-device after and promptly to get ultra-fine formed material of the present invention above-mentioned ultra-fineization processing.
In making the charged flow at high speed process of above-mentioned fluidised machined material, also comprise the motion control (as the focusing of subband electrofluid) of charged fluid, temperature control (comprising: infrared, microwave, heat radiation, refrigeration system), ultrasonic wave control (carrying out dispersion of materials), chemical reaction (changing the performance of machined material), active force control (moving reposefully to guarantee the charged fluid of high speed by the interaction force between the balance different fluid) or rotation are controlled (producing the characteristic that turning effort power is controlled machined material by making fluid) and then the performance of machined material are further improved, and wherein chemical reaction can be before injection to the modification of machined material, in the course of injection, carry out during the collection or later on; Chemical reaction can have only a kind of reaction, also multiple reaction can be arranged, when multiple reaction, reaction can take place simultaneously, also can take place at different time, diverse location, chemical reaction comprise polymerization, crosslinked, grafting, replacement, addition, elimination, cooperation, precipitation, decomposition, in and the reaction of class organic or inorganic.
Described rotation control comprises rotating electric field control, rotating excitation field technology and swing-around trajectory control, and the frequency of rotating electric field, rotating excitation field is between 10
-3Hz～10
9Hz.
The process that the described machined material that the charged flow at high speed of above-mentioned fluidised machined material is also comprised make lotus that electric charge be arranged further disperses or stretches under the effect of follow-up active force, follow-up active force comprises that electric field action power, magnetic field active force, fluid force and other comprise the active force of heat, sound, the direction of its direction of follow-up active force and charged high-velocity fluid has certain included angle, angle is between 0～360 degree, and preferred 30～150 spend; Electric field and magnetic field and make the charged electric field of fluid coupling make the charged current physical efficiency hard to bear to the specific active force that comprises attraction or repulsion force, to charged fluid have attract or the electric-field intensity of repulsive interaction between 0.1V/ millimeter～1000kV/ millimeter, magnetic field intensity is between 0.001 milli tesla～30 teslas; Follow-up active force can have only a kind of active force, and multiple active force acting in conjunction also can be arranged; Can not comprise in the whole process of preparation, comprise once or once above follow-up active force process.
Utilize fluid impact to the machined material from the nozzle ejection is carried out ultra-fineization impact processing; Fluid impact is by other high velocity fluid strikes, stretch, the fluid components that disperses processed material, the fluid that is used for impacting can comprise the composition that can dissolve machined material, also can comprise the composition that can solidify machined material, can also comprise the composition that can carry out chemical reaction or physical reactions with machined material, fluid in the fluid impact can be a gas, liquid, supercritical fluid, plasma, liquid particles is contained in carrying object, solid granulates is contained in carrying object, impact fluid can have the electric charge identical or opposite with the machined material fluid by lotus, also can neutral; Its pressure limit is between 1 atmospheric pressure to 5000 atmospheric pressure, and the speed of impact fluid is between 1.5 mm/second～1000 meter per seconds.
Described gathering-device can be the wet gathering-device of doing that also can include solvent or steam for collecting drum, collecting conveyer belt, collecting board or collecting pit; The ultra-fine formed material of collecting gained through gathering-device through follow-up acupuncture, water thorn, braiding, heat stick, chemistry sticks, wrap removed the part composition by other material, dissolving or screen after promptly further obtain on a large scale by undersized solid, particle, fiber, fibre bundle or the ultra-fine formed material of film shape that nucleocapsid, hollow form or cavernous particle or fiber constituted.
Described charged corona charging, induction charging, contact charging, triboelectric charging, the charged current bulk charging of comprising; Charged can be the nozzle place at fluid issuing, certain electric charge in the past or on later on by lotus, electric charge field comprises direct current positive electric field, direct current negative electric field or alternating electric field, makes the charged electric field of fluid between 0.1V/ millimeter～1000kV/ millimeter.
A kind of electric projectile through high-speed liquid system for preparing super-fine material is characterized in that it is made up of high-speed jet equipment, charged equipment, collecting device at least.
Said system also comprises the synkinesia control device, and described synkinesia control device is installed between collecting device and the charged equipment.
Also comprise aftertreatment device, aftertreatment device is installed in before the collecting device.
Details are as follows:
The fluidisation of machined material and storage means comprise dissolving, fusion, evaporation, plasmaization, pulverize machined material is become comprise gaseous state, liquid state, supercritical fluid, plasma state, and fluid in contain the highdensity composition of relative main fluid composition such as solid granulates and be contained in the fluid form that carrying object, liquid particles are contained in carrying object.For can not by dissolving, fusion, evaporation, plasmaization, the fluidised machined material of pulverizing then by use can fluidisation and can by chemical reaction or physical effect before the high speed electrofluid sprays or in the process or the method for back generation machined material or reaction intermediate make the machined material fluidisation.
The charged flow at high speed of machined material can be comprised make machined material charged, drive machined material flow at high speed and charged high-velocity fluid synkinesia.
Machined material charged is by adopting in the methods such as corona charging, induction charging, contact charging, triboelectric charging, charged current bulk charging one or more to make machined material charged.Make corresponding power supply of the charged needs of machined material and electrode.Machined material is charged can be the nozzle place at fluid issuing, certain electric charge in the past or on later on by lotus.Electric charge field can be direct current positive electric field, direct current negative electric field or alternating electric field.
Drive the machined material flow at high speed and be by selecting for use the pressure that is applied on the nozzle place machined material fluid to comprise that mechanicals efforts, compression system, negative pressure system or fluid impact and follow-up active force comprise that in high voltage electric field, high-intensity magnetic field, the fluid impact one or more realize.Wherein fluid impact is machined material is impacted and to be realized by other material high-velocity fluid that pressure produces.
Make machined material flow at high speed nozzle comprise single shower nozzle, the coaxial pair of shower nozzle, the many shower nozzles of axially parallel.The cross section of the shower nozzle of nozzle comprises various plane geometric shapes such as circle, rectangle, abnormity.Nozzle can be formed the nozzle array with four-dimensional spacetime distribution by surpassing a nozzle as required.The high-velocity fluid of different spray nozzles ejection can lotus have identical charges also can lotus have opposite charges not lotus electric charge is arranged.The high-velocity fluid of different spray nozzles ejection can be a same material, also can be different materials, can also be the part identical materials.Different materials in the different spray nozzles can not react mutually, chemical reaction or physical effect can take place yet.
Lotus has the high-velocity fluid of electric charge further to be disperseed or stretch by the method for follow-up active force.Follow-up active force can be that electric field action power, magnetic field active force, fluid force or other comprise the active force of heat, sound.The direction of its direction of follow-up active force and charged high-velocity fluid has certain included angle, and angle is between 0～360 degree, but preferred 30～150 degree.Electric field and magnetic field and make the charged electric field of fluid coupling make the charged current physical efficiency hard to bear to the specific active force that comprises attraction or repulsion force.
