CN1560608A - On-line automatic analizer for urban saprobia toxic and its using method - Google Patents
On-line automatic analizer for urban saprobia toxic and its using method Download PDFInfo
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- CN1560608A CN1560608A CNA2004100213555A CN200410021355A CN1560608A CN 1560608 A CN1560608 A CN 1560608A CN A2004100213555 A CNA2004100213555 A CN A2004100213555A CN 200410021355 A CN200410021355 A CN 200410021355A CN 1560608 A CN1560608 A CN 1560608A
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Abstract
The invention is a online automatic analyzer for city waste water biology toxin, which includes instrument shell, operating panel connected to the electric control device, the instrument has photobacterium thermal retardation box, buffer liquid box and rinsing box, the photobacterium thermal retardation box is placed with a medicine container; a precise testing device is assembled under the instrument, the device has a fixed dark box, the rotary long spindle penetrates the dark box, a round board is connected to the rotary long spindle, the round board is assembled with six small containers, a drop interface is arranged on the dark box cover, which is connected to the photobacterium thermal retardation box container, the buffer liquid box and the rinsing box; the top of the rotary long spindle is assembled with a electric magnet for elevating the rotary spindle, and a power gearing device is arranged; a photoelectric detector is arranged above the dark box.
Description
Technical field
The invention belongs to a kind of urban environmental protection monitoring field, particularly a kind of municipal effluent bio-toxicity on-line automatic analyzer and using method thereof.
Background technology
For the needs of the monitoring that conforms, solve that the bio-toxicity monitoring exists cumbersome, time-consuming, expense is high and the problem of aspects such as repeated and sensitivity.External always in the method for testing of constantly studying the improvement bio-toxicity, make its quick, sensitive, economy and facility.Domestic also constantly the introduction and the more perfect new technology and the new method of microorganism toxicity monitorings.As the photogen toxicity test is in recent years both at home and abroad in the achievement in research aspect biological acute toxicity and the genetoxic monitoring.Abroad begin one's study and pollute, develop into the measuring technology of comparative maturity to the seventies with the photobacteria monitoring of environmental from middle nineteen sixties.Scholar's research application with countries such as the U.S., Britain, the Soviet Union, Japan, Australia is more, and the project that has has been applied for patent, and the Beckmann apparatus company research in this respect of the U.S. has obtained breakthrough progress since the eighties.They have developed special testing tool and the photobacteria test is supporting, are doing many successful researchs aspect the bio-toxicity of using photobacteria method mensuration noxious material.Make this method obtain the popularization of very fast development.After this, the various countries scholar adopts this method to measure bio-toxicity one after another, estimates environmental quality.All obtained application in fields such as environmental monitoring, medical and health, biochemical analysises.In recent years, Chinese scholar is done a lot of work to research and the application of photobacteria, development and production special testing tool, set up photobacteria method bio-toxicity test macro (LB system), for photogen toxicity monitoring lays the foundation applying of China.
But there are following problems in the above-mentioned testing tool that in the past utilized photobacteria to make: supporting as special testing tool and photobacteria test that Beckman company produces, to use but belong in the laboratory, and price is high and too harsh to environment requirement.What the on-line automatic analyzer of North America instrument production adopted is COD or BOD method, also only rests on the aspect of using in the laboratory.Biology department of domestic East China Normal University and Nanjing Transistor Factory once produced the testing tool that utilizes photobacteria to make, but it is to belong to manual sampling, the manual read fetches data, the intermittence test mode, non-online can only be in the laboratory together with the freezing equipment work in combination.Public Health College, Harbin Medical Univ Hygiene Toxicology teaching and research room once reported and produced acute toxicity photobacteria sensor and acute toxicity fast measuring instrument, design a kind of acute toxicity bacterial luminescence sensor and flow type microcomputer fast measuring environmental contaminants determination of acute toxicity instrument of forming with photobacterium phosphoreum and silicon photo diode, the purpose of qualitative test can only be realized, the toxic grade of online test function and reduced concentration analytical test judgement sewage can not be realized.
