CN1600419A - Industrial reduction method for catalyst of Fischer-Tropsch synthesis in use for reactor in slurry state bed - Google Patents
Industrial reduction method for catalyst of Fischer-Tropsch synthesis in use for reactor in slurry state bed Download PDFInfo
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- 239000003054 catalyst Substances 0.000 title claims abstract description 137
- 230000015572 biosynthetic process Effects 0.000 title claims description 54
- 238000003786 synthesis reaction Methods 0.000 title claims description 54
- 238000000034 method Methods 0.000 title claims description 41
- 239000002002 slurry Substances 0.000 title claims description 34
- 238000010438 heat treatment Methods 0.000 claims abstract description 11
- 239000007788 liquid Substances 0.000 claims abstract description 11
- 230000001105 regulatory effect Effects 0.000 claims abstract description 11
- 238000001816 cooling Methods 0.000 claims abstract description 7
- 238000006722 reduction reaction Methods 0.000 claims description 135
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 58
- 239000007789 gas Substances 0.000 claims description 31
- 229910052757 nitrogen Inorganic materials 0.000 claims description 29
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 23
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 9
- 238000011946 reduction process Methods 0.000 claims description 9
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- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 239000012188 paraffin wax Substances 0.000 claims description 7
- 238000011084 recovery Methods 0.000 claims description 5
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 4
- 230000001143 conditioned effect Effects 0.000 claims description 3
- 238000003825 pressing Methods 0.000 claims description 3
- 238000013461 design Methods 0.000 claims description 2
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- 238000001556 precipitation Methods 0.000 claims description 2
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- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 10
- 239000012071 phase Substances 0.000 description 10
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- 230000003197 catalytic effect Effects 0.000 description 3
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- 229910001567 cementite Inorganic materials 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
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- 238000005245 sintering Methods 0.000 description 2
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- 239000011261 inert gas Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
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Abstract
An industrial process for reducing the Fe-based Fischer-Tropsch catalyst used for slurry-bed reactor includes reducing by H2 and CO2 in reducing unit and regulating. Said reducing unit is composed of compressor, two heat exchangers for heating and cooling, reducing reactor, vapor-liquid separator, mixer of catalyst and others, and feeder of catalyst.
Description
Technical field
The present invention relates to a kind of industrial reduction method of iron-base fischer-tropsch synthesis catalyst, the catalyst that this method obtains will be used for industrial paste state bed reactor and carry out Fischer-Tropsch synthesis.
Background technology
At present commonplace Fischer-Tropsch building-up process is to utilize synthesis gas, and Fischer-Tropsch is synthetic carrying out in slurry attitude bed under the effect of catalyst and under 200～250 ℃, the operating condition of 2.0～5.0MPa, generates a series of hydrocarbon compound.Hydrocarbon compound obtains thick product after Quench, flash distillation, separation, filtration: heat is coagulated oil, cold oil and wax.The synthetic used catalyst of Fischer-Tropsch has multiple, and commonly used be iron-based or cobalt-base catalyst, and ferrum-based catalyst is owing to less expensive, thereby has obtained extensive use in the Fischer-Tropsch building-up process.
After need reducing, iron-base fischer-tropsch synthesis catalyst just has activity, in existing bibliographical information and patent, the reduction of iron-base fischer-tropsch synthesis catalyst is carried out in the Fischer-Tropsch synthesis device, come reducing catalyst according to certain inlet gas composition, temperature, pressure and air speed, the synthetic reactivity of Fischer-Tropsch is stablized gradually with the raising of reducing degree, switches to synthetic state after reduction is finished.More than report is generally the process of carrying out in the laboratory.
For industrial paste state bed reactor, if building-up process and reduction process are carried out in same reactor, maximum problem is the online updating and the reduction of catalyst.Catalyst begin the Fischer-Tropsch building-up process after reduction is finished first, after operation a period of time, catalyst is inactivation gradually, needs to add new catalyst and replace the part catalyst.Reduce if directly catalyst is added in the synthesis reactor, since the catalyst that adds be in the very high state of moisture (in this moment reactor dividing potential drop of water may account for stagnation pressure 20%), to cause reducing insufficient, and cause the sintering and the fragmentation of catalyst easily.If use high H
2The gas of/CO ratio restores after system is replaced, and then needs to spend considerable time to carry out, and has caused the interruption of building-up process, and the Fischer-Tropsch synthetic space-time yield sharply descends.The commercial plant of large-scale continuous production obviously can not be operated in this way.So the syrup state bed Fischer Tropsch for industry is synthetic, should dispose independently a reduction reactor and a supporting reduction unit thereof.
