Background technology
Known in the past motor is with magnet rotor (for example opening flat 07-79537 communique with reference to the spy), at yoke outer peripheral face as the drum of magnetic, utilize a plurality of permanent magnets of heat-curing type adhesive securement according to each utmost point in the axis direction connection, make this a series of permanent magnet separate predetermined distance and arrange, constitute multipole magnetic pole at circumferencial direction.
The adhesive linkage between yoke and permanent magnet that utilizes above-mentioned bonding agent to constitute, because the heating of the motor when environment and running are set, typical temperature is changing in-40 ℃~+ 100 ℃ left and right sides scopes approximately, at a high speed, in the big capacity motor, ceiling temperature reaches+140 ℃.In addition, the anisotropy of magnet is the direction vertical with bonding plane, and the direction vertical with anisotropy (the periphery direction of yoke) obtained negative coefficient of linear expansion.
In above-mentioned magnet rotor, the spring rate of bonding agent reduces under abominable temperature environment, exists shear bond strength and stretching adhesive strength to reduce, the problem that the reliability of bonding agent reduces.
And, moment of torsion and centrifugal force during owing to rotation, adhesive linkage is easy to generate micro-strain, thereby exists the motor characteristics problem of unstable.
And, because permanent magnet, adhesive linkage are different with yoke coefficient of linear expansion separately, so produce thermal stress respectively owing to variations in temperature, but when the spring rate of adhesive linkage uprises, it is big that the thermal stress of adhesive linkage becomes, and at the interface bonding that therefore exists adhesive linkage and permanent magnet peeled off, permanent magnet produces problems such as fracture.
And, when the spring rate of adhesive linkage uprises, exist and make motor bear problem thus from the corresponding reduction of resistance to impact of the impact of outside.
And, when solidifying, bonding agent to the process that solid changes, produces volume contraction from liquid, but when bonding agent produces cure shrinkage, apply the power of compression direction at the bonding plane of permanent magnet, bonding agent is then accepted the power of draw direction from permanent magnet, under the identical situation of the spring rate of bonding agent, cure shrinkage is big more, and curing shrinkage internal stress applies big more power at compression direction to the bonding plane of permanent magnet.After bonding agent solidified, because the variations in temperature of motor, bonding agent was also flexible, so the compression stress of following the temperature rising to be applied to the bonding plane of permanent magnet reduces, final tensile force acts on permanent magnet, and under the situation that temperature reduces, the compression stress at permanent magnet increases on the contrary.And under the excessive situation of cure shrinkage, in the serviceability temperature scope of motor, it is big that tensile force or compression stress become, and at the interface bonding that exists adhesive linkage and permanent magnet peeled off, permanent magnet produces the problem of fracture.
Embodiment
Below, with reference to description of drawings preferred implementation of the present invention, but in execution mode, same parts, position or corresponding component, position are given prosign and described.
Fig. 1 is the stereogram of motor of the present invention with magnet rotor, and this motor is assemblied on the motor of elevator traction machine with magnet rotor.
This motor has with magnet rotor: the yoke 1 that is made of the magnetic of drum; At the outer peripheral face of this yoke 1, at axis direction and separate a plurality of permanent magnets 2 of the arranged spaced of regulation at circumferencial direction; And by this permanent magnet 2 is bonded in the adhesive linkage 3 that the room temperature curing type bonding agent on the yoke 1 constitutes.This permanent magnet 2 is sheet neodymium sintered magnets (Nd-Fe-B).
This motor moment of torsion of the adhesive linkage 3 of magnet rotor according to motor needs to have the shear bond strength more than the 3MPa in-40 ℃~140 ℃ whole temperature province.
The application's inventor has investigated the characteristic that constitutes the room temperature curing type bonding agent of adhesive linkage 3 by carrying out thermal cycling test etc.
Below, various embodiments of the present invention are described.
Embodiment 1
Bonding agent of the present invention is that the dual liquid type modified acroleic acid is bonding agent (being called the invention bonding agent later on), its constituent of table 1 expression.In addition, though not shown in this table 1, as curing catalysts, added the cumene hydroperoxide of necessary amount to A reagent, added the acetylacetone,2,4-pentanedione vanadyl of necessary amount to B reagent.
Table 1
The composition title |
A reagent |
B reagent |
Acrylonitrile-butadiene rubber methyl methacrylate-butadiene-styrol copolymer |
15% |
15% |
Methyl methacrylate |
40% |
40% |
2-hydroxyethyl methacrylate |
15% |
15% |
Double cyclopentenyl oxygen ethyl-methyl acrylate |
10% |
10% |
Methacrylic acid |
15% |
15% |
The acrylic compounds oligomer |
5% |
5% |
The A reagent of biliquid and the biliquid proportioning of B reagent are 1: 1.
At thickness is on the iron block of 30mm, the side by side wide 22mm that makes by sheet neodymium sintered magnet (Nd-Fe-B) of configuration 10 (length overall 500mm), the test film of long 50mm, thick 6mm on its length direction, use the invention bonding agent under room temperature (23 ℃~25 ℃) temperature conditions, to place 24 hours, make curing, bonding.
Then, respectively after placing 2 hours under-40 ℃ of environment, make test film ambient temperature rise to 140 ℃ with 2 hours, placement 2 hours under 140 ℃ of environment then.Afterwards, made ambient temperature drop to-40 ℃ again with 2 hours from 140 ℃.This as a circulation, is added up to and carry out 300 circulations, the test film that uses the invention bonding agent is observed.
In this thermal cycling test, do not produce bonding the peeling off at the interface of fracture, adhesive linkage and the test film of test film.
The relation of the spring rate when in addition, the present application person has measured temperature and this temperature to the foregoing invention bonding agent.Fig. 2 is the performance plot of this moment.
According to this figure, under the use lower limit temperature of motor was-40 ℃, the spring rate E of invention bonding agent was 4 * 10
9Pa, under the SC service ceiling temperature of motor was 140 ℃, the spring rate E of invention bonding agent was 3.8 * 10
8Pa distinguishes that spring rate E reduces with the rising of temperature.And the cure shrinkage of this invention bonding agent under 23 ℃~25 ℃ is 13%.
The relation of shear bond strength τ when in addition, the application's inventor has measured spring rate E and this spring rate E to described invention bonding agent.When carrying out this mensuration, the invention bonding agent was placed 24 hours under room temperature (23 ℃~25 ℃) temperature conditions, test film is bonded on the iron block.And, use the pull-up universal testing machine of A Musi that the test film that is bonded on the iron block is applied weighing load, measured the shear bond strength of bonding agent.
Fig. 3 is the performance plot of this moment.In this Fig. 3, shear bond strength τ increases with the increase of the spring rate E of invention bonding agent, is 1 * 10 at spring rate E
8Pa~7 * 10
9During the Pa scope, shear bond strength τ is between the relational expression (line of formula among the figure (2)) of the relational expression (line of formula among the figure (1)) of lg τ=0.477lgE-2.816 and lg τ=0.477lgE-3.339.
; according to the moment of torsion of motor, in-40 ℃~140 ℃ whole temperature province, need the above shear bond strength of 3MPa; so promptly under 140 ℃, need guarantee the shear bond strength that 3MPa is above in the higher limit of this temperature province of the lower limit of expression shear bond strength.
Bonding agent of the present invention as shown in Figure 2, the spring rate E during this temperature is 3.8 * 10
8Pa, and according to Fig. 3, the shear bond strength that is equivalent to this spring rate E is more than the 3MPa, can guarantee sufficient shear bond strength so distinguish the whole temperature province (40 ℃~140 ℃) in the serviceability temperature scope of motor.
Like this,,, distinguish that the bonding agent at the interface of fracture, adhesive linkage and the test film that can not produce test film is peeled off, and guarantee the shear bond strength of required abundance durable in use in the serviceability temperature zone of motor using under the situation of bonding agent of the present invention.
Embodiment 2
As the 1st bonding agent, the amount of the methacrylic acid of the composition of invention bonding agent shown in the adjustment form 1 has been made bonding agent in 5%~25% scope, so that this bonding agent is when temperature is-40 ℃, the spring rate of bonding agent is 1 * 10
8Pa~7 * 10
9In the Pa scope, in the time of 140 ℃, the spring rate of bonding agent is 1 * 10
8Pa~2 * 10
9In the Pa scope, in the time of-40 ℃~140 ℃, the lower limit 1 * 10 of the spring rate of described bonding agent when connecting-40 ℃
8 Lower limit 1 * 10 when Pa and 140 ℃
8The straight line of Pa, the higher limit 7 * 10 when being connected-40 ℃
9 Higher limit 2 * 10 when Pa and 140 ℃
9In the zone between the straight line of Pa.At this moment, the cure shrinkage of the 1st bonding agent under 23 ℃~25 ℃ temperature is in 8%~15% scope.
As the 2nd bonding agent, the amount that makes the methacrylic acid of the bonding agent of invention shown in the table 1 composition is more than the 25 weight %, and the spring rate E that has made bonding agent is 7 * 10 in the time of-40 ℃
9Pa is above, in the time of 140 ℃, be 2 * 10
9The bonding agent that Pa is above.At this moment, the cure shrinkage of the 2nd bonding agent under 23 ℃~25 ℃ temperature is in 8%~15% scope.
As the 3rd bonding agent, the amount that makes the methacrylic acid of the bonding agent of invention shown in the table 1 composition is below the 5 weight %, and the spring rate E that has made bonding agent is 1 * 10 when-40 ℃ and 140 ℃
8The bonding agent that Pa is following.At this moment, the cure shrinkage of the 3rd bonding agent under 23 ℃~25 ℃ temperature is in 8%~15% scope.
And, the 1st bonding agent~the 3rd bonding agent has been carried out and the identical thermal cycling test of embodiment 1 described bonding agent.
