CN1571207A - Colloid electrolyte - Google Patents
Colloid electrolyte Download PDFInfo
- Publication number
- CN1571207A CN1571207A CNA2004100224920A CN200410022492A CN1571207A CN 1571207 A CN1571207 A CN 1571207A CN A2004100224920 A CNA2004100224920 A CN A2004100224920A CN 200410022492 A CN200410022492 A CN 200410022492A CN 1571207 A CN1571207 A CN 1571207A
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- CN
- China
- Prior art keywords
- stabilizer
- colloidal electrolyte
- dispersant
- adsorbent
- defoamer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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Abstract
The invention provides a colloid electrolyte, composed in weight percent of: gelating agent 0.1-5, dispersant or absorbent 18-30, stabilizer 18-34, defoaming agent 0.6-3, and vitriol and water the rest, where the gelating agent is composed of at least a high- molecular polymer. It is used in storage battery, especially valve-regulated aluminum acid storage battery to increase battery capacity and prolong service life.
Description
Technical field:
The present invention is relevant with electrolyte, and is special relevant with the colloidal electrolyte that is used for valve controlling sealed lead-acid battery (being maintenance free cell).
Background technology:
Valve controlling sealed lead-acid battery has advantages such as non-maintaining, no acid mist is overflowed, free from environmental pollution, long-life, is extensively adopted by industries such as electric power, communication, traffic, national defence, the energy.But contain the element silicon that increases internal resistance in the battery liquid that uses at present, can not absorb various harmful metal ions (as iron, manganese, magnesium, arsenic etc.) and chlorine, amine etc. that storage battery produces in charge and discharge process, battery capacity is low, and useful life is short.
Summary of the invention:
The objective of the invention is in order to overcome above deficiency, provide a kind of storage battery that is used for especially for making battery capacity big in the valve controlling sealed lead-acid battery, the colloidal electrolyte of long service life.
The object of the present invention is achieved like this:
Colloidal electrolyte of the present invention is characterized in that being made up of following raw material by weight percentage:
Gel 0.1～5,
Dispersant or adsorbent 18～30,
Stabilizer 18～34,
Defoamer 0.6～3,
Sulfuric acid and water surplus.
Above-mentioned gel is made up of at least a high molecular polymer.
Above-mentioned colloidal electrolyte is made up of following raw material by weight percentage:
Gel 1～5,
Dispersant or adsorbent 25～30,
Stabilizer 18～25,
Defoamer 1～2,
Sulfuric acid and water surplus.
Above-mentioned colloidal electrolyte is made up of following raw material by weight percentage:
Gel 0.5～2,
Dispersant or adsorbent 20～24,
Stabilizer 22～30,
Defoamer 2～3,
Sulfuric acid and water surplus.
Above-mentioned colloidal electrolyte is made up of following raw material by weight percentage:
Gel 0.1～0.5,
Dispersant or adsorbent 18～22,
Stabilizer 30～34,
Defoamer 0.6～1,
Sulfuric acid and water surplus.
Above-mentioned high molecular polymer is a macrogol, polyvinyl alcohol, and polyacrylamide, fatty alcohol also can adopt other high molecular polymer.
Above-mentioned stabilizer is made up of magnesium sulfate, zinc sulfate, aluminum sulfate, tartaric acid, disodium ethylene diamine tetraacetate.
Above-mentioned dispersant or adsorbent adopt the yin, yang resin, and defoamer adopts tributyl phosphate.
The present invention utilizes high molecular polymer to have very strong gelation and dispersant or adsorbent and stabilizer, sulfuric acid has strong compatibility, decentralized medium there is good intermiscibility and forms high-energy gel electrolyte, do not contain element silicon, make the electrolyte reserves big, can constantly absorb various harmful metal ions (as iron, manganese, magnesium, arsenic etc.) and chlorine, amine etc. that storage battery produces in charge and discharge process, internal resistance is very little, in-fighting is very little, thereby increased battery capacity, made big, the long service life of battery capacity.The present invention is specially adapted in the valve controlling sealed lead-acid battery.
Embodiment:
Embodiment 1:
Present embodiment 1 colloidal electrolyte is made up of following raw material by weight percentage:
Macrogol 1,
Yin, yang resin 30,
Stabilizer 25,
Tributyl phosphate 2,
Sulfuric acid and water surplus.
Above-mentioned stabilizer is made up of magnesium sulfate, zinc sulfate, aluminum sulfate, tartaric acid, disodium ethylene diamine tetraacetate.
Embodiment 2:
Present embodiment 2 colloidal electrolytes are made up of following raw material by weight percentage:
Macrogol 2.5,
Polyvinyl alcohol 2.5,
Yin, yang resin 30,
Stabilizer 18,
Tributyl phosphate 1,
Sulfuric acid and water surplus.
Embodiment 3:
Present embodiment 3 colloidal electrolytes are made up of following raw material by weight percentage:
Polyvinyl alcohol 0.5,
Yin, yang resin 24,
Stabilizer 30,
Tributyl phosphate 3,
Sulfuric acid and water surplus.
Embodiment 4:
Present embodiment 4 colloidal electrolytes are made up of following raw material by weight percentage:
Polyvinyl alcohol 1,
Fatty alcohol 1,
Yin, yang resin 20,
Stabilizer 22,
Tributyl phosphate 2,
Sulfuric acid and water surplus.