Summary of the invention
Purpose of the present invention be exactly provide in order to overcome the defective that above-mentioned prior art exists a kind of independently, the industrial reduction method of the iron-base fischer-tropsch synthesis catalyst that is used for paste state bed reactor that reducing degree is high.
Purpose of the present invention can be achieved through the following technical solutions:
Be used for the industrial reduction method of the iron-base fischer-tropsch synthesis catalyst of paste state bed reactor, it is characterized in that, this method comprises following processing step:
(1) ferrum-based catalyst and paraffin adding catalyst dosage bunker are mixed, obtain catalyst slurry;
(2) catalyst slurry is sent in the reduction reactor, simultaneously by compressor with synthesis gas and add hydrogen and be pressed in the reduction reactor and carry out reduction reaction with above-mentioned catalyst slurry, the reduction reaction process comprises reduction phase and two stages of adjusting stage;
(3) will reduce good catalyst slurry force feed stores to the catalyst charge groove stand-by.
Described ferrum-based catalyst adopts the precipitation method to prepare, and the weight percentage of the contained Fe of this catalyst is 45～68%, and each components by weight consists of Fe: Cu: SiO
2: K
2O: Na
2O=100: 0.5～20: 2～50: 0.1～10: 0.05～5.
The reduction phase of described reduction reaction, reduction reactor operating temperature are 185～260 ℃, and pressure is 2.0～5.0MPa, are 10～40/1 H with ratio
2/ CO reducing gases is reduced to catalyst, and this stage need be supplied with and add heat, and the temperature that is masked as reduction reactor of end begins to continue to rise, and this recovery time in stage is 12～24h.
The adjusting stage of described reduction reaction carries out after reduction phase, and the operating temperature of reduction reactor is 230～260 ℃, and pressure is 2.0～5.0MPa, H
2The ratio of/CO is 10～40/1; This stage need be removed reaction heat, and end mark is that the temperature of reduction reactor and the outlet composition of gas tend towards stability, and the expression reduction is finished, and this recovery time in stage is 24～48h.
The whole reduction process of described catalyst is at the higher inlet linear speed work of finishing drilling, and the inlet linear speed is 0.15～0.5m/s.
The reduction of described catalyst is carried out in the reduction reactor that is independent of the Fischer-Tropsch synthesis device, and an independently reduction unit is set, and this reduction reactor is a paste state bed reactor, and the catalyst weight concentration in the slurries is 5～50%.
Described catalyst dosage bunker is provided with at least one, establish heat(ing) coil in mechanical agitator, dosage bunker hot nitrogen bubbling pipe and the dosage bunker in this dosage bunker, pressure is controlled by regulating the aperture of pressing nitrogen to add valve in dosage bunker atmospheric valve and the dosage bunker, and the catalyst slurry for preparing is delivered to reduction reactor with nitrogen pressure.
Described reduction reactor is realized a stable H by the relative scale of adjusting fresh synthesis gas, fresh hydrogen under the constant prerequisite of bed inlet linear speed
2/ CO ratio.
Described reduction reactor inlet is provided with at least one compressor, at least one heating heat exchanger, and the reduction reactor outlet is provided with at least one cooling heat exchanger, at least one vapour liquid separator.
The reduction phase of described reduction reaction, reduction reactor need provide and add heat, and reducing gases is sent into reduction reactor after being heated to higher temperature through heating heat exchanger, and this moment, the by-pass bypass valve was closed; In reduction reactor, feed a certain amount of high steam toward the reactor inner coil pipe again and guarantee operating temperature.