Summary of the invention
Purpose of the present invention is intended to solve the above problems, a kind of municipal effluent bio-toxicity on-line automatic analyzer device and using method thereof are provided, the realization instrument is temperature automatically controlled, guarantee test freezing preservation and the online activation of luminous bacillus in instrument, automatically finish and get sewage sample and the reduced concentration test of judging that other relative determining method of toxic level is essential, online test and the slave computer that can be used as test network use, and be simple in structure, cost is low.
On-line automatic analyzer device provided by the invention is as follows: it comprises Instrument shell, connects the guidance panel of electric control gear, it is characterized in that: photogen insulation can, damping fluid case and the cleaning case of the top assembling band case lid of instrument, place medical rank container in the photogen insulation can; At the bottom of instrument assembling precise testing device, this device is provided with fixedly camera bellows, one rotation major axis penetrates in the camera bellows, with the affixed plectane of rotation major axis, six small containers of assembling on the plectane, the bottom of each small container is the opening shape, assemble rotating chassis in the bottom of camera bellows, the vortex-like sealing-plug of salable small container bottom is set on it, covers at camera bellows four dropper joints are set, they connect photogen insulation can inner pressurd vessel, damping fluid case and cleaning case by the circulation pipeline of charged magnet valve respectively; The electromagnet that the upper end assembling of rotation major axis promotes the rotation major axis, and the actuating unit that the driven in rotation major axis rotates is set; Above camera bellows, be provided with photodetector, photodetector top connecting screw rod, screw rod group is contained in fixedly on the swivel nut, and the screw rod upper end connects stepper motor; The circulation pipeline that covers also by charged magnet valve at camera bellows connects foul water tank.
On above-mentioned rotation major axis, assemble photoelectric switch.
On above-mentioned photodetector, assemble photoelectric switch.
The using method of on-line automatic analyzer device provided by the invention is as follows:
The start-up temperature control device is controlled at 20 ℃ with testing sample environment temperature in the camera bellows, and environment temperature in the medical rank container of insulation can of storage photogen is controlled at 0 ℃-4 ℃, and the environment temperature in the instrument box is controlled at 2 ℃; With photogen, damping fluid, clear water and sewage are respectively charged into the photogen insulation can, the damping fluid case, cleaning case and foul water tank, six small containers in the online precise testing device camera bellows are with the rotation of rotation major axis, according to different concentration proportionings respectively the small container of each in camera bellows inject luminous bacillus successively, damping fluid, three kinds of liquid of sewage, after three kinds of liquid mixing in the test container are even, the small container of its below of general who has surrendered entangles under the control photodetector, detect, photodetector is tested the variation of light intensity in each small container successively, with data storage, demonstration also is uploaded to host computer, after detection finishes, the control photodetector rises, promote small container, bleed off test liquid; Small container is injected the clear water washing, promote small container, bleed off the liquid in it, in order to avoid next measurement result is exerted an influence.
The advantage that the present invention has: can realize the online detection of municipal effluent bio-toxicity, simple to operate, easy to maintenance, the automaticity height, so can access the rational ratio of performance to price, can be applicable to online auto monitoring than rugged surroundings, utilize it to can be used as unit and use, also can serve as the front end product of monitoring network system.Be applicable to the on-line monitoring or the analytical instrument of used band metering such as biology, environmental protection, petrochemical complex, food, storage.
Description of drawings
Fig. 1 is an instrument general structure synoptic diagram of the present invention.
Fig. 2 is the structural representation of photogen insulation can.
Fig. 3 is the structural representation of precise testing device.
Fig. 4 is the A-A cut-open view of Fig. 3.
