CN1686926A - Method for preparing laminar oxide material of lithium, cobalt, nickel and manganese through solid phase reaction in low heat - Google Patents
Method for preparing laminar oxide material of lithium, cobalt, nickel and manganese through solid phase reaction in low heat Download PDFInfo
- Publication number
- CN1686926A CN1686926A CNA2005100116761A CN200510011676A CN1686926A CN 1686926 A CN1686926 A CN 1686926A CN A2005100116761 A CNA2005100116761 A CN A2005100116761A CN 200510011676 A CN200510011676 A CN 200510011676A CN 1686926 A CN1686926 A CN 1686926A
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- lico
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- lithium
- solid phase
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- 238000000034 method Methods 0.000 title claims abstract description 24
- 239000000463 material Substances 0.000 title claims abstract description 22
- 238000003746 solid phase reaction Methods 0.000 title claims abstract description 13
- 239000011572 manganese Substances 0.000 title claims description 29
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims description 27
- 229910052748 manganese Inorganic materials 0.000 title abstract description 7
- 229910052759 nickel Inorganic materials 0.000 title abstract description 5
- 229910052744 lithium Inorganic materials 0.000 title description 5
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title description 4
- 229910017052 cobalt Inorganic materials 0.000 title description 2
- 239000010941 cobalt Substances 0.000 title description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title description 2
- 238000002360 preparation method Methods 0.000 claims abstract description 19
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910012735 LiCo1/3Ni1/3Mn1/3O2 Inorganic materials 0.000 claims abstract description 7
- 238000001291 vacuum drying Methods 0.000 claims abstract description 5
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 14
- 229910013733 LiCo Inorganic materials 0.000 claims description 11
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 8
- 206010037660 Pyrexia Diseases 0.000 claims description 7
- 239000012467 final product Substances 0.000 claims description 6
- KFDQGLPGKXUTMZ-UHFFFAOYSA-N [Mn].[Co].[Ni] Chemical compound [Mn].[Co].[Ni] KFDQGLPGKXUTMZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000000498 ball milling Methods 0.000 claims description 5
- 235000006408 oxalic acid Nutrition 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000000047 product Substances 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- 238000002156 mixing Methods 0.000 abstract description 10
- 229910001416 lithium ion Inorganic materials 0.000 abstract description 8
- 239000002243 precursor Substances 0.000 abstract 3
- 229910012652 LiCo1 Inorganic materials 0.000 abstract 1
- 150000001242 acetic acid derivatives Chemical class 0.000 abstract 1
- 239000007772 electrode material Substances 0.000 abstract 1
- 238000000227 grinding Methods 0.000 abstract 1
- GLXDVVHUTZTUQK-UHFFFAOYSA-M lithium;hydroxide;hydrate Chemical compound [Li+].O.[OH-] GLXDVVHUTZTUQK-UHFFFAOYSA-M 0.000 abstract 1
- 238000007599 discharging Methods 0.000 description 10
- 238000009413 insulation Methods 0.000 description 10
- 238000010792 warming Methods 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 239000007791 liquid phase Substances 0.000 description 8
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000000975 co-precipitation Methods 0.000 description 5
- 239000007774 positive electrode material Substances 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- 238000011161 development Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000005245 sintering Methods 0.000 description 4
- 238000010671 solid-state reaction Methods 0.000 description 4
- 229910014689 LiMnO Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 235000011837 pasties Nutrition 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000010532 solid phase synthesis reaction Methods 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910003548 Li(Ni,Co,Mn)O2 Inorganic materials 0.000 description 2
- 229910013716 LiNi Inorganic materials 0.000 description 2
- 239000010405 anode material Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229910012820 LiCoO Inorganic materials 0.000 description 1
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 1
- 241000080590 Niso Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 239000006258 conductive agent Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- XIXADJRWDQXREU-UHFFFAOYSA-M lithium acetate Chemical compound [Li+].CC([O-])=O XIXADJRWDQXREU-UHFFFAOYSA-M 0.000 description 1
- 229910002102 lithium manganese oxide Inorganic materials 0.000 description 1
- VLXXBCXTUVRROQ-UHFFFAOYSA-N lithium;oxido-oxo-(oxomanganiooxy)manganese Chemical compound [Li+].[O-][Mn](=O)O[Mn]=O VLXXBCXTUVRROQ-UHFFFAOYSA-N 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- AIYYMMQIMJOTBM-UHFFFAOYSA-L nickel(ii) acetate Chemical compound [Ni+2].CC([O-])=O.CC([O-])=O AIYYMMQIMJOTBM-UHFFFAOYSA-L 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 238000003836 solid-state method Methods 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000000967 suction filtration Methods 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910006290 γ-MnOOH Inorganic materials 0.000 description 1
Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Battery Electrode And Active Subsutance (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2005100116761A CN1269242C (en) | 2005-04-30 | 2005-04-30 | Method for preparing laminar oxide material of lithium, cobalt, nickel and manganese through solid phase reaction in low heat |
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CNB2005100116761A CN1269242C (en) | 2005-04-30 | 2005-04-30 | Method for preparing laminar oxide material of lithium, cobalt, nickel and manganese through solid phase reaction in low heat |
Publications (2)
Publication Number | Publication Date |
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CN1686926A true CN1686926A (en) | 2005-10-26 |
CN1269242C CN1269242C (en) | 2006-08-09 |
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CNB2005100116761A Expired - Fee Related CN1269242C (en) | 2005-04-30 | 2005-04-30 | Method for preparing laminar oxide material of lithium, cobalt, nickel and manganese through solid phase reaction in low heat |
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CN (1) | CN1269242C (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1330602C (en) * | 2006-02-28 | 2007-08-08 | 济宁市无界科技有限公司 | Lithium ion cell blended positive pole material and its preparing method |
CN102163709A (en) * | 2011-03-09 | 2011-08-24 | 合肥工业大学 | Cobalt nickel manganese lithium oxide-cooper oxide compound positive material for lithium ion battery and preparation method thereof |
CN101677125B (en) * | 2008-09-16 | 2013-07-10 | 中国科学院福建物质结构研究所 | Method for preparing layered cathode material of lithium ion battery |
CN104362329A (en) * | 2014-09-18 | 2015-02-18 | 长沙矿冶研究院有限责任公司 | Method for preparing lithium-rich manganese-based layered lithium battery cathode material based on efficient solid-phase chemical complexation reaction |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102064317B (en) * | 2009-11-13 | 2014-11-19 | 深圳市比克电池有限公司 | LiFe1-xMxPO4 compound containing carbon element and preparation method thereof |
-
2005
- 2005-04-30 CN CNB2005100116761A patent/CN1269242C/en not_active Expired - Fee Related
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1330602C (en) * | 2006-02-28 | 2007-08-08 | 济宁市无界科技有限公司 | Lithium ion cell blended positive pole material and its preparing method |
CN101677125B (en) * | 2008-09-16 | 2013-07-10 | 中国科学院福建物质结构研究所 | Method for preparing layered cathode material of lithium ion battery |
CN102163709A (en) * | 2011-03-09 | 2011-08-24 | 合肥工业大学 | Cobalt nickel manganese lithium oxide-cooper oxide compound positive material for lithium ion battery and preparation method thereof |
CN102163709B (en) * | 2011-03-09 | 2013-01-09 | 合肥工业大学 | Cobalt nickel manganese lithium oxide-cooper oxide compound positive material for lithium ion battery and preparation method thereof |
CN104362329A (en) * | 2014-09-18 | 2015-02-18 | 长沙矿冶研究院有限责任公司 | Method for preparing lithium-rich manganese-based layered lithium battery cathode material based on efficient solid-phase chemical complexation reaction |
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Publication number | Publication date |
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CN1269242C (en) | 2006-08-09 |
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Owner name: SHENZHEN TIANJIAO TECHNOLOGY DEVELOPMENT CO., LTD. Free format text: FORMER OWNER: BEIJING UNIVERSITY OF SCIENCE AND TECHNOLOGY Effective date: 20100524 |
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Free format text: CORRECT: ADDRESS; FROM: 100083 NO.30 XUEYUAN ROAD, HAIDIAN DISTRICT, BEIJING TO: 518119 2/F, BUILDING A28, BENKANG INDUSTRIAL DISTRICT, KUIYONG STREET, LONGGANG DISTRICT, SHENZHEN CITY |
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Effective date of registration: 20100524 Address after: 2, building 518119, A28 building, Ben Kang Industrial Zone, Kwai Chung street, Longgang District, Shenzhen Patentee after: Tianjiao Tech Development Co., Ltd., Shenzhen City Address before: 100083 Haidian District, Xueyuan Road, No. 30, Patentee before: University of Science and Technology Beijing |
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Effective date of registration: 20190428 Address after: 276000 Yan'an Road 119, Linyi Economic and Technological Development Zone, Shandong Province Patentee after: Shandong Tianjiao new energy Co. Ltd. Address before: 518119 2nd Floor, Building A28, Pengkang Industrial Zone, Kuiyong Street, Longgang District, Shenzhen Patentee before: Tianjiao Tech Development Co., Ltd., Shenzhen City |
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Granted publication date: 20060809 Termination date: 20200430 |
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CF01 | Termination of patent right due to non-payment of annual fee |