CN1623645A - Photo catalytic equipment for gas-solid sulfurizing bed - Google Patents
Photo catalytic equipment for gas-solid sulfurizing bed Download PDFInfo
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- CN1623645A CN1623645A CN 200410051984 CN200410051984A CN1623645A CN 1623645 A CN1623645 A CN 1623645A CN 200410051984 CN200410051984 CN 200410051984 CN 200410051984 A CN200410051984 A CN 200410051984A CN 1623645 A CN1623645 A CN 1623645A
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- fluidized bed
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Abstract
A gas-solid fluidized-bed photocatalyzing equipment has a gas-solid fluidized-bed reactor composed of axially sleeved two quartz tubes. The ring region between them is a reaction region filled by TiO2-silica gel catalyst. The UV lamp as light source is positioned in the center of internal quartz tube. Its advantages are high heat and mass transfer efficiency, and high photocatalyzing efficiency.
Description
Technical field
The present invention relates to a kind of gas-solid fluidized bed photocatalytic equipment, specifically be a kind of have heat transfer, mass-transfer efficiency height, easily realize extensive the processing and continued operation, realization response thing, catalyst fully contact with incident light better, the gas-solid fluidized bed photocatalytic equipment of advantages such as raising photocatalysis efficiency.
Background technology
The structure of reactor can be divided into fixed bed and fluid bed, and fixed bed is adopted in present research mostly, and it exists incident light can not penetrate bed inside, and light utilization efficiency is not high, and institute takes up space big, and treatment scale is little, can not continued operation, and defective such as photocatalysis efficiency is low.
Summary of the invention
The objective of the invention is to shortcoming, a kind of gas-solid fluidized bed photochemical catalytic oxidation equipment is provided at the prior art existence.The present invention is a kind of gas-solid fluidized bed photocatalysis apparatus, main by adopting gas-solid fluidized bed reactor to replace fixed bed, shortcomings such as the light utilization efficiency that solves fixed bed is not high, photocatalysis efficiency is low, thus realize carrying out continuously the processing, continued operation, light utilization efficiency height of pollutant, the process that photocatalysis efficiency is high.
For achieving the above object, the present invention has taked following technical scheme:
A kind of gas-solid fluidized bed photocatalytic equipment comprises gas-solid fluidized bed 1 and light source 2, and gas-solid fluidized bed 1 has circulus, by outer tube 5 and in pipe 6 constitute the center of pipe 6 in light source 2 vertically places; Be provided with distribution grid 7 in the bottom of interior pipe 6; The bottom of outer tube 5 is provided with gas feed 4, and the top is provided with gas vent 3.
Gas-solid fluidized bed 1 outer tube 5 has layer structure, and bottom has cone-shaped structure, and the bottom of circular cone is gas feed 4; Intermediate layer and top layer have cylindrical-shaped structure, and the caliber of top layer cylinder is greater than the caliber of intermediate layer cylinder.
Interior pipe is all quartz ampoule with outer tube, and the annulus between interior pipe and the outer tube is a reaction zone, fills TiO therebetween
2/ silica-gel catalyst.
The used material of distribution grid of interior pipe bottom is a G1 core plate, and light source 2 is a ultraviolet lamp.
Compared with the prior art, the present invention has following beneficial effect:
Gas-solid fluidized bed photochemical catalytic oxidation of the present invention system, the mass-transfer efficiency of whole bed improves in the strenuous exercise of catalyst in the fluid bed, also can increase owing to the motion of catalyst on the illumination surface that is subjected to of catalyst, improve the utilization rate of light, this system can issue third contact of a total solar or lunar eclipse catalytic reaction in the situation of heating and feeding high-speed gas, thereby make catalyst regeneration, realize continued operation, that the incident light portion that has overcome fixed bed reactors can penetrate that bed inside, light utilization efficiency are not high, institute takes up space is big, treatment scale is little, can not continued operation, defective such as photocatalysis efficiency is low.
Figure of description
Fig. 1 is a structural representation of the present invention;
Fig. 2 is the fluidized bed photo catalysis oxidation toluene process chart in the embodiment.
The specific embodiment
The invention will be further described below in conjunction with Figure of description.
The structure of gas-solid fluidized bed photocatalysis apparatus of the present invention comprises gas-solid fluidized bed 1 and light source 2 as shown in Figure 1, and gas-solid fluidized bed 1 has circulus, by outer tube 5 and in pipe 6 constitute the center of pipe 6 in light source 2 vertically places; Be provided with distribution grid 7 in the bottom of interior pipe 6; The bottom of outer tube 5 is provided with gas feed 4, and the top is provided with gas vent 3.
Gas-solid fluidized bed 1 outer tube 5 has layer structure, and bottom has cone-shaped structure, and the bottom of circular cone is gas feed 4; Intermediate layer and top layer have cylindrical-shaped structure, and the internal diameter of top layer cylinder is greater than the internal diameter of intermediate layer cylinder.
