CN1583978A - Nanometer micro-emulsified fuel oil synergist and preparing method thereof - Google Patents
Nanometer micro-emulsified fuel oil synergist and preparing method thereof Download PDFInfo
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- CN1583978A CN1583978A CN 03153658 CN03153658A CN1583978A CN 1583978 A CN1583978 A CN 1583978A CN 03153658 CN03153658 CN 03153658 CN 03153658 A CN03153658 A CN 03153658A CN 1583978 A CN1583978 A CN 1583978A
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- 239000000295 fuel oil Substances 0.000 title claims abstract description 50
- 238000000034 method Methods 0.000 title abstract description 4
- 239000003607 modifier Substances 0.000 claims abstract description 25
- 239000003444 phase transfer catalyst Substances 0.000 claims abstract description 24
- 238000002360 preparation method Methods 0.000 claims abstract description 24
- 238000002242 deionisation method Methods 0.000 claims abstract description 19
- 239000007788 liquid Substances 0.000 claims abstract description 19
- 239000002283 diesel fuel Substances 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 239000003502 gasoline Substances 0.000 claims abstract description 11
- 238000004945 emulsification Methods 0.000 claims description 52
- 239000013543 active substance Substances 0.000 claims description 23
- 239000012452 mother liquor Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000012747 synergistic agent Substances 0.000 claims description 11
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- 238000002156 mixing Methods 0.000 claims description 8
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- 238000003756 stirring Methods 0.000 claims description 7
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- 230000003389 potentiating effect Effects 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 6
- CUBCNYWQJHBXIY-UHFFFAOYSA-N benzoic acid;2-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC=C1.OC(=O)C1=CC=CC=C1O CUBCNYWQJHBXIY-UHFFFAOYSA-N 0.000 claims description 5
- -1 glyceryl alcohol Chemical compound 0.000 claims description 5
- 238000010907 mechanical stirring Methods 0.000 claims description 5
- 239000011259 mixed solution Substances 0.000 claims description 5
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- 239000000047 product Substances 0.000 claims description 5
- 230000000087 stabilizing effect Effects 0.000 claims description 5
- 241000158728 Meliaceae Species 0.000 claims description 4
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- 229920001219 Polysorbate 40 Polymers 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
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- 239000000194 fatty acid Substances 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 239000004021 humic acid Substances 0.000 claims description 3
- 239000000249 polyoxyethylene sorbitan monopalmitate Substances 0.000 claims description 3
- 235000010483 polyoxyethylene sorbitan monopalmitate Nutrition 0.000 claims description 3
- 229940101027 polysorbate 40 Drugs 0.000 claims description 3
- 150000005846 sugar alcohols Polymers 0.000 claims description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005642 Oleic acid Substances 0.000 claims description 2
- 150000008431 aliphatic amides Chemical group 0.000 claims description 2
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 claims description 2
- 235000020661 alpha-linolenic acid Nutrition 0.000 claims description 2
- 150000004982 aromatic amines Chemical group 0.000 claims description 2
- 150000002170 ethers Chemical class 0.000 claims description 2
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- 150000002195 fatty ethers Chemical class 0.000 claims description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 2
- 229960004488 linolenic acid Drugs 0.000 claims description 2
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 claims description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920000136 polysorbate Polymers 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical class [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract description 7
- 239000000446 fuel Substances 0.000 abstract description 7
- 229930195733 hydrocarbon Natural products 0.000 abstract description 7
- 238000002485 combustion reaction Methods 0.000 abstract description 6
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 6
- 239000003921 oil Substances 0.000 abstract description 6
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000006213 oxygenation reaction Methods 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 230000000996 additive effect Effects 0.000 description 5
- 239000003344 environmental pollutant Substances 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 231100000719 pollutant Toxicity 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N N-phenyl amine Natural products NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000001721 carbon Chemical group 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical group CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 239000003643 water by type Substances 0.000 description 3
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical group CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical group CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- 239000003747 fuel oil additive Substances 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 239000004530 micro-emulsion Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 238000001956 neutron scattering Methods 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 230000010494 opalescence Effects 0.000 description 1
- 230000037081 physical activity Effects 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Landscapes
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
This invention relates to nano microemulsified oil process agent. It contains phase transfer catalyst, microemulsified aid, microemulsified surfactant, active deionization, and interfacial modifier. The preparation method is that confect the parent liquid from the former two components and the auxiliary liquid from latter three and then compound the process agent. And so it can improve the ability of hydrocarbon fuel such as gasoline, diesel oil and heavy oil. Moreover, it can reduce the surface tension of oil molecules by using interfacial modifier and can obviously advance the normal combustion, detergeney, microsystem lubricity, resistance to corrosion, and anti-oxygenation of the fuel. Additionally, of course, it reduces the force of attraction between oil molecules.