Fluid impact is meant the fluid components (as shown in Figure 3) of wanting material processed by other high velocity fluid strikes, stretching, dispersion.Can comprise the composition that can dissolve material to be prepared in the impact fluid also can comprise the composition that can solidify material to be prepared and can also comprise the composition that can carry out chemical reaction or physical effect with material to be prepared.Fluid in the fluid force can be that gas, liquid, supercritical fluid, plasma, liquid particles are contained in carrying object, solid granulates is contained in carrying object.Follow-up active force impact fluid can lotus has the electric charge identical or opposite with being applied fluid also can neutral.
Follow-up active force can have only a kind of active force, and multiple active force acting in conjunction also can be arranged.Can not comprise in the electric projectile through high-speed liquid method, can comprise once, can comprise the follow-up active force effect that surpasses more than once yet.Follow-up active force method is applicable to the processing to material of Electrofluid Mechanics injection method and high-velocity fluid method.
The electric projectile through high-speed liquid process can also be improved electric projectile through high-speed liquid process and the material performance after processed by supplementary means.Supplementary means comprises the motion control of charged fluid such as the focusing of subband electrofluid, by infrared, microwave, heat radiation, the temperature control that refrigeration system is carried out, carry out dispersion of materials by ultrasonic wave, change the performance of machined material by chemical reaction, move reposefully to guarantee the charged fluid of high speed by the interaction force between the balance different fluid, by making fluid produce the characteristic that turning effort power is controlled machined material, ventilation is to discharge gaseous material, process is carried out noise reduction to be handled, process is monitored, process adopts automation control etc.
Charged fluid motion control is meant by electric field, magnetic field, sound field, pressure etc. can comprise the motion control in being controlled at of focusing, TRAJECTORY CONTROL, scope to charged fluid to the have an effect energy field of power of charged fluid in charged fluid motion process.Charged fluid motion control electromagnetic field effect comprises electrostatic field, magnetic field effect or adopts electrostatic field simultaneously and the magnetic field effect.Charged fluid motion control electromagnetic field effect is in the zones of different of electric projectile through high-speed liquid process, and it also can be different being applied to field intensity on the charged fluid and can being identical.When controlling the motion of charged high-velocity fluid by electrostatic field, the electric field that is applied with the charged electric field of machined material is complementary, can be direct current positive electric field, direct current negative electric field or AC field.When making the charged electric field of machined material be DC electric field, it is identical to control the electric field of the charged high-velocity fluid motion electric polarity charged with making machined material by electrostatic field; If making the charged electric field of machined material is AC field, make the charged electric field of machined material also be the suitable AC field of phase place.Control its phase place variation of magnetic field of charged high-velocity fluid motion and the phase place of the charged electric field of machined material is complementary by the magnetic field effect.
Machined material in by electric projectile through high-speed liquid method processing procedure to the chemical reaction of machined material modification can be before injection, in the course of injection, collect during or carry out later on; Chemical reaction can have only a kind of reaction to take place, and also can have multiple reaction to take place, and when multiple reaction took place, reaction can take place simultaneously, also can take place at different time, diverse location.Chemical reaction comprises organic and inorganic reactions such as polymerization, crosslinked, grafting, replacement, addition, elimination, cooperation, precipitation, decomposition, neutralization.
The fluid force balance regulation can be guaranteed the even running of high-velocity fluid.Force balance regulating and controlling effect power comprises that pressure, acoustic pressure power of pressure such as fluid etc. or attraction, repulsive force comprise electric field force, magnetic field force of phase matched etc.When adopting the fluid pressure regulation and control, increase the regulation and control fluid hose on Electrofluid Mechanics injection nozzle limit.When adopting the electric field force regulation and control, adopt the electric field that applies the identical or phase matched of polarity.When adopting the magnetic field force regulation and control, the space-time magnetic field that can adopt suitable configuration.Solid fluid is comprised that single fluid or nucleocapsid fluid etc. have the fluid of outward pressure, apply accordingly to internal pressure according to parameters such as its internal pressure size and flow velocitys.When the hollow fluid is equal to, have inwardly and the fluid of outward pressure apply corresponding from inside to outside and two kinds of active forces of ecto-entad.When needing two kinds or two or more regulating and controlling effect power simultaneously, can choose the regulating and controlling effect power of difference or same type as required.The purpose of force balance regulation and control is to improve the flow stability of fluid and mixing, dispersive property by amount of force inside and outside the fluid of control nozzle and follow-up active force action system.
Can effectively improve dispersive property by fluid turning effort power: can improve dispersing uniformity then can improve dispersing uniformity and material film simultaneously for fiber mechanical performance for particle by the prepared super-fine material of electric projectile through high-speed liquid method.The method that can produce turning effort power to charged high-velocity fluid comprises rotating electric field technology, rotating excitation field technology and swing-around trajectory technology.
The collection of machined material can be adopted and collect drum, collect collecting devices collection machined materials such as conveyer belt, collecting board, collecting pit.Collection system can be the wet system that the system done also can include solvent or steam.
The back processing of machined material comprises that the acupuncture, water thorn, braiding, the heat that increase the super-fine material intensity that obtains are sticked, chemistry sticks, wrap by other material, dissolving and remove part become the to grade screening etc. of process, super-fine material.
Machined material through preparation and stores processor after to comprise that thereby gaseous state, liquid state, plasma state, solid granulates are contained in the fluid form that carrying object, liquid particles be contained in carrying object and are made machined material can stretch, disperse by lotus with certain electric charge and high-speed motion.The temperature control of the movement locus by controlling charged fluid in the charged high-speed motion process of material, infrared, microwave, heat radiation, refrigeration system etc., hyperacoustic dispersion, the chemical modification processing of chemical reaction, the balance regulation of charged high-velocity fluid active force, turning effort power is improved the high speed electrofluid course of injection and the machined material that obtains to the processing such as winding, dispersion and ventilation of machined material performance.Collect by collecting devices such as collecting drum, collection conveyer belt, collecting board, collecting pit then.At last by acupuncture, water thorn, braiding, heat stick, chemistry sticks, wrap and removed part become the to grade screening of processing and super-fine material by other material, dissolving and can obtain on a large scale by undersized solid, particle, fiber, fibre bundle or film that nucleocapsid, hollow form or cavernous particle or fiber constituted.
Beneficial effect of the present invention:
Thereby multiply each other to produce on a large scale, at an easy rate and have undersized particle or fiber super-fine material by high-velocity fluid is sprayed stretching, peptizaiton to material to the stretching of material, peptizaiton and Electrofluid Mechanics on a large scale.
Description of drawings
Fig. 1 is a device systems structural representation of the present invention.
Fig. 2 is another version schematic diagram of this Fig. 1.
