CN1572279A - Abluent composition - Google Patents
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- CN1572279A CN1572279A CNA2004100451996A CN200410045199A CN1572279A CN 1572279 A CN1572279 A CN 1572279A CN A2004100451996 A CNA2004100451996 A CN A2004100451996A CN 200410045199 A CN200410045199 A CN 200410045199A CN 1572279 A CN1572279 A CN 1572279A
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Abstract
This cleanser composition essentially comprises (A) a phosphoric ester-based surfactant and (B) an N-acyl-[alpha]-alanine or a salt thereof in the formulation weight ratio(A/B) of (99:1) to (40:60), wherein the component B is preferably an N-acyl-L-alanine or a salt thereof, more preferably an N-acylalanine alkali metal salt. To obtain a cleanser composition quick in foaming startup in cleansing, excellent in foam volume, foam spreadability and foam retention, giving neither residual feeling nor unfavorable touch feeling for the skin and hair in rinsing, giving moist and refreshing feeling to the skin after dried, and giving the hair moist feeling and softness and lightness.
Description
Technical field
The present invention relates to phosphate ester be surfactant and N-acyl-alpha--alanine or its salt serve as must composition skin or hair composition of detergent.Composition of detergent of the present invention when washing bubble morning, foam volume, foam ductility and retentivity good, with regard to the sensation during with regard to washing, do not give the residual sense of skin and hair, rough sense, with regard to dried sensation, skin wet and frank usability can be given, its soft and light composition of detergent can be given when bringing moist feeling to hair.
Background technology
At present, be the anion surfactant of representative, the betaine type amphoteric surfac-tant is used as skin or hair usefulness detergent (compositions) owing to its foam volume, cleaning strength height clean composition use with alkyl sulfate salt, polyoxyethylene alkyl ether sulfate salt, long-chain fatty acid soap alkali, phosphoric acid ester surfactant.But this existing detergent (compositions), for skin the shortcoming of wizened sense is arranged when washing the time has residual sense or rough sense strong, dry, parch when having residual sense or rough sense strong, dry when wash for hair puzzled by force, hair shortcoming such as is difficult to sleek.
Rough mitigation the when washing for making, give purposes such as conditioning effect, in detergent, used the such cationic macromolecule conditioner of cellulose of cationization, but in order to demonstrate effect of sufficient, a large amount of cationic macromolecules that cooperate, can make the detergent foam degradation, and existence makes the people feel to have the problem of residual sense when washing and after dry.
In addition, glycerol, propylene glycol, sodium lactate etc. are known as wetting agent, but the only combination of these wetting agents and detergent and the skin and the hair composition of detergent that form, and the moist feeling of skin is not improved fully.
The spy opens and discloses a kind of composition of detergent with selectivity washing function that cooperates N-acyl-alpha--alanine salt in the 2000-265191 communique.And, emphasized in the document that so-called " selectivity washing function " is exactly can wash spot on the skin, keratinous protein useless well off and from the lipid of sebaceous gland, and be difficult to remove the lipid from epidermis cell such as the necessary cholesterol of the defensive enginery of skin, ceramide.But research according to the inventor: in the document concrete disclosed composition of detergent exist not good as bubble amount, the foam maintenance aspect of detergent key property, shortcoming such as skin brisk and neat sense after drying is not good.
Alkanoyl alkyltaurate and phosphoric acid ester surfactant have been proposed to contain in the Te Kaiping 04-198125 communique, and the technical scheme of the composition of detergent of N-acyl amino hydrochlorate.As the instantiation such as the coco-nut oil fatty acid acyl glutamic acid triethanolamine of N-acyl amino hydrochlorate, and the cooperation example of lauryl sodium phosphate and coco-nut oil fatty acid acyl glutamic acid triethanolamine is disclosed.But research according to the inventor, it is not good that there are aspects such as foaming morning as the detergent key property, bubble amount in concrete disclosed composition of detergent in the document, skin and hair there is residual sense, with regard to dried sensation, existence can not make skin have the situation of abundant brisk and neat sense, to hair, existence can not be given the situation of its abundant soft and light sensation, does not fully reach requirement.