The adjusting stage of described reduction reaction, reduction reactor need be removed heat, progressively reduce the high steam feeding amount of reactor inner coil pipe with the increase of this stage reducing degree, drive material heating heat exchanger by-pass bypass valve into or directly reduce heating heat exchanger outlet design temperature and reduce inlet temperature; If inlet temperature is reduced to 110 ℃, to solidify for avoiding place, gas access paraffin occurring, the aperture that need stop the by-pass bypass valve this moment is regulated, and feeds boiler feedwater to remove heat in the reactor inner coil pipe.
Described reduction reactor adds valve by the reactor high pressure nitrogen of regulating the top and comes conditioned reaction device pressure behind complete and continuous reduction cycle of experience; When discharging, needs slurries are pressed into follow-up catalyst charge groove with nitrogen.
Establish heat(ing) coil in charge chute hot nitrogen bubbling pipe and the charge chute in the described catalyst charge groove, regulate pressure by the aperture of regulating charge chute nitrogen adding valve and charge chute atmospheric valve; When synthesis reactor need be added catalyst, catalyst slurry is pressed in the synthesis reactor with thermal high nitrogen.
The required reducing condition of fischer-tropsch synthetic catalyst is different with synthesis condition.The H that building-up process is required
2/ CO is lower, reduces under synthesis condition, and along with the increase on catalyst activity surface, Fischer-Tropsch synthesis begins to carry out on the catalyst, generates a large amount of moisture.Prove that according to existing bibliographical information and experimental study the increase of moisture will have following influence to ferrum-based catalyst: with the cementite with activity of generation after the catalyst surface reduction or the oxide that elemental iron is oxidized to non-activity; Thereby insufficient catalyst activity that makes that causes reducing is lower; Promote the sintering of catalyst; Cause the fragmentation of catalyst.Therefore, the condition of reduction is unsuitable identical with synthesis condition.
Compared with prior art, the industrial reduction method of iron-base fischer-tropsch synthesis catalyst of the present invention is an independently reduction process, and this reduction process is a batch process, and the catalyst after the reduction adds synthesis reactor as required.Because reduction process and building-up process are two independently processes, can adopt higher H in reduction process
2/ CO ratio has effectively reduced the influence of the moisture of reduction later stage Fischer-Tropsch synthesis generation for reducing catalyst.
For iron-base fischer-tropsch synthesis catalyst, the reduction process of catalyst can successively be divided into reduction phase and two stages of adjusting stage.At reduction phase, main what take place is that partial oxidation iron contained in the catalyst is reduced to the iron atom with catalytic activity and the endothermic reaction of cementite; And,, begin to have the Fischer-Tropsch synthesis of heat release on catalyst, to take place along with the raising of catalyst reduction degree in the adjusting stage, and rate of heat release surpassed the heat absorption rate of catalyst activity composition reduction, and aggregate performance is exothermic reaction.The different phase that the present invention is directed to reduction has been determined different process conditions, to obtain best catalyst activity.
For industrial paste state bed reactor and since each additional amount be in the synthesis reactor catalytic amount 1/5～1/20, the catalytic amount of reduction is identical with additional amount, required reactor diameter is less, is easy to realize the abundant reduction of the uniform and catalyst of gas.Simultaneously, the catalyst that reduction is good can carry out online updating, can guarantee the long synthetic operation cycle like this, realizes the long-term and stable production of Fischer-Tropsch building-up process.In addition,, can carry out synchronously, also reduce the time that building-up process is interrupted with synthetic because reduction is independently.
In the operation cycle of whole reduction reactor, the gas at reduction reactor top enters vapour liquid separator after the cooling heat exchanger cooling, liquid discharges as reaction waste, the discharging of a gas part, a part is mixed the back as circulating air and is used compressor boost with fresh supply gas (mist of fresh synthesis gas and supply hydrogen), send to the preceding preheater inlet of reactor.
Reduction reactor comes conditioned reaction device pressure by the high pressure nitrogen addition at top behind complete and continuous reduction cycle of experience.When needs discharge, close all valves except that reactor high pressure nitrogen inlet valve and reactor slurry drain valve, with high pressure nitrogen slurries are pressed in the catalyst charge groove.
Establish heat(ing) coil in the catalyst charge groove, to keep the good catalyst slurry of reduction in higher temperature, the bottom feeds the sedimentation that the hot nitrogen bubbling prevents catalyst, and the pressure of catalyst slurry liquid bath is regulated by nitrogen addition and the discharging discharge quantity of speeding.When synthesis reactor need be added catalyst, close all valves except that charge chute nitrogen inlet valve and charge chute slurries drain valve, with thermal high nitrogen catalyst slurry is pressed in the synthesis reactor.