Description
Technical field
The present invention relates to a kind of nano micro-emulsification synergist for fuel oil and preparation method thereof, it is a kind of synergistic agent that is widely used in hydrocarbon fuel such as gasoline, diesel oil, heavy oil.
Background technology
Domestic fuel oil additive development is later, and kind is simple, mainly all concentrates on the additive based on the simple function of purification agent, and it is a lot of that technology duplicates.Traditional vapour, diesel oil detergent (referring to CN98103579.5) performance are simple, and mainly also concentrating on poly-alkylamide and polyetheramine etc. is main detergent-dispersant additive, its function singleness, and fuel-economizing is not obvious.In addition, traditional purification agent adds certain dirty effect of falling in vapour, the diesel oil, but because the adding and the other reasons of nitride generally can cause amount of nitrogen oxides to raise, and oxynitride are the arch-criminals who causes photo-chemical smog in the urban atmosphere.
After diesel oil emulsifier (referring to CN02111285.1) adds, can reduce pollution during the burning of the diesel oil emulsification of formation, and fuel-economizing is to a certain degree arranged, but the unstable of diesel oil emulsification is brought many inconvenience to the user.
At present, the additive kind that is applied on bavin, the heavy oil is a lot, but great majority are to act as main mixed type additive (referring to CN02157655.6) with metal ion catalysis, after duration of service is long, can cause combustion equipment ash depositions such as boiler, kiln serious, even influence trouble-free burning.
Summary of the invention
The technical issues that need to address of the present invention provide the nano micro-emulsification synergist for fuel oil of a kind of brand-new, multi-functional, efficient, stable performance, fuel-economizing.
Another technical problem that the present invention need solve provides the method that a kind of micro-emulsion technology that simply utilizes one of nanochemistry research and nano material preparation technology prepares the nano micro-emulsification fuel oil additive.
Nano micro-emulsification synergist for fuel oil of the present invention, synthetic by the common reaction of phase-transfer catalyst, microemulsified tensio-active agent, microemulsifying assistant, deionization active water and interface modifier five parts, wherein each components contents is formed, phase-transfer catalyst is 8-12 (weight %), the microemulsified tensio-active agent is 16-23 (weight %), microemulsifying assistant is 30-46 (weight %), and the deionization active water is 10-30 (weight %), and interface modifier is 14-25 (weight %).
Nano micro-emulsification synergist for fuel oil of the present invention, its phase-transfer catalyst comprises Triton series, factions of department row and tween series, its microemulsified tensio-active agent comprises the salt that alkylsulphonic acid, citric acid, Whitfield's ointment, linolenic acid, oleic acid etc. form, its microemulsifying assistant is based on polyalcohols, fatty acid, fatty ethers, polyamide-based, polyamines class that its interface modifier comprises.
Nano micro-emulsification synergist for fuel oil of the present invention, the prescription of its nano micro-emulsification gasoline synergist is, phase-transfer catalyst is 8-10 (weight %), the microemulsified tensio-active agent is 16-20 (weight %), microemulsifying assistant is 35-40 (weight %), the deionization active water is 15-30 (weight %), and interface modifier is 15-20 (weight %).
