CN1659964A - Combination I of killing insects and acarids prepared from benzoate of abanmectin in methylamine group - Google Patents
Combination I of killing insects and acarids prepared from benzoate of abanmectin in methylamine group Download PDFInfo
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- CN1659964A CN1659964A CN 200410056845 CN200410056845A CN1659964A CN 1659964 A CN1659964 A CN 1659964A CN 200410056845 CN200410056845 CN 200410056845 CN 200410056845 A CN200410056845 A CN 200410056845A CN 1659964 A CN1659964 A CN 1659964A
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- insecticides
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Abstract
An insecticide composition for killing insect and mite contains at least one specific insect growth regulator, biologic source, nereistoxin, organic phosphorus, pyrethroid and/or other insecticides, and methylamino abamectin benzoate (4''-methylamino-4''-deoxyabamectin B1 benzoate).
Description
The present invention relates to desinsection, miticide composition that emamection benaoate and specificity insect growth regulator, IGR, biogenic, nereistoxin, organic phosphor, pyrethroid and/or other insecticides are formed.
Emamection benaoate is from fermented product Avermectin B
1A kind of novel semi-synthetic insecticide of beginning, it is high to the larva activity of lepidopterous insects, mainly is stomach poison function, has action of contace poison concurrently.Emamection benaoate can be penetrated into the epidermis of target crop, forms the storage layer of an active ingredient, thereby long-term residual effect can be arranged.If make composition with specificity insect growth regulator, IGR, biogenic, nereistoxin, organic phosphor, pyrethroid and/or other insecticides, their insecticidal effect can have significantly to be increased, they are better to the compatibility of environment, simultaneously can also alleviate the pesticide resistance of insect, reduce farmer's burdens.
The specificity insect growth regulator, IGR, biogenic, nereistoxin, organic phosphor, pyrethroid and/or the other insecticides example that are applicable to composition of the present invention are as follows:
(A) specificity insect growth regulator, IGR insecticide
1, the young urea (Chlorbenzuron) that goes out
2, desinsection grand (triflumuron)
3, Teflubenzuron (teflubenzuron)
4, fluorine bell urea (hexatlumuron)
5, diflubenzuron (diflubenzuron)
6, flucycloxuron (flucycloxuron)
7, ring worm hydrazides (chromafenozide)
8, flufenoxuron (flufenoxurom)
9, methoxyfenozide (methoxyfenozide)
10, worm hydrazides (tebufenozide)
(B) biological source insecticide
1, bacillus thuringiensis,Bt (Bacullus thuringiensis)
2, Avermectin (abamectin)
(C) nereistoxin insecticide
1, desinsection list
2, dimehypo (dimthypo)
(D) organophosphorus insecticide
1, Hostathion (Triazophos)
2, chlopyrifos (chlorpyrifos)
(E) pyrethroid insectide
1, decis (deltamethrin)
2, sumicidin (fenvalerate)
3, cyfloxylate (cyfluthrin)
4, gamma cyhalothrin (lambdacyhalothrin)
5, cypermethrin (cypermethrin)
6, beta-cypermethrin
(F) other insecticides
1, chlorfenapyr (chlorfenapyr)
2, Imidacloprid (imidacloprid)
3, fluorine worm nitrile (fipronil)
The common name that provides in A, B, C, D, E and the F group compound of representing to have following IUPAC title in the above:
(A) specificity insect growth regulator, IGR
(1) adjacent chlorobenzene formacyl-3-(4-chlorphenyl) urea of 1-;
(2) 1-2 (2-chlorobenzene formacyl)-3-(4-Trifluoromethoxyphen-l) urea;
(3) N-(3,5-two chloro-2,4-difluorophenyl)-N '-(2,6-two fluorobenzoyl) urea;
(4) 1-[3,5-two chloro-4-(1,1,2,2-tetrafluoro ethyoxyl) phenyl]-3-(2, the 6-difluoro benzoyl) urea;
(5) 1-(4-chlorphenyl)-3-(2, the 6-difluoro benzoyl) urea;
(6) 1-[α-(the amino oxygen of 4-chloro-α-cyclopropyl benzal) is right-tolyl]-3-(2, the 6-difluoro benzoyl) urea;
(7) 2 '-tert-butyl groups-5-methyl-2 '-(3, the 5-dimethylbenzoyl) chroman-6-formylhydrazine;
(8) 1-[4-(α-three fluoro-is to toloxyl for 2-chloro-α, α)-2 fluorophenyls]-3-(2,6-two fluorobenzoyl) urea;
(9) the N-tert-butyl group-N '-(3-methyl-2-toluyl groups)-3,5-dimethyl benzene formylhydrazine;
(10) 1-(1, the 1-dimethyl ethyl)-1-(4-ethylamino benzonitrile acyl group)-3,5 ,-dimethyl benzene formylhydrazine.
