CN1560145A - Application of oxime antioxygenic stabilizing agent in printing ink - Google Patents
Application of oxime antioxygenic stabilizing agent in printing ink Download PDFInfo
- Publication number
- CN1560145A CN1560145A CNA200410012804XA CN200410012804A CN1560145A CN 1560145 A CN1560145 A CN 1560145A CN A200410012804X A CNA200410012804X A CN A200410012804XA CN 200410012804 A CN200410012804 A CN 200410012804A CN 1560145 A CN1560145 A CN 1560145A
- Authority
- CN
- China
- Prior art keywords
- printing ink
- oxime
- stablizer
- look
- oximes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Printing Methods (AREA)
Abstract
The invention relates to the application of an oxime antioxidant stabilizer, especially the application of the oxime antioxidant stabilizer in recess-engraving, gravure etching, special-color flat letterpress and special-color flat gravure printing ink. It adds 0.55-1.5% of oxime complex stabilizer in banknote printing ink containing 0.4-1.5% of drier, uses the oxime antioxidant stabilizer to complex with the metallic salt of the drier in the above printing ink to generate a complex, so as to inhibit the drying action of the metallic salt drier, ensure the stability of the printing ink in the storing and printing course and prevent the printing ink from polymerizing and skinning and roughening because of the overlong storage time. As the printing ink is transferred on the print-bearing objects by printing, the surface area of the printing ink is enlarged and the osmosis and volatilization of the oxime, the metallic ions in the metallic salt drier break away from the isolation and restriction of the complexing agent and activate, thus making the printing ink oxidized and polymerized into films. It enhances the printing activity of the printing ink, prolongs the storage cycle of the printing ink and achieves the purpose of on-paper fast drying after printing and on-machine slow drying.
Description
Technical field
The present invention relates to a kind of application of oxime antioxygenic stablizer, the application of especially a kind of oxime antioxygenic stablizer in the special look deep-etch plate of the special look plano-convex of carved gravure etching plate version printing ink.
Background technology
Common ink is with carved gravure, etching plate, special look plano-convex version, specially look deep-etch plate printing ink is different, and the pigment ratio of common ink is simple and cheap, generally all is three primary colors, color is more bright-coloured, good luster connects material content height, and the siccative kind of use is single.Carved gravure, etching plate, special look plano-convex version, special look deep-etch plate ink technology content height, technology strictness, material expensive, combination is complicated, a kind of color is prepared by multiple pigment, make the color preparation also complicated, it is low to connect material content, and other exotic materials and siccative are wide in variety, this just makes that prescription is special, the interrelated complexity of material.Ink quality requires high, and the China ink that adapts according to the needs design of printing type.
The effect of antioxygen stable material will suppress the oxypolymerization of printing ink exactly, to improve the printing adaptability of ink setting aspect, the kind of antioxidant stabilizer is a lot, as phenols, amine, phosphorous acid esters etc., be familiar with the Resorcinol that phenols is arranged also commonly used, amine EDTA etc., phenols easily residues in the printing ink, to carved gravure, etching plate, specially look plano-convex version, specially the dryness influence of look deep-etch plate printing ink is very big, and be difficult to hold consumption, the improper meeting of consumption obviously delays printing ink when producing drying, waiting time is long and can influence color of ink.The wetting ability of amine, phosphorous acid lipid be adapted to thermoplastic resin such as polyvinyl chloride, polypropylene, polystyrene and to the influential and carved gravure of rubber roll, etching plate, specially look plano-convex version, specially the look deep-etch plate to connect in the material mainly be that modified resins oil, above-mentioned oxidation inhibitor add in the printing ink and gives birth to the reversible reaction with the metal-salt difficult labour.Dryness delayed synchronously when this will cause ink transfer on printing, was difficult to meet the requirement of high speed, efficient modern print production.