Embodiment
See Fig. 1-4, technical scheme particular content of the present invention is as follows:
In the front of instrument is the guidance panel 9 that connects electric control gear, and insulation can 11, damping fluid case 12 and cleaning case 14 are installed in the top in Instrument shell; Place medical rank container 10 in the insulation can 11, test is housed in the medical rank container 10 uses bacterium, loam cake with handles 30 is housed on the insulation can 11, insulation can 11 has two-layer, middle fill insulant material 33, (is not from figure inwall to insulation can 11 inwalls?) post Po Er paster 31, heat radiator 32 and temperature sensor.Damping fluid case 12 tops have rubber hose coupling 13 directly to reach outside the housing, can directly inject damping fluid outside, and damping fluid mainly is a liquid volume in the adding container, and to reach the purpose of variable concentrations, damping fluid is to the not influence of luminous intensity of luminous bacillus.Two rubber hose couplings 15,16 are arranged above the cleaning case 14, directly stretch out outside the housing, a joint connects running water pipe, and another joint can regularly add an amount of clean-out system.At the fixing assembling in the bottom of instrument camera bellows, the environment temperature precision prescribed is higher in the camera bellows, and camera bellows has two-layer, and middle fill insulant material sticks Po Er paster and temperature sensor (not shown) on the cabinet wall.Be provided with exploration hole and four dropper joints 27 on camera bellows loam cake 2, wherein three dropper joints connect photogen insulation can inner pressurd vessel 11, damping fluid case 12 and cleaning case 14 by the circulation pipeline of charged magnet valve respectively; The circulation pipeline adopts the oxirane medical Transfusion device, and the air intake structure of transfusion device upper end can stop extraneous bacterium to be invaded in the medical rank container 10, avoids the test in the medical rank container to be polluted with bacterium.One rotation major axis 8 penetrates camera bellows lid 2, plectane 28 and the 8 affixed and synchronous rotations of rotation major axis, six stainless steel small containers 1 are along circumferentially being connected on the plectane 28, the bottom of each small container 1 is the opening shape, assemble rotating chassis 29 in the bottom of camera bellows, six vortex-like polyamine fat sealing-plugs 36 of salable small container bottom are set on it.Camera bellows the bottom also be provided with discharge orifice 35.The electromagnet 19 (employing prior art) that the upper end assembling of rotation major axis 8 promotes the rotation major axis.Side at rotation major axis 8 is assembled stepper motor 23 and the cogwheel gearing 26 that the driven in rotation major axis rotates, be connected with and cogwheel gearing meshed gears 25 on the rotation major axis 8, utilize six stainless steel small containers 1 of step motor control with 8 rotations of rotation major axis and accurate location; Install the plectane 20 in belt length hole on the major axis 8,, constitute the photoelectric switch of control rotation major axis 8 at the supporting with it optoelectronic switch 21 of side assembling.Photoelectric switch is converted to electric signal with light signal, thereby control step motor 23 rotates, and the reference position that makes six stainless steel small containers 1 is all on fixing position.So just can make the concentration of wastewater that injects 1 li of stainless steel small container that certain rules is arranged, thereby avoid because accident power-off or when restarting at every turn, the reference position of test container may be all different, can make the mistake to total system control, not have regularity with the concentration that causes the test specimens of injecting each small container 1.Be provided with photodetector 5 (employing prior art) above camera bellows, photodetector 5 top connecting screw rods 7, screw rod 7 are assembled in fixedly on the swivel nut 6, and screw rod 7 upper ends connect stepper motor 22; Side at photodetector 5 is assembled the photoelectric switch that is made of sheet metal 4 and optoelectronic switch 3.Its effect is a photodetector 5 when dropping to lowermost end, and optoelectronic switch provides an electric signal, and control step motor 22 backward rotation reset photodetector 5.The foul water tank 17 that is located at the instrument outside is by the dropper joint 27 on the pipeline connection camera bellows lid 2 of charged magnet valve, and foul water tank 17 connects submersible pumps 18.The effect of foul water tank 17 is to filter the municipal effluent that submersible pump is discharged, and blocks pipeline to prevent sewage impurity.