Proposition contains the technical scheme of the composition of detergent of N-acyl group alanine salt and higher fatty acids and surfactant in the Te Kaiping 08-003585 communique; cooperation lauroyl Sodium L-alaninate 20wt%, sodium laurate 5wt% are wherein disclosed, and the Formulation Example of the cleansing milk of 5wt% lauryl sodium phosphate.But according to the inventor's etc. research, the foam volume and the foam retentivity of this cleansing milk prescription are not good enough, and have skin not good enough shortcoming of brisk and neat sense after drying.
Propose to contain the technical scheme of the composition of detergent of phosphoric acid ester surfactant and anion surfactant in the Te Kaiping 08-165235 communique, wherein disclose the cooperation example of 2-hexyl decyl potassium phosphate and N-lauroyl-Beta-alanine triethanolamine salt and lauric acid triethanolamine salt.But research according to inventor etc., this composition of detergent of example that cooperates is not good aspect the foaming early of detergent key property, skin and hair there are residual sense and rough sense, with regard to dried sensation, existence can not make skin have the situation of sufficient moist feeling, with to hair fully moist feeling can not make it that situation of soft and light sense is arranged, fully do not meet the demands.
Propose to contain the technical scheme of the composition of detergent of phosphoric acid ester surfactant and secondary amide type N-acyl amino acid type surfactant in the Te Kaiping 05-156286 communique, wherein disclose the cooperation example of lauryl nitranol salt and lauroyl glycine sodium salt etc.But research according to inventor etc., this composition of detergent is not good aspect the foaming early of detergent key property, skin and hair there is residual sense, with regard to dried sensation, existence can not have the situation of sufficient moist feeling to skin, with can not have abundant moist feeling can not make it that situation of soft and light sense is arranged to hair, fully do not meet the demands yet.
The invention summary
The present invention In view of the foregoing makes, it is good that purpose is to be provided at when washing bubble morning, foam volume, foam ductility and retentivity, do not give skin and the residual sense of hair, rough sense during washing, give skin wet and brisk and neat usability after the drying, make its soft and light composition of detergent when bringing moist feeling to hair.
Result of study such as the inventor etc. with keen determination find; phosphoric acid ester surfactant (composition (A)) and N-acyl-alpha--alanine or its salt (composition (B)) both can guarantee foaming, foam volume, foamy ductility and maintenance as the detergent key property with specific cooperation mixed; can satisfy simultaneously again at when washing and dry back skin and/or hair and have good feel, finish the present invention thus.
That is, the present invention relates to:
(1) skin or hair composition of detergent is characterized in that it contains (A) phosphoric acid ester surfactant and (B) general formula (I) at least:
(R represents that carbon number is 8～26 saturated or unsaturated acyl group in the formula) represented N-acyl-alpha--alanine or its salt; (A) the phosphoric acid ester surfactant and (B) mixed proportion of N-acyl-alpha--alanine or its salt be ((A)/(B)) 99/1～40/60 (weight % compares)
(2) above-mentioned (1) described composition of detergent, wherein said (B) N-acyl-alpha--alanine or its salt are N-acyl group-L-alanine or its salt,
(3) above-mentioned (1) or (2) described composition of detergent, wherein said (B) N-acyl-alpha--alanine or its salt be N-acyl-alpha--alanine alkali metal salt and
(4) any described composition of detergent in above-mentioned (1)～(3) wherein also contains (C) long-chain fatty acid or its salt,
(5) above-mentioned (4) described composition of detergent, the content of wherein said long-chain fatty acid or its salt account for 0.1～60 overall weight % of compositions,
(6) contain the detergent of any described composition of detergent in above-mentioned (1)～(5).
According to the invention provides composition of detergent, when washing bubble morning, foam volume, foam ductility and retentivity good, with regard to the sensation during with regard to washing, do not give the residual sense of skin and hair, rough sense, with regard to dried sensation, can give skin wet and brisk and neat usability, make it soft and light when bringing moist feeling to hair.
The description of preferred embodiment
Below the present invention is described in detail.
Composition of detergent of the present invention must contain phosphoric acid ester surfactant (composition (A)) and N-acyl-alpha--alanine (composition (B)).According to the record of above-mentioned patent documentation, the known N-acyl group neutral amino acid (or its salt) that multiple cleaning ingredients as detergent is arranged is important but use N-acyl-alpha--alanine or its salt in the present invention.