Nano micro-emulsification synergist for fuel oil of the present invention, in the composition of its nano micro-emulsification gasoline synergist, phase-transfer catalyst is a Triton-100, and the microemulsified tensio-active agent is the alkyl mahogany acid, microemulsifying assistant is ten glyceryl alcohol or Fatty Alcohol(C12-C14 and C12-C18) about carbon atom, and interface modifier is an aliphatic amide.
Nano micro-emulsification synergist for fuel oil of the present invention, the prescription of its nano micro-emulsification diesel oil potentiating agent is, phase-transfer catalyst is 8-10 (weight %), the microemulsified tensio-active agent is 18-22 (weight %), microemulsifying assistant is 32-43 (weight %), the deionization active water is 25-30 (weight %), and interface modifier is 14-18 (weight %).
Nano micro-emulsification synergist for fuel oil of the present invention, in the composition of its nano micro-emulsification diesel oil potentiating agent, phase-transfer catalyst is a polysorbate40, and the microemulsified tensio-active agent is a humic acids, microemulsifying assistant is 12 glyceryl alcohols about carbon atom, and interface modifier is a polyamines.
Nano micro-emulsification synergist for fuel oil of the present invention, the prescription of its nano micro-emulsification additive for heavy oil is, phase-transfer catalyst is 9-12 (weight %), the microemulsified tensio-active agent is 11-17 (weight %), microemulsifying assistant is 35-44 (weight %), the deionization active water is 15-20 (weight %), and interface modifier is 15-20 (weight %).
Nano micro-emulsification synergist for fuel oil of the present invention, in the composition of its nano micro-emulsification heavy oil synergistic agent, phase-transfer catalyst is that department sends 60, and the microemulsified tensio-active agent is a Whitfield's ointment, and microemulsifying assistant is ten ethers about carbon atom, and interface modifier is an aromatic amine.
The preparation method of nano micro-emulsification synergist for fuel oil of the present invention finishes (each raw material all by weight) branch three step:
1, preparation mother liquor: put into after phase-transfer catalyst, two kinds of materials of microemulsified tensio-active agent are mixed in proportion container inner control temperature under 40-70 ℃ and pressure 0.7-1.5 normal atmosphere, stirred 5-10 hour mother liquor.
2, the auxiliary liquid of preparation: microemulsifying assistant, deionization active water and three kinds of materials of interface modifier are mixed in proportion, under normal temperature and normal pressure, through the low pressure seal reactor mix and individual hour of mechanical stirring 7-15 to uniform and stable mixed solution occurring.
3, synthetic synergistic agent: speed stabilizing added above-mentioned mother liquor when the auxiliary liquid that will prepare stirred, and small amount of precipitate can occur during beginning, quickened to stir until dissolving, treat the throw out dissolving disperse to form stablize mixing solutions after, can be packed as finished product.
Adopt the nano micro-emulsification synergist for fuel oil of preparation method's preparation of the present invention, the water-in-oil particle that in fuel oil, is dispersed into, measure its particle size range in the 1-100 nanometer with neutron scattering experiment, synergist solution opalescence can not occur in fuel oil, and the microemulsion system of formation is a thermodynamic stable system.