The course of work of the present invention is as follows:
Put into the medical grade container 10 of insulation can 11 as the photogen of indicator organism, because the accuracy requirement of photogen storage temperature is higher, biological nature according to luminous bacillus is learnt, temperature is at 2 ℃, photogen keeps active and stops growing, and therefore will make insulation can 11 interior temperature remain at 4 ℃.When temperature is higher than 4 ℃, temperature sensor is exported a signal, starts Po Er paster 31 refrigeration, and when temperature was lower than 4 ℃ insulation can 11 in, temperature sensor was exported a signal, starts Po Er paster 31 and heats.Damping fluid, cleaning fluid and sewage are put into damping fluid case 12, cleaning case 14 and foul water tank 17 respectively.
The small container 1 of vortex-like back cover on-line analysis test is around 8 rotations of rotation major axis, according to different concentration proportionings respectively the small container of each in camera bellows 1 inject luminous bacillus, damping fluid, three kinds of liquid of sewage successively, after three kinds of liquid mixing in the test container are even, the control temperature makes temperature remain on 25 ℃.So that make measurement result more accurate.The environment temperature precision prescribed is not high in the whole instrument housing, remains on more than 2 ℃ to get final product.When temperature is lower than 2 ℃, start 31 heating of Po Er paster, when ambient temperature is too high, start Po Er paster 31 refrigeration.
22 rotations of electric control system controls stepper motor, by the transmission of screw rod 7 and nut 6, control photodetector 5 descends.When photodetector 5 drops to lowermost end, the sleeve pipe 34 of its lower end inserts into the inner from the exploration hole of camera bellows, the stainless-steel tube small container 1 of its below is entangled, detect, measuring small container 1 in the darkroom can Be Controlled rotate detected continuously to guarantee a plurality of specimen, start photodetector 5 and test the variation of light intensity in six small containers successively, with data storage, demonstration also is uploaded to host computer, test was gone through 10 minutes, 20 of each test point store test data, after detection finishes, stepper motor 22 reverse rotations, rotate to drive photodetector 5 by bolt and nut and rise, so as not to during 1 rotation of test small container and photodetector 5 interfere phenomenon.Promote small container 1, small container 1 bottom breaks away from vortex-like polyamine fat sealing-plug 36, bleeds off test liquid; Small container 1 is injected the clear water washing, bleed off the liquid in it, in order to avoid next measurement result is exerted an influence.
Show after the class of pollution of sewage toxicity is calculated by the special software bag and be stored in the corresponding database.Measurement data shows and is stored in the program of single-chip microcomputer at working site LED, and realizes serial communication by 485/232 change-over circuit, and field data is sent to remote control room, both can realize single-set operation, also can realize the networking operation.
The corresponding relation of luminous bacillus luminous intensity parameter and measured matter toxicity index, be to set up relevant toxicity analytical database, and the photobacteria toxicity test method of percentiles grade classification principle that adopts U.S. BULICH.A.A to propose is carried out the toxic grade division by testing.The metric of toxicity intensity is as follows:
(1) relative light intensity: relative light intensity=sample light intensity/contrast light intensity * 100%
(2) press down the light rate relatively: press down light rate=contrast light intensity-sample light intensity/contrast light intensity * 100% relatively
(3) EC50:EC50 makes the toxic concentration of luminous intensity minimizing 50% or the dilute concentration (or extension rate) of sewage.