(B) biological source insecticide
(1) bacillus thuringiensis,Bt;
(2) Avermectin.
(C) sandworm toxin insecticide
(1) 2-N, N dimethylamine base-1-sodium thiosulfate base-3-propane thiosulfate;
(2) 2-N, N dimethylamine base-1, two (the thiosulfonic acid sodium base) propane of 3-.
(D) organophosphorus insecticides
(1) O, O-diethyl-O-1-phenyl-1,2,4-triazole-3-thiophosphate;
(2) O, O-diethyl-O-(3,5, the 6-trichloro-2-pyridyl) phosphorothionate;
(E) pyrethroid insecticides
(1) dextrorotation-cis-2,2-dimethyl-3-(2, the 2-dibromo vinyl) cyclopropane-carboxylic acid (s)-alpha-cyano-3-phenoxy group benzyl ester;
(2) alpha-cyano-3-benzyloxy phenoxy base (R, S)-2-(4-chlorphenyl)-3 Methylbutanoic acid ester;
(3) alpha-cyano-3-phenoxy group-4-luorobenzyl (IR, 3R)-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester;
(4) 3-(2-chloro-3,3,3-trifluoro-propenyl)-2,2-dimethyl cyclopropane carboxylic acid-alpha-cyano-3-phenoxybenzyl ester;
(5) alpha-cyano-(3-benzyloxy phenoxy base) (1RS)-1R, 3R-3-(2, the 2-dichloroethylene)-2,2-dimethylcyclopropane carbonyl acid ester;
(6) 2,2-dimethyl-3-(2, the 2-dichloroethylene) cyclopropane-carboxylic acid-alpha-cyano-(3-phenoxy group)-benzyl ester.
(F) other insecticides
(1) 4-bromo-2-(4-chlorphenyl)-1-ethoxyl methyl-5-trifluoromethyl pyrpole-3-nitrile;
(2) 1-(6-chloro-3-pyridylmethyl)-N-Nitroimidazoline-2-base amine;
(3) (±)-5-amino-1-(2,6-two chloro-α, α, α-three fluoro-is right-tolyl)-4-trifluoromethyl sulfinyl pyrazole-3-nitrile;
For composition of the present invention, preferablely in the above listed specificity insect growth regulator, IGR be the young urea that goes out, UC 62644, Teflubenzuron, diflubenzuron, flufenoxuron, worm hydrazides.
Composition of the present invention can be two combinations, also can be the composition that aforesaid compound forms more than three kinds.
The mechanism of action difference of the various compositions of composition of the present invention, mutually synergy between them, the pesticide resistance of insect, evil mite reduces, thus the insecticidal effect of composition apparently higher than each component insecticidal effect of single time spent, and insecticidal spectrum is wider.
Composition of the present invention can be used for various crop and prevent and treat various pests, evil mite, and the lepidoptera pest in wheat, tobacco, fruit tree, grape, vegetables, cotton and the forestry is had special efficacy.As mythimna separata, the blue or green worm of tobacco, cigarette beetle, cabbage looper, colorado potato beetle, cotton spider mites, aphis fabae, oriental fruit moth, grape steinernema, beet armyworm, diamond-back moth, prodenia litura, cabbage caterpillar, pine caterpillars, cotton bollworm etc.
The ratio of emamection benaoate and specificity insect growth regulator, IGR, biogenic, nereistoxin, organic phosphor, pyrethroid and/or other insecticides is 1: 160～80: 1 based on the parts by weight of active constituent in the present composition, and the best is 1: 40～40: 1.
Composition of the present invention can also comprise emulsifier, solvent, auxiliary agent or filler, and the parts by weight of its shared composition are 0.5%～95%.
Composition of the present invention can wiring solution-forming, emulsion, granula, wetting powder, aqua, suspending agent, pulvis, dust agent, paste, soluble powder, microemulsion, missible oil, aerosol, fumicants and sustained release agent.
Composition of the present invention also will add surface reactive materials such as emulsifier, dispersant, wetting agent, to increase stability, wetability, the permeability of composition.
The product that the present invention describes can be the finished product preparation form, and promptly material mixes in the product.Yet the composition of composition also can provide with preparation separately, directly mixes in jar before use.
Composition of the present invention also can contain other active constituent, and for example other has the compound of weeding, desinsection or bactericidal property, also can mix with nematocide, protective agent, growth regulator, nutrient for plants or soil conditioner.
Composition of the present invention can use by common method, as pouring into a mould, spray, spray, dust or putting cigarette.