Nano micro-emulsification synergist for fuel oil of the present invention is diffusion rapidly after adding fuel oil, uniform dissolution.It also can make the physical activity of fuel oil improve at fuel combustion process, and then improves the combustionproperty of fuel oil.The synthesis result of this effect significantly reduces the consumption of fuel oil, and the dynamic performance of engine (power-equipment such as boiler) increases substantially, and the noxious pollutant in the exhaust emissions significantly reduces.Simultaneously, the adding of nano micro-emulsification synergist for fuel oil has prevented that the carbon deposit of combustion chamber internal surface from generating, and plays the effect of maintenance at any time.Old original carbon deposit there is the effect of decomposition, and discharges with waste gas.The average rate of economizing gasoline of automobile-used nano micro-emulsification synergist for fuel oil is 8-15%.Boiler is 6-14% with the average rate of economizing gasoline of nano micro-emulsification synergist for fuel oil.Automobile-used nano micro-emulsification synergist for fuel oil can reduce pollutant emission 30%-60% such as carbon monoxide, hydrocarbon polymer, oxynitride simultaneously.Boiler can reduce pollutant emission 20%-60% such as smoke intensity, carbon monoxide, hydrocarbon polymer, oxynitride simultaneously with the nano micro-emulsification synergist for fuel oil.
Nano micro-emulsification synergist for fuel oil of the present invention is for improving gasoline, diesel oil, the efficient enhancer composition of hydrocarbon fuel performances such as heavy oil, contain polyalcohols, fatty acid, aliphatic ether amine, introducing selective interface properties-correcting agent can make the fuel molecule surface tension descend, it can strengthen the combustion completion of hydrocarbon fuel significantly, detergency, the micro-system oilness, erosion resistance, oxidation-resistance and reduce between oil molecule characteristic such as gravitation, it can comprehensively solve purification agent and remove colloid, the effect of carbon deposit, but also can improve the burning of fuel oil in the combustion chamber, can reduce the exhaust pollutant carbon monoxide fully and effectively, hydrocarbon polymer and oxynitride.This nano micro-emulsification synergist for fuel oil does not contain the toxic metal ion, does not have ash after having burnt, and also has good peace and quiet effect simultaneously, can suitably remove oil circuit settling, maintain equipment.
Embodiment
Embodiment 1
The prescription of nano micro-emulsification gasoline synergist of the present invention is, phase-transfer catalyst is a Triton-100, content is 10% (weight), the microemulsified tensio-active agent is the dodecyl mahogany acid, and content is 20% (weight), and microemulsifying assistant is a nonylcarbinol, content is 40% (weight), the deionization active water is 15% (weight), and interface modifier is a stearylamine, and content is 15% (weight).
The preparation method of nano micro-emulsification gasoline synergist of the present invention is:
1, preparation mother liquor: after 10 gram Triton-100 and 20 gram alkyl mahogany acids are mixed, put into container inner control temperature under 40 ℃ and pressure 1 normal atmosphere, stirred 5 hours mother liquor.
2, the auxiliary liquid of preparation: 40 gram nonylcarbinols, 15 gram deionization active waters and three kinds of mixing of materials of 15 gram stearylamines are formed secondary liquid composition, under normal temperature and normal pressure, through the low pressure seal reactor mix and mechanical stirring 7 hours to uniform and stable mixed solution occurring, promptly get to assist liquid.
3, synthetic synergistic agent: speed stabilizing added above-mentioned mother liquor when the auxiliary liquid that will configure stirred, and small amount of precipitate can occur during beginning, quickened to stir until dissolving, treat the throw out dissolving disperse to form stablize mixing solutions after, packing promptly gets 100 and restrains finished products.
Embodiment 2
The prescription of nano micro-emulsification diesel oil potentiating agent of the present invention is, phase-transfer catalyst is a polysorbate40, content is 8% (weight), the microemulsified tensio-active agent is a humic acids, and content is 20% (weight), and microemulsifying assistant is a n-dodecanol, content is 32% (weight), the deionization active water is 25% (weight), and interface modifier is third triamine, and content is 15% (weight).
The preparation method of nano micro-emulsification diesel oil potentiating agent of the present invention is:
1, preparation mother liquor: after 8 gram polysorbate40s and 20 gram humic acidss are mixed, put into container inner control temperature under 70 ℃ and pressure 1 normal atmosphere, stirred 7 hours mother liquor.