Fig. 3 be of the present invention be schematic diagram to sprinkler body.
Fig. 4 is a dual-system structure schematic diagram of the present invention.
The specific embodiment
The present invention is further illustrated below in conjunction with drawings and Examples.
Shown in Fig. 1,2,4.System of the present invention is made up of high-speed jet equipment (can select Tianjin Green's pump industry C002 of Co., Ltd gear pump for use), charged equipment (can select the BGG40 of BMEI company high voltage direct current generator for use), collecting device (can select Switzerland HABASIT high-speed plane driving-belt for use), synkinesia control device, aftertreatment device.The annexation of each capital equipment can make up and get final product referring to Fig. 1, Fig. 2, structure shown in Figure 4 according to the difference of purposes, purpose, institute's rapidoprint.The two synkinesia control device that is adopted of the difference of Fig. 1 and Fig. 2 is different, and adopting among Fig. 1 is conventional motion control device, among Fig. 2 institute to employing be rotary motion control device, Fig. 4 is a dual-system structure schematic diagram of the present invention.
The method of the ultra-fine powder grain material of the described preparation of present embodiment specifically also can be summarized as following 4 steps:
1, the preparation of machined material and storage;
2, make the charged flow at high speed of machined material;
3, material is collected;
4, back processing.
The preparation of machined material and the purpose of storage are to make the machined material fluidisation.Usually the method for machined material preparation and storage comprises that dissolving, fusion, evaporation, plasmaization, pulverizing make machined material become fluid form.Corresponding units is the preparation and the storage area 1 of machined material.
The charged process of machined material can adopt methods such as corona charging, induction charging, contact charging, triboelectric charging, charged current bulk charging to make machined material charged.Make corresponding power supply 2a of the charged needs of machined material and electrode 2b.Machined material is charged can be the nozzle place at fluid issuing, certain electric charge in the past or on later on by lotus.Electric charge field can be direct current positive electric field, direct current negative electric field or alternating electric field.
Driving the machined material flow at high speed is by being applied to the 3b of pressure differential system on the nozzle 3a place machined material fluid, it comprises mechanicals efforts, pressurization, negative pressure or fluid impact and follow-up active force, and follow-up active force comprises that the 3c of high voltage electric field system, the 3d of high-intensity magnetic field system, the 3e of fluid impact system realize.Wherein other material high-velocity fluid of being produced by the 3e of pressure differential system of fluid impact impacts machined material and realizes.
Secondary process comprises the motion control of charged fluid such as the focusing system 4a of subband electrofluid, by infrared, microwave, heat radiation, the temperature control system that refrigeration system is carried out, carry out dispersion of materials by ultrasonic wave, change the performance of machined material by chemical reaction, move reposefully to guarantee the charged fluid of high speed by the interaction force between force balance system balancing different fluid, by making fluid produce the characteristic that the turning effort power 4c of system controls machined material, ventilation is to discharge gaseous material, process is carried out noise reduction to be handled, process is monitored, process adopts automation control etc.
The collection of processed purpose material can be adopted and collect drum 5a, collect collecting devices collection machined materials such as conveyer belt 5b, collecting board, collecting pit.Collection system can be the wet system that the system done also can include solvent or steam.
The back processing of machined material comprises that the acupuncture, water thorn, braiding, the heat that increase the super-fine material intensity that obtains are sticked, chemistry sticks, wrap by other material, dissolving and remove part become the to grade screening etc. of process, super-fine material.
Need be by spinning fibre or the material that is produced fine particle through preparing and storage area is handled the back to comprise gaseous state, liquid, plasma state, solid granulates is contained in carrying object, liquid particles be contained in carrying object interior fluid form by charged part lotus on certain electric charge, and comprise mechanicals efforts by the pressure differential that is applied on the nozzle place fluid that drives machined material flow at high speed part, pressurization, negative pressure or fluid impact and follow-up active force comprise high voltage electric field, high-intensity magnetic field, thereby fluid impact makes charged fluid high-speed motion stretch to machined material, disperse.Meanwhile, secondary process partly plays a role: controlled by focusing, the movement locus of electric field, magnetic field effect control by charged fluid motion control such as subband electrofluid; By temperature control systems such as infrared, microwave, heat radiation, refrigeration systems, charged high-velocity fluid is carried out temperature control; By dispersion of materials systems such as ultrasonic waves charged high-velocity fluid is disperseed; Carry out chemical reaction by chemical reaction system; Regulate and control interaction force between fluid by fluid force balance regulation system; Make that by charged fluid turning effort power generation systems rotating active force in the charged high-velocity fluid makes machined material twine, disperse; By ventilating system to the charged fluid of high speed ventilate, dry handle etc.Then by the collection drum of collecting part, collect collecting device such as conveyer belt, collecting board, collecting pit and the collection material state control system is collected machined material.Comprise that the acupuncture, water thorn, braiding, the heat that increase institute's ultra-fine grain that obtains or fiber membrane intensity are sticked, chemistry sticks, wrap and removed part by other material, dissolving and become to grade to process after system of processing, ultra-fine grain or fiber screening system carry out processing and can obtain on a large scale by the processing part, back at last by undersized solid, particle, fiber, fibre bundle or film that nucleocapsid, hollow form or cavernous particle or fiber constituted.Describe the present invention referring now to the following examples, these embodiment only are used to explain the present invention and are not used for limiting scope of the present invention.
Specific embodiment:
Embodiment 1.
The preparation weight average molecular weight is the dimethyl formamide solution of 200,000 PLA 10% (mass fraction), join in the fluid reservoir and apply the high pressure of 12MPa, be connected to the nozzle of high speed Electrofluid Mechanics injection apparatus with conduit, nozzle is the spinneret of 0.8 millimeter circular spray orifice, the positive pole of high voltage source is received on the electrode of spinneret inboard, negative pole and collection plate join.Distance between nozzle and collection plate is controlled at about 40cm, nozzle (positive pole) and be about 40kv to the voltage between electrode (negative pole), the nozzle place solution flow rate of Electrofluid Mechanics injection apparatus is about 1l/min, can obtain the PLA superfine fibre by collection plate.
The preparation weight average molecular weight is the dimethyl formamide solution of 200,000 PLA 10% (mass fraction), join in the fluid reservoir and apply the high pressure of 12MPa, be connected to the nozzle of high speed Electrofluid Mechanics injection apparatus with conduit, nozzle is the spinneret of 0.8 millimeter special-shaped spray orifice, the positive pole of high voltage source is received on the electrode of spinneret inboard, negative pole and collection plate join.Distance between nozzle and collection plate is controlled at about 40cm, nozzle (positive pole) and be about 40kv to the voltage between electrode (negative pole), the nozzle place solution flow rate of Electrofluid Mechanics injection apparatus is about 1l/min, can obtain to have the PLA superfine fibre of high porosity by collection plate.
