CN1586859A - Manufacturing method of composite material mold for resin transfer molding process - Google Patents
Manufacturing method of composite material mold for resin transfer molding process Download PDFInfo
- Publication number
- CN1586859A CN1586859A CN 200410062758 CN200410062758A CN1586859A CN 1586859 A CN1586859 A CN 1586859A CN 200410062758 CN200410062758 CN 200410062758 CN 200410062758 A CN200410062758 A CN 200410062758A CN 1586859 A CN1586859 A CN 1586859A
- Authority
- CN
- China
- Prior art keywords
- electroforming
- metal shell
- master mold
- epoxy resin
- composition metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 54
- 239000002131 composite material Substances 0.000 title claims abstract description 31
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 229920005989 resin Polymers 0.000 title claims abstract description 15
- 239000011347 resin Substances 0.000 title claims abstract description 15
- 238000001721 transfer moulding Methods 0.000 title claims abstract description 8
- 229910052751 metal Inorganic materials 0.000 claims abstract description 99
- 239000002184 metal Substances 0.000 claims abstract description 99
- 238000005323 electroforming Methods 0.000 claims abstract description 81
- 239000000463 material Substances 0.000 claims abstract description 45
- 239000007788 liquid Substances 0.000 claims abstract description 34
- 238000004070 electrodeposition Methods 0.000 claims abstract description 22
- 239000007787 solid Substances 0.000 claims abstract description 15
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000004140 cleaning Methods 0.000 claims abstract description 9
- 238000005498 polishing Methods 0.000 claims abstract description 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000007796 conventional method Methods 0.000 claims abstract description 7
- 239000010936 titanium Substances 0.000 claims abstract description 7
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 62
- 239000010949 copper Substances 0.000 claims description 55
- 229910052802 copper Inorganic materials 0.000 claims description 52
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 50
- 239000003822 epoxy resin Substances 0.000 claims description 43
- 229920000647 polyepoxide Polymers 0.000 claims description 43
- 239000003795 chemical substances by application Substances 0.000 claims description 42
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 32
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 26
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 20
- 239000011521 glass Substances 0.000 claims description 20
- 239000004744 fabric Substances 0.000 claims description 19
- 238000010438 heat treatment Methods 0.000 claims description 19
- 239000000843 powder Substances 0.000 claims description 18
- 239000004411 aluminium Substances 0.000 claims description 15
- 229910052782 aluminium Inorganic materials 0.000 claims description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 15
- 238000005507 spraying Methods 0.000 claims description 15
- 239000000080 wetting agent Substances 0.000 claims description 15
- 238000000465 moulding Methods 0.000 claims description 14
- 229910045601 alloy Inorganic materials 0.000 claims description 13
- 239000000956 alloy Substances 0.000 claims description 13
- 229910007570 Zn-Al Inorganic materials 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 12
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims description 10
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 10
- 238000010891 electric arc Methods 0.000 claims description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 10
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 10
- DITXJPASYXFQAS-UHFFFAOYSA-N nickel;sulfamic acid Chemical compound [Ni].NS(O)(=O)=O DITXJPASYXFQAS-UHFFFAOYSA-N 0.000 claims description 10
- 238000013019 agitation Methods 0.000 claims description 9
- VWFLTHZUCYHIEC-UHFFFAOYSA-N cobalt sulfamic acid Chemical compound [Co].S(N)(O)(=O)=O VWFLTHZUCYHIEC-UHFFFAOYSA-N 0.000 claims description 9
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 9
- 238000012856 packing Methods 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 7
- 239000004327 boric acid Substances 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000007747 plating Methods 0.000 claims description 5
