CN101518764A

CN101518764A - Interface assistance type spinneret-free electrofluid mechanics method and application thereof

Info

Publication number: CN101518764A
Application number: CN200710007165A
Authority: CN
Inventors: 张爱华; 张继中
Original assignee: Individual
Current assignee: Individual
Priority date: 2006-05-29
Filing date: 2007-02-05
Publication date: 2009-09-02
Also published as: CN101468339A; WO2007143910A1; CN1861268A; CN101486021A

Abstract

The invention relates to an interface assistance type spinneret-free electrofluid mechanics method. Especially, acting force suitable for the motion direction of charged fluid, namely the direction of the acting force being the same as that of electro-jet or the acting force with the same direction component existing, is added on a spinneret-free electrofluid mechanics interface, namely an initial jet interface of charged processed material, besides electrostatic interaction and the action of an optional magnetic field in vertical direction on an acute nadel that is formed by the perturbation effect of a magnetic fluid free surface and perpendicular to a surface layer. The added acting force aims at helping the charged fluid break through the surface tension of the electrofluid mechanics interface as well as the interaction force in the fluid so as to process and treat the processed material. The method is applicable for preparing or coating superfine material with one or more than one of functions such as separation, protection, antibiosis, deodorization, catalysis, sensing, decoration, structural support, biological compatibility, storage, controlled release, electric conduction, restoration, medical treatment, health care, intelligent response, fragrance and adhesion. The prepared superfine material is applied in the structural form of solid, hollow or nucleocapsid particles, fiber, films, cloth blocks or blocks and can be processed on large scale at low cost.

Description

A kind of interface assistance type spinneret-free electrofluid mechanics method and application thereof

Technical field

The present invention relates to a kind of New type of current mechanics method, particularly effect and the spinneret-free with the initial jet boundary of machined material place power-assisted combines with electric fluid mechanics method, can be with cheap cost, on a large scale material is carried out Electrofluid Mechanics processing.This method is applicable to as having in separation, protection, antibiotic, deodorization, catalysis, sensing, decoration, support structure, bio-compatible, storage, controlled release, conduction, reparation, medical treatment, health care, intelligent response, fragrance, the adhesive function a kind of or surpass a kind of preparation method of super-fine material of function or the coating process of material.Prepared super-fine material is applied with particle, fiber, film, cloth or block structure.

Background technology

Thereby electric fluid mechanics method refers to machined material and utilizes electrostatic force and accurate balanced inside motive force and break through the surface tension of processed fluid attitude material and internal action power and form in the mode of jet and be dispersed in other fluid attitude medium that can not mix fully mutually with small fluid attitude material form and curing forms the method that comprises particle, fiber under charged situation, comprise electrostatic spray method, electrostatic spray and method of electrostatic spinning, estimated current mechanics method is all undertaken by spinning head the processing of material.Electric fluid mechanics method can obtain the refinement material with cheap price, convenience and position-controllable ground owing to introduced electrostatic force, and therefore electrostatic spray and Electrostatic Spray Technology have been widely used in industrial and agricultural production, the life at present.And electrostatic spinning is because the low development that also is at present of its production capacity.

Yet estimated current mechanics method is still waiting further to improve and improves to adapt to the needs that people obtain super-fine material and production capacity raising.This is then can reduce cost owing to super-fine material has very big superior performance production capacity raising.Yet current electric fluid mechanics method utilizes electrostatic force and accurate balanced inside motive force (pressure that promptly is applied on the machined material is identical except that edge effect) often to be difficult to satisfy these needs of people merely.People find that in the Electrofluid Mechanics process size of the high more material that obtains of voltage that machined material is applied is big more, if and apply lower voltage, electrostatic force and accurate balanced inside motive force are difficult to break through the interfacial tension and the material internal active force of material again, particularly for the higher material of viscosity, very big as the raw materials used often viscosity of electrostatic spinning, thus simple pass through pressure advance machined material to flow and apply its processing that is obtained of high voltage after material not only size is big but also the big production capacity of difficulty of processing is extremely low.

But not being used for the initial jet boundary of machined material place, the proportionality action masterpiece then can solve the existing problem of estimated current mechanics method effectively.The lack of balance active force owing to the active force that is applied jet boundary place size, direction inconsistent results cause wherein part at the interface active force make fluidised machined material that the preferential outstanding jet boundary of part is arranged greatly, thereby can help the fluidisation machined material to break through surface tension and internal action power and be easier to form jet.For charged jet, because the structure of the standing shape fluidisation machined material that produced of lack of balance active force and the point effect of electrostatic field be complementary, so more obvious for the booster action of charged jet.

In fact people have successfully introduced still incognizant lack of balance active force in hydrodynamic methods.When for example people utilize flash distillation, a large amount of bubble growths, fragmentation are arranged in the liquid, thereby produce the lack of balance active force and the effect of improving atomizing effect is introduced into the spraying field.At present, flash evaporation technology successfully has been applied to nonwoven and generator fuel nozzle field.Similarly, people are applied to the spraying field with ultrasonic wave can produce the lack of balance active force in liquid material characteristics, have also obtained good effect.Aspect electric fluid mechanics method, people have improved the electron spray effect by introducing air-flow, but owing to do not recognize its mechanism of action, present gas helps the designed air-flow of electron spray still to fail to make full use of the lack of balance active force that air-flow produces aspect flow velocity, the streamer mode comprising, therefore still can further improve, improve.So the lack of balance active force is introduced effect that electric fluid mechanics method is expected to improve prior art, is reduced cost.

In addition on the one hand, present electric fluid mechanics method is owing to be difficult to process machined material by simple electrostatic force and inner accurate balanced thrust, and if can adopt electrofluid mechanics method without spinning jet not only can save the manufacturing of costly complicated spinning head and maintenance cost but also can process on a large scale, produce.But the electric fluid mechanics method that has only few spinneret-free at present, an only example is to utilize vertical direction magnetic field to combine with electric fluid mechanics method perpendicular to the sharp-pointed nadel effect on top layer and form new electrofluid mechanics method without spinning jet magnetic fluid Free Surface disturbance effect is formed, yet this method has only obtained a spot of superfine fibre because the power-assisted effect is less by this method people.For this reason, the present invention combines other stronger lack of balance active force of effect and spinneret-free and forms assistance type spinneret-free electrofluid mechanics method with electric fluid mechanics method, this method is applicable to as having in separation, protection, antibiotic, deodorization, catalysis, sensing, decoration, support structure, bio-compatible, storage, controlled release, conduction, reparation, medical treatment, health care, intelligent response, fragrance, the adhesive function a kind of or above a kind of preparation method of super-fine material of function or as the coating process of material.

Summary of the invention

The purpose of this invention is to provide a kind of interface assistance type spinneret-free electrofluid mechanics method system and application.

Technical scheme of the present invention is:

A kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that may further comprise the steps:

A, at first make the machined material fluidisation;

B, secondly by being that the initial electric jet boundary of charged fluidisation machined material place increases that to destatic active force and available vertical direction magnetic field formed to magnetic fluid Free Surface disturbance effect be that force direction is identical with electric jet direction or have an active force of equidirectional component perpendicular to adapting with the charged fluid direction of motion outside the sharp-pointed nadel effect on top layer at the spinneret-free electrofluid mechanics interface, thereby process so that help the surface tension at charged fluid breakthrough Electrofluid Mechanics interface and the inner interaction force of fluid to form charged jet, handle machined material;

C, collect by the machined material of gathering-device after with the processing of above-mentioned interface assistance type spinneret-free electrofluid mechanics method.

A kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that the fluidisation of machined material comprises dissolving, fusion, evaporation, plasmaization, pulverizing becomes machined material to comprise the gaseous state of phase homogeneous or non-homogeneous phase, liquid, supercritical fluid, plasma state, contain the highdensity composition of relative main fluid composition in the fluid as carrying object and comprise that solid granulates is contained in carrying object, liquid particles is contained in carrying object and contains the low-density composition of relative main fluid composition comprise gaseous state in interior fluid form and the fluid as carrying object, the plasma state material is contained in than gaseous state, the carrying object that the plasma state material density is high.Phase homogeneous described here is meant homogeneous gaseous state, homogeneous plasma state, homogeneous liquid state, the homogeneous shooting flow figure of no phase boundary.But not the homogeneous phase is meant the orderly or unordered mixture of the different phase structure materials that have phase boundary, as comprising the little drop of the aqueous solution in the fluid oil, includes solid-state microparticle in the supercritical water solution, micro-bubble is contained in the aqueous solution.For can not by dissolving, fusion, evaporation, distillation, plasmaization, the fluidised machined material of pulverizing then by use can fluidisation and can by chemical reaction or physical effect before interface assistance type spinneret-free electrofluid mechanics method is handled or in the process or the method for back generation machined material or reaction intermediate make the machined material fluidisation.

A kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that power-assisted passes through the amount of force of the non-electrostatic interaction that influences jet and/or the inconsistent approach of direction that three kinds of lack of balance active forces are initial jet boundary place diverse location and realize:

A, produce power-assisted at the initial electric jet boundary of machined material place by fluid attitude material internal

B, produce power-assisted at the initial electric jet boundary of machined material place by applied external force

C, produce power-assisted at the initial electric jet boundary of machined material place by fluid attitude material internal and applied external force simultaneously

A kind of interface assistance type spinneret-free electrofluid mechanics method it is characterized in that described power-assisted comprise centrifugal force, gravity, vibration active force, except that vertical direction magnetic field to a kind of in the formed active force that can produce the lack of balance effect perpendicular to the oscillation action power the sharp-pointed nadel effect on top layer, bubble force of explosion, ultrasonication power, high-velocity fluid gravitation, high velocity fluid strikes power, negative pressure gravitation and other of magnetic fluid Free Surface disturbance effect or surpass a kind of.And vertical direction magnetic field to magnetic fluid Free Surface disturbance effect formed sharp-pointed nadel effect perpendicular to the top layer can select for use and combine with other power-assisted and form power-assisted jointly.

When a kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that centrifugal action power is power-assisted by with machined material attached to producing centrifugal action power and can applying on the device of high voltage electric field, at centrifugal force and electrostatic force machined material is handled.The device that can produce centrifugal force and apply high voltage electric field can be a roller, perhaps machined material be positioned at the roller lower reservoir and when roller rotates, be attached to machined material on the roller or machined material above the roller sprinkle on roller, roller rotates with certain speed under charged situation then, thereby under the acting in conjunction of centrifugal force and electrostatic force, machined material is processed, and preferred rotary speed guarantees that centrifugal force can not shed away machined material, but when suitable electric field action power square one-tenth jet and machined material is processed; The device that can produce centrifugal force and apply high voltage electric field also can be a flat rotating disk, thereby perhaps the machined material sprinkle on the rotating disk or machined material machined material is formed centrifugal force when being delivered on the rotating disk in dial rotation by conduit, then by applying electric field, thereby make machined material obtain the acting in conjunction of centrifugal force and electrostatic force and form jet and machined material is processed.Preferably on rotating disk, inlay or be carved with guide ribs or guiding groove in the smooth dispersion on the rotating disk for guaranteeing machined material.When using centrifugal force, preferably the point effect of sharp-pointed fine nadel when guaranteeing electrostatic interaction is housed at roller surface or disk edge for improving electrofluid jet effect as the lack of balance active force.

When a kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that gravity as power-assisted, thus fluid attitude machined material move under the gravity effect spinneret-free and with electrode that power supply is connected near and be subjected to electric field action and gravity effect simultaneously and form electric jet and machined material is handled.For improving electrofluid jet effect preferably in the electrode of the fluidisation machined material trickling sharp-pointed fine nadel point effect when guaranteeing electrostatic interaction to the top.

When a kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that vibration force as power-assisted, fluid attitude machined material is by being directed on the platy structure device that can hold a certain amount of fluidisation machined material that is connected with vibrating machine and power supply, thereby mechanical oscillation produce vibration force and power electrode produces electric field action and makes fluidisation machined material on the platy structure device form electric jet under the acting in conjunction of vibration active force and electric field action power and machined material is handled then.For the platy structure device surface that improves electrofluid jet effect preferably fluid machined material place the point effect of electrode when guaranteeing electrostatic interaction of the sharp-pointed fine nadel in top.

A kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that when using the oscillation action masterpiece as power-assisted, the lack of balance active force can obtain by the outer mechanical oscillation of machined material container, also can obtain as the vibration spike group on the basket bar that is fixed on dispersion, can also obtain by in the machined material container, being furnished with the clapp oscillator that can produce the specific wave of oscillation by the mechanical device of the vibration in the machined material container.After obtaining oscillation action power by said method, machined material can vibrate promptly have liquid to leave the liquid plane and under capillary effect, be rendered as the top sharp-pointed and with the comparatively roomy structure that helps most advanced and sophisticated electrostatic interaction in junction, liquid plane, oscillation action power just combines with electrostatic force and can effectively handle machined material as a result.

A kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that when using the bubble force of explosion as power-assisted, bubble can obtain by the mode that imports gas in the machined material container, also can be by the mode of local machined material of initiation or the gasification of other material such as the high speed rotation or the infra-red radiation of impeller, the microwave radiation, the electric furnace heating wire heating is carried out partial operation and is obtained, can also gas be pressed into the mode that machined material reduces pressure then by high pressure and obtain, can also obtain by the mode that imports in machined material material that can generating gasification.After in machined material, introducing bubble, the bubble of machined material inside is because proportion is littler so can be floated on the machined material liquid level than machined material, yet because gravitational effect, floating becomes the weakest part gradually to the bubble top of liquid level, steep oneself-meeting in the capillary active force therapeutic method to keep the adverse qi flowing downward and to begin explosion from the top, and in moment that bubble breaks machined material is produced the lack of balance active force and impels machined material outwards to move, if make machined material be subjected to electrostatic force simultaneously by high-pressure electrostatic then can be effectively machined material be processed in conjunction with electrostatic force and bubble force of explosion, handle.

A kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that when using ultrasonication power as power-assisted supersonic generator can be installed in the below of machined material liquid level and directly to the machined material effect or by other liquid ultrasonic wave is passed to the machined material effect by ultrasonic wave.When the ultrasonic wave effect combines with static, can handle, process machined material well.

A kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that when using high-velocity fluid gravitation as power-assisted, high-velocity fluid can be high-speed motion comprise that gas, liquid, supercritical fluid, plasma, liquid particles are contained in carrying object, solid granulates and are contained in the carrying object one or more.High-velocity fluid is by through the machined material container and pass on its liquid level one or surpass one conduit and move, and perhaps near the conduit that passes to outward the machined material liquid level by the machined material container moves.When high-velocity fluid moves, increase the active force of machined material on its electrostatic interaction direction thereby its high-speed motion can produce negative pressure and machined material is produced gravitation around it, this active force combines with electrostatic force then and can process, handle machined material well.

A kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that when using high velocity fluid strikes power as power-assisted, high-velocity fluid can be high-speed motion comprise that gas, liquid, supercritical fluid, plasma, liquid particles are contained in carrying object, solid granulates and are contained in the carrying object one or more.Thereby high-velocity fluid is by one outside the machined material liquid level or surpass in one the conduit to impact machined material with the angled direction of electric jet direction and machined material is applied lack of balance active force and the sputter machined material that adapts with jet direction.This active force combines with electrostatic force and can carry out thinning processing to machined material.

A kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that when using negative pressure gravitation as the lack of balance active force, thus of can connect by negative pressure generation device such as vavuum pump of negative pressure gravitation or surpass one conduit such as the liquid level of the hopper base of funnelform structure and machined material near machined material being produced hopper base central role power greatly and the little lack of balance active force in edge.Its action direction of this active force is consistent with electrostatic force, and it is in conjunction with carrying out thinning processing to machined material effectively.

A kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that the interpolation of machined material in the interface assistance type spinneret-free electrofluid mechanics method can directly add from the machined material liquid level, an other end of pipeline that also can be by being connected in the machined material container that carries out electric fluid mechanics method processing adds, can also adopt fluidised machined material is delivered to produce on the charged Electrofluid Mechanics processing apparatus of power-assisted and convection cell machined material, and preferably add and regulate the liquid level of machined material by pipeline.

A kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that making above-mentioned fluidised machined material by destaticing active force and available vertical direction magnetic field to also comprising motion control, temperature control, the proterties control of charged fluid and then make process optimization in the formed process that forms charged jet perpendicular to the power-assisted outside the sharp-pointed nadel effect on top layer of magnetic fluid Free Surface disturbance effect, it is characterized in that:

(I), the motion control of charged fluid comprises movement locus control, motor pattern control, moving equilibrium control, the control of motion active force

The control of A, movement locus promptly comprises that to charged fluid or fluid the movement locus of accelerations, deceleration, dispersion, focusing, orientation, scope controls by electric field, magnetic field, sound field, mechanicals efforts.When movement locus need be rotated control during for helical form.Rotation control comprises rotating electric field control, rotating excitation field technology and swing-around trajectory control, and the frequency of rotating electric field, rotating excitation field is between 10 ^-3Hz～10 ⁹Hz.

The control of B, motor pattern is that the fluidisation machined material forms sub-thread in the mode of spinneret-free or surpasses the jet motion of sub-thread after being subjected to electric field action power and power-assisted.When adopting above the sub-thread jet, different jets are arranged arbitrarily as required in four-dimensional spacetime.Different jets can spray same material, also can be different materials, can also be the part identical materials.Different jets can be with identical electric charge, also can be with opposite electric charge, and can also neutral.The spinneret-free jet can form composite charged jet with being combined by the spinning head that contains optional geometry nozzle.Different materials in the different strand jets can not react mutually, chemical reaction or physical effect can take place yet.

The control of C, moving equilibrium comprise by equilibrium phase with or different fluid in and mutual interaction force carry out steady or jiggly motion as requested to guarantee charged jet.

D, the control of motion active force comprise adopts mechanicals efforts to comprise that one or more active forces in pressure, thrust, pulling force, centrifugal force, centripetal force, acoustic force, other high-velocity fluid active force and gravity, electric field action power, the magnetic field active force move with suitable track and pattern with the control fluid.

(II), temperature control comprises that carrying out temperature by infrared, microwave, heat radiation, heat-generating system, heat-exchange system, refrigeration system controls.Different phase in the auxiliary charged jet process of spinneret-free interface assistance can adopt identical or different temperature control.

(III), proterties control be meant to the physics of machined material and or chemical property control, comprise physical behavior control and chemical reaction control.To the control of the proterties of machined material can be before jet, in the jet process, collect during or carry out later on.Proterties control can have only physical behavior control procedure or chemical property control procedure, also can have physical behavior control procedure and chemical property control procedure simultaneously.

The control of A, physical behavior be meant by light, sound, electricity, magnetic, heat, mechanism make machined material all or part of by solidifying, evaporation, distillation, dissolving, fusion, mixing, be separated in interior approach pattern, the phase of charged jet machined material are controlled.The auxiliary charged jet of interface assistance that is controlled at of physical behavior prepares in the process of super-fine material and can be undertaken by a kind of method or approach, also can be undertaken by several different methods or approach; Can adopt in the different phase of process also can be by different physical behavior control method or approach with a kind of physical behavior control method or approach.

B, chemical property control are meant the chemical composition that changes the auxiliary charged jet machined material of interface assistance by chemical reaction.Chemical reaction can have only a kind of reaction, also multiple reaction can be arranged, and when multiple reaction, reaction can take place simultaneously, also can take place at different time, diverse location.Chemical reaction comprises polymerization, crosslinked, grafting, replacement, addition, elimination, cooperation, precipitation, decomposition, neutralization, redox reaction, esterification, hydrolysis, dehydration, cracking reaction, increases chain reaction, complex reaction, displacement reaction, disproportionated reaction, catalytic reaction, the reaction of rearrangement reaction class organic or inorganic.

A kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that the process that the described machined material that the auxiliary charged jet of above-mentioned fluidised machined material interface assistance is also comprised make lotus that electric charge be arranged further disperses or stretches under the effect of follow-up active force, follow-up active force comprises electric field action power, the magnetic field active force, fluid force, mechanicals efforts and other comprise heat, the active force of sound, the direction of its direction of follow-up active force and charged jet has certain included angle, angle is between 0～360 degree, electric field and magnetic field and make the charged electric field of fluid coupling make the charged current physical efficiency hard to bear to the specific active force that comprises attraction or repulsion force, to charged fluid have attract or the electric-field intensity of repulsive interaction between 0.1V/ millimeter～1000kV/ millimeter, magnetic field intensity is between 0.001 milli tesla～30 teslas; Follow-up active force can have only a kind of active force, and multiple active force acting in conjunction also can be arranged; Can not comprise in the whole process of preparation, comprise once or once above follow-up active force process.

A kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that utilizing fluid impact that the machined material that forms charged jet is carried out ultra-fineization impact processing; Fluid impact is by other high velocity fluid strikes, stretch, the fluid components that disperses processed material, the fluid that is used for impacting can comprise the composition that can dissolve machined material, also can comprise the composition that can solidify machined material, can also comprise the composition that can carry out chemical reaction or physical reactions with machined material, fluid in the fluid impact can be a gas, liquid, supercritical fluid, plasma, liquid particles is contained in carrying object, solid granulates is contained in carrying object, impact fluid can have the electric charge identical or opposite with the machined material fluid by lotus, also can neutral; Its pressure limit is between 1 atmospheric pressure to 5000 atmospheric pressure, and the speed of impact fluid is between 1.5 mm/second～1000 meter per seconds.

A kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that charged in the electric fluid mechanics method comprises one or more in corona charging, induction charging, contact charging, the charged current bulk charging, and preferably electrode is placed the contact charging method in the machined material container.Electric charge field comprises direct current positive electric field, direct current negative electric field or alternating electric field, makes the charged electric field of fluid between 0.1V/ millimeter～1000kV/ millimeter.

A kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that described gathering-device for collecting drum, collecting conveyer belt, collecting board or collecting pit, can be the wet gathering-device of doing that also can include solvent or steam; The super-fine material of collecting through gathering-device can be unordered, partial order or all orderly; The ultra-fine formed material of collecting gained through gathering-device through or without follow-up acupuncture, water thorn, braiding, heat stick, chemistry sticks, wrap removed a kind of in part composition or the screening step by other material, dissolving or surpass can obtain after a kind of method is handled undersized comprise in solid, nucleocapsid, hollow or cavernous particle or the fiber a kind of or above a kind of particle that super-fine material constituted, fiber, film or block ultra-fine formed material of pattern.

A kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that it is made up of spinneret-free machined material warehousing and transportation facilities, power-assisted generation equipment, charged equipment, collecting device at least.

A kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that machined material can obtain to comprise the ultra-fine grain and the superfine fibre of solid, hollow or nucleocapsid structure by this method.

It is a kind of or surpass a kind of preparation method of super-fine material of function or the coating process of material that a kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that this method is applicable to as having in separation, protection, antibiotic, deodorization, catalysis, sensing, decoration, support structure, bio-compatible, storage, controlled release, conduction, reparation, medical treatment, health care, intelligent response, fragrance, the adhesive function.Prepared super-fine material is applied with particle, fiber, film, cloth or block structure, and the ratio that it accounts in material therefor is between 1%～100%.

Beneficial effect of the present invention:

Thereby can cheap, efficient, high production capacity ground machined material be converted into corresponding super-fine material by will under the situation of spinneret-free, combining and be applied to the jet field with electrostatic force as the lack of balance active force of power-assisted.This method is for the cheapness of super-fine material, generate to use and to have certain facilitation on a large scale.

Description of drawings

Fig. 1 is a spinneret-free machined material sprinkle roller centrifugal force type electric fluid mechanics method system architecture schematic diagram.1 high voltage source 1a is to electrode and gathering-device; The 1b working electrode; 2 electric jets; 3 machined materials; 3a machined material liquid level; 3b machined material sprinkle assembly; The machined material of 3c sprinkle; 4 rollers; 4a roller edge sharp projection; 5 roller rotation directions

Fig. 2 is a spinneret-free machined material roller impact type electric fluid mechanics method system architecture schematic diagram.1 high voltage source 1a is to electrode and gathering-device; The 1b working electrode; 2 electric jets; 3 hold the container of machined material; The 3a machined material, wherein 3a-a is a kind of fluidised machined material, and wherein 3a-b is another fluidised machined material; 3b machined material liquid level; 4 rollers; 4a roller edge sharp projection; 4b is a roller wheel shaft; 5 roller rotation directions.

Fig. 3 spinneret-free rotating disk centrifugal force type electric fluid mechanics method system architecture schematic diagram.1 high voltage source; 1a is to electrode and gathering-device; The 1b working electrode; 2 electric jets; 3 machined materials; 3a machined material liquid level; 4 rotating disks; Guiding groove on the 4a rotating disk; 4b disk edge sharp projection; 5 dial rotation directions

Fig. 4 is a spinneret-free machined material sprinkle needle electrode gravity type electric fluid mechanics method system architecture schematic diagram.1 high voltage source 1a is to electrode and gathering-device; The 1b working electrode; 2 electric jets; 3 machined materials; 3a machined material liquid level; 3b machined material sprinkle assembly; The machined material of 3c sprinkle; The 4a perforated membrane; The 4b wire netting; 4c wire netting below nadel.

Fig. 5 is a spinneret-free machined material sprinkle needle electrode gravity mechanical vibration force convolution electric fluid mechanics method system architecture schematic diagram.1 high voltage source 1a is to electrode and gathering-device; The 1b working electrode; 2 electric jets; 3 machined materials; 3a machined material liquid level; 3b machined material sprinkle assembly; The machined material of 3c sprinkle; The 4a perforated membrane; The 4b wire netting; 4c wire netting below nadel; The 4d mechanical vibrator; 4e mechanical oscillation direction.

Fig. 6 is spinneret-free machined material sprinkle needle electrode and rotating machinery vibrating power convolution electric fluid mechanics method system architecture schematic diagram.1 high voltage source 1a is to electrode and gathering-device; The 1b working electrode; 2 electric jets; 3 machined materials; 3a machined material liquid level; 3b machined material sprinkle assembly; The machined material of 3c sprinkle; 4 rollers; 4a roller edge sharp projection; 4b is a roller wheel shaft; The 5a perforated membrane; The 5b wire netting; 5c wire netting top nadel; 6 roller rotation directions.

The built-in mechanical oscillation formula of Fig. 7 spinneret-free electric fluid mechanics method system architecture schematic diagram.1 high voltage source; 1a is to electrode and gathering-device; The 1b working electrode; 2 electric jets; 3 machined materials; 3a machined material liquid level; 4 mechanical oscillation assemblies; 5 mechanical oscillation power supplys

Fig. 8 spinneret-free external mechanical oscillatory type electric fluid mechanics method system architecture schematic diagram.1 high voltage source; 1a is to electrode and gathering-device; The 1b working electrode; 2 electric jets; 3 machined materials; 3a machined material liquid level; 4 mechanical oscillation assemblies; 5 mechanical oscillation power supplys

The built-in alternating wave generator oscillatory type of Fig. 9 spinneret-free electric fluid mechanics method system architecture schematic diagram.1 high voltage source; 1a is to electrode and gathering-device; The 1b working electrode; 2 electric jets; 3 machined materials; 3a machined material liquid level; 4 wave of oscillation transduction assemblies; 5 wave of oscillation power supplys

Figure 10 spinneret-free air feed bubble blasting type electric fluid mechanics method system architecture schematic diagram.1 high voltage source; 1a is to electrode and gathering-device; The 1b working electrode; 2 electric jets; 3 machined materials; 3a machined material liquid level; 4 bubbles; The bubble of 4a explosion; 5 gas cylinders; 6 gas conduits

The local gasification of Figure 11 spinneret-free bubble blasting type electric fluid mechanics method system architecture schematic diagram.1 high voltage source; 1a is to electrode and gathering-device; The 1b working electrode; 2 electric jets; 3 machined materials; 3a machined material liquid level; 4 bubbles; The bubble of 4a explosion; 5 local vaporization modules; 6 local gasification power supplys

Decompression bubble blasting type electric fluid mechanics method system architecture schematic diagram after the common supercharging of Figure 12 spinneret-free gas and machined material.1 high voltage source; 1a is to electrode and gathering-device; The 1b working electrode; 2 electric jets; 3 machined materials; 3a machined material liquid level; 4 bubbles; The bubble of 4a explosion; The reservoir vessel of 5 machined materials and the common supercharging of gas

Figure 13 spinneret-free ultrasonic wave action type electric fluid mechanics method system architecture schematic diagram.1 high voltage source; 1a is to electrode and gathering-device; The 1b working electrode; 2 electric jets; 3 machined materials; 3a machined material liquid level; 4 ultrasonic wave transducer assemblies; 5 ultrasonic powers