Photobacteria test method of percentiles grade classification
| EC50 or LC50 (percentage concentration) | The toxicity rank | Grade |
| ＜25% 25-75% 75-100%＞100% or can not ask EC50 | Strong malicious little poison is nontoxic | I II III IV |
Claims (4)
1, a kind of municipal effluent bio-toxicity on-line automatic analyzer, it comprises Instrument shell, connects the guidance panel of electric control gear, it is characterized in that: photogen insulation can, damping fluid case and the cleaning case of the top assembling band case lid of instrument, place medical rank container in the photogen insulation can; At the bottom of instrument assembling precise testing device, this device is provided with fixedly camera bellows, one rotation major axis penetrates in the camera bellows, with the affixed plectane of rotation major axis, six small containers of assembling on the plectane, the bottom of each small container is the opening shape, assemble rotating chassis in the bottom of camera bellows, the vortex-like sealing-plug of salable small container bottom is set on it, covers at camera bellows four dropper joints are set, they connect photogen insulation can inner pressurd vessel, damping fluid case and cleaning case by the circulation pipeline of charged magnet valve respectively; The electromagnet that the upper end assembling of rotation major axis promotes the rotation major axis, and the actuating unit that the driven in rotation major axis rotates is set; Above camera bellows, be provided with photodetector, photodetector top connecting screw rod, screw rod group is contained in fixedly on the swivel nut, and the screw rod upper end connects stepper motor; The circulation pipeline that covers also by charged magnet valve at camera bellows connects foul water tank.
2, municipal effluent bio-toxicity on-line automatic analyzer according to claim 1 is characterized in that: assemble photoelectric switch on the above-mentioned rotation major axis.
3, municipal effluent bio-toxicity on-line automatic analyzer according to claim 1 is characterized in that: assemble photoelectric switch on the above-mentioned photodetector.
4, a kind of using method of municipal effluent bio-toxicity on-line automatic analyzer: it is characterized in that: the start-up temperature control device, testing sample environment temperature in the camera bellows is controlled at 20 ℃, environment temperature in the medical rank container of insulation can of storage photogen is controlled at 0 ℃-4 ℃, the environment temperature in the instrument box is controlled at 2 ℃; With photogen, damping fluid, clear water and sewage are respectively charged into the photogen insulation can, the damping fluid case, cleaning case and foul water tank, six small containers in the online precise testing device camera bellows are with the rotation of rotation major axis, according to different concentration proportionings respectively the small container of each in camera bellows inject luminous bacillus successively, damping fluid, three kinds of liquid of sewage, after three kinds of liquid mixing in the test container are even, the small container of its below of general who has surrendered entangles under the control photodetector, detect, photodetector is tested the variation of light intensity in each small container successively, with data storage, demonstration also is uploaded to host computer, after detection finishes, the control photodetector rises, promote small container, bleed off test liquid; Small container is injected the clear water washing, promote small container, bleed off the liquid in it.
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| Application Number | Priority Date | Filing Date | Title |
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| CN 200410021355 CN1266467C (en) | 2004-03-10 | 2004-03-10 | On-line automatic analizer for urban saprobia toxic and its using method |
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| CN 200410021355 CN1266467C (en) | 2004-03-10 | 2004-03-10 | On-line automatic analizer for urban saprobia toxic and its using method |