The preparation weight average molecular weight is the dimethyl formamide solution of 200,000 PLA 10% (mass fraction), join in the fluid reservoir and apply the high pressure of 12MPa, be connected to the nozzle of high speed Electrofluid Mechanics injection apparatus with conduit, nozzle is the spinneret of 0.8 millimeter spray orifice, the positive pole of high voltage source is received on the electrode of spinneret inboard, negative pole and collection plate join.Distance between nozzle and collection plate is controlled at about 40cm, nozzle (positive pole) and be about 40kv to the voltage between electrode (negative pole), diameter is arranged successively from 50 centimetres in distance nozzle 4 centimeters, 30 centimetres to 10 centimetres and spacing are that 5 centimetres the metal copper ring group that is connected to another high voltage source focuses on, the metal copper ring to electrode grounding, metal copper ring (positive pole) and be about 5000 volts to the voltage that applies on the electrode (negative pole).The solution flow rate 1l/min of nozzle place of Electrofluid Mechanics injection apparatus can obtain high density PLA superfine fibre by collection plate.
Preparation 10% (mass fraction) weight average molecular weight is the dimethyl formamide solution of 200,000 PLA, join in the fluid reservoir and apply the high pressure of 12MPa, be connected to the nozzle of Electrofluid Mechanics injection apparatus with conduit, nozzle is long 10 centimetres wide spray orifices of 2 millimeters, the positive pole of high voltage source is received on the electrode of spinneret inboard, negative pole and collection plate join.Distance between nozzle and collection plate is controlled at about 40cm, nozzle (positive pole) and be about 40kv to the voltage between electrode (negative pole), nozzle be that 10 centimetres of length are vertical with nozzle to electrode, the stainless steel strip that the top is sharp-pointed, nozzle link to each other with an electro-motor to electrode and are rotated to produce rotating electric field with 1000 rev/mins speed.Collection plate between nozzle and to electrode between and near to electrode.The solution flow rate 1l/min of nozzle place of Electrofluid Mechanics injection apparatus can obtain the highly PLA superfine fibre of commissure by collection plate.
Embodiment 5.
The preparation weight average molecular weight is the dimethyl formamide solution of 200,000 PLA 10% (mass fraction), join in the fluid reservoir and apply the high pressure of 12MPa, be connected to the nozzle of Electrofluid Mechanics injection apparatus with conduit, nozzle is long 10 centimetres wide spray orifices of 2 millimeters, the positive pole of high voltage source is received on the electrode of spinneret inboard, negative pole and collection plate join.Distance between nozzle and collection plate is controlled at about 40cm, nozzle (positive pole) and be about 40kv to the voltage between electrode (negative pole), diameter is arranged successively from 50 centimetres in distance nozzle 4 centimeters, 30 centimetres to 10 centimetres and spacing are that 5 centimetres the metal copper ring group that is connected to another high voltage source focuses on, the metal copper ring to electrode grounding, metal copper ring (positive pole) and be about 5000 volts to the voltage that applies on the electrode (negative pole).Nozzle to electrode be length be 10 centimetres vertical with nozzle, the stainless steel strip that the top is sharp-pointed, nozzle links to each other with an electro-motor to electrode and is rotated to produce rotating electric field with 1000 rev/mins speed, and the next door has a purge conduits that links to each other with air pump to blow toward collecting the superfine fibre yarn bulging.Collect drum between nozzle and between to electrode, with distance to electrode be 0.5 centimetre.Collect drum and link to each other, collect the high speed Electrofluid Mechanics with 3000 rev/mins speed rotation and spray product with another electro-motor.The solution flow rate 1l/min of nozzle place of Electrofluid Mechanics injection apparatus, the product that obtains are PLA superfine fibre yarn.
Embodiment 6.
Be 1,000,000 polystyrene with weight average molecular weight by the screw extruder fusion and apply the high pressure of 10MPa, be connected to the nozzle of Electrofluid Mechanics injection apparatus with conduit, nozzle is the spinneret of 0.8 millimeter circular spray orifice, the positive pole of high voltage source is received on the electrode of spinneret inboard, negative pole and collection plate join.Distance between nozzle and collection plate is controlled at about 40cm, nozzle (positive pole) and be about 40kv to the voltage between electrode (negative pole), and the solution flow rate 1l/min of nozzle place of Electrofluid Mechanics injection apparatus can obtain polystyrene superfine fiber by collection plate.
Embodiment 7.
Be 50,000 polyacrylonitrile with weight average molecular weight by the screw extruder fusion and apply the high pressure of 10MPa, be connected to the nozzle of Electrofluid Mechanics injection apparatus with conduit, nozzle is the spinneret of 0.8 millimeter special-shaped spray orifice, the positive pole of high voltage source is received on the electrode of spinneret inboard, negative pole and collection plate join.Distance between nozzle and collection plate is controlled at about 40cm, nozzle (positive pole) and be about 40kv to the voltage between electrode (negative pole), the solution flow rate 1l/min of nozzle place of Electrofluid Mechanics injection apparatus can obtain polyacrylonitrile hollow superfine fibre felt by conveyer belt.Polyacrylonitrile superfine fibre felt is got ultra-fine hollow carbon fiber through heat bonding, stretching, high-temperature process.
Embodiment 8.
The flint clay grog is flowed out from nozzle by the melting furnace fusion, at nozzle place fused solution by 40KV high voltage source lotus with positive charge, and the compressed air by 20MPa is jetted with the angles of 60 degree to charged fused solution, the flint clay grog is drawn into extremely several microns flint clay fiber of hundreds of nanometers under the acting in conjunction of compressed air and high voltage electric field stretching action, and pass through in net formula condensers collection cotton to electrode front 0.5 centimeters, carry out thermal finalization by acupuncture mechanism blanket and by heat-treatment furnace at the bottom of the directly-heated type roller subsequently, at last by shearing, the fibrofelt that the clot acquisition is made of the flint clay superfine fibre.
Embodiment 9.
It with weight average molecular weight 1,000,000 polyacrylonitrile fusion, join in the fluid reservoir and apply the high pressure of 30MPa, be connected to the nozzle of Electrofluid Mechanics injection apparatus with conduit, nozzle is the spinneret of 0.8 millimeter spray orifice, solution flow rate is controlled at 10l/min, the positive pole of high voltage source is received on the electrode of spinneret inboard, negative pole and collection plate join.The voltage that is applied on the polystyrene fused solution is 10KV, the electric field TRAJECTORY CONTROL devices at a distance of falling two metallic plates that tilt with injection direction that cause 5 centimetres from 50 centimetres that have been applied in 5KV after the fused solution ejection are controlled at that motion in the certain space reaches the high voltage electric field of the strong magnetic field action that is subjected to the 0.5T vertical with injection direction after 50 centimetres and the 1KV/cm vertical with former injection direction and magnetic direction and the temperature that lotus has identical charges is the acting in conjunction of the impact of the 100 high speed gaseous fluids of spending, the charged fluid of high speed between gas nozzle is 10 meters/minute collection conveyer belt collection with movement velocity between to electrode by one after about 50 centimetres of motion on the new direction, obtain the polyacrylonitrile superfine fibre, handle through acupuncture, heat can obtain polyacrylonitrile superfine fibre film after sticking processing.This polyacrylonitrile superfine fibre film becomes the ultrafine carbon fiber film after heating, stretching carbonization treatment.