2, the auxiliary liquid of preparation: 32 gram n-dodecanols, 25 gram deionization active waters and three kinds of mixing of materials of 15 gram propylene diamine are formed secondary liquid composition, under normal temperature and normal pressure, through the low pressure seal reactor mix and mechanical stirring 10 hours to uniform and stable mixed solution occurring, promptly get to assist liquid.
3, synthetic synergistic agent: speed stabilizing added above-mentioned mother liquor when the auxiliary liquid that will configure stirred, and small amount of precipitate can occur during beginning, quickened to stir until dissolving, treat the throw out dissolving disperse to form stablize mixing solutions after, packing promptly gets 100 and restrains finished products.
Embodiment 3
The prescription of water-in-oil-type nanometer heavy oil synergistic agent of the present invention is, phase-transfer catalyst is that department sends 60, content is 12% (weight), the microemulsified tensio-active agent is a Whitfield's ointment, and content is 17% (weight), and microemulsifying assistant is an ether in positive last of the ten Heavenly stems, content is 36% (weight), the deionization active water is 15% (weight), and interface modifier is an aniline, and content is 20% (weight).
The preparation method of nano micro-emulsification heavy oil synergistic agent of the present invention is:
1, preparation mother liquor: after send 60 and 17 gram Whitfield's ointments to mix the 12 gram departments, put into container inner control temperature 70 ℃ with pressure 1 normal atmosphere under stirring 10 hours mother liquor.
2, the auxiliary liquid of preparation: 36 grams ether in the positive last of the ten Heavenly stems, 15 gram deionization active waters and three kinds of mixing of materials of 20 gram aniline are formed secondary liquid composition, under normal temperature and normal pressure, through the low pressure seal reactor mix and mechanical stirring 10 hours to uniform and stable mixed solution occurring, promptly get to assist liquid.
3, synthetic synergistic agent: speed stabilizing added above-mentioned mother liquor when the auxiliary liquid that will configure stirred, and small amount of precipitate can occur during beginning, quickened to stir until dissolving, treat the throw out dissolving disperse to form stablize mixing solutions after, packing promptly gets 100 and restrains finished products.
Claims (10)
1, nano micro-emulsification synergist for fuel oil, it is characterized in that this nano micro-emulsification synergist for fuel oil comprises phase-transfer catalyst, microemulsified tensio-active agent, microemulsifying assistant, deionization active water and interface modifier, wherein each components contents is formed, phase-transfer catalyst is 8-12 (weight %), the microemulsified tensio-active agent is 16-23 (weight %), microemulsifying assistant is 30-46 (weight %), and the deionization active water is 10-30 (weight %), and interface modifier is 14-25 (weight %).
2, nano micro-emulsification synergist for fuel oil according to claim 1, it is characterized in that described phase-transfer catalyst comprises Triton series, factions of department row and tween series, described microemulsified tensio-active agent comprises the salt that alkylsulphonic acid, citric acid, Whitfield's ointment, linolenic acid, oleic acid etc. form, described microemulsifying assistant is based on polyalcohols, fatty acid, fatty ethers, polyamide-based, polyamines class that described interface modifier comprises.
3, nano micro-emulsification synergist for fuel oil according to claim 1, the prescription that it is characterized in that the nano micro-emulsification gasoline synergist is, phase-transfer catalyst is 8-10 (weight %), the microemulsified tensio-active agent is 16-20 (weight %), microemulsifying assistant is 35-40 (weight %), the deionization active water is 15-30 (weight %), and interface modifier is 15-20 (weight %).
4, nano micro-emulsification synergist for fuel oil according to claim 3, it is characterized in that in the composition of described nano micro-emulsification gasoline synergist, phase-transfer catalyst is a Triton-100, the microemulsified tensio-active agent is the alkyl mahogany acid, microemulsifying assistant is ten glyceryl alcohol or Fatty Alcohol(C12-C14 and C12-C18) about carbon atom, and interface modifier is an aliphatic amide.