Be among the present invention when using described N-acyl-alpha--alanine (salt) (composition (B)) and phosphoric acid ester surfactant (composition (A)); make both mixed proportions ((A)/(B)) reach 99/1～40/60 (weight % ratio); foaming, foam volume, foamy ductility and the maintenance that both can guarantee can be formed thus, the composition of detergent that has good feel at when washing and dry back skin and/or hair can be satisfied again simultaneously as the detergent key property.
The composition that uses among the present invention (A) phosphoric acid ester surfactant is the ester that forms of the alcohol of phosphoric acid and carbon number 8～22 (preferred 8～18) (single, two or trialkyl ester), or the phosphoric acid ester surfactant that forms from the derivant of described ester.Be two or the situation of trialkyl ester under, 2 or 3 alkyl from alcohol can be the same or different, so, also can be metals such as unneutralized acid type, sodium, potassium, calcium, or salt of weak base such as triethanolamine, arginine, lysine, choline etc. to the situation of list or dialkyl.In addition, described phosphoric acid ester surfactant also can be the product of 1～20 mole of addition gained of Oxyranyle.
Described phosphoric acid ester surfactant is monoesters or its salt preferably, its instantiation as, single lauryl sodium phosphate, single lauryl p diethylaminobenzoic acid hydramine, single lauryl nitranol, single lauryl potassium phosphate, single myristyl sodium phosphate, single myristyl potassium phosphate, single myristyl p diethylaminobenzoic acid hydramine, single myristyl nitranol etc.Wherein preferred especially single lauryl sodium phosphate, single lauryl p diethylaminobenzoic acid hydramine, single lauryl nitranol, single lauryl potassium phosphate.
1 kind in described phosphoric acid ester surfactant (composition (A)) or 2 kinds or above the use together all can.Its use level determines suitably that according to formed purpose product (being the concrete purposes of composition of detergent) there is no particular limitation to this, 0.1～50 preferably overall with respect to compositions weight %, preferred especially 0.5～30 weight %.Use level is when 0.1 weight % is following, and is low as the foam volume of detergent key property, foamy ductility and maintenance performance.Unfavorable rough sense is arranged when washing when use level surpasses 50 weight %, and dry back skin does not have moist feeling.
Composition used in the present invention (B) N-acyl-alpha--alanine or its salt are from the represented compound or its salt of above-mentioned general formula (I); also can be N-acyl group-D-alanine, N-acyl group-L-alanine (salt) or N-acyl group-DL-alanine (salt), or be selected from above-mentioned two kinds or above mixture.
R represents the saturated or unsaturated acyl group of carbon number 8～26 in the formula (I), branch or straight chain all can, for example caprylyl, capryl, lauroyl, myristoyl, palmityl, stearyl, oleoyl etc.
Can be the represented all identical unification compound of acyl group of R in the general formula by the represented chemical compound of general formula (I) in the present invention, also can be the represented mutually different mixture of acyl group of R in the general formula.For described mixture; for example derive from natural mixture fatty acid by coco-nut oil fatty acid, Adeps Bovis seu Bubali fatty acid, sclerosis tallow fatty acids, Castor Oil Fatty Acid, olive oil, palm oil fatty acid etc., or the fatty acid of synthetic gained (containing branched chain fatty acid) gained contain acylated compound etc.The represented chemical compound of general formula (I); R in the preferred formula is the acyl group from fatty acid mixed, and in this case, the average carbon atom number of acyl group (being R) is 8～26; preferred 8～18, be acyl group especially preferably from coco-nut oil fatty acid from the acyl group of fatty acid mixed.
The salt of the chemical compound that formula (I) is represented for example can be, alkaline-earth metal, monoethanolamine, diethanolamine, triethanolamine, 2-amino-2-methyl-1-propanol, 2-amino-2-methyls-1 such as alkali metal such as sodium, potassium, magnesium, calcium, the formed salt of alkali composition of basic amino acids such as the inorganic amine of the organic amine of ammediol etc., ammonia etc., lysine, ornithine, arginine etc.For described salt, consider preferred as alkali salt from the angle of product form stability, consider most preferably sodium salt from the angle of foam ductility and maintenance.
N-acyl-alpha--the alanine of composition among the present invention (B) or its salt are considered preferred N-acyl group-DL-alanine or its salt, N-acyl group-L-alanine or its salt from the angle of easy acquisition, preferred especially N-acyl group-L-alanine or its salt.