Embodiment 10.
With weight average molecular weight is the polylactic acid acetone solution and the 4% hydroxyapatite (Ca of 20 ten thousand 10% (mass fractions)
10(PO
4)
6(OH)
.2) acetone soln 5ml mix, add in the storage tank and apply the high pressure of 12MPa, nozzle is the jet array formed of the metal shower nozzle of 100 0.9mm and connects in the positive pole of the high-voltage DC power supply of 40KV, solution flow rate is controlled at 1l/min, collects the superfine fibre assembly that is obtained at the collection conveyer belt that anodal 40 centimeters one of distance link to each other with negative pole with 10 meters/minute speed.Air blast carries out the drying processing with the air purge superfine fibre of 60 degree and to it near collecting conveyer belt, obtains osseous tissue renovating material after coiling, cutting.
Embodiment 11.
With mass concentration is that 2% aqueous acetic acid is a solvent, and the preparation mass concentration is 15% collagen solution; Preparing mass concentration in addition is the chloroformic solution of 5% poly butyric, one valerate (PHBV); Two kinds of solution place different device for storing liquid also to apply the high pressure of 12MPa respectively respectively, two kinds of solution spray at a distance of 50 centimetres metallic nozzle relatively from two respectively, all apply the positive voltage of 20KV on two metallic nozzle, about 25 centimetres is to be a gases at high pressure nozzle near the two metallic nozzle central authorities in distance two metallic nozzle, the flow velocity of gas is 3 meter per seconds, it can apply a thrust vertical with two nozzles to the material from the intersection nearby of two metallic nozzle ejection, thereby mixed material is blowed to gathering-device, gathering-device is the collection drum of 1000 rev/mins of turn ups, its ground connection, and apart from 50 centimetres at gas nozzle.Near collecting drum, the dry gas air-blast device is arranged, can after coiling, cutting, obtain tissue renovation material with speed acquisition poly butyric one valerate (PHBV) of 200 gram/min and the superfine fibre that mixes of collagen at last.
Embodiment 12.
Be 50,000 polyacrylonitrile with weight average molecular weight by the screw extruder fusion and apply the high pressure of 10MPa, be connected to the nozzle of Electrofluid Mechanics injection apparatus with conduit, nozzle is the spinneret of 0.8 millimeter circular spray orifice, nozzle links to each other with a ultrasonic generator, simultaneously the positive pole of high voltage source is received on the electrode of spinneret inboard, negative pole and collection plate join.Distance between nozzle and collection plate is controlled at about 40cm, nozzle (positive pole) and be about 40kv to the voltage between electrode (negative pole), the solution flow rate 1l/min of nozzle place of Electrofluid Mechanics injection apparatus can obtain polyacrylonitrile ultra-fine grain film by conveyer belt.
Embodiment 13.
Prepare 5% ammonia spirit of 5% MS-53 and 5% cellulose acetate-phthalate, after adding proper additive, inject fluid reservoir and apply the high pressure of 10MPa, be connected to the nozzle of Electrofluid Mechanics injection apparatus with conduit, nozzle is the spinneret of 0.8 millimeter circular spray orifice, the positive pole of high voltage source is received on the electrode of spinneret inboard, negative pole and collection plate join.Distance between nozzle and collection plate is controlled at about 40cm, nozzle (positive pole) and be about 40kv to the voltage between electrode (negative pole), the solution flow rate 1l/min of nozzle place of Electrofluid Mechanics injection apparatus can obtain containing MS-53 ultra-fine grain film by conveyer belt.
Embodiment 14.
The Ropinirole (Ropirinole) of preparation 2% is 4-[2-(dipropyl amino) ethyl]-1,3-dihydro-2H-indol-2-one-hydrochloride, the aqueous solution of 5% polyethylene glycol and 0.5%Tween 80, be forced into 10MPa, be connected to the nozzle of Electrofluid Mechanics injection apparatus with conduit, nozzle is the spinneret of 0.8 millimeter circular spray orifice, the positive pole of high voltage source is received on the electrode of spinneret inboard, and negative pole and collection plate join.Distance between nozzle and collection plate is controlled at about 40cm, nozzle (positive pole) and be about 40kv to the voltage between electrode (negative pole), the solution flow rate 1l/min of nozzle place of Electrofluid Mechanics injection apparatus.Can obtain containing the polyethylene glycol superfine fibre of Ropinirole by conveyer belt.This superfine fibre can be used as drug use after operation behind cutting, the compressing tablet etc.
Embodiment 15.
Prepare the polyvinyl alcohol water solution and the 10% polystyrene acetone soln of 10% (mass fraction) respectively, be connected to the nozzle of Electrofluid Mechanics injection apparatus separately by conduit after injecting fluid reservoir respectively and applying the high pressure of 10MPa, nozzle is the spinneret of 0.8 millimeter circular spray orifice, the positive pole of the high pressure positive supply of 30KV is received on the electrode of poly-vinyl alcohol solution spinneret inboard, the negative pole of-30KV high pressure negative supply is connected on the electrode of polystyrene solution spinneret inboard, and two nozzles are at a distance of 60 centimetres.Centre at two nozzles promptly is 30 centimetres of cotton conveyer belts with 5 meters/minute transmission for ground connection apart from the distance of two nozzles, and polyvinyl alcohol and polystyrene superfine fiber all form complex fabric cloth with speed commissure on cotton of 1l/min.This complex fabric cloth promptly becomes the protective materials with pathogeny microbial protection ability after sticking by chemistry and heat respectively with chitin fiber cloth and nylon fiber cloth.
Embodiment 16.
With zink rod by electric arc melting after by pressure for the 20MPa temperature be 200 degree and gases at high pressure that positive electricity is arranged by 40KV high voltage source lotus with liquid Zn from nozzle sentence 1l/min the speed ejection after two charged high-velocity fluids of metallic plate control that applied 5KV flow within the specific limits, flowed after about 50 centimetres by with the conveyer belt that electrode is linked to each other on low carbon steel plate with 10 meters/minute speed collection zinc ultra-fine grain.