- 238000005086 pumping Methods 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 239000011152 fibreglass Substances 0.000 abstract description 7
- 239000000243 solution Substances 0.000 description 22
- 239000000126 substance Substances 0.000 description 10
- 229910017709 Ni Co Inorganic materials 0.000 description 9
- 229910003267 Ni-Co Inorganic materials 0.000 description 9
- 229910003262 Ni‐Co Inorganic materials 0.000 description 9
- 238000012545 processing Methods 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 7
- 238000007666 vacuum forming Methods 0.000 description 7
- 238000006424 Flood reaction Methods 0.000 description 4
- 238000013461 design Methods 0.000 description 4
- 229920002635 polyurethane Polymers 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- 241001234523 Velamen Species 0.000 description 3
- 238000005275 alloying Methods 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 230000009977 dual effect Effects 0.000 description 3
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 229910003271 Ni-Fe Inorganic materials 0.000 description 2
- 229910003286 Ni-Mn Inorganic materials 0.000 description 2
- 206010070834 Sensitisation Diseases 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000011157 advanced composite material Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- PYRZPBDTPRQYKG-UHFFFAOYSA-N cyclopentene-1-carboxylic acid Chemical compound OC(=O)C1=CCCC1 PYRZPBDTPRQYKG-UHFFFAOYSA-N 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000007772 electroless plating Methods 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 229910001092 metal group alloy Inorganic materials 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 230000008313 sensitization Effects 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 238000007738 vacuum evaporation Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000013536 elastomeric material Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000013519 translation Methods 0.000 description 1
Images
Landscapes
- Moulds For Moulding Plastics Or The Like (AREA)
Abstract
Description
Hardness HV | Cost | Die life | Production cycle (week) | |
The conventional metals mould | 750MPa | ??100% | >100,000 | ????4~8 |
Composite material mould | 50MPa | ??10~15% | <1000 | ????2~3 |
Electroforming Ni-Co alloy mold | 550MPa | ??25~35% | >100,000 | ????3~4 |
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2004100627584A CN1320991C (en) | 2004-07-09 | 2004-07-09 | Manufacturing method of composite material mold for resin transfer molding process |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2004100627584A CN1320991C (en) | 2004-07-09 | 2004-07-09 | Manufacturing method of composite material mold for resin transfer molding process |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1586859A true CN1586859A (en) | 2005-03-02 |
CN1320991C CN1320991C (en) | 2007-06-13 |
Family
ID=34603772
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2004100627584A Expired - Lifetime CN1320991C (en) | 2004-07-09 | 2004-07-09 | Manufacturing method of composite material mold for resin transfer molding process |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1320991C (en) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102108534A (en) * | 2010-11-30 | 2011-06-29 | 华侨大学 | Mold making method based on ultrasonic pulse electrodeposition and spray forming and mold |
CN102154676A (en) * | 2011-04-14 | 2011-08-17 | 华侨大学 | Method for electrodepositing and strengthening low-melting-point metal spray mould |
CN102691079A (en) * | 2012-05-03 | 2012-09-26 | 杭州先临快速成型技术有限公司 | Method for rapidly manufacturing low-temperature alloy casting mould |
CN103085197A (en) * | 2011-11-01 | 2013-05-08 | 郑钧介 | Method for manufacturing waterproof and air-permeable plastic shoe body by using electroforming layer mold |
CN106938509A (en) * | 2017-05-18 | 2017-07-11 | 大连日瑞铸模有限公司 | A kind of compound resin metal die and preparation method thereof |
CN107009105A (en) * | 2017-05-12 | 2017-08-04 | 广东工业大学 | The preparation method and device of a kind of micro-fluidic mould in T-shaped section |
CN108927460A (en) * | 2017-05-23 | 2018-12-04 | 成都飞机工业(集团)有限责任公司 | A kind of deep U type sheet metal component molding die processing method |
CN109338419A (en) * | 2018-12-03 | 2019-02-15 | 台州市黄岩圣发模具有限公司 | A kind of PDCPD nickel mould and its electroforming manufacturing process |