In addition, about the 1st bonding agent~the 3rd bonding agent, under room temperature (23 ℃~25 ℃) temperature conditions, placed 24 hours, it is bonding that test film is solidified on iron block, then under 140 ℃ of atmosphere temperatures, use the pull-up universal testing machine of A Musi that the test film that is bonded on the iron block is applied weighing load, measured the shear bond strength of bonding agent.
As a result, the 1st bonding agent does not produce bonding peeling off at the interface bonding agent and permanent magnet, and permanent magnet also produces fracture.And the shear bond strength under 140 ℃ of atmosphere temperatures can be guaranteed more than the 3MPa in measuring.
The 2nd bonding agent is bonding the peeling off of generation at the interface of bonding agent and permanent magnet.
The 3rd bonding agent does not produce bonding peeling off at the interface bonding agent and permanent magnet, and permanent magnet also produces fracture.But the shear bond strength under 140 ℃ of atmosphere temperatures is lower than 3MPa in measuring.
Distinguish that according to the foregoing description the 1st bonding agent can be used for the magnet rotor of the motor of traction machine, but the 2nd bonding agent and the 3rd bonding agent are not suitable for.
Embodiment 3
As the 1st bonding agent, use the bonding agent identical with the 1st bonding agent of embodiment 2.
As the 2nd bonding agent, using the spring rate E of bonding agent is 4.0 * 10 in the time of-40 ℃
9Pa, in the time of 140 ℃, be 1.3 * 10
9Cure shrinkage when Pa and 23 ℃ is 3% bonding agent (Mitsui Chemicals (strain) system EH455).
As the 3rd bonding agent, having made spring rate E is 4 * 10 in the time of-40 ℃
9Pa, in the time of 140 ℃, be 1.1 * 10
8Pa, and the amount of the methyl methacrylate of invention bonding agent composition shown in the increase table 1, the cure shrinkage in the time of 23 ℃ is 16% bonding agent.
And, the 1st bonding agent~the 3rd bonding agent has been carried out and the identical thermal cycling test of embodiment 1 described bonding agent.
As a result, the 1st bonding agent is as described in the embodiment 2, bonding agent and permanent magnet do not produce bonding peeling off at the interface, permanent magnet also produces fracture.
The 2nd bonding agent is bonding the peeling off of generation at the interface of bonding agent and permanent magnet.The bonding agent that uses among this bonding agent and the embodiment 1,2 is compared, and cure shrinkage reduces, and curing shrinkage internal stress shown in Figure 4 (the arrow ィ among Fig. 4) reduces, that is, the oblique line integral body among the figure moves downwards.Therefore think at high temperature that bonding agent imposes on bonding agent when expanding compression stress increases, the result produces above-mentioned bonding peeling off.
The 3rd bonding agent is bonding the peeling off of generation at the interface of bonding agent and permanent magnet.The bonding agent that uses among this bonding agent and the embodiment 1,2 is compared, and cure shrinkage increases, and curing shrinkage internal stress shown in Figure 4 (the arrow ィ among Fig. 4) increases, that is, the oblique line integral body among the figure is moved upward.Therefore think at low temperatures that bonding agent imposes on bonding agent when shrinking tensile stress increases, the result has produced above-mentioned bonding peeling off.
On the other hand, in the present embodiment, the cure shrinkage when the 1st bonding agent uses 23 ℃ is 8%~15% bonding agent, and act on the stress approximate zero of adhesive linkage this moment as shown in Figure 4 when the medium temperature of serviceability temperature is 50 ℃.Promptly, in Fig. 4, follow the cure shrinkage of bonding agent, shown in arrow ィ, produce stress at adhesive linkage, in temperature when this room temperature descends, stress rises according to the arrow Ha, when this room temperature rose, stress reduced according to the arrow mouth in temperature, and the stress that promptly acts on adhesive linkage in the medium temperature of serviceability temperature 50 ℃ the time is almost nil.
In addition, under the situation of using the little bonding agent of spring rate and coefficient of linear expansion, the preferred consolidation shrinkage is bigger, and under the situation of using the big bonding agent of spring rate and coefficient of linear expansion, the preferred consolidation shrinkage is less.
In addition, about being the proportioning of bonding agent, having illustrated that as an example ratio of A reagent, B reagent is 1: 1 a situation, but can in 2: 1~1: 2 scope, be applied at the dual liquid type modified acroleic acid shown in each embodiment.
And, about permanent magnet the neodymium sintered magnet has been described, but has been not limited thereto certainly, for example also can use neodymium, iron, boron based magnet, samarium, cobalt based magnet, ferrite based magnet.
And this invention bonding agent is not limited to the motor of elevator traction machine, can certainly be applicable to the identical motor of motor of environment for use and elevator traction machine.
As mentioned above, the present invention can be used as the motor magnet rotor of motor serviceability temperature traction machine in-40 ℃~140 ℃ scopes, for example elevator, and can prevent bonding peeling off and the permanent magnet fracture, and has sufficient adhesive strength.