Embodiment 17
The Ciprofloxacin chloroformic solution of preparation 3% and 10% aqueous gelatin solution, relative and the built-in electrode that connects with the 10KV power supply sprays so that the speed of 1l/min is relative under the pressure of 12MPa by two respectively for two kinds of reagent, meanwhile there are two strands of high-speed airs of like charges to impact the charged fluid of reagent with the direction vertical with two reagent nozzles by lotus, have below four strands of charged fluids of high speed one be connected with the 40KV high voltage source and be connected with the impingement flow of 1m/s ventilation duct and high voltage electric field acting device will impact mixed charged fluid lead to above particle collection device and exhaust duct, the collection conveyer belt that ultra-fine medicament capsule particle is grounded is collected gas and is then discharged from the top of collecting conveyer belt and be used to after treatment recycle.
Embodiment 18.
The titanium tetrachloride vapors that has applied 200 degree of high pressure is sprayed from mutually perpendicular two nozzles that the double as electrode is connected with the positive pole of 10KV high voltage source, the oxygen that has applied 200 degree of high pressure on their opposite sprays from two other nozzle that is connected with the 10KV high-voltage power cathode equally, gas is subjected to below it linking to each other with the 40KV high-voltage power cathode after high velocity impact reaction and the impact that is connected with the high-speed gas of 1m/s moves upward, the collection conveyer belt that is grounded of particle of reaction is collected unreacted gas and is promptly reacted the gas of generation and be used to recycle after then separated, then can obtain the titanium dioxide superfines.
Embodiment 19.
The zinc acetate aqueous solution of 0.05M is forced into behind the 1MPa on the conveyer belt that the nozzle that links to each other with the 30KV high voltage source and link to each other with ultrasonic generator by a built-in electrode is ejected into the ultra-fine drop of zinc acetate with the speed of 1l/min 40 centimetres of external grounds and is heated on the electro-conductive glass of 400 degree, can obtain the transparent composite conducting glass material that is attached with the zinc oxide ultra-fine particle film with the motion of 1m/min speed.This material promptly can be used for the making material of senser element behind 450 ℃ of about 2h of annealing.
Embodiment 20.
17 parts of 5% peacock green butyl ether atoleine solution and 3000 part of 5% hydroxyethyl cellulose aqueous solution mixed be forced into of the speed injection of the nozzle of 5MPa by a built-in electrode that links to each other with the negative electrode of 30KV high pressure negative supply with 1l/min, the same charged air that the nozzle both sides have and spray charged fluid to be the 1m/s of 5 degree angle temperature, 130 degree flow charged sample fluid impact, the peacock green butyl ether microcapsules of ultra-fine hydroxyethylcellulose parcel are collected by the conveyer belt of 40 centimetres of external grounds, gas is then by cooling, withdrawal liquid paraffin is removed most of water air and is then recycled.
Embodiment 21.
10% the calcium oxide aqueous solution that is added with the 1%w/v additive is pressurized to the speed injection of the nozzle of 5MPa by a built-in electrode that links to each other with the negative electrode of 30KV high pressure negative supply with 1l/min, from another at a distance of about 60 centimeters, carbon dioxide passes through the nozzle ejection of a built-in electrode that links to each other with the positive electrode of 30KV high pressure positive supply with the speed of 500ml/min, two strands of charged fluids meet below have one with 1m/s flow air impingement flow aerial particle is blowed to above, by cyclone separation device that particle is separated from the gas and collect the solid ultra-fine grain, gas then recycles.
Embodiment 22.
The preparation by weight/volume is 1.88% theophylline; 3.6% methacrylic acid; the N of 37.4% methacrylic acid glycol ester and 0.4% azodiisobutyronitrile; nozzle by a built-in electrode that links to each other with the positive electrode of 30kV high pressure positive supply dinethylformamide solution is forced into 5MPa under nitrogen protection after upwards sprays in can seeing through the space cover of ultraviolet light with the speed of 1l/min; the same charged nitrogen that the nozzle both sides have and spray charged fluid to be the 1m/s of 5 degree angle temperature, 60 degree flow charged sample fluid impact; the outside of charged high velocity jet fluid cover has ultraviolet light that charged high-velocity fluid is shone simultaneously; by cyclone separation device that particle is separated from the gas and collect the solid ultra-fine grain, gas then recycles.The solid ultra-fine grain is dry after theophylline is removed in methyl alcohol and acetate extracting, obtains can be used in the polymer ultra-fine grain with theophylline molecular engram that molecular engram separates.
The invention will be further described below in conjunction with method and system.
The preparation of machined material and storage be by comprise dissolving, fusion, evaporation, plasmaization, pulverize machined material is become comprise gaseous state, liquid state, supercritical fluid, plasma state, and fluid in contain the highdensity composition of relative main fluid composition such as solid granulates and be contained in the fluid form that carrying object, liquid particles be contained in carrying object and make the machined material fluidisation.For can not by dissolving, fusion, evaporation, plasmaization, the fluidised machined material of pulverizing then by use can fluidisation and can by chemical reaction or physical effect before the high speed electrofluid sprays or in the process or the raw material of back generation machined material or the method for reaction intermediate make the machined material fluidisation.
Make the charged flow at high speed machined material of machined material charged, drive the machined material flow at high speed, improve three parts that precedence is optional such as supplementary means of electric projectile through high-speed liquid process and the material performance after processed
Charged is to make machined material charged by methods such as corona charging, induction charging, contact charging, triboelectric charging, charged current bulk chargings.Make corresponding power supply of the charged needs of machined material and electrode.Machined material is charged can be the nozzle place at fluid issuing, certain electric charge in the past or on later on by lotus.Electric charge field comprises direct current positive electric field, direct current negative electric field or alternating electric field, makes the charged electric field of fluid between 0.1V/ millimeter～1000kV/ millimeter.
Be applied to pressure on the nozzle place machined material fluid and comprise that mechanicals efforts, compression system, negative pressure system or fluid impact and follow-up active force comprise that high voltage electric field, high-intensity magnetic field, fluid impact realize.Wherein other material high-velocity fluid of being produced by pressure of fluid impact impacts machined material and realizes.The pressure limit of pressurization is between 1 atmospheric pressure to 5000 atmospheric pressure, and the speed of impact fluid is between 1.5 mm/second～1000 meter per seconds.
Make the swiftly flowing nozzle of machined material comprise single shower nozzle, the coaxial pair of shower nozzle, the many shower nozzles of axially parallel.The cross section of the shower nozzle of nozzle comprises optional plane geometric shapes such as circle, rectangle, abnormity.Nozzle can be formed the four-dimensional spacetime nozzle array by surpassing a nozzle as required.The high-velocity fluid of different spray nozzles ejection can select lotus to have identical charges, lotus that opposite charges or not charged lotus are arranged.The high-velocity fluid of different spray nozzles ejection can be selected same material, different materials or part identical materials.Different materials in the different spray nozzles can not react mutually, chemical reaction or physical effect can take place yet.