CN109423668A (en) * | 2017-09-01 | 2019-03-05 | 泉州市同兴反光材料有限公司 | A kind of four square plate process flows making reflecting mould |
CN109732816A (en) * | 2019-02-22 | 2019-05-10 | 长沙博兴汽车科技有限公司 | It is a kind of using foam as the composite material manufacture craft of mould substrate |
CN111519217A (en) * | 2020-05-07 | 2020-08-11 | 吉林大学 | Slush molding die and reinforcement treatment method and application thereof |
CN111621818A (en) * | 2020-06-09 | 2020-09-04 | 南通市众惠模具有限公司 | Die cavity surface galvanizing process |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1704241A1 (en) * | 1966-10-11 | 1971-05-06 | Tarcisio Ottogalli | Process for the production of casting molds with electrolytically profiled matrices, particularly suitable for the production of objects from injection molding compound with precisely predetermined wall thicknesses |
JPH01294015A (en) * | 1988-05-23 | 1989-11-28 | Nissan Shatai Co Ltd | Preparation of electroformed mold |
JPH02243307A (en) * | 1989-03-17 | 1990-09-27 | Yamaha Motor Co Ltd | Electroforming mold |
US5632878A (en) * | 1994-02-01 | 1997-05-27 | Fet Engineering, Inc. | Method for manufacturing an electroforming mold |
JP4588942B2 (en) * | 2001-08-23 | 2010-12-01 | 本田技研工業株式会社 | Manufacturing method of resin mold |
-
2004
- 2004-07-09 CN CNB2004100627584A patent/CN1320991C/en not_active Expired - Lifetime
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102108534A (en) * | 2010-11-30 | 2011-06-29 | 华侨大学 | Mold making method based on ultrasonic pulse electrodeposition and spray forming and mold |
CN102154676A (en) * | 2011-04-14 | 2011-08-17 | 华侨大学 | Method for electrodepositing and strengthening low-melting-point metal spray mould |
CN103085197A (en) * | 2011-11-01 | 2013-05-08 | 郑钧介 | Method for manufacturing waterproof and air-permeable plastic shoe body by using electroforming layer mold |
CN102691079A (en) * | 2012-05-03 | 2012-09-26 | 杭州先临快速成型技术有限公司 | Method for rapidly manufacturing low-temperature alloy casting mould |
CN102691079B (en) * | 2012-05-03 | 2015-02-25 | 杭州先临快速成型技术有限公司 | Method for rapidly manufacturing low-temperature alloy casting mould |
CN107009105A (en) * | 2017-05-12 | 2017-08-04 | 广东工业大学 | The preparation method and device of a kind of micro-fluidic mould in T-shaped section |
CN106938509A (en) * | 2017-05-18 | 2017-07-11 | 大连日瑞铸模有限公司 | A kind of compound resin metal die and preparation method thereof |
CN108927460A (en) * | 2017-05-23 | 2018-12-04 | 成都飞机工业(集团)有限责任公司 | A kind of deep U type sheet metal component molding die processing method |
CN109423668A (en) * | 2017-09-01 | 2019-03-05 | 泉州市同兴反光材料有限公司 | A kind of four square plate process flows making reflecting mould |
CN109338419A (en) * | 2018-12-03 | 2019-02-15 | 台州市黄岩圣发模具有限公司 | A kind of PDCPD nickel mould and its electroforming manufacturing process |
CN109732816A (en) * | 2019-02-22 | 2019-05-10 | 长沙博兴汽车科技有限公司 | It is a kind of using foam as the composite material manufacture craft of mould substrate |
CN111519217A (en) * | 2020-05-07 | 2020-08-11 | 吉林大学 | Slush molding die and reinforcement treatment method and application thereof |
CN111621818A (en) * | 2020-06-09 | 2020-09-04 | 南通市众惠模具有限公司 | Die cavity surface galvanizing process |
Also Published As
Publication number | Publication date |
---|---|
CN1320991C (en) | 2007-06-13 |
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Legal Events
Date | Code | Title | Description |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20081212 Address after: 261 mailbox, Beijing City Patentee after: Sinomatech Wind Power Blade Co., Ltd. Address before: 261 mailbox, Beijing City Patentee before: Beijing Research Design Inst. of GRP Product |
|
ASS | Succession or assignment of patent right |
Owner name: ZHONGCAI WIND POWER SCIENCE BLADE CO., LTD. Free format text: FORMER OWNER: BEIJING REINFORCED GLASS DESIGN INSTITUTE, BEIJING CITY Effective date: 20081212 |
|
EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Sinoma Technology (Baicheng) wind turbine blade Co., Ltd. Assignor: Sinomatech Wind Power Blade Co., Ltd. Contract record no.: 2011990000693 Denomination of invention: Method for producing composite material mould for resin transfer moulding process Granted publication date: 20070613 License type: Exclusive License Open date: 20050302 Record date: 20110720 |