In addition, be that the angle that the residual sense of compositions when washing waits is less considered from washing, preferably use N-acyl group-L-alanine or its salt.
As the object lesson of the represented compound or its salt of formula (I), N-coco-nut oil fatty acid acyl group-DL-alanine sodium salt for example; N-coco-nut oil fatty acid acyl group-L-alanine sodium salt; N-coco-nut oil fatty acid acyl group-DL-alanine potassium salt; N-coco-nut oil fatty acid acyl group-L-alanine potassium salt; N-coco-nut oil fatty acid acyl group-DL-alanine triethanolamine salt; N-coco-nut oil fatty acid acyl group-L-alanine triethanolamine salt; N-coco-nut oil fatty acid acyl group-DL-alanine lysinate; N-coco-nut oil fatty acid acyl group-L-alanine lysinate; N-coco-nut oil fatty acid acyl group-DL-alanine arginine salt; N-coco-nut oil fatty acid acyl group-L-alanine arginine salt; N-lauroyl-DL-alanine sodium salt; N-lauroyl-L-alanine sodium salt; N-lauroyl-DL-alanine potassium salt; N-lauroyl-L-alanine potassium salt; N-lauroyl-DL-alanine triethanolamine salt; N-lauroyl-L-alanine triethanolamine salt; N-lauroyl-DL-alanine lysinate; N-lauroyl-L-alanine lysinate; N-lauroyl-DL-alanine arginine salt; N-lauroyl-L-alanine arginine salt; N-myristoyl-DL-alanine sodium salt; N-myristoyl-L-alanine sodium salt; N-myristoyl-DL-alanine potassium salt; N-myristoyl-L-alanine potassium salt; N-myristoyl-DL-alanine triethanolamine salt; N-myristoyl-L-alanine triethanolamine salt; N-myristoyl-DL-alanine lysinate; N-myristoyl-L-alanine lysinate; N-myristoyl-DL-alanine arginine salt; N-myristoyl-L-alanine arginine salt; N-palmityl-DL-alanine sodium salt; N-palmityl-L-alanine sodium salt; N-palmityl-DL-alanine potassium salt; N-palmityl-L-alanine potassium salt; N-palmityl-DL-alanine triethanolamine salt; N-palmityl-L-alanine triethanolamine salt; N-palmityl-DL-alanine lysinate; N-palmityl-L-alanine lysinate; N-palmityl-DL-alanine arginine salt; N-palmityl-L-alanine arginine salt; N-stearoyl-DL-alanine sodium salt; N-stearoyl-L-alanine sodium salt; N-stearoyl-DL-alanine potassium salt; N-stearoyl-L-alanine potassium salt; N-stearoyl-DL-alanine triethanolamine salt; N-stearoyl-L-alanine triethanolamine salt; N-stearoyl-DL-alanine lysinate; N-stearoyl-L-alanine lysinate; N-stearoyl-DL-alanine arginine salt; N-stearoyl-L-alanine arginine salt; N-stearoyl-DL-alanine sodium salt; N-stearoyl-L-alanine sodium salt; N-stearoyl-DL-alanine potassium salt; N-stearoyl-L-alanine potassium salt; N-stearoyl-DL-alanine triethanolamine salt; N-stearoyl-L-alanine triethanolamine salt; N-stearoyl-DL-alanine lysinate; N-stearoyl-L-alanine lysinate; N-stearoyl-DL-alanine arginine salt; N-stearoyl-L-alanine arginine salt etc.Among these, preferred acyl group is a coco-nut oil fatty acid acyl group type, preferred especially N-coco-nut oil fatty acid acyl group-L-alanine sodium salt.
Described composition (B) N-acyl-alpha--alanine or its salt; 1 kind or 2 kinds or above the use together all can; its use level is suitably determined according to formed purpose product (being the concrete purposes of composition of detergent); there is no particular limitation to this; common 0.03～50 weight % overall with respect to compositions; preferred 0.1～30 weight %, preferred especially 1.0～25 weight %.
In the composition of detergent of the present invention, as mentioned above, the cooperation ratio of the phosphoric acid ester surfactant of composition (A) and composition (B) N-acyl-alpha--alanine or its salt is that 99/1～40/60 (weight % ratio) is important.Departed from above-mentioned cooperation ratio, the ratio height of composition (A), bubbling, early this key property as detergent is not good, to skin, and dried moist feeling, to hair, dried moist feeling and soft and light etc. sensation are all not good, on the other hand, when the ratio of composition (B) is high, not good as the foam volume of detergent key property and foam retentivity etc., for skin, the dry brisk and neat sense in back is not good.