The present composition can illustrate with following embodiment:
The preparation of embodiment 1 10.2% suspending agent
Emamection benaoate 0.2% (weight)
Young urea 10% (weight) goes out
Auxiliary agent 11% (weight)
Filler 36.8% (weight)
Water 42% (weight)
Various components are mixed, in sand mill, be ground to the active ingredient particle diameter less than 3 μ m.
The preparation of embodiment 2 3.5% wetting powders
Emamection benaoate 0.5% (weight)
UC 62644 3% (weight)
Auxiliary agent 10% (weight)
Filler 86.5% (weight)
Various materials are added in the mixing kettle successively, under stirring condition, it is fully mixed, be crushed to particle diameter less than 44 μ m.
The preparation of embodiment 3 50.5% soluble powders
Emamection benaoate 0.5% (weight)
Desinsection list 50% (weight)
Auxiliary agent 4% (weight)
Filler 45.5% (weight)
Various materials are added in the mixing kettle successively, under stirring condition, it is fully mixed, form through modulation, spraying.
The preparation of embodiment 4 15.6% granulas
Emamection benaoate 0.6% (weight)
Hostathion 15% (weight)
Bentonite 30% (weight)
Talcum 52.4% (weight)
Sulphur ammonium 2% (weight)
Various materials are added in the mixing kettle successively, under stirring condition, it is fully mixed, through kneading, dissolving, drying, size degradation, granulation success.
The embodiment 5 10.2% emamection benaoates suspending agent that goes out
Control efficiency to beet armyworm
Place: Shanghai
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | ??0.05 | ??0.01 | |
| 0.2% emamection benaoate+10% young the urea that goes out | ??96.93 | ??96.88 | ??99.05 | ??99.03 | ????a | ????A |
| 1% emamection benaoate EC | ??93.71 | ??93.61 | ??95.48 | ??95.38 | ????b | ????B |
| The 20% young urea SC that goes out | ??89.89 | ??89.72 | ??90.51 | ??90.31 | ????c | ????C |
| ?CK | ??1.63 | ??- | ??2.07 | ??- | ????d | ????D |
Embodiment 6 50.5% emamection benaoate desinsection list soluble powders
Control efficiency to cotton bollworm
Place: Zibo
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | ??0.05 | ??0.01 | |
| 0.5% emamection benaoate+50% desinsection list | ??92.20 | ??92.07 | ??94.22 | ??94.07 | ????a | ????A |
| 1% emamection benaoate EC | ??90.55 | ??90.39 | ??92.02 | ??91.82 | ????b | ????B |
| 90% desinsection list soluble powder | ??83.55 | ??83.28 | ??84.99 | ??84.61 | ????c | ????C |
| ?CK | ??1.63 | ??- | ??2.45 | ??- | ????d | ????D |
The embodiment 7 8.2% emamection benaoates suspending agent that goes out
Control efficiency to apple skin worm
The place; Yantai
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | ??0.05 | ??0.01 | |
| 0.2% emamection benaoate+8% young the urea that goes out | ??92.04 | ??91.89 | ??96.45 | ??96.37 | ????a | ????A |
| 1% emamection benaoate EC | ???89.51 | ???89.32 | ??91.90 | ???91.71 | ????b | ????B |
| The 20% young urea SC that goes out | ???86.57 | ???86.32 | ??87.30 | ???87.00 | ????c | ????C |
| ?CK | ???1.80 | ???- | ??2.30 | ???- | ????d | ????D |
Embodiment 8 3.5% emamection benaoates are decided the worm wetting powder
Control efficiency to oriental tobacco budworm
Place: Qingzhou
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | ??0.05 | ??0.01 | |
| 0.5% emamection benaoate+3% UC 62644 | ????95.43 | ???95.32 | ????99.03 | ???99.00 | ???a | ????A |
| 1% emamection benaoate EC | ????90.49 | ???90.27 | ????93.42 | ???93.21 | ???b | ????B |
| 5% UC 62644 (pressing down hooligan) EC | ????87.90 | ???87.62 | ????91.82 | ???91.55 | ???b | ????B |
| ?CK | ????2.30 | ???- | ????3.14 | ???- | ???c | ????C |
Embodiment 9 15.6% emamection benaoate Hostathion granulas
Control efficiency to cabbage caterpillar
Test site: Binzhou
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | ??0.05 | ??0.01 | |
| 0.6% emamection benaoate+15% Hostathion | ??87.76 | ??87.62 | ??93.24 | ??93.08 | ????a | ????A |
| 1% emamection benaoate EC | ??83.40 | ??83.21 | ??91.82 | ??91.62 | ????b | ????B |
| 40% Hostathion EC | ??72.64 | ??72.32 | ??77.07 | ??76.52 | ????c | ????C |
| ?CK | ??1.15 | ??- | ??2.35 | ??- | ????d | ????D |