Figure 14 spinneret-free high-velocity fluid gravitative type electric fluid mechanics method system architecture schematic diagram.1 high voltage source; 1a is to electrode and gathering-device; The 1b working electrode; 2 electric jets; 3 machined materials; 3a machined material liquid level; 4 booster pumps; The fluid attitude material of 5 superchargings; 6 high-velocity fluid conduits; 7 high-velocity fluids

Figure 15 spinneret-free high velocity fluid strikes formula electric fluid mechanics method system architecture schematic diagram.1 high voltage source; 1a is to electrode and gathering-device; The 1b working electrode; 2 electric jets; 3 machined materials; 3a machined material liquid level; 4 booster pumps; The fluid attitude material of 5 superchargings; 6 high-velocity fluid conduits; 7 high speed impact fluids

Figure 16 spinneret-free suction type electric fluid mechanics method system architecture schematic diagram.1 high voltage source; 1a is to electrode and gathering-device; The 1b working electrode; 2 electric jets; 3 machined materials; 3a machined material liquid level; 4 vavuum pumps; 5 negative pressure feed-through assemblies

Figure 17 is spinneret-free machined material sprinkle needle electrode gravity type electric fluid mechanics method and the built-in mechanical oscillation formula of spinneret-free electric fluid mechanics method coupling system structural representation.Wherein the assembly of spinneret-free machined material sprinkle needle electrode gravity type electric fluid mechanics method comprises: 1 positive high voltage power supply, and 1a is to electrode and gathering-device; The 1b working electrode; 2 electric jets; 3 machined materials; 3a machined material liquid level; 3b machined material sprinkle assembly; The machined material of 3c sprinkle; The 4a perforated membrane; The 4b wire netting; 4c wire netting below nadel.And the assembly of the built-in mechanical oscillation formula of spinneret-free electric fluid mechanics method comprises 1 ' negative high voltage power source; 1 ' a is to electrode and gathering-device; 1 ' b working electrode; 2 ' the electric jet; 3 ' machined material; 3 ' a machined material liquid level; 4 ' mechanical oscillation assembly; 5 ' mechanical oscillation power supply

Figure 18 is that the two relative impact type electric fluid mechanics methods of roller of the positive negative electric field of spinneret-free machined material prepare microcapsules system architecture schematic diagram.Wherein negative electric field roller impact type electric fluid mechanics method system comprises: 1 negative high voltage power source; 2 electric jets; 3 hold the container of machined material; 3a low viscosity machined material; 3b machined material liquid level; 4 rollers; 4a roller edge sharp projection; 4b is a roller wheel shaft; 5 roller rotation directions.And positive electric field roller impact type electric fluid mechanics method system comprises: 1 ' positive high voltage power supply; 2 ' the electric jet; 3 ' holds the container of machined material; 3 ' a low viscosity machined material; 3 ' b machined material liquid level; 4 ' roller; 4 ' a roller edge sharp projection; 4 ' b is a roller wheel shaft; 5 ' roller rotation direction.Gathering-device is conveyer belt 8 and the collection container 10 that the below is equipped with earth electrode 9.

Figure 19 is that the two relative impact type electric fluid mechanics methods of roller of the positive negative electric field of spinneret-free machined material prepare microfiber bundle system architecture schematic diagram.Wherein negative electric field roller impact type electric fluid mechanics method system comprises: 1 negative high voltage power source; 2 electric jets; 3 hold the container of machined material; 3a high viscosity machined material; 3b machined material liquid level; 4 rollers; 4a roller edge sharp projection; 4b is a roller wheel shaft; 5 roller rotation directions.And positive electric field roller impact type electric fluid mechanics method system comprises: 1 ' positive high voltage power supply; 2 ' the electric jet; 3 ' holds the container of machined material; 3 ' a high viscosity machined material; 3 ' b machined material liquid level; 4 ' roller; 4 ' a roller edge sharp projection; 4 ' b is a roller wheel shaft; 5 ' roller rotation direction.Gathering-device is for running roller in relative rotation 6 and can obtain microfiber bundle 7.

The continuous coating system structural representation of Figure 20 spinneret-free combination roller impact type electric fluid mechanics method.Continuously coating system is made up of the rotation running roller 7 and the earth electrode 8 of the opposite A of electric field and B subsystem, film to be coated 6, control film to be coated.Wherein the A subsystem comprises negative high voltage power source A1; Machined material A3; The many groups roller A4 that is connected with negative high voltage power source.And the B subsystem comprises positive high voltage power supply B1; Machined material B3; The many groups roller B4 that is connected with the positive high voltage power supply.

The specific embodiment

The present invention is further illustrated below in conjunction with drawings and Examples.

Embodiment 1:

Spinneret-free machined material sprinkle roller centrifugal force type electric fluid mechanics method as shown in Figure 1.Machined material is showered on the roller 4 by machined material sprinkle assembly 3b, and the machined material 3c of sprinkle is subjected to centrifugal action power by roller edge sharp projection 4a when roller rotates.Roller is connected to high voltage source 1 as working electrode 1b, electrode and gathering-device 1a are merged.Be subjected to centrifugal force and electrostatic force simultaneously and form electric jet 2 having applied under the situation that high voltage electric field and roller rotate machined material 3, thereby machined material is processed.

Embodiment 2:

Spinneret-free machined material roller impact type electric fluid mechanics method is as shown in Figure 2.Fluidisation machined material 3a is positioned at roller lower reservoir 3 and when roller 4 rotates machined material is attached on the roller, and is subjected to centrifugal action power at roller edge sharp projection 4a place.Roller is connected to high voltage source 1 as working electrode 1b, and electrode and gathering-device 1a are merged.Be subjected to centrifugal force and electrostatic force simultaneously and form electric jet 2 having applied under the situation that high voltage electric field and roller rotate two kinds of machined material 3a-a and 3a-b, thereby two kinds of machined materials are processed simultaneously.

Embodiment 3:

Spinneret-free rotating disk centrifugal force type electric fluid mechanics method system architecture as shown in Figure 3.Fluidisation machined material 3 is directed on the rotating disk 4, thereby the machined material disk edge sharp projection 4b place that arrives along guiding groove 4a on the rotating disk obtains centrifugal force when dial rotation.Rotating disk is connected to high voltage source 1 as working electrode 1b, electrode and gathering-device 1a are merged.Machined material 3 is subjected to centrifugal force and electrostatic force simultaneously and forms electric jet 2 under the situation that has applied high voltage electric field and dial rotation, thereby machined material is processed.

Embodiment 4:

Spinneret-free machined material sprinkle needle electrode gravity type electric fluid mechanics method as shown in Figure 4.Machined material forms spraying liquid 3c by machined material sprinkle assembly 3b and has deposited to the perforated membrane 4a of homogenize gravity effect, and move to by perforated membrane under the gravity effect wire netting 4b below nadel on.Wire netting 4b is connected to high voltage source 1 as working electrode 1b, electrode and gathering-device 1a are merged.Machined material 3 is subjected to gravity and electrostatic force simultaneously and forms electric jet 2 under the situation that has applied high voltage electric field, thereby machined material is processed.