The cooperation ratio of composition among the present invention (A) and composition (B) ((A)/(B)) is preferably 99/1～50/50 (weight % than), more preferably 99/10～75/25 (weight % than), preferred especially 85/15～75/25 (weight % than).
The long-chain fatty acid of employed composition (C) or its salt are saturated or unsaturated fatty acid or its salt of straight or branched among the present invention, it can be the identical unification compound of carbon number, also can form promptly so-called higher fatty acids soap bases by the mixture of the different chemical compound of carbon number.As the alkali composition of salt can be alkali metal such as sodium, potassium for example, alkaline-earth metal such as magnesium, calcium, monoethanolamine, diethanolamine, triethanolamine, 2-amino-2-methyl-1-propanol, 2-amino-2-methyl-1, basic amino acids such as the inorganic amine of organic amines such as ammediol, ammonia etc., lysine, ornithine, arginine etc.For described long-chain fatty acid or its salt, when it is the same unification compound of carbon atom, carbon number preferably 8～26, especially preferably 8～18, when it was the mixture of the different chemical compound of carbon number, preferred average carbon atom number was 8～26, especially preferably 8～18.Preferred object lesson as described long-chain fatty acid or its salt, for example lauric acid, myristic acid, Palmic acid, stearic acid, coco-nut oil fatty acid, sclerosis tallow fatty acids, palm oil fatty acid, hardened palm oil fat acid, Stigma Croci fatty acid oil, tallow fatty acids, behenic acid, oleic acid, isostearic acid etc. and salt thereof, wherein preferred lauric acid (salt), myristic acid (salt), Palmic acid (salt), stearic acid (salt), coco-nut oil fatty acid (salt).
Composition (C) can be used with composition (A) and composition (B) in the composition of detergent of the present invention, particularly when further foaming, the foam that improves as the detergent key property keeps performance, can also further reduce the residual sense when washing skin and hair.
1 kind of described composition (C) long-chain fatty acid or its salt or 2 kinds or above the use together all can, its use level is suitably determined according to formed purpose product (being the concrete purposes of composition of detergent), there is no particular limitation to this, common 0.1～60 weight % overall with respect to compositions, preferably account for 0.5～30 weight %, especially preferably account for 1～30 weight %.
In composition of detergent of the present invention, in the scope of not damaging purpose of the present invention (effect), can be used simultaneously with compositions such as the oil preparation that is generally used for cosmetics, powder (pigment, pigment, resin), fluorine compounds, resin, binding agent, macromolecule, antiseptic, spice, UV absorbent, wetting agent, polyhydric alcohol, physiologically active ingredient, salt, solvent, antioxidant, antibacterial, antiperspirant, chelating agen, nertralizer, pH regulator agent.
The compositions that composition of detergent of the present invention can be mixed with from faintly acid to the alkalescence scope is used, from the low angle of the zest of skin is considered preferred pH5.0～8.0.
Composition of detergent of the present invention does not have special restriction to dosage form (form), liquid, cream pasty state, gel, solid, shaped, dosage form (form) arbitrarily such as Powdered all can, from the angle of bubbling rapidly consider preferred use liquid.
Composition of detergent of the present invention can be used as various hair detergents such as shampoo, conditioning shampoo liquid and clean product, makeup removing, facial milk cleanser, bath gel, handwashing liquid, bar soap, shaving foam and shaves recklessly various skin cleaners such as cream and use, and can be used as dentifrice etc. in addition.
The present invention will be described in more detail below by embodiment, but the present invention is not subjected to the restriction of the following example.
Production Example 1 (synthesizing of N-coco-nut oil fatty acid acyl group-L-alanine sodium salt)
In the 30.0gL-alanine, add 167g water, in pH10.98～11.02, reaction temperature 33～37 ℃ keep down in, drip simultaneously while the Oleum Cocois fat acyl chloride of 73.68g and 27wt%-NaOH aqueous solution stirred in 1 hour time.After the maturation in 1 hour, the temperature of rising reactant liquor is added the sulphuric acid of 75wt% and is adjusted pH value to 2.0.Be warmed up to 80 ℃ again, stir about left standstill and made organic layer and water layer layering in 10 minutes after 10 minutes.The water layer of about 200g is removed from the bottom of container.In residual organic layer, add hot water, reach 80 ℃ again, stir 10 minutes, left standstill 10 minutes, remove the water layer after the layering, obtain organic layer.In organic layer, add 27% NaOH aqueous solution and water, adjust pH value to 6.8, obtain goal object (N-coco-nut oil fatty acid acyl group-L-alanine sodium salt).