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| CN1266467C CN1266467C (en) | 2006-07-26 |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100504359C (en) * | 2005-09-23 | 2009-06-24 | 中国科学院生态环境研究中心 | On-line monitoring chemical light-illuminating detector for contaminant in aquatic sample |
| CN100514061C (en) * | 2007-08-31 | 2009-07-15 | 清华大学 | Casing tube type photobacteria optical fiber probe head for detecting water toxicity and preparing method thereof |
| CN101477056B (en) * | 2009-01-22 | 2010-12-08 | 浙江清华长三角研究院 | Multichannel photobacteria on-line water quality toxicity monitoring device and monitoring method |
| CN102234609A (en) * | 2010-04-27 | 2011-11-09 | 杭州绿洁水务科技有限公司 | System and method of comprehensive toxicity detection of water body |
| CN101371135B (en) * | 2006-01-20 | 2011-12-14 | 英特利泰克水有限公司 | Apparatus for sensing at least one parameter in a liquid |
| CN101477131B (en) * | 2009-01-13 | 2012-01-11 | 浙江理工大学 | On-line automatic analyzer for synthetic biological toxicity in water and its use method |
| CN101571534B (en) * | 2009-05-25 | 2013-01-16 | 嘉兴凯实生物科技有限公司 | Water quality toxicity detector |
| CN103076318A (en) * | 2012-12-27 | 2013-05-01 | 力合科技（湖南）股份有限公司 | Toxicity detection device |
| CN106292507A (en) * | 2016-08-18 | 2017-01-04 | 合肥信诺捷科节能服务有限公司 | A kind of intelligent industrial wastewater detection device |
| CN108195827A (en) * | 2018-02-02 | 2018-06-22 | 哈尔滨工业大学 | A kind of Dual-window water quality toxicity analysis and detection device and its detection method |
| CN109916889A (en) * | 2019-04-03 | 2019-06-21 | 张颖 | A kind of industrial wastewater water quality on-line quick detection system and its detection method |
| CN111189782A (en) * | 2020-02-26 | 2020-05-22 | 杭州电子科技大学 | Water quality detection equipment for fresh water biotoxicity monitoring system |
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2004
- 2004-03-10 CN CN 200410021355 patent/CN1266467C/en not_active Expired - Fee Related
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100504359C (en) * | 2005-09-23 | 2009-06-24 | 中国科学院生态环境研究中心 | On-line monitoring chemical light-illuminating detector for contaminant in aquatic sample |
| CN101371135B (en) * | 2006-01-20 | 2011-12-14 | 英特利泰克水有限公司 | Apparatus for sensing at least one parameter in a liquid |
| CN100514061C (en) * | 2007-08-31 | 2009-07-15 | 清华大学 | Casing tube type photobacteria optical fiber probe head for detecting water toxicity and preparing method thereof |
| CN101477131B (en) * | 2009-01-13 | 2012-01-11 | 浙江理工大学 | On-line automatic analyzer for synthetic biological toxicity in water and its use method |
| CN101477056B (en) * | 2009-01-22 | 2010-12-08 | 浙江清华长三角研究院 | Multichannel photobacteria on-line water quality toxicity monitoring device and monitoring method |
| CN101571534B (en) * | 2009-05-25 | 2013-01-16 | 嘉兴凯实生物科技有限公司 | Water quality toxicity detector |
| CN102234609A (en) * | 2010-04-27 | 2011-11-09 | 杭州绿洁水务科技有限公司 | System and method of comprehensive toxicity detection of water body |
| CN103076318A (en) * | 2012-12-27 | 2013-05-01 | 力合科技（湖南）股份有限公司 | Toxicity detection device |
| CN106292507A (en) * | 2016-08-18 | 2017-01-04 | 合肥信诺捷科节能服务有限公司 | A kind of intelligent industrial wastewater detection device |
| CN106292507B (en) * | 2016-08-18 | 2019-03-22 | 合肥信诺捷科节能服务有限公司 | A kind of intelligent industrial wastewater detection device |
| CN108195827A (en) * | 2018-02-02 | 2018-06-22 | 哈尔滨工业大学 | A kind of Dual-window water quality toxicity analysis and detection device and its detection method |
| CN108195827B (en) * | 2018-02-02 | 2020-06-09 | 哈尔滨工业大学 | Double-window water quality toxicity analysis and detection device and detection method thereof |
| CN109916889A (en) * | 2019-04-03 | 2019-06-21 | 张颖 | A kind of industrial wastewater water quality on-line quick detection system and its detection method |
| CN109916889B (en) * | 2019-04-03 | 2021-05-25 | 张颖 | Industrial wastewater quality online rapid detection system and detection method thereof |
| CN111189782A (en) * | 2020-02-26 | 2020-05-22 | 杭州电子科技大学 | Water quality detection equipment for fresh water biotoxicity monitoring system |
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