In the present embodiment, the caliber of interior pipe 6 is 39mm, and the caliber of outer tube 5 top layers is 60mm, and the caliber in intermediate layer is 49mm.
Interior pipe is all quartz ampoule with outer tube, and the annulus between interior pipe and the outer tube is a reaction zone, fills TiO therebetween
2/ silica-gel catalyst.
The used material of distribution grid of interior pipe bottom is a G1 core plate, and light source 2 is a ultraviolet lamp.
Operation principle of the present invention is: gas enters fluid bed by the gas feed of bottom with the given pace finite concentration, through behind the distribution grid, enter the annular reaction district, because gas has given pace, just make catalyst motion in the annular reaction district to form fluidization gradually that gas is after fully reacting with fluidised catalyst under certain ultraviolet ray intensity irradiation, obtain degraded, discharge from the gas vent on top.
In the present embodiment, with the butyl titanate is predecessor, hydrolysis in ethanol, condensation, make solution obtain colloidal sol through the sol-solvent process, this method technology is comparatively simple, and mild condition is evenly distributed, the preparation and the load of nano titanium oxide once can be finished, be the method for using and have prospect at present the most always.
In order to satisfy actual light-catalyzed reaction requirement, usually will utilize the energy of forms such as heat, ultrasonic wave or microwave, the microcellular structure of carrier is enlarged, catalyst is entered in the hole evenly distribute and on carrier, be fixed up, constitute composite catalyst, or make photocatalysis membrana, and be difficult to reclaim thereby overcome the suspended particulate catalyst, be unfavorable for the shortcoming of commercial Application.Silica gel is one of comparatively common fluid bed filler, and its fluidizing performance is better, is easy to combine with titanium dioxide, and cheap and easy to get, so makes the carrier of nano titanium oxide in this experiment with it.
As accompanying drawing 2 is fluidized bed photo catalysis oxidation toluene process chart, the interior air of steel cylinder divides three parts among Fig. 2, a part directly enters surge flask, and a part feeds the toluene doleiform and becomes the toluene gaseous mixture to enter surge flask, and a part feeds water bottle formation wet air and enters surge flask.The gas flow of each arm shows flow by each valve regulated by flowmeter.Mist is entered by reactor bottom in the surge flask, is discharged by the top through behind the catalyst layer.Import and export bypass thief hatch place at reactor extracts the gas sample respectively, draws import and export gaseous mixture toluene chromatogram by the analysis of GC900A type chromatograph, and then draws the degradation rate of toluene.
In the present embodiment, be 60mgm with initial concentration
-3Toluene gas, it is 4.0cms by the superficial gas velocity of bed
-1, ultraviolet ray intensity is 15W, with this understanding, the conversion ratio of toluene can reach 97.2%.
Claims (3)
1, a kind of gas-solid fluidized bed photocatalytic equipment comprises gas-solid fluidized bed (1) and light source (2), it is characterized in that gas-solid fluidized bed (1) has circulus, is made of outer tube (5) and interior pipe (6), and light source (2) vertically places the center of interior pipe (6); Be provided with distribution grid (7) in the bottom of interior pipe (6); The bottom of outer tube (5) is provided with gas feed (4), and the top is provided with gas vent (3).
2, gas-solid fluidized bed photocatalytic equipment according to claim 1 is characterized in that the outer tube (5) of gas-solid fluidized bed (1) has layer structure, and bottom has cone-shaped structure, and the bottom of circular cone is gas feed (4); Intermediate layer and top layer have cylindrical-shaped structure, and the caliber of top layer cylinder is greater than the caliber of intermediate layer cylinder.