Production Example 2 (synthesizing of N-coco-nut oil fatty acid acyl group-DL-alanine sodium salt)
Except replacing the L-alanine, use the method identical to obtain goal object (N-coco-nut oil fatty acid acyl group-DL-alanine sodium salt) with above-mentioned Production Example 1 with the DL-alanine.
Be prepared as follows the composition of detergent (embodiment 1～6, comparative example 1～5) of stating composition shown in the table 1 and carry out following evaluation experimental.In addition, the amount of each gradation composition of being put down in writing in the table (numerical value in the table) is as 100 o'clock percentage by weights (%) with compositions overall (containing remaining water).
[evaluation experimental]
1. the member as 5 panels of evaluation of foaming, foam volume, foamy ductility and the maintenance etc. of detergent key property is estimated by washing one's hands.As described evaluation, adopt the equalization point that a table is converted into by following, 4.1 or above for ◎, 3.5～4.0 be zero, 3.0～3.4 for ▲, 2.9 or followingly be.
(foaming)
5: early
4: a little earlier
3: common
2: slow slightly
1: late
(foam volume)
5: abundant
4: abundant slightly
3: common
2: not enough slightly
1: not enough
(foam ductility)
5: good
4: good slightly
3: common
2: bad slightly
1: bad
(foam maintenance)
5: good
4: good slightly
3: common
2: bad slightly
1: bad
2. carry out sensory evaluation by experiment and the hair washing experiment of washing one's hands
Residual sense and rough sense, dried moist feeling and brisk and neat sense when in the experiment of washing one's hands, estimating washing.
Residual sense and rough sense when in hair washing experiment, estimating washing by 5 panelists, dried moist feeling and pliability, slim and graceful degree (soft and slim and graceful).
As evaluation, the equalization point that divides 5 grades of 1 point (bad)～5 point (well) to carry out, calculate 5 estimators, equalization point 4.1 or above for ◎, 3.5～4.0 be zero, 3.0～3.4 for ▲, 2.9 or following for *.
[table 1]
| Gradation composition | Embodiment | Comparative example | |||||||||
| ????1 | ????2 | ????3 | ????4 | ????5 | ????6 | ????1 | ????2 | ????3 | ????4 | ????5 | |
| The lauryl sodium ascorbyl phosphate | ????10 | ????10 | ????10 | ????10 | ????4.8 | ????10 | ????10 | ????10 | ????3 | ????10 | |
| Lauryl nitranol salt | ????8 | ||||||||||
| N-coco-nut oil fatty acid acyl group-DL-alanine sodium salt | ????2 | ||||||||||
| N-coco-nut oil fatty acid acyl group-L-alanine sodium salt | ????2 | ????2 | ????4 | ????7.2 | ????9 | ||||||
| N-lauroyl-DL-alanine potassium salt | ????2 | ||||||||||
| N-coco-nut oil fatty acid acyl glutamic acid sodium salt *1 | ????2 | ||||||||||
| N-coco-nut oil fatty acid acyl group Sodium sarcosinate *2 | ????2 | ||||||||||
| N-coco-nut oil fatty acid acyl group-N-methyl-Beta-alanine sodium salt *3 | ????2 | ||||||||||
| The coco-nut oil fatty acid sodium salt | ????1 | ????1 | ????2 | ????1 | ????1 | ????1 | ????2 | ????2 | |||
| Water | Remaining | Remaining | Remaining | Remaining | Remaining | Remaining | Remaining | Remaining | Remaining | Remaining | Remaining |
| (key property) | |||||||||||
| Bubble | ????◎ | ????◎ | ????◎ | ????◎ | ????◎ | ????◎ | ????▲ | ????▲ | ????▲ | ????◎ | ????▲ |
| Foam volume | ????○ | ????○ | ????○ | ????◎ | ????○ | ????▲ | ????▲ | ????◎ | ????◎ | ????▲ | ????◎ |
| The foam ductility | ????◎ | ????◎ | ????◎ | ????◎ | ????○ | ????○ | ????○ | ????◎ | ????◎ | ????○ | ????○ |
| Foam keeps | ????○ | ????○ | ????○ | ????◎ | ????○ | ????○ | ????○ | ????◎ | ????◎ | ????▲ | ????○ |
| (skin) | |||||||||||