Lotus has the high-velocity fluid of electric charge further to be disperseed or stretch by follow-up active force.Follow-up active force comprises that electric field action power, magnetic field active force, fluid force and other comprise the active force of heat, sound.The direction of its direction of follow-up active force and charged high-velocity fluid has certain included angle, and angle is between 0～360 degree, but preferred 30～150 degree.Electric field and magnetic field and make the charged electric field of fluid coupling make the charged current physical efficiency hard to bear to the specific active force that comprises attraction or repulsion force.To charged fluid have attract or the electric-field intensity of repulsive interaction between 0.1V/ millimeter～1000kV/ millimeter, magnetic field intensity is between 0.001 milli tesla～30 teslas.
Fluid impact is meant the fluid components of wanting material processed by other high velocity fluid strikes, stretching, dispersion.Can comprise the composition that can dissolve material to be prepared in the impact fluid also can comprise the composition that can solidify material to be prepared and can also comprise the composition that can carry out chemical reaction or physical effect with material to be prepared.Fluid in the fluid force can be that gas, liquid, supercritical fluid, plasma, liquid particles are contained in carrying object, solid granulates is contained in carrying object.Follow-up active force impact fluid can lotus has the electric charge identical or opposite with being applied fluid also can neutral.
Follow-up active force can have only a kind of active force, and multiple active force acting in conjunction also can be arranged.Can not comprise in the electric projectile through high-speed liquid method, can comprise once, can comprise the follow-up active force effect that surpasses more than once yet.Follow-up active force method is applicable to the processing to material of Electrofluid Mechanics injection method and high-velocity fluid method.
The focusing of the motion control of charged fluid such as subband electrofluid, by infrared, microwave, heat radiation, the temperature control that refrigeration system is carried out, carry out dispersion of materials by ultrasonic wave, change the performance of machined material by chemical reaction, move reposefully to guarantee the charged fluid of high speed by the interaction force between the balance different fluid, by making fluid produce the characteristic that turning effort power is controlled machined material, ventilation is to discharge gaseous material, process is carried out noise reduction to be handled, process is monitored, process adopts automation control etc.
Can comprise the motion control in being controlled at of focusing, TRAJECTORY CONTROL, scope to charged fluid to the have an effect energy field of power of charged fluid by electric field, magnetic field, sound field etc.Charged fluid motion control electromagnetic field effect comprises electrostatic field, magnetic field effect or adopts electrostatic field simultaneously and the magnetic field effect.Charged fluid motion control electromagnetic field effect the zones of different of electric projectile through high-speed liquid process be applied to field intensity on the charged fluid can be identical also can be different.When controlling the motion of charged high-velocity fluid by electrostatic field, the electric field that is applied with the charged electric field of machined material is complementary, can be direct current positive electric field, direct current negative electric field or AC field, field intensity is between 0.1V/ millimeter～1000kV/ millimeter, but preferred 0.01KV/ millimeter～5kV/ millimeter.When making the charged electric field of machined material be DC electric field, it is identical to control the electric field of the charged high-velocity fluid motion electric polarity charged with making machined material by electrostatic field; If making the charged electric field of machined material is AC field, make the charged electric field of machined material also be the suitable AC field of phase place.Magnetic field intensity by the charged high-velocity fluid motion of magnetic field effect control is between 0.001 milli tesla～30 teslas, but preferred 0.050～1 tesla, changes and the phase place of the charged electric field of machined material is complementary for its phase place of AC magnetic field.
To the chemical reaction of machined material modification can be before injection, in the course of injection, can also collect or back processing during.Chemical reaction can have only a kind of reaction to take place, and also can have multiple reaction to take place, and when multiple reaction took place, reaction can take place simultaneously, also can take place at different time, diverse location.Chemical reaction comprises organic and inorganic reactions such as polymerization, crosslinked, grafting, replacement, addition, elimination, cooperation, precipitation, decomposition, neutralization.
Force balance regulating and controlling effect power comprises that pressure, acoustic pressure power of pressure such as fluid etc. or attraction, repulsive force comprise electric field force, magnetic field force of phase matched etc.When adopting the fluid pressure regulation and control, increase the regulation and control fluid hose on Electrofluid Mechanics injection nozzle limit.When adopting the electric field force regulation and control, adopt the electric field that applies the identical or phase matched of polarity.When adopting the magnetic field force regulation and control, the space-time magnetic field that can adopt suitable configuration.Solid fluid is comprised that the fluid that single fluid or nucleocapsid fluid etc. have an outward pressure applies accordingly to internal pressure according to parameters such as its internal pressure size and flow velocitys.When the hollow fluid is equal to, have inwardly and the fluid of outward pressure apply corresponding from inside to outside and two kinds of active forces of ecto-entad.When needing two kinds or two or more regulating and controlling effect power simultaneously, can choose the regulating and controlling effect power of difference or same type as required.Force balance regulation and control can improve the flow stability of fluid and mixing, dispersive property by amount of force inside and outside the fluid of control nozzle and follow-up active force action system.
Fluid turning effort power can effectively be improved the dispersive property by the prepared super-fine material of electric projectile through high-speed liquid method: can improve dispersing uniformity then can improve dispersing uniformity and material film simultaneously for fiber mechanical performance for particle.The method that can produce turning effort power to charged high-velocity fluid comprises rotating electric field technology, rotating excitation field technology and swing-around trajectory technology.The frequency of rotating electric field, rotating excitation field is between 10
-3Hz～10
9Hz.
Charged current body movement controlling method, fluid force balance regulation method and turning effort power method for generation are applicable to Electrofluid Mechanics injection method and the application of high-velocity fluid method in material processed.
The collection of ultra-fine formed material of the present invention can be adopted and collect drum, collect collecting devices collection machined materials such as conveyer belt, collecting board, collecting pit.Collection system can be the wet system that the system done also can include solvent or steam.
Machined material after being collected by gathering-device also can carry out back processing, and back processing can be adopted and comprise that the acupuncture, water thorn, braiding, the heat that increase the super-fine material intensity that obtains are sticked, chemistry sticks, wraps by other material, dissolves partly the grade screening etc. of process, super-fine material of one-tenth of removal.
The process medium fluid volume flow rate of electric projectile through high-speed liquid rapidoprint is between 10 milliliters/hour～10 liters/second, and linear flow speed is between 1.5 mm/second-1000 meter per second, but the linear flow speed of fluid at least one time period greater than 0.5 meter per second.The high speed of high-velocity fluid can be the short time as also can being long less than 1 second.The speed of fluid can change as after can first low speed at a high speed, also can be earlier back low speed at a high speed, can also first low speed after low speed etc. more at a high speed.
The material that the present invention can prepare can be that the mixture of ultra-fine grain, superfine fibre, ultra-fine grain and superfine fibre can also be the assembly such as the nonwoven of ultra-fine grain or superfine fibre.Ultra-fine grain, superfine fibre or its assembly can be solid, hollow, nucleocapsid structure, loose structure.The size of super-fine material is between 1 nanometer～500 micron.
Claims (10)
1, a kind of preparation super-fine material electric projectile through high-speed liquid method is characterized in that may further comprise the steps:
A, at first make the machined material fluidisation;
B, secondly make the charged flow at high speed of above-mentioned fluidised machined material, comprise and make fluidised machined material obtain required ultra-fine formed material by the nozzle ejection that is applied with pressure, its volume flow rate is between 10 milliliters/hour～10 liters/second, linear flow speed is between 1.5 mm/second～1000 meter per seconds, and the linear flow speed of fluid is the speed flow at high speed greater than 0.5 meter per second at least one time period, and charged in all or part of time period of the flow process of fluidised machined material, electric charge field is between 0.1V/ millimeter～1000kV/ millimeter;
C, collect by the machined material of gathering-device after and promptly to get ultra-fine formed material of the present invention above-mentioned ultra-fineization processing.
2, preparation super-fine material electric projectile through high-speed liquid method according to claim 1, it is characterized in that in making the charged flow at high speed process of above-mentioned fluidised machined material, also comprising motion control, temperature control, ultrasonic wave control, chemical reaction, active force control or the rotation control of charged fluid and then make processed further refinement, wherein chemical reaction to the modification of machined material can be before injection, in the course of injection, collect during or carry out later on; Chemical reaction can have only a kind of reaction, also multiple reaction can be arranged, when multiple reaction, reaction can take place simultaneously, also can take place at different time, diverse location, chemical reaction comprise polymerization, crosslinked, grafting, replacement, addition, elimination, cooperation, precipitation, decomposition, in and the reaction of class organic or inorganic.
3, preparation super-fine material electric projectile through high-speed liquid method according to claim 2 is characterized in that described rotation control comprises rotating electric field control, rotating excitation field technology and swing-around trajectory control, and the frequency of rotating electric field, rotating excitation field is between 10
-3Hz～10
9Hz.
4, preparation super-fine material electric projectile through high-speed liquid method according to claim 1, it is characterized in that the process that the described machined material that the charged flow at high speed of above-mentioned fluidised machined material is also comprised make lotus that electric charge be arranged further disperses or stretches under the effect of follow-up active force, follow-up active force comprises electric field action power, the magnetic field active force, fluid force and other comprise heat, the active force of sound, the direction of its direction of follow-up active force and charged high-velocity fluid has certain included angle, angle is between 0～360 degree, electric field and magnetic field and make the charged electric field of fluid coupling make the charged current physical efficiency hard to bear to the specific active force that comprises attraction or repulsion force, to charged fluid have attract or the electric-field intensity of repulsive interaction between 0.1V/ millimeter～1000kV/ millimeter, magnetic field intensity is between 0.001 milli tesla～30 teslas; Follow-up active force can have only a kind of active force, and multiple active force acting in conjunction also can be arranged; Can not comprise in the whole process of preparation, comprise once or once above follow-up active force process.
5, preparation super-fine material electric projectile through high-speed liquid method according to claim 1 is characterized in that utilizing fluid impact to the machined material from the nozzle ejection is carried out ultra-fineization impact processing; Fluid impact is by other high velocity fluid strikes, stretch, the fluid components that disperses processed material, the fluid that is used for impacting can comprise the composition that can dissolve machined material, also can comprise the composition that can solidify machined material, can also comprise the composition that can carry out chemical reaction or physical reactions with machined material, fluid in the fluid impact can be a gas, liquid, supercritical fluid, plasma, liquid particles is contained in carrying object, solid granulates is contained in carrying object, impact fluid can have the electric charge identical or opposite with the machined material fluid by lotus, also can neutral; Its pressure limit is between 1 atmospheric pressure to 5000 atmospheric pressure, and the speed of impact fluid is between 1.5 mm/second～1000 meter per seconds.
6, preparation super-fine material electric projectile through high-speed liquid method according to claim 1, it is characterized in that described gathering-device for collecting drum, collecting conveyer belt, collecting board or collecting pit, can be the wet gathering-device of doing that also can include solvent or steam; The ultra-fine formed material of collecting gained through gathering-device through follow-up acupuncture, water thorn, braiding, heat stick, chemistry sticks, wrap removed the part composition by other material, dissolving or screen after promptly further obtain on a large scale by undersized solid, particle, fiber, fibre bundle or the ultra-fine formed material of film shape that nucleocapsid, hollow form or cavernous particle or fiber constituted.
7, preparation super-fine material electric projectile through high-speed liquid method according to claim 1 is characterized in that described charged corona charging, induction charging, contact charging, triboelectric charging, the charged current bulk charging of comprising; Charged can be the nozzle place at fluid issuing, certain electric charge in the past or on later on by lotus, electric charge field comprises direct current positive electric field, direct current negative electric field or alternating electric field, makes the charged electric field of fluid between 0.1V/ millimeter～1000kV/ millimeter.
8, a kind of electric projectile through high-speed liquid system for preparing super-fine material is characterized in that it is made up of high-speed jet equipment, charged equipment, collecting device at least.
9, the electric projectile through high-speed liquid system of preparation super-fine material according to claim 8 is characterized in that it also comprises the synkinesia control device, and described synkinesia control device is installed between collecting device and the charged equipment.
10, according to Claim 8 or the electric projectile through high-speed liquid system of 9 described preparation super-fine materials, it is characterized in that it also comprises aftertreatment device, aftertreatment device is installed in before the collecting device.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007143910A1 (en) * | 2006-05-29 | 2007-12-21 | Aihua Zhang | Interfacial boost type spinning-nozzle free electrofluid dynamic method and its application |
| CN103691530A (en) * | 2007-07-27 | 2014-04-02 | 卡吉尔公司 | Micronization of polyols |
| CN104307695A (en) * | 2014-10-09 | 2015-01-28 | 吉林大学 | Piezoelectric-static hybrid driven planar dispensing device |
| CN114377825A (en) * | 2021-12-29 | 2022-04-22 | 东南大学 | Device for improving dispersion degree of nano particles in polymer nano composite material |
-
2005
- 2005-06-20 CN CNB2005100406336A patent/CN100469452C/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007143910A1 (en) * | 2006-05-29 | 2007-12-21 | Aihua Zhang | Interfacial boost type spinning-nozzle free electrofluid dynamic method and its application |
| CN101518764A (en) * | 2006-05-29 | 2009-09-02 | 张爱华 | Interface assistance type spinneret-free electrofluid mechanics method and application thereof |
| CN103691530A (en) * | 2007-07-27 | 2014-04-02 | 卡吉尔公司 | Micronization of polyols |
| CN104307695A (en) * | 2014-10-09 | 2015-01-28 | 吉林大学 | Piezoelectric-static hybrid driven planar dispensing device |
| CN114377825A (en) * | 2021-12-29 | 2022-04-22 | 东南大学 | Device for improving dispersion degree of nano particles in polymer nano composite material |
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