The catalyst slurry of this flow process adopts the high-pressure inert gas strength to carry rather than carry with pump, has reduced the breakage of catalyst in transmission effectively.
As seen, this invention had both solved the deficiency that the synthetic catalyst reduction exists in the prior art, can not produce new problem again.
Description of drawings
Figure 1 shows that the Fischer-Tropsch synthetic iron-based catalyst reducing process flow chart of an industrial intermediate experiment.
The specific embodiment
Embodiment 1
As shown in Figure 1, unreduced catalyst is sent in the catalyst dosage bunker 4, entered in the reduction reactor 3 after being made into slurries with melt paraffin.After with hydrogen being the compressed machine 1 compression supercharging of reducing gases and heat exchanger 2 heat exchange of main component, entering reduction reactor 3 and under certain temperature and pressure, reduce.The exit gas of reduction reactor 3 enters in the gas-liquid separator 6 after being cooled to normal temperature through reduction cooler 5, and the liquid after the separation is sent to wastewater treatment, and uncooled gas mixes with virgin gas after reduce after recycle compressor 1 pressurizes, and returns in the reduction reactor.Like this, reduction reactor 3, heating heat exchanger 2, cooling heat exchanger 5, compressor 1 and gas-liquid separator 6 have just constituted a reduction unit when carrying out the catalyst reduction course of reaction.
The catalyst slurry that reduction is good drains in the catalyst charge groove 7.Then, according to the needs of synthesis unit catalyst slurry is disposed to synthesis reactor from catalyst charge groove 7 again.
Squeeze into catalyst dosage bunker 4 after the melt paraffin metering, fresh raw catalyst is poured into by catalyst charging hopper 9, and the hot nitrogen bubbling pipe 10 by the bottom carries out the stirring that bubbling prevents sedimentation and agitator 11 catalyst and paraffin are mixed.The pressure of catalyst dosage bunker 4 is to control by regulating the aperture of pressing nitrogen to add valve 14 in dosage bunker atmospheric valve 13 and the dosage bunker.The temperature of catalyst dosage bunker 4 guarantees by heat(ing) coil 12 in the dosage bunker.The operating temperature of catalyst dosage bunker is controlled at 150 ℃, and operating pressure is 2.0MPa.
After slurries mix, close dosage bunker atmospheric valve 13, open dosage bunker baiting valve 19, confirm to press in the dosage bunker nitrogen to add valve 14 and open, under the effect of pressure reduction, enter reduction reactor 3.After adding fully, slurries close dosage bunker baiting valve 19, slurries and the 1200Nm that enters from tower bottom through 1 compression of reduction recycle compressor
3Reduction reaction takes place at reduction reactor 3 in/h gaseous mixture.The loadings of catalyst is 600kg, and reducing gas inlet linear speed is 0.45m/s.Phase I---the reduction temperature of reduction phase is 190 ℃, and the reduction temperature of second stage---adjusting stage is 230 ℃, and operating pressure maintains 3.0MPa all the time in reduction.Reduction reactor 3 decides the aperture of reaction gas inlet temperature (realizing by the aperture of adjusting heating heat exchanger main line valve 26 and cooling by-pass valve 15), steam valve 16 and cooling water valve 17 with the mean temperature of bed.
The reduction reactor exit gas enters reduction cooler 5 by the cat head gaseous phase outlet and is cooled to 40 ℃ and enters gas-liquid separator 6 (gas return path pressure is controlled to be 2.7MPa by emptying valve 20) and separate, water after the separation is by the control of separator liquid level controller, and gas comes out from the top afterwards and 200Nm
3The virgin gas of/h is mixed, by adjusting pure hydrogen and H in the virgin gas
2/ CO makes mixed H than the ratio that is 1 synthesis gas
2/ CO ratio is 35, enters reduction recycle compressor 1 then and is compressed to 3.05MPa, enters reduction reactor 3 through behind the preheater 2 again.
After catalyst slurry reduces, reduction unit is carried out shut-down operation.After the parking of confirming reduction unit is finished, close all valves except that the reactor high pressure nitrogen adds valve 8 and reactor baiting valve 21, utilize pressure reduction that catalyst is pressed into catalyst charge groove 7 and join in the Fischer-Tropsch synthesis device with preparation.The pressure of catalyst charge groove 7 adds valve 23 by control charge chute atmospheric valve 22 and charge chute high pressure nitrogen and keeps.By the bottom pine for press nitrogen bubble pipe 25 to carry out bubbling preventing sedimentation, the temperature of catalyst charge groove 7 guarantees by heat(ing) coil 24 in the charge chute.
According to 8 batches of catalyst of above-mentioned technology coreduction, the catalyst that reduction the is good synthesis reactor of packing into, in building-up process, one week was carried out the online updating of a catalyst, promptly discharge a certain amount of old catalyst slurry, replenish the good fresh catalyst slurries of reduction of equivalent amount and concentration again, with the average activity of regular recovery catalyst in reactor.At 240 ℃, 3.0MPa, the inlet linear speed is under the synthesis condition of 0.45m/s, H
2All the time maintain 80～90% level with the total conversion of CO.
In the present embodiment, used Fischer-Tropsch synthetic iron-based catalyst composition is as follows: the quality percentage composition of Fe is 50.05%.Each components by weight of catalyst consists of Fe: Cu: SiO
2: K
2O: Na
2O=100: 11.23: 32.58: 6.71: 0.17.
Substantially the same manner as Example 1, difference is the operating condition of reduction process: the arrival line speed control is made as 0.15m/s, and the temperature of reduction phase and adjusting stage is 230 ℃, and operating pressure is 4.7MPa, and all the other operating conditions are constant.Under the synthesis condition identical with embodiment 1, the catalyst after the reduction still carries out one time online updating a week, and operation result shows that total conversion is constant substantially under this operating condition, but still can maintain 80～90% level.
Embodiment 3
Identical with embodiment 1 operating condition, but the composition of catalyst changes to some extent: and the quality percentage composition of Fe is 60%.Each components by weight of catalyst consists of Fe: Cu: SiO
2: K
2O: Na
2O=100: 2.73: 15.33: 1.68: 1.03.Operation result shows, presses embodiment 1 determined operating condition, and total conversion slightly descends, but still can maintain 80～90% level.
Claims (13)
1. be used for the industrial reduction method of the iron-base fischer-tropsch synthesis catalyst of paste state bed reactor, it is characterized in that, this method comprises following processing step:
(1) ferrum-based catalyst and paraffin adding catalyst dosage bunker are mixed, obtain catalyst slurry;
(2) catalyst slurry is sent in the reduction reactor, simultaneously by compressor with synthesis gas and add hydrogen and be pressed in the reduction reactor and carry out reduction reaction with above-mentioned catalyst slurry, the reduction reaction process comprises reduction phase and two stages of adjusting stage;
(3) will reduce good catalyst slurry force feed stores to the catalyst charge groove stand-by.
2. the industrial reduction method that is used for the iron-base fischer-tropsch synthesis catalyst of paste state bed reactor according to claim 1, it is characterized in that, described ferrum-based catalyst adopts the precipitation method to prepare, the weight percentage of the contained Fe of this catalyst is 45～68%, and each components by weight consists of Fe: Cu: SiO
2: K
2O: Na
2O=100: 0.5～20: 2～50: 0.1～10: 0.05～5.
3. the industrial reduction method that is used for the iron-base fischer-tropsch synthesis catalyst of paste state bed reactor according to claim 1, it is characterized in that, the reduction phase of described reduction reaction, the reduction reactor operating temperature is 185～260 ℃, pressure is 2.0～5.0MPa, is 10～40/1 H with ratio
2/ CO reducing gases is reduced to catalyst, and this stage need be supplied with and add heat, and the temperature that is masked as reduction reactor of end begins to continue to rise, and this recovery time in stage is 12～24h.
4. the industrial reduction method that is used for the iron-base fischer-tropsch synthesis catalyst of paste state bed reactor according to claim 1, it is characterized in that the adjusting stage of described reduction reaction carries out after reduction phase, the operating temperature of reduction reactor is 230～260 ℃, pressure is 2.0～5.0MPa, H
2The ratio of/CO is 10～40/1; This stage need be removed reaction heat, and end mark is that the temperature of reduction reactor and the outlet composition of gas tend towards stability, and the expression reduction is finished, and this recovery time in stage is 24～48h.
5. the industrial reduction method that is used for the iron-base fischer-tropsch synthesis catalyst of paste state bed reactor according to claim 1 is characterized in that: the whole reduction process of described catalyst is at the higher inlet linear speed work of finishing drilling, and the inlet linear speed is 0.15～0.5m/s.
6. the industrial reduction method that is used for the iron-base fischer-tropsch synthesis catalyst of paste state bed reactor according to claim 1, it is characterized in that: the reduction of described catalyst is carried out in the reduction reactor that is independent of the Fischer-Tropsch synthesis device, and an independently reduction unit is set, this reduction reactor is a paste state bed reactor, and the catalyst weight concentration in the slurries is 5～50%.
7. the industrial reduction method that is used for the iron-base fischer-tropsch synthesis catalyst of paste state bed reactor according to claim 1, it is characterized in that, described catalyst dosage bunker is provided with at least one, establish heat(ing) coil in mechanical agitator, dosage bunker hot nitrogen bubbling pipe and the dosage bunker in this dosage bunker, pressure is controlled by regulating the aperture of pressing nitrogen to add valve in dosage bunker atmospheric valve and the dosage bunker, and the catalyst slurry for preparing is delivered to reduction reactor with nitrogen pressure.
8. the industrial reduction method that is used for the iron-base fischer-tropsch synthesis catalyst of paste state bed reactor according to claim 1, it is characterized in that, described reduction reactor is realized a stable H by the relative scale of adjusting fresh synthesis gas, fresh hydrogen under the constant prerequisite of bed inlet linear speed
2/ CO ratio.
9. the industrial reduction method that is used for the iron-base fischer-tropsch synthesis catalyst of paste state bed reactor according to claim 1, it is characterized in that, described reduction reactor inlet is provided with at least one compressor, at least one heating heat exchanger, and the reduction reactor outlet is provided with at least one cooling heat exchanger, at least one vapour liquid separator.
10. the industrial reduction method that is used for the iron-base fischer-tropsch synthesis catalyst of paste state bed reactor according to claim 3, it is characterized in that, the reduction phase of described reduction reaction, reduction reactor need provide and add heat, reducing gases is sent into reduction reactor after being heated to higher temperature through heating heat exchanger, this moment, the by-pass bypass valve was closed; In reduction reactor, feed a certain amount of high steam toward the reactor inner coil pipe again and guarantee operating temperature.
11. the industrial reduction method that is used for the iron-base fischer-tropsch synthesis catalyst of paste state bed reactor according to claim 4, it is characterized in that, the adjusting stage of described reduction reaction, reduction reactor need be removed heat, progressively reduce the high steam feeding amount of reactor inner coil pipe with the increase of this stage reducing degree, drive material heating heat exchanger by-pass bypass valve into or directly reduce heating heat exchanger outlet design temperature and reduce inlet temperature; If inlet temperature is reduced to 110 ℃, to solidify for avoiding place, gas access paraffin occurring, the aperture that need stop the by-pass bypass valve this moment is regulated, and feeds boiler feedwater to remove heat in the reactor inner coil pipe.
12. the industrial reduction method that is used for the iron-base fischer-tropsch synthesis catalyst of paste state bed reactor according to claim 1, it is characterized in that, described reduction reactor adds valve by the reactor high pressure nitrogen of regulating the top and comes conditioned reaction device pressure behind complete and continuous reduction cycle of experience; When discharging, needs slurries are pressed into follow-up catalyst charge groove with nitrogen.
13. the industrial reduction method that is used for the iron-base fischer-tropsch synthesis catalyst of paste state bed reactor according to claim 1, it is characterized in that, establish heat(ing) coil in charge chute hot nitrogen bubbling pipe and the charge chute in the described catalyst charge groove, regulate pressure by the aperture of regulating charge chute nitrogen adding valve and charge chute atmospheric valve; When synthesis reactor need be added catalyst, catalyst slurry is pressed in the synthesis reactor with thermal high nitrogen.
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| CN100404137C (en) * | 2005-06-21 | 2008-07-23 | 上海兖矿能源科技研发有限公司 | Industrial reduction method of particle iron-base fischer-tropsch synthesis catalyst |
| CN102165040A (en) * | 2008-09-30 | 2011-08-24 | 日本石油天然气·金属矿物资源机构 | Bubble column reactor and method for controlling bubble column reactor |
| CN101703937B (en) * | 2009-09-29 | 2012-05-23 | 武汉凯迪工程技术研究总院有限公司 | Method for regenerating cobalt-base catalyst for slurry-phase Fischer-Tropsch synthesis |
| CN103170284A (en) * | 2013-04-03 | 2013-06-26 | 神华集团有限责任公司 | Fischer-Tropsch synthesis system and process of high-temperature and high-pressure slurry bed reactor |
| CN103769241A (en) * | 2014-02-18 | 2014-05-07 | 神华集团有限责任公司 | Fixed-bed Fischer-tropsch catalyst reduction activation system and technology |
| CN106311361A (en) * | 2015-06-24 | 2017-01-11 | 神华集团有限责任公司 | System and method for activation and online renewing of catalyst |
| CN106552571A (en) * | 2015-09-30 | 2017-04-05 | 江苏创新石化有限公司 | A kind of production system of strong adaptability electro-desalting agent |
| CN107638848A (en) * | 2017-10-20 | 2018-01-30 | 中科合成油工程股份有限公司 | A kind of online charging process of paste state bed reactor catalyst and its special equipment system |
| CN114345340A (en) * | 2022-01-08 | 2022-04-15 | 安庆市长虹化工有限公司 | Preparation process and working system of carrier copper nanotube dehydrogenation catalyst |
-
2003
- 2003-09-22 CN CN 03151105 patent/CN1233461C/en not_active Expired - Lifetime
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100404137C (en) * | 2005-06-21 | 2008-07-23 | 上海兖矿能源科技研发有限公司 | Industrial reduction method of particle iron-base fischer-tropsch synthesis catalyst |
| CN102165040A (en) * | 2008-09-30 | 2011-08-24 | 日本石油天然气·金属矿物资源机构 | Bubble column reactor and method for controlling bubble column reactor |
| CN102165040B (en) * | 2008-09-30 | 2014-03-19 | 日本石油天然气·金属矿物资源机构 | Bubble column reactor and method for controlling bubble column reactor |
| US8906314B2 (en) | 2008-09-30 | 2014-12-09 | Japan Oil, Gas And Metals National Corporation | Bubble column reactor and method of controlling bubble column reactor |
| CN101703937B (en) * | 2009-09-29 | 2012-05-23 | 武汉凯迪工程技术研究总院有限公司 | Method for regenerating cobalt-base catalyst for slurry-phase Fischer-Tropsch synthesis |
| CN103170284A (en) * | 2013-04-03 | 2013-06-26 | 神华集团有限责任公司 | Fischer-Tropsch synthesis system and process of high-temperature and high-pressure slurry bed reactor |
| CN103170284B (en) * | 2013-04-03 | 2016-02-17 | 神华集团有限责任公司 | Fischer-Tropsch synthesis system and process of high-temperature and high-pressure slurry bed reactor |
| CN103769241A (en) * | 2014-02-18 | 2014-05-07 | 神华集团有限责任公司 | Fixed-bed Fischer-tropsch catalyst reduction activation system and technology |
| CN106311361A (en) * | 2015-06-24 | 2017-01-11 | 神华集团有限责任公司 | System and method for activation and online renewing of catalyst |
| CN106552571A (en) * | 2015-09-30 | 2017-04-05 | 江苏创新石化有限公司 | A kind of production system of strong adaptability electro-desalting agent |
| CN107638848A (en) * | 2017-10-20 | 2018-01-30 | 中科合成油工程股份有限公司 | A kind of online charging process of paste state bed reactor catalyst and its special equipment system |
| CN114345340A (en) * | 2022-01-08 | 2022-04-15 | 安庆市长虹化工有限公司 | Preparation process and working system of carrier copper nanotube dehydrogenation catalyst |
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