Embodiment 5:

Spinneret-free machined material sprinkle needle electrode gravity vibration convolution electric fluid mechanics method as shown in Figure 5.Machined material forms spraying liquid 3c by machined material sprinkle assembly 3b and has deposited to the perforated membrane 4a of homogenize gravity effect, and is subjected to the gravity effect by perforated membrane to the nadel of the below of wire netting 4b.Perforated membrane and wire netting are subjected to mechanical vibrator 4d control together and make its up-down vibration 4e.Wire netting 4b is connected to high voltage source 1 as working electrode 1b, electrode and gathering-device 1a are merged.Machined material 3 is subjected to gravity, mechanical oscillation active force and electrostatic force simultaneously and forms electric jet 2 under the situation that has applied high voltage electric field, thereby machined material is processed.

Embodiment 6:

Spinneret-free machined material sprinkle needle electrode and rotating machinery vibrating convolution electric fluid mechanics method are as shown in Figure 6.Machined material forms spraying liquid 3c and has deposited to the perforated membrane 5a that active force is vibrated in homogenize by machined material sprinkle assembly 3b, and by perforated membrane to the nadel 5c of the top of wire netting 5b.Perforated membrane and wire netting are subjected to swing roller 4 to rotate its roller pointed tooth 4a that is caused together and beat the mechanical double vibrations 5d of initiation.Wire netting 5b is connected to high voltage source 1 as working electrode 1b, electrode and gathering-device 1a are merged.Machined material 3 is subjected to mechanical oscillation active force and electrostatic force simultaneously and forms electric jet 2 under the situation that has applied high voltage electric field and mechanical oscillation effect, thereby machined material is processed.

Embodiment 7:

The built-in mechanical oscillation formula of spinneret-free electric fluid mechanics method system architecture as shown in Figure 7.Mechanical oscillation assembly 4 is placed machined material 3, under the situation of opening mechanical oscillation power supply 5, the mechanical oscillation assembly vibrates and causes the machined material vibration, and oscillation action power can cause that the part solution interface forms the power-assisted that therefore sharp-pointed jet state can be used as electric fluid mechanics method.High voltage source 1 is connected working electrode 1b places machined material liquid level 3a down electrode and gathering-device 1a to be merged.When opening mechanical oscillation power supply and high voltage source at the same time,, electrostatic force and the acting in conjunction of oscillation action power also and then to machined material process thereby forming electric jet 2.

Embodiment 8:

Spinneret-free external mechanical oscillatory type electric fluid mechanics method system architecture as shown in Figure 8.Mechanical oscillation assembly 4 is placed outside the machined material 3, under the situation of opening mechanical oscillation power supply 5, the mechanical oscillation assembly vibrates and causes the machined material vibration, and oscillation action power can cause that the part solution interface forms the power-assisted that therefore sharp-pointed jet state can be used as electric fluid mechanics method.High voltage source 1 is connected working electrode 1b places machined material liquid level 3a down electrode and gathering-device 1a to be merged.When opening mechanical oscillation power supply and high voltage source at the same time,, electrostatic force and the acting in conjunction of oscillation action power also and then to machined material process thereby forming electric jet 2.

Embodiment 9:

The built-in alternating wave generator oscillatory type of spinneret-free electric fluid mechanics method system architecture as shown in Figure 9.Wave of oscillation transduction assembly 4 is placed among the machined material 3, under the situation of opening wave of oscillation power supply 5, to produce the wave of oscillation in the machined material and cause the machined material vibration, oscillation action power can cause that the part solution interface forms the power-assisted that therefore sharp-pointed jet state can be used as electric fluid mechanics method.High voltage source 1 is connected working electrode 1b places machined material liquid level 3a down electrode and gathering-device 1a to be merged.When opening wave of oscillation power supply and high voltage source at the same time,, electrostatic force and the acting in conjunction of oscillation action power also and then to machined material process thereby forming electric jet 2.

Embodiment 10:

Spinneret-free air feed bubble blasting type electric fluid mechanics method system architecture as shown in figure 10.Gas in the gas cylinder 5 enters machined material 3 by gas conduit 6 and forms bubble 4.After in machined material, introducing bubble, the bubble of machined material inside is because proportion is littler so can be floated on the machined material liquid level 3a than machined material, yet because gravitational effect, floating becomes the weakest part gradually to the bubble top of liquid level, steeping oneself-meeting in the capillary active force therapeutic method to keep the adverse qi flowing downward begins explosion from the top, and in the moment that bubble breaks machined material is produced the lack of balance active force and impels machined material outwards to move.High voltage source 1 is connected working electrode 1b places machined material liquid level 3a down electrode and gathering-device 1a to be merged.When opening air feed source of the gas and high voltage source at the same time,, electrostatic force and the acting in conjunction of bubble blast action power also and then to machined material process thereby forming electric jet 2.

Embodiment 11:

The local gasification of spinneret-free bubble blasting type electric fluid mechanics method system architecture as shown in figure 11.Local vaporization module 5 is placed machined material 3, and after opening local gasification power supply 6, the part material is formed bubble 4 by gasification in the machined material.Machined material liquid level 3a goes up and explosion forms force of explosion owing to bubble can be floated to, and the bubble force of explosion can be used as the power-assisted of electrofluid mechanics method without spinning jet, therefore place machined material liquid level 3a down and after when high voltage source 1 being connected working electrode 1b to electrode and gathering-device 1a merging, when opening local gasification power supply and high voltage source simultaneously, electrostatic force and the acting in conjunction of bubble blast action power can form electric jet 2 and also and then to machined material process.

Embodiment 12:

Decompression bubble blasting type electric fluid mechanics method system architecture as shown in figure 12 after the common supercharging of spinneret-free gas and machined material.After the mixture of gas and machined material is pressurized and from pressurized container 5, be released into another container and reduce pressure, will form the situation that a large amount of bubbles 4 are gushed out.The last also explosion of machined material liquid level 3a that can be floated to another container owing to bubble forms force of explosion, and the bubble force of explosion can be used as the power-assisted of electrofluid mechanics method without spinning jet, therefore place machined material liquid level 3a down and after when high voltage source 1 being connected working electrode 1b to electrode and gathering-device 1a merging, when opening the reservoir vessel switch of machined material and the common supercharging of gas and high voltage source simultaneously, electrostatic force and the acting in conjunction of bubble blast action power can form electric jet 2 and and then machined material be processed.

Embodiment 13:

Spinneret-free ultrasonic wave action type electric fluid mechanics method system architecture as shown in figure 13.Ultrasonic wave transducer assembly 4 is placed among the machined material 3, under the situation of opening ultrasonic power 5, to produce ultrasonic wave in the machined material and make machined material be subjected to the ultrasonic wave active force, this active force can cause that the part solution interface forms the power-assisted that therefore sharp-pointed jet state can be used as electric fluid mechanics method.High voltage source 1 is connected working electrode 1b places machined material liquid level 3a down electrode and gathering-device 1a to be merged.When opening ultrasonic power and high voltage source at the same time,, electrostatic force and the acting in conjunction of ultrasonic wave active force also and then to machined material process thereby forming electric jet 2.

Embodiment 14:

Spinneret-free high-velocity fluid gravitative type electric fluid mechanics method system architecture as shown in figure 14.When behind the fluid attitude material 5 that certain fluid attitude material is formed supercharging by booster pump 4 this material being become high-velocity fluid 7 during by high-velocity fluid conduit 6 ejection.If this high-velocity fluid just in time on machined material liquid level 3a near, high-velocity fluid will drive machined material 3 and move together.High voltage source 1 is connected working electrode 1b places machined material liquid level 3a down electrode and gathering-device 1a to be merged.When opening booster pump and high voltage source at the same time, electrostatic force and the acting in conjunction of high-velocity fluid gravitation can form electric jet 2 and also and then to machined material process.