Embodiment 5:
Present embodiment 5 colloidal electrolytes are made up of following raw material by weight percentage:
Polyvinyl lactam 0.1,
Yin, yang resin 22,
Stabilizer 34,
Tributyl phosphate 1,
Sulfuric acid and water surplus.
Embodiment 6:
Present embodiment 6 colloidal electrolytes are made up of following raw material by weight percentage:
Polyacrylamide 0.5,
Yin, yang resin 18,
Stabilizer 30,
Tributyl phosphate 0.6,
Sulfuric acid and water surplus.
Stabilizer is identical with embodiment 1 among embodiment 2～embodiment 6.
The manufacture craft flow process of colloidal electrolyte is in the various embodiments described above: the preliminary treatment of resin (cleaning, abrasive dust)-→ polymerization reaction of high molecular polymer (in reactor, add water heat stirrings)-→ in proportion prescription-→ aluminum sulfate in the stabilizer, magnesium sulfate, zinc sulfate, tartaric acid, disodium ethylene diamine tetraacetate are dissolved respectively-→ add tributyl phosphate synthesize faint yellow pastel-→ add sulfuric acid and become the dark brown thick liquid with water.
Claims (10)
1, colloidal electrolyte is characterized in that being made up of following raw material by weight percentage:
Gel 0.1～5,
Dispersant or adsorbent 18～30,
Stabilizer 18～34,
Defoamer 0.6～3,
Sulfuric acid and water surplus.
Above-mentioned gel is made up of at least a high molecular polymer.
2, colloidal electrolyte as claimed in claim 1 is characterized in that being made up of following raw material by weight percentage:
Gel 1～5,
Dispersant or adsorbent 25～30,
Stabilizer 18～25,
Defoamer 1～2,
Sulfuric acid and water surplus.
3, colloidal electrolyte as claimed in claim 1 is characterized in that being made up of following raw material by weight percentage:
Gel 0.5～2,
Dispersant or adsorbent 20～24,
Stabilizer 22～30,
Defoamer 2～3,
Sulfuric acid and water surplus.
4, colloidal electrolyte as claimed in claim 1 is characterized in that being made up of following raw material by weight percentage:
Gel 0.1～0.5,
Dispersant or adsorbent 18～22,
Stabilizer 30～34,
Defoamer 0.6～1,
Sulfuric acid and water surplus.
5,, it is characterized in that high molecular polymer is a macrogol, polyvinyl alcohol, polyacrylamide, fatty alcohol as the described colloidal electrolyte of one of claim 1～4.
6,, it is characterized in that stabilizer is made up of magnesium sulfate, zinc sulfate, aluminum sulfate, tartaric acid, disodium ethylene diamine tetraacetate as the described colloidal electrolyte of one of claim 1～4.
7, colloidal electrolyte as claimed in claim 5 is characterized in that stabilizer is made up of magnesium sulfate, zinc sulfate, aluminum sulfate, tartaric acid, disodium ethylene diamine tetraacetate.
8, as the described colloidal electrolyte of one of claim 1～4, it is characterized in that dispersant or adsorbent adopt the yin, yang resin, defoamer adopts tributyl phosphate.
9, colloidal electrolyte as claimed in claim 5 is characterized in that dispersant or adsorbent adopt the yin, yang resin, and defoamer adopts tributyl phosphate.
10, colloidal electrolyte as claimed in claim 1 is characterized in that dispersant or adsorbent adopt the yin, yang resin, and defoamer adopts tributyl phosphate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2004100224920A CN1571207A (en) | 2004-05-12 | 2004-05-12 | Colloid electrolyte |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2004100224920A CN1571207A (en) | 2004-05-12 | 2004-05-12 | Colloid electrolyte |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1571207A true CN1571207A (en) | 2005-01-26 |
Family
ID=34480158
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2004100224920A Pending CN1571207A (en) | 2004-05-12 | 2004-05-12 | Colloid electrolyte |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1571207A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104614418A (en) * | 2013-04-28 | 2015-05-13 | 天和自动化科技（苏州）股份有限公司 | Enclosed dissolved oxygen sensor |
| CN104614419A (en) * | 2013-04-28 | 2015-05-13 | 天和自动化科技（苏州）股份有限公司 | High precision dissolved oxygen detector |
| CN104698045A (en) * | 2013-04-28 | 2015-06-10 | 天和自动化科技（苏州）股份有限公司 | Dissolved oxygen (DO) electrochemical sensor |
| CN104698049A (en) * | 2013-04-28 | 2015-06-10 | 天和自动化科技（苏州）股份有限公司 | Environment-friendly dissolve oxygen (DO) sensor |
-
2004
- 2004-05-12 CN CNA2004100224920A patent/CN1571207A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104614418A (en) * | 2013-04-28 | 2015-05-13 | 天和自动化科技（苏州）股份有限公司 | Enclosed dissolved oxygen sensor |
| CN104614419A (en) * | 2013-04-28 | 2015-05-13 | 天和自动化科技（苏州）股份有限公司 | High precision dissolved oxygen detector |
| CN104698045A (en) * | 2013-04-28 | 2015-06-10 | 天和自动化科技（苏州）股份有限公司 | Dissolved oxygen (DO) electrochemical sensor |
| CN104698049A (en) * | 2013-04-28 | 2015-06-10 | 天和自动化科技（苏州）股份有限公司 | Environment-friendly dissolve oxygen (DO) sensor |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |