Concrete, mortar waterproof agent and production technique thereof and constructional method
Technical field
The present invention relates to that a kind of building is impervious, water-resisting agent and production technique and constructional method.
Background technology
In the buildings water-tight concrete, usually adopt to add admixture, add cement, improve methods such as sand coarse aggregate ratio, reach impervious purpose, for the sake of assurance, water-tight concrete meet water or back side again with terpolymer EP rubber, polyamine fat film, coiled material such as SBS modifying asphalt does dual waterproof, this method requires anti-water termination necessary smooth, dry, not only have long construction period, problem that waterproof construction technology is more numerous and diverse, also have problems such as building comprehensive cost height, maintenance cost height.
Existing water-proofing composition such as Japanese Patent (JP60005054) are dispersed in lipid acid in the water, owing to controlled temperature, temperature control temporal differences, make the dissolving of lipid acid complete inadequately, emulsion reaction is also thorough inadequately, makes in the water-resisting agent effective ingredient of lipid acid not enough, has influenced waterproof effect.This invention is made defoamer with tbp, and defoaming effect is bad, therefore, has influenced the ultimate compression strength of the waterproof effect and the material of material.Have aluminium hydroxide to add in this day the present invention's prescription, it is big to add the retroaction in thermal response of this material, because aluminium destroys the stable of lipid acid, effective ingredient is reduced be good at many.
Summary of the invention
The purpose of this invention is to provide a kind of concrete, mortar waterproof agent and production technique thereof, solve the problem that concrete and mortar waterproof construction cycle are long, waterproof construction technology is numerous and diverse, also comprehensive cost height, the high problem of maintenance cost are built in solution, and solve the problem that the dissolving that has water-proofing composition lipid acid now is complete inadequately, emulsion reaction is thorough inadequately, the effective ingredient of lipid acid is stable inadequately, influence waterproof effect.
The technical scheme of concrete of the present invention, mortar waterproof agent is characterized in that: with lipid acid and water is main raw material, and per 100 parts of proportionings of calculating in mass are:
Water: lipid acid is 60-80 part: 20-40 part adds the emulsification properties-correcting agent of 0.4-0.6 part, the admixture of 0.3-0.5 part and the defoamer of 0.01-0.02 part in addition.
Above-mentioned water is the tap water of tap water or ph>50.
Above-mentioned lipid acid is one or more the combination wherein of soap, vegetables oil, stearic acid.
Above-mentioned emulsification properties-correcting agent is one or more the combination wherein of sodium hydroxide, potassium hydroxide, sodium sulfate.
Above-mentioned defoamer is the FPGM defoamer.
Above-mentioned admixture is one or more the combination wherein of potassium bichromate, glycerol, polyvinyl alcohol, trolamine, sodium sulfonate, methylcellulose gum, copper sulfate, water glass.
The production technique of this concrete, mortar waterproof agent is characterized in that processing step is as follows:
(1), lipid acid, water are placed the dissolving of heating in the Reaktionsofen, its condition is 80 ℃ of need 2.0 hours, 100 ℃ of need 1.0 hours;
(2), cool to 60-70 ℃ and add emulsification properties-correcting agent stirring constant temperature;
(3), heat and add admixture to 75-85 ℃ and stirred constant temperature 2 hours;
(4), heat 85-95 ℃ and add defoamer;
(5), be cooled to 70-80 ℃, constant temperature when thick shape appears in reactant;
(6), go out finished product.
The constructional method of this concrete, mortar waterproof agent 1., it is characterized in that: it is 250-350 times that the described concrete of claim 1, mortar waterproof agent are diluted with water to mass ratio, substitute mixing water, ready-mixed concrete is used for impervious, water-proof concrete construction.
The constructional method of this concrete, mortar waterproof agent 2., it is characterized in that: it is 150-200 times that the described concrete of claim 1, mortar waterproof agent are diluted with water to mass ratio, place of water is come mix cement paste or sand-cement slurry, is used for cement sand plaster, leak stopping, waterproof, protection against the tide.
Beneficial effect: concrete, mortar waterproof agent are main raw material with lipid acid and water, add emulsification properties-correcting agent, admixture, defoamer, solved the problem that dissolving is complete inadequately, emulsion reaction is thorough inadequately, waterproof effect is stablized, influenced to effective ingredient lipid acid inadequately of existing water-proofing composition lipid acid.The present invention improves stability and weather resistance to concrete, mortar, can prevent the water droplet space, reduces dry shrinkage, suppresses the crack, improves concrete, mortar strength, increases concrete slump, reduces water consumption, and workability is good.Mortar is reduced delamination degree, improve adhesivity, workability is good, increases anti-permeability performance, waterproof, and moisture effect is good; Easy construction, cold at normal temperatures construction, anti-water termination is done the wet influence of not having; Do not fire, alkaline-resisting, oil resistant; 100 ℃ of high temperature and subzero-30 ℃ low temperature all do not influence impervious waterproof effect; Long quality-guarantee period, convenient transportation, expense are low, in ceramic mosaic, wall floor tile decorative engineering, are used for adhesive material and have waterproof effect equally; , waterproof construction saving comprehensive fund more impervious: water-tight concrete 10-20%, waterproof mortar 20-40% than conventional method.The dissolving of lipid acid is complete, and emulsion reaction is thorough, makes that the effective ingredient of lipid acid increases greatly in the water-resisting agent, and defoaming effect is good, and the waterproof effect of material and the ultimate compression strength of material improve.Concrete mortar water-resisting agent technical performance index is as follows:
Test subject | Performance index |
Acceptable end product | Measured value |
Clean slurry stability | Qualified | Qualified |
Time of coagulation | Initial set (min) is not less than final set (h) and is not more than | ????45 ????10 | ????185 ????4.20 |
Compressive strength rate (%) is not less than | 7d | ????100 | ????108 |
?28d | ????90 | ????106 |
Permeable pressure ratio (%) is not less than | ????300 | ????340 |
48 water demand ratios (%) are not more than | ????65 | ????54 |
28 shrinkage ratios (%) are not more than | ????125 | ????103 |
Action of rust to reinforcing bar | To the effect of reinforcing bar non-corroding |
The test of JC474-1999 acceptable end product is pressed by national building materials test center, meets the requirements.
The present invention can be widely used between industry and covil construction roofing, lavatory, the vault of tunnel, subway, oil depot, the requirement of pond (drinking the pond) humidity meets water, impervious, the leak stopping of back side etc., waterproof, protection against the tide.Be fit to concrete, mortar waterproof agent and the production technique thereof of complex construction, use the concrete of its mix, waterproof mortar to have hydrophobic nature, impervious, waterproof, moisture effect are good, short construction period, and comprehensive cost reduces.The present invention is nontoxic, tasteless, production and transport, uses whole process pollution-free, to the waterproof basal plane do, wet no requirement (NR), impervious, waterproof effect is permanent.
Embodiment
Embodiment one: concrete, mortar waterproof agent are to be main raw material with lipid acid and cement, per 100 parts of mass ratioes are: water: lipid acid is 70 parts: 30 parts, add the emulsification properties-correcting agent of 0.4-0.5 part, the admixture of 0.3-0.4 part and the defoamer of 0.01--0.02 part in addition.
Water is the tap water or the tap water of PH>5.
The addition content of lipid acid is: 25 parts in soap, 2.0 parts of vegetables oil, 3.0 parts of stearic acid.
The addition content of emulsification properties-correcting agent is: 0.4 part in sodium hydroxide, 0.13 part in potassium hydroxide, 0.025 part in sodium sulfate.
The volume of admixture is: 0.35 part of potassium bichromate, 0.0025 part of glycerol, 0.0015 part of water glass, 0.002 part of sodium sulfonate.
The FPGM type defoamer that defoamer adopts Tianjin to produce, consumption is 0.015 part.
This concrete, mortar waterproof agent production craft step are as follows:
(1), lipid acid, water places the dissolving of heating in the Reaktionsofen, its temperature be 80 ℃ 2.0 hours, 100 ℃ 1.0 hours;
(2), cooling adds strong mixing for 90 ℃;
(3), cooling adds emulsification properties-correcting agent stirring constant temperature for 70 ℃;
(4), heat 90 ℃ and add admixture and stirred isothermal reaction 2 hours;
(5), constant temperature adds the defoamer stirring for 90 ℃;
(6), 75 ℃ of constant temperature when thick shape appears in reactant of cooling;
(7), go out finished product.
The dilute with water quality than embodiment is during use: water-tight concrete is with 300 times, and waterproof mortar is with 200 times.
Embodiment two: concrete, mortar waterproof agent are to be main raw material with lipid acid and cement, per 100 parts of mass ratioes are: water: lipid acid is 75 parts: 25 parts, add a little emulsification properties-correcting agent, admixture and defoamer in addition, be used for place of water and come mix concrete, cement paste or sand-cement slurry.
Water is the tap water or the tap water of PH>5
The addition content of lipid acid is: 20 parts in soap, 5.0 parts of stearic acid.
The addition content of emulsification properties-correcting agent is: 0.4 part in sodium hydroxide, 0.15 part in potassium hydroxide.
The volume of admixture is: 0.35 part of potassium bichromate, 0.0025 part of glycerol, 0.0035 part of water glass.
The FPGM type defoamer that defoamer adopts Tianjin to produce, consumption is 0.015 part.
Embodiment three: concrete, mortar waterproof agent are to be main raw material with lipid acid and cement, and per 100 parts of mass ratioes are: water: lipid acid is 65 parts: 35 parts, add a little emulsification properties-correcting agent, admixture and defoamer in addition.
Water is the tap water or the tap water of PH>5
The addition content of lipid acid is: 30 parts in soap, 2.0 parts of vegetables oil, 3.0 parts of stearic acid.
The addition content of emulsification properties-correcting agent is: 0.5 part in sodium hydroxide.
The volume of admixture is: 0.35 part of potassium bichromate, 0.0035 part of trolamine, 0.002 part of sodium sulfonate.
The FPGM type defoamer that defoamer adopts Tianjin to produce, consumption is 0.017 part.
Embodiment four: concrete, mortar waterproof agent are to be main raw material with lipid acid and cement, its per 100 parts of mass ratioes are: water: lipid acid is 80 parts: 20 parts, add a little emulsification properties-correcting agent, admixture and defoamer in addition, be used for place of water and come mix concrete, cement paste or sand-cement slurry.
Water is the tap water or the tap water of PH>5.
The addition content of lipid acid is: 15 parts in soap, 5.0 parts of vegetables oil.
The addition content of emulsification properties-correcting agent is: 0.6 part in potassium hydroxide.
The volume of admixture is: 0.35 part of polyvinyl alcohol, 0.004 part of methylcellulose gum, 0.002 part in copper sulfate.
The FPGM type defoamer that defoamer adopts Tianjin to produce, consumption is 0.012 part.