The oxime antioxygenic stablizer, when for example methyl ethyl ketoxime, butyraldehyde oxime are used for common coating, common printing ink, its addition is controlled at below 0.5%, this is because the siccative kind of the metal-salt in the common printing ink is single, the limited amount of the oxime antioxygenic stablizer of required consumption is controlled at below 0.5% and just can reaches requirement.For example the recommendation consumption of methyl ethyl ketoxime is the 0.1-0.5% of coating total amount, concrete visible address is that the code name that the Quzhou kairine chemical industry company limited on No. 5, man chemical industrial park South Mountain, Shen, Quzhou, Zhejiang road produces is the methyl ethyl ketoxime product of anti KL-841, and it recommends consumption is the 0.1-0.5% of coating total amount.The butyraldehyde oxime of commodity Troykyd Anti-Skin BTO by name, its performance and purposes:, special odor is arranged for little white low-viscosity (mobile) liquid (in storage process, may become shallow straw yellow) that is sallow.This product effective constituent minimum 99%.Density 0.901～0.912g/cm3 (27).Viscosity (Gardner) A-1 (maximum).41 ℃ of minimums of flash-point.This product is as anti.Low smelly, actual water white transparency, volatilization is proposed to be used in varnish colour fully, especially contains in the batching of capable and experienced property such as tung oil and so on consumption 0.12～0.36g/100ml paint formulation.The methyl ethyl ketoxime of putting down in writing in all the other producers and the technical manual, butyraldehyde oxime recommend consumption identical therewith and close.Yet there are no in oxime antioxygenic stablizer Application Areass such as methyl ethyl ketoxime, butyraldehyde oximes and to surpass 0.5% report.
And carved gravure, etching plate, specially look plano-convex version, specially look deep-etch plate ink composition is more than the common ink complexity, wherein to urge dried salt be that multiple metal urges that dried salt is composite to form to metal, experiment shows that methyl ethyl ketoxime, butyraldehyde oxime addition are lower than 0.5%, be not enough to carved gravure, etching plate, specially look plano-convex version, specially the composite metal in the look deep-etch plate printing ink is urged the abundant complexing of dried salt.Effect is undesirable.
Summary of the invention
The object of the present invention is to provide the application of a kind of oxime antioxygenic stablizer in the special look deep-etch plate of the special look plano-convex of carved gravure etching plate version printing ink, interpolation oxime antioxygenic stablizer helps solving the equilibrium problem of ink setting, shorten the print production cycle, improve the printability of carved gravure, etching plate, special look plano-convex version, special look deep-etch plate printing ink.
Technical scheme of the present invention is:
A kind of oxime antioxygenic stablizer adds 0.55～1.5% oximes complexing stablizer in carved gravure, etching plate, specially look plano-convex version, the specially application in the look deep-etch plate printing ink in printing ink, oximes complexing stablizer is R
1C (=NOH) R
2, R wherein
1=C
2-C
3Carbochain, R
2=H or CH
3
The another kind of technical scheme of the present invention is expressed as:
The application of a kind of oxime antioxygenic stablizer in printing ink adds 0.55～1.5% oximes complexing stablizer in printing ink, oximes complexing stablizer is R
1C (=NOH) R
2, R wherein
1=C
2-C
3Carbochain, R
2=H or CH
3, wherein printing ink is specially carved gravure, etching plate, special look plano-convex version, special look deep-etch plate printing ink.
More excellent technical scheme has following:
The oxime antioxygenic stablizer adds 0.55～1.5% oximes complexing stablizer in carved gravure, etching plate, specially look plano-convex version, the specially application in the look deep-etch plate printing ink in the printing ink that contains siccative 0.4～1.5%.
The oxime antioxygenic stablizer adds 1.1～1.5% oximes complexing stablizer in carved gravure, etching plate, specially look plano-convex version, the specially application in the look deep-etch plate printing ink in printing ink.
The application of methyl ethyl ketoxime in carved gravure, etching plate, special look plano-convex version, special look deep-etch plate printing ink.
The application of butyraldehyde oxime in carved gravure, etching plate, special look plano-convex version, special look deep-etch plate printing ink.
The application of oxime antioxygenic stablizer in carved gravure, etching plate, special look plano-convex version, special look deep-etch plate printing ink, oximes complexing stablizer is the combination of methyl ethyl ketoxime and butyraldehyde oxime.