3, gas-solid fluidized bed photocatalytic equipment according to claim 1 is characterized in that the interior pipe (6) of gas-solid fluidized bed (1) and the annulus between the outer tube (5) are reaction zone, fills TiO therebetween
2/ silica-gel catalyst.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410051984 CN1623645A (en) | 2004-10-29 | 2004-10-29 | Photo catalytic equipment for gas-solid sulfurizing bed |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410051984 CN1623645A (en) | 2004-10-29 | 2004-10-29 | Photo catalytic equipment for gas-solid sulfurizing bed |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1623645A true CN1623645A (en) | 2005-06-08 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410051984 Pending CN1623645A (en) | 2004-10-29 | 2004-10-29 | Photo catalytic equipment for gas-solid sulfurizing bed |
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| CN (1) | CN1623645A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102773057A (en) * | 2012-08-09 | 2012-11-14 | 西安交通大学 | Photocatalytic decomposition reactor of hydrogen sulfide based on fluidized bed technology and hydrogen producing device for photocatalytic decomposition reactor of hydrogen sulfide |
| CN102921364A (en) * | 2012-11-14 | 2013-02-13 | 天津市先权工贸发展有限公司 | Fluidized bed photo-thermal reactor |
| CN103739608A (en) * | 2013-11-28 | 2014-04-23 | 湖南科源生物制品有限公司 | Method for preparing artemisinin by using residue obtained through extraction of artemisinin from sweet wormwood herb |
| CN103739610A (en) * | 2013-11-28 | 2014-04-23 | 湖南科源生物制品有限公司 | Method and equipment for preparing artemisinin by adopting dihydroarteannuic acid as raw material |
| CN103739609A (en) * | 2013-11-28 | 2014-04-23 | 湖南科源生物制品有限公司 | Method and equipment for scale production of artemisinin |
| CN103785339A (en) * | 2013-11-28 | 2014-05-14 | 湖南科源生物制品有限公司 | Photosensitized oxidation reaction equipment and application thereof |
| CN111326811A (en) * | 2018-12-13 | 2020-06-23 | 多氟多化工股份有限公司 | Battery pole piece photocatalytic degradation device and battery pole piece photocatalytic degradation equipment |
| CN111437689A (en) * | 2020-04-01 | 2020-07-24 | 华中科技大学 | Double-channel high-temperature photo-thermal catalytic reaction device |
| CN112588211A (en) * | 2021-01-18 | 2021-04-02 | 重庆大学 | Titanium dioxide carbonization boiling chlorination simulation reactor and simulation method |
| CN113578209A (en) * | 2021-08-19 | 2021-11-02 | 西安交通大学 | Magnetic confinement solar photo-thermal complementary fluidized bed reactor capable of continuously operating day and night |
-
2004
- 2004-10-29 CN CN 200410051984 patent/CN1623645A/en active Pending
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102773057B (en) * | 2012-08-09 | 2015-08-26 | 西安交通大学 | A kind of photocatalysis Decomposition hydrogen sulfide reactor based on fluidization and device for producing hydrogen thereof |
| CN102773057A (en) * | 2012-08-09 | 2012-11-14 | 西安交通大学 | Photocatalytic decomposition reactor of hydrogen sulfide based on fluidized bed technology and hydrogen producing device for photocatalytic decomposition reactor of hydrogen sulfide |
| CN102921364A (en) * | 2012-11-14 | 2013-02-13 | 天津市先权工贸发展有限公司 | Fluidized bed photo-thermal reactor |
| CN103739608B (en) * | 2013-11-28 | 2016-01-27 | 湖南科源生物制品有限公司 | The residue utilizing sweet wormwood to extract Artemisinin prepares the method for Artemisinin |
| CN103739610B (en) * | 2013-11-28 | 2016-03-30 | 湖南科源生物制品有限公司 | A kind of take dihydroartemisinic acid as the method and apparatus that Artemisinin prepared by raw material |
| CN103785339A (en) * | 2013-11-28 | 2014-05-14 | 湖南科源生物制品有限公司 | Photosensitized oxidation reaction equipment and application thereof |
| CN103739610A (en) * | 2013-11-28 | 2014-04-23 | 湖南科源生物制品有限公司 | Method and equipment for preparing artemisinin by adopting dihydroarteannuic acid as raw material |
| CN103785339B (en) * | 2013-11-28 | 2015-10-28 | 湖南科源生物制品有限公司 | A kind of photosensitized oxidation consersion unit and application thereof |
| CN103739608A (en) * | 2013-11-28 | 2014-04-23 | 湖南科源生物制品有限公司 | Method for preparing artemisinin by using residue obtained through extraction of artemisinin from sweet wormwood herb |
| CN103739609B (en) * | 2013-11-28 | 2016-03-02 | 湖南科源生物制品有限公司 | A kind of method and apparatus of scale production of artemisinin |
| CN103739609A (en) * | 2013-11-28 | 2014-04-23 | 湖南科源生物制品有限公司 | Method and equipment for scale production of artemisinin |
| CN111326811A (en) * | 2018-12-13 | 2020-06-23 | 多氟多化工股份有限公司 | Battery pole piece photocatalytic degradation device and battery pole piece photocatalytic degradation equipment |
| CN111326811B (en) * | 2018-12-13 | 2021-08-13 | 多氟多新材料股份有限公司 | Battery pole piece photocatalytic degradation device and battery pole piece photocatalytic degradation equipment |
| CN111437689A (en) * | 2020-04-01 | 2020-07-24 | 华中科技大学 | Double-channel high-temperature photo-thermal catalytic reaction device |
| CN111437689B (en) * | 2020-04-01 | 2021-02-02 | 华中科技大学 | Double-channel high-temperature photo-thermal catalytic reaction device |
| CN112588211A (en) * | 2021-01-18 | 2021-04-02 | 重庆大学 | Titanium dioxide carbonization boiling chlorination simulation reactor and simulation method |
| CN112588211B (en) * | 2021-01-18 | 2022-05-10 | 重庆大学 | Titanium dioxide carbonization boiling chlorination simulation reactor and simulation method |
| CN113578209A (en) * | 2021-08-19 | 2021-11-02 | 西安交通大学 | Magnetic confinement solar photo-thermal complementary fluidized bed reactor capable of continuously operating day and night |
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