Embodiment 15:

Spinneret-free high velocity fluid strikes formula electric fluid mechanics method system architecture as shown in figure 15.When behind the fluid attitude material 5 that certain fluid attitude material is formed supercharging by booster pump 4 this material being become high-velocity fluid 7 during by high-velocity fluid conduit 6 ejection.When if this high-velocity fluid impacts machined material liquid level 3a downwards, high-velocity fluid will drive machined material 3 and move together.High voltage source 1 is connected working electrode 1b places machined material liquid level 3a down electrode and gathering-device 1a to be merged.When opening booster pump and high voltage source at the same time, electrostatic force and the acting in conjunction of high velocity fluid strikes power can form electric jet 2 and also and then to machined material process.

Embodiment 16:

Spinneret-free suction type electric fluid mechanics method system architecture as shown in figure 16.When open vavuum pump 4 and by negative pressure feed-through assembly 5 near causing negative pressure above the machined material liquid level 3a, negative pressure will cause machined material 3 and move in the negative pressure feed-through assemblies.With high voltage source 1 connect working electrode 1b place machined material liquid level 3a down and to electrode with gathering-device 1a merging and place in the negative pressure feed-through assembly.When opening vavuum pump and high voltage source at the same time, electrostatic force and the acting in conjunction of suction function power can form electric jet 2 and also and then to machined material process.

Embodiment 17:

Spinneret-free machined material sprinkle needle electrode gravity type electric fluid mechanics method and the built-in mechanical oscillation formula of spinneret-free electric fluid mechanics method coupling system structure are as shown in figure 17.Machined material 3 forms spraying liquid 3c by machined material sprinkle assembly 3b and has deposited to the perforated membrane 4a of homogenize gravity effect, and move to by perforated membrane under the gravity effect wire netting 4b below nadel on.Wire netting 4b is connected to high pressure negative supply 1 as working electrode 1b, electrode and gathering-device 1a are merged.Machined material 3 is subjected to gravity and electrostatic force simultaneously and forms electric jet 2 under the situation that has applied the high pressure negative electric field, thereby machined material is processed.And thereunder, mechanical oscillation assembly 4 ' places machined material 3 ', under the situation of opening mechanical oscillation power supply 5 ', the mechanical oscillation assembly vibrates and causes the machined material vibration, and oscillation action power can cause that the part solution interface forms the power-assisted that therefore sharp-pointed jet state can be used as electric fluid mechanics method.High pressure positive supply 1 ' is connected working electrode 1 ' b places machined material liquid level 3 ' a down electrode and gathering-device 1a to be merged.When opening mechanical oscillation power supply and high voltage source at the same time,, electrostatic force and the acting in conjunction of oscillation action power also and then to machined material process thereby forming electric jet 2 '.Transmit the junction formation of net 1a place by machined material 3 formed super-fine materials, collection transmission net and the compound composite superfine material membrane of super-fine material that machined material 3 ' forms by spinneret-free machined material sprinkle needle electrode gravity type electric fluid mechanics method charged jet 2 that forms and the electric jet 2 ' that passes through the formation of the built-in mechanical oscillation formula of spinneret-free electric fluid mechanics method in collection.

Embodiment 18:

The two relative impact type electric fluid mechanics methods of roller of the positive negative electric field of spinneret-free machined material prepare the microcapsules system architecture as shown in figure 18.Low viscosity fluid machined material 3a i.e. 3% hexamethylene diamine glycerite is positioned at roller lower reservoir 3 and when roller 4 rotates machined material is attached on the roller, and is subjected to centrifugal action power at roller edge sharp projection 4a place.Roller is connected to 20000 volts of negative high voltage power sources 1 as working electrode.Be subjected to centrifugal force and electrostatic force and form electric jet 2 having applied under the situation that high voltage electric field and roller rotate two kinds of machined material 3a, thereby machined material 3a is processed.Its opposite low viscosity fluid machined material 3 ' a promptly 6% adipyl chlorotoluene solution be positioned at roller lower reservoir 3 ' and machined material be attached on the roller during in roller 4 ' rotation, and be subjected to centrifugal action power at roller edge sharp projection 4 ' a place.Roller is connected to 20000 volts of positive high voltage power supplys 1 ' as working electrode.Be subjected to centrifugal force and electrostatic force and form electric jet 2 ' having applied under the situation that positive high voltage electric field and roller rotate machined material 3 ' a, thereby machined material 3 ' a is processed.Electricity jet 2 and electric jet 2 ' aloft meet, and to take place that polycondensation reaction forms with polyamide-66 be that the glycerine of wall material is ultrafine microencapsulated and owing to the electric field action that is subjected to gravity and below earth electrode 9 thereof is settled down on the conveyer belt, at last by transmission in the collection container 10 that arrives.

Embodiment 19:

The two relative impact type electric fluid mechanics methods of roller of the positive negative electric field of spinneret-free machined material prepare the microfiber bundle system architecture as shown in figure 19.High viscosity fluid machined material 3a i.e. 12% mean molecule quantity is the N of 100,000 polyacrylonitrile, N '-dimethyl formamide solution is positioned at roller lower reservoir 3 and when roller 4 rotates machined material is attached on the roller, and is subjected to centrifugal action power at roller edge sharp projection 4a place.Roller is connected to negative high voltage power source 1 as working electrode.Be subjected to centrifugal force and electrostatic force and form electric jet 2 having applied under the situation that high voltage electric field and roller rotate two kinds of machined material 3a, thereby machined material 3a is processed.Its opposite high viscosity fluid machined material 3 ' a promptly 12% mean molecule quantity be the N of 100,000 polyacrylonitrile, N '-dimethyl formamide solution is positioned at roller lower reservoir 3 ' and when roller 4 ' rotates machined material is attached on the roller, and is subjected to centrifugal action power at roller edge sharp projection 4 ' a place.Roller is connected to positive high voltage power supply 1 ' as working electrode.Be subjected to centrifugal force and electrostatic force and form electric jet 2 ' having applied under the situation that positive high voltage electric field and roller rotate machined material 3 ' a, thereby machined material 3 ' a is processed.Electricity jet 2 and electric jet 2 ' aloft meet form the microfiber bundle that combines by the polyacrylonitrile superfine fibre and owing to be subjected to gravity and below running roller 6 thereof downward active force form continuous microfiber bundle 7.

Embodiment 20:

The continuous coating system structure of spinneret-free combination roller impact type electric fluid mechanics method as shown in figure 20.Continuously coating system is made up of the rotation running roller 7 and the earth electrode 8 of the opposite A of electric field and B subsystem, film to be coated 6, control film to be coated.Wherein the A subsystem comprises negative high voltage power source A1; Machined material A3; The many groups roller A4 that is connected with negative high voltage power source.And the B subsystem comprises positive high voltage power supply B1; Machined material B3; The many groups roller B4 that is connected with the positive high voltage power supply.During work, the fluidisation coated media is that machined material adopts the A3 of varnish and adopts the B3 of red paint to be subjected to the centrifugal action power of roller and electrostatic field power simultaneously and form charged jet A2 and B2.Owing to the charged polarity opposite earth electrode 8 that reach between the two of charged jet A2 with B2, charged jet is all coated the one side of the film of being controlled by running roller to be coated successively in the mode of varnish-red paint.Because A and B subsystem have many groups, therefore film to be coated can and form evenly coating with the fast speeds motion.