| Residual sense during washing | ????◎ | ????○ | ????○ | ????◎ | ????◎ | ????○ | ????▲ | ????○ | ????○ | ????○ | ????○ |
| Rough sense during washing | ????◎ | ????◎ | ????◎ | ????◎ | ????◎ | ????◎ | ????◎ | ????▲ | ????▲ | ????○ | ????○ |
| Dried moist feeling | ????◎ | ????◎ | ????◎ | ????○ | ????◎ | ????◎ | ????◎ | ????▲ | ????▲ | ????◎ | ????▲ |
| Dried brisk and neat sense | ????○ | ????○ | ????○ | ????◎ | ????○ | ????○ | ????▲ | ????◎ | ????◎ | ????▲ | ????○ |
| (hair) | |||||||||||
| Residual sense during washing | ????◎ | ????○ | ????○ | ????◎ | ????○ | ????○ | ????▲ | ????○ | ????○ | ????○ | ????○ |
| Rough sense during washing | ????◎ | ????◎ | ????◎ | ????◎ | ????◎ | ????◎ | ????◎ | ????▲ | ????▲ | ????◎ | ????○ |
| Dried moist feeling | ????◎ | ????◎ | ????◎ | ????◎ | ????◎ | ????◎ | ????◎ | ????▲ | ????▲ | ????◎ | ????▲ |
| Dried soft and light degree | ????◎ | ????◎ | ????◎ | ????◎ | ????◎ | ????◎ | ????▲ | ????▲ | ????▲ | ????◎ | ????▲ |
In the table:
*1: " ア ミ ソ Off ト " CS-22 aginomoto society system
*2: fine chemistry society system is ground in " ソ イ Port Application " SC river
*3: fine chemistry society system is ground in " ア ラ ノ Application " ACE river
As can be seen from Table 1, the composition of detergent of embodiment is good about foamy complete key property (foaming, foam volume, foam ductility and foam keep) performance, with regard to the sensation during with regard to washing, do not give the residual sense of skin and hair, rough sense, with regard to dried sensation, can give skin wet and brisk and neat usability, make its soft and light sensation when bringing moist feeling to hair.
Embodiment 7,8
Prescription shown in the according to the form below is prepared cleansing milk (embodiment 7) and bath gel (embodiment 8) with conventional method.They all keep showing well aspect arbitrary key property at foaming, foam volume, foam ductility and foam, and the sensation during use is also very good.In addition, the amount of each gradation composition of being put down in writing in the table (numerical value in the table) is totally as 100 o'clock percentage by weight (%) with compositions.
[table 2]
(cleansing milk)
| Formulation | Use level (wt%) |
| Water | 32.25 |
| Lauryl phosphoric acid K | 25 |
| Glycerol | 25 |
| Pulvis Talci | 3 |
| N-coco-nut oil fatty acid acyl group-L-alanine sodium salt | 3 |
| Sorbitol | 1.5 |
| The dodecanamide propyl betanin | 1.5 |
| Caprylin | 1.5 |
| Denatured alcohol | 1 |
| Lauric acid | 1 |
| Citric acid | 0.05 |
| Decyl glucoside | 1 |
| The lauryl hydroxyl sulfo betaine | 1 |
| Myristic acid | 1 |
| Stearic acid | 1 |
| Hydroxypropyl emthylcellulose | 0.5 |
| Propylene glycol | 0.5 |
| Benzoate | 0.2 |
[table 3]
(bath gel)
| Formulation | Use level (wt%) |
| Water | 74.2 |
| Lauryl phosphoric acid K | 10.0 |
| Polyoxyethylene lauryl ether sulfate | 2.0 |
| Decyl glucoside | 2.0 |
| N-coco-nut oil fatty acid acyl group-L-alanine sodium salt | 3 |
| Caprylin | 1.0 |
| Diglycol stearate | 1.0 |
| The dodecanamide propyl betanin | 1.0 |
| Lauric acid polyglycerin ester-10 | 1.0 |
| コカミド?MEA | 1.0 |
| DPG | 1 |
| Lauric acid | 0.8 |
| ラウレス-4 | 0.8 |
| Hydroxypropyl emthylcellulose | 0.5 |
| Citric acid | 0.05 |
| Propylene glycol | 0.5 |
| Edetate | 0.2 |
Claims (6)
1, skin or hair composition of detergent is characterized in that, it contains (A) phosphoric acid ester surfactant and (B) general formula (I) at least:
(R represents that carbon number is 8～26 saturated or unsaturated acyl group in the formula) represented N-acyl-alpha--alanine or its salt, (A) the phosphoric acid ester surfactant and (B) the cooperation ratio ((A)/(B)) of N-acyl-alpha--alanine or its salt be 99/1～40/60 (weight % than).