5, nano micro-emulsification synergist for fuel oil according to claim 1, the prescription that it is characterized in that the nano micro-emulsification diesel oil potentiating agent is, phase-transfer catalyst is 8-10 (weight %), the microemulsified tensio-active agent is 18-22 (weight %), microemulsifying assistant is 32-43 (weight %), the deionization active water is 25-30 (weight %), and interface modifier is 14-18 (weight %).
6, nano micro-emulsification synergist for fuel oil according to claim 5, it is characterized in that in the composition of described nano micro-emulsification diesel oil potentiating agent, phase-transfer catalyst is a polysorbate40, the microemulsified tensio-active agent is a humic acids, microemulsifying assistant is 12 glyceryl alcohols about carbon atom, and interface modifier is a polyamines.
7, nano micro-emulsification synergist for fuel oil according to claim 1, the prescription that it is characterized in that nano micro-emulsification heavy oil synergistic agent is, phase-transfer catalyst is 9-12 (weight %), the microemulsified tensio-active agent is 11-17 (weight %), microemulsifying assistant is 35-44 (weight %), the deionization active water is 15-20 (weight %), and interface modifier is 15-20 (weight %).
8, nano micro-emulsification synergist for fuel oil according to claim 7, it is characterized in that in the composition of described nano micro-emulsification heavy oil synergistic agent, phase-transfer catalyst is that department sends 60, the microemulsified tensio-active agent is a Whitfield's ointment, microemulsifying assistant is ten ethers about carbon atom, and interface modifier is an aromatic amine.
9, the preparation method of nano micro-emulsification synergist for fuel oil may further comprise the steps:
(1), preparation mother liquor: put into after phase-transfer catalyst, two kinds of materials of microemulsified tensio-active agent are mixed in proportion container inner control certain temperature and pressure stir certain hour mother liquor.
(2), the auxiliary liquid of preparation: microemulsifying assistant, deionization active water and three kinds of materials of interface modifier are mixed in proportion, under normal temperature and normal pressure, through the low pressure seal reactor mix and the mechanical stirring certain hour to uniform and stable mixed solution occurring.
(3), synthetic synergistic agent: speed stabilizing added above-mentioned mother liquor when the auxiliary liquid that will prepare stirred, and small amount of precipitate can occur during beginning, quickened to stir until dissolving, treat the throw out dissolving disperse to form stablize mixing solutions after, can be packed as finished product.
10, the preparation method of nano micro-emulsification synergist for fuel oil according to claim 9, the temperature that it is characterized in that described preparation mother liquor be 40-70 (℃), pressure is 0.7-1.5 (normal atmosphere), churning time be 5-10 (hour), the churning time of the auxiliary liquid of described preparation be 7-15 (hour).
Priority Applications (1)
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104479773A (en) * | 2014-11-14 | 2015-04-01 | 山东永泰化工有限公司 | Heavy oil emulsifier and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101418243B (en) * | 2008-12-08 | 2010-05-12 | 山东鑫海汽车配件有限公司 | Nano fuel additive agent and preparation method thereof |
| CN102643688B (en) * | 2012-04-09 | 2015-06-03 | 北京博雅思明环保科技有限公司 | Nanometre fuel additive and preparation method for same |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1329130A (en) * | 2001-06-13 | 2002-01-02 | 谢学秀 | Nanometer emulsion fuel additive composite and its preparation method |
| CN1422934A (en) * | 2001-12-06 | 2003-06-11 | 徐涛 | Micro emulsion fuel production process and formula |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104479773A (en) * | 2014-11-14 | 2015-04-01 | 山东永泰化工有限公司 | Heavy oil emulsifier and preparation method thereof |
| CN104479773B (en) * | 2014-11-14 | 2015-12-30 | 山东永泰化工有限公司 | A kind of heavy-oil emulsifying agent and preparation method thereof |
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