Claims

1, a kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that may further comprise the steps:

A, at first make the machined material fluidisation;

2, a kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that the fluidisation of machined material comprises dissolving, fusion, evaporation, plasmaization, pulverizing becomes machined material to comprise the gaseous state of phase homogeneous or the non-homogeneous of phase, liquid, supercritical fluid, plasma state, contain the highdensity composition of relative main fluid composition in the fluid as carrying object and comprise that solid granulates is contained in carrying object, liquid particles is contained in carrying object and contains the low-density composition of relative main fluid composition comprise gaseous state in interior fluid form and the fluid as carrying object, the plasma state material is contained in than gaseous state, the plasma state material density is high comprises liquid state, the carrying object of supercritical fluid.For can not by dissolving, fusion, evaporation, distillation, plasmaization, the fluidised machined material of pulverizing then by use can fluidisation and can by chemical reaction or physical effect before interface assistance type spinneret-free electrofluid mechanics method is handled or in the process or the method for back generation machined material or reaction intermediate make the machined material fluidisation.

3, a kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that power-assisted passes through the amount of force of the non-electrostatic interaction that influences jet and/or the inconsistent approach of direction that three kinds of lack of balance active forces are initial jet boundary place diverse location and realize:

Power-assisted described here comprise centrifugal force, gravity, vibration active force, except that vertical direction magnetic field to magnetic fluid Free Surface disturbance effect formed perpendicular to the oscillation action power the sharp-pointed nadel effect on top layer, bubble force of explosion, ultrasonication power, high-velocity fluid gravitation, high velocity fluid strikes power, negative pressure gravitation, and other can produce a kind of in active force of lack of balance effect or surpass a kind of.And vertical direction magnetic field to magnetic fluid Free Surface disturbance effect formed sharp-pointed nadel effect perpendicular to the top layer can select for use and combine with other power-assisted and form power-assisted jointly.

4, a kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that making above-mentioned fluidised machined material by destaticing active force and available vertical direction magnetic field to also comprising motion control, temperature control, the proterties control of charged fluid and then make process optimization in the formed process that forms charged jet perpendicular to the power-assisted outside the sharp-pointed nadel effect on top layer of magnetic fluid Free Surface disturbance effect, it is characterized in that:

The control of A, movement locus promptly comprises that to charged fluid or fluid accelerations, decelerations, dispersion, focusing, orientation, scope are controlled at interior movement locus and control by electric field, magnetic field, sound field, mechanicals efforts.When movement locus need be rotated control during for helical form.Rotation control comprises rotating electric field control, rotating excitation field technology and swing-around trajectory control, and the frequency of rotating electric field, rotating excitation field is between 10 ^-3Hz～10 ⁹Hz.

The control of B, motor pattern is that the fluidisation machined material forms sub-thread in the mode of spinneret-free or surpasses the jet motion of sub-thread after being subjected to electric field action power and power-assisted.When adopting above the sub-thread jet, different jets are arranged arbitrarily as required in four-dimensional spacetime.Different jets can spray same material, also can be different materials, can also be the part identical materials.Different jets can be with identical electric charge, also can be with opposite electric charge, and can also neutral.The spinneret-free jet can form composite charged jet with being combined by the jet that spinning head carried out that contains optional geometry nozzle.Different materials in the different strand jets can not react mutually, chemical reaction or physical effect can take place yet.

D, the control of motion active force comprise adopts mechanicals efforts to comprise that one or more active forces in pressure, thrust, pulling force, centrifugal force, centripetal force, acoustic force, other fluid force and gravity, electric field action power, the magnetic field active force move with suitable track and pattern with the control fluid.

5, a kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that the process that the described machined material that the auxiliary charged jet of above-mentioned fluidised machined material interface assistance is also comprised make lotus that electric charge be arranged further disperses or stretches under the effect of follow-up active force, follow-up active force comprises electric field action power, the magnetic field active force, fluid force, mechanicals efforts and other comprise heat, the active force of sound, the direction of its direction of follow-up active force and charged jet has certain included angle, angle is between 0～360 degree, electric field and magnetic field and make the charged electric field of fluid coupling make the charged current physical efficiency hard to bear to the specific active force that comprises attraction or repulsion force, to charged fluid have attract or the electric-field intensity of repulsive interaction between 0.1V/ millimeter～1000kV/ millimeter, magnetic field intensity is between 0.001 milli tesla～30 teslas; Follow-up active force can have only a kind of active force, and multiple active force acting in conjunction also can be arranged; Can not comprise in the whole process of preparation, comprise once or once above follow-up active force process.

6, a kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that utilizing fluid impact that the machined material that forms charged jet is carried out ultra-fineization impact processing; Fluid impact is by other high velocity fluid strikes, stretch, the fluid components that disperses processed material, the fluid that is used for impacting can comprise the composition that can dissolve machined material, also can comprise the composition that can solidify machined material, can also comprise the composition that can carry out chemical reaction or physical reactions with machined material, fluid in the fluid impact can be a gas, liquid, supercritical fluid, plasma, liquid particles is contained in carrying object, solid granulates is contained in carrying object, impact fluid can have the electric charge identical or opposite with the machined material fluid by lotus, also can neutral; Its pressure limit is between 1 atmospheric pressure to 5000 atmospheric pressure, and the speed of impact fluid is between 1.5 mm/second～1000 meter per seconds.

7, a kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that described gathering-device for collecting drum, collecting conveyer belt, collecting board or collecting pit, can be the wet gathering-device of doing that also can include solvent or steam; The super-fine material of collecting through gathering-device can be unordered, partial order or all orderly; The ultra-fine formed material of collecting gained through gathering-device through or without follow-up acupuncture, water thorn, braiding, heat stick, chemistry sticks, wrap removed a kind of in part composition or the screening step by other material, dissolving or surpass can obtain after a kind of method is handled undersized comprise in solid, nucleocapsid, hollow or cavernous particle or the fiber a kind of or above a kind of particle that super-fine material constituted, fiber, film or block ultra-fine formed material of pattern.

8, a kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that charged in the electric fluid mechanics method comprises one or more in corona charging, induction charging, contact charging, the charged current bulk charging, and preferably electrode is placed the contact charging method in the machined material container.Electric charge field comprises direct current positive electric field, direct current negative electric field or alternating electric field, makes the charged electric field of fluid between 0.1V/ millimeter～1000kV/ millimeter.

9, a kind of interface assistance type spinneret-free electrofluid mechanics method is characterized in that it is made up of spinneret-free machined material warehousing and transportation facilities, power-assisted generation equipment, charged equipment, collecting device at least.

10, to it is characterized in that this method is applicable to as having in separation, protection, antibiotic, deodorization, catalysis, sensing, decoration, support structure, bio-compatible, storage, controlled release, conduction, reparation, medical treatment, health care, intelligent response, fragrance, the adhesive function a kind of or surpass a kind of preparation method of super-fine material of function or the coating process of material for a kind of interface assistance type spinneret-free electrofluid mechanics method.Prepared super-fine material is applied with particle, fiber, film, cloth or block structure, and the ratio that it accounts in material therefor is between 1%～100%.