Embodiment 10 4.5% emamection benaoate chlorine cyanogen creams
Control efficiency to diamond-back moth
Test site: Qingzhou
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | ??0.05 | ??0.01 | |
| 0.5% emamection benaoate+4% cypermethrin | ???92.19 | ???92.06 | ???97.06 | ????97.03 | ????a | ????A |
| 1% emamection benaoate EC | ???86.93 | ??86.71 | ???94.31 | ???94.25 | ????b | ????B |
| 20% cypermethrin EC | ???68.83 | ??68.32 | ???71.63 | ???71.32 | ????c | ????C |
| ?CK | ???1.62 | ??- | ???1.07 | ???- | ????d | ????D |
Embodiment 11 10.5% emamection benaoate Tebufenozide suspending agents
Control efficiency to beet armyworm
Test site: Shanghai
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | ???0.05 | ???0.01 | |
| 0.5% emamection benaoate+10% worm hydrazides | ????93.63 | ????93.50 | ????97.06 | ????97.03 | ????a | ????A |
| 1% emamection benaoate EC | ????89.34 | ????89.12 | ????94.21 | ????94.15 | ????b | ????B |
| 20% worm hydrazides SC | ????87.29 | ????87.02 | ????93.67 | ????93.60 | ????b | ????B |
| ?CK | ????2.05 | ????- | ????1.05 | ????- | ????c | ????C |
Embodiment 12 5.5% emamection benaoate chlorfenapyr suspending agents
Control efficiency to cabbage caterpillar
Test site: Zibo
| Handle | The spray medicine after 3 days | The spray medicine after 7 days | Difference | |||
| The rate that goes down (%) | Preventive effect (%) | The rate that goes down (%) | Preventive effect (%) | ??0.05 | ??0.01 | |
| 0.5% emamection benaoate+5% chlorfenapyr | ???89.61 | ???89.51 | ????93.62 | ???93.49 | ????a | ????A |
| 1% emamection benaoate EC | ???85.34 | ???85.19 | ????84.74 | ???84.73 | ????b | ????B |
| 10% chlorfenapyr SC | ???83.00 | ???82.83 | ????83.94 | ???83.62 | ????b | ????B |
| ?CK | ???0.98 | ???- | ????1.96 | ???- | ????c | ????C |
Claims (2)
1. Pesticidal combination, it contains 4 " methylamino-4 "-deoxidation Avermectin B1 benzoate---emamection benaoates of at least a other insecticides and following I structure; Wherein other insecticides is 4-bromo-2-(4-chlorphenyl)-1-ethoxyl methyl-5-trifluoromethyl pyrpole-3-nitrile, 1-(6-chloro-3-pyridylmethyl)-N-Nitroimidazoline-2-base amine, (±)-5-amino-1-(2,6-two chloro-α, α, α-three fluoro-is right-tolyl)-4-trifluoromethyl sulfinyl pyrazole-3-nitrile; Wherein the ratio of structural formula I and other insecticides is 1: 160 to 80: 1 based on the parts by weight of active component; Except that active constituent, also contain emulsifier, solvent, auxiliary agent and filler.
2. according to the Pesticidal combination of claim 1, the ratio of structural formula I and other insecticides is 1: 40 to 40: 1 based on the parts by weight of active component.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410056845 CN1659964A (en) | 2001-07-31 | 2001-07-31 | Combination I of killing insects and acarids prepared from benzoate of abanmectin in methylamine group |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410056845 CN1659964A (en) | 2001-07-31 | 2001-07-31 | Combination I of killing insects and acarids prepared from benzoate of abanmectin in methylamine group |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 01123750 Division CN1274219C (en) | 2001-07-31 | 2001-07-31 | Methlaminoabamectin benzoate pesticide and miticide composite |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1659964A true CN1659964A (en) | 2005-08-31 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410056845 Pending CN1659964A (en) | 2001-07-31 | 2001-07-31 | Combination I of killing insects and acarids prepared from benzoate of abanmectin in methylamine group |
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| Country | Link |
|---|---|
| CN (1) | CN1659964A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102578114A (en) * | 2012-01-20 | 2012-07-18 | 山东潍坊双星农药有限公司 | Pesticide composite containing emamectin benzoate and tebufenozide |
-
2001
- 2001-07-31 CN CN 200410056845 patent/CN1659964A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102578114A (en) * | 2012-01-20 | 2012-07-18 | 山东潍坊双星农药有限公司 | Pesticide composite containing emamectin benzoate and tebufenozide |
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