2, composition of detergent as claimed in claim 1, wherein said (B) N-acyl-alpha--alanine or its salt are N-acyl group-L-alanine or its salt.
3, composition of detergent as claimed in claim 1 or 2, wherein said (B) N-acyl-alpha--alanine or its salt are N-acyl-alpha--alanine alkali metal salts.
4, as any described composition of detergent in the claim 1～3, wherein also contain (C) long-chain fatty acid or its salt.
5, composition of detergent as claimed in claim 4, the content of wherein said (C) long-chain fatty acid or its salt totally is 0.1～60 weight % with respect to compositions,
6, contain detergent just like any described composition of detergent in the claim 1～5.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003129553A JP4059134B2 (en) | 2003-05-07 | 2003-05-07 | Cleaning composition |
| JP129553/03 | 2003-05-07 | ||
| JP129553/2003 | 2003-05-07 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1572279A true CN1572279A (en) | 2005-02-02 |
| CN100408019C CN100408019C (en) | 2008-08-06 |
Family
ID=33505356
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100451996A Expired - Fee Related CN100408019C (en) | 2003-05-07 | 2004-04-30 | Abluent composition |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP4059134B2 (en) |
| KR (1) | KR101062626B1 (en) |
| CN (1) | CN100408019C (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MY179962A (en) * | 2014-04-09 | 2020-11-19 | Lion Corp | Liquid cleanser composition packaged in foamer container |
| CN108451783A (en) * | 2018-06-04 | 2018-08-28 | 苏州欧丽特生物医药有限公司 | A kind of skin care compositions and methods and preparation method thereof |
| BR112020024723A2 (en) * | 2018-06-04 | 2021-03-23 | Suzhou Oulit Biopharm Co., Ltd | supramolecular polymer of self-organized amino acid, its preparation and application |
| JP7391397B2 (en) | 2018-06-04 | 2023-12-05 | ▲蘇▼州欧▲麗▼特生物医▲薬▼有限公司 | Novel amino acid self-assembled supramolecular polymer and its production method and use |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0543890A (en) * | 1991-08-13 | 1993-02-23 | Kao Corp | Detergent composition |
| JP3087398B2 (en) * | 1991-12-04 | 2000-09-11 | 味の素株式会社 | Detergent composition |
| JPH08165235A (en) * | 1994-12-15 | 1996-06-25 | Kao Corp | Skin washing article |
| JP2002047148A (en) * | 2000-08-03 | 2002-02-12 | Noevir Co Ltd | Shampoo composition |
| JP4542279B2 (en) * | 2001-03-30 | 2010-09-08 | 株式会社ファンケル | Cleaning composition |
| JP2002322491A (en) * | 2001-04-23 | 2002-11-08 | Fancl Corp | Cleansing composition |
| JP2003034623A (en) * | 2001-07-19 | 2003-02-07 | Nikko Seiyaku Kk | Composition for shampoo |
-
2003
- 2003-05-07 JP JP2003129553A patent/JP4059134B2/en not_active Expired - Fee Related
-
2004
- 2004-04-30 CN CNB2004100451996A patent/CN100408019C/en not_active Expired - Fee Related
- 2004-05-07 KR KR1020040032282A patent/KR101062626B1/en active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| JP4059134B2 (en) | 2008-03-12 |
| KR20040095728A (en) | 2004-11-15 |
| JP2004331568A (en) | 2004-11-25 |
| KR101062626B1 (en) | 2011-09-07 |
| CN100408019C (en) | 2008-08-06 |
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