Utilize the chemical complexing reaction principle, promptly generate the characteristic of complex compound with certain component and another certain compound in mutually, the complex compound of the two generation also separates with original mixture.This reversible chemical complexing reaction also suppresses the oxypolymerization of printing ink to improve the printing adaptability of carved gravure, etching plate, special look plano-convex version, special look deep-etch plate ink setting aspect with stabilization simultaneously.Operable siccative major ingredient is cobalt, manganese, zirconium and some rare earth elements in carved gravure, etching plate, special look plano-convex version, the special look deep-etch plate printing ink, the oximes antioxidant stabilizer has=C=NOH group and low molecular weight, this coordination compound that contains dative bond, it can with carved gravure, etching plate, specially look plano-convex version, specially the metallic element of siccative play the effect that complex reaction reaches shielding in the look deep-etch plate printing ink, its pair key can also play stabilization with oxygen, and this is applicable to carved gravure, etching plate, special look plano-convex version, special look deep-etch plate printing ink.Oximes antioxidant stabilizer branch commonly used has methyl ethyl ketoxime, butyraldehyde oxime.Metal-salt content is proportional in its speed of speed of printing ink oxidative polymerization on printing and the printing ink, in the banknote printing ink that contains siccative 0.4～1.5%, add 0.55～1.5% oximes complexing stablizer, and can increase and decrease along with the increase and decrease of metal-salt content in the printing ink, the ratio that this helps suitably improving metal-salt content in the printing ink, reach carved gravure, etching plate, specially look plano-convex version, specially look deep-etch plate printing ink doing soon on the paper in printing process stable purpose.
The invention has the advantages that: utilize the oximes antioxidant stabilizer to carved gravure, etching plate, specially look plano-convex version, specially the metal-salt of siccative can play the chemical complexing reacting generating complex, suppress urging the effect of doing, having guaranteed that printing ink stablizes, prevents printing ink staging life long and polymerization skinning and returning slightly in storage and printing process of metal-salt siccative in the look deep-etch plate printing ink.When printing ink when printing is transferred on the stock, the surface-area of printing ink increases, because the infiltration and the volatilization of oximes, the metal ion in the metal-salt siccative has been broken away from the isolation restriction of complexing agent and has been activated, makes the printing ink oxidization polymerization to form film.
The present invention passes through carved gravure, etching plate, special look plano-convex version, the specially application and the exploration of look deep-etch plate printing ink oxidation inhibitor, filter out the oximes antioxidant stabilizer, the oximes antioxidant stabilizer has complexing action to the metal-salt in the ink drier, utilize the chemical complexing reaction principle, add carved gravure in the auxiliary agent mode, etching plate, special look plano-convex version, specially help solving the equilibrium problem of ink setting in the look deep-etch plate printing ink, shorten the print production cycle, improve carved gravure, etching plate, special look plano-convex version, the printability of special look deep-etch plate printing ink, and prolongation carved gravure, etching plate, special look plano-convex version, specially the resting period of look deep-etch plate printing ink reaches on the paper of printing back and does soon, dry slow purpose on the machine.
Embodiment
Embodiment 1
A kind of oxime antioxygenic stablizer adds 0.55～1.5% oximes complexing stablizer in carved gravure, etching plate, specially look plano-convex version, the specially application in the look deep-etch plate printing ink in printing ink, oximes complexing stablizer is R
1C (=NOH) R
2, R wherein
1=C
2-C
3Carbochain, R
2=H or CH
3Oximes complexing stablizer slowly added to stir in the printing ink get final product.
Embodiment 2
The oxime antioxygenic stablizer adds 0.55～1.5% oximes complexing stablizer in carved gravure, etching plate, specially look plano-convex version, the specially application in the look deep-etch plate printing ink in the printing ink that contains siccative 0.4～1.5%.All the other are with embodiment 1.
Embodiment 3
The oxime antioxygenic stablizer adds 1.1～1.5% oximes complexing stablizer in carved gravure, etching plate, specially look plano-convex version, the specially application in the look deep-etch plate printing ink in printing ink.All the other are with embodiment 1.
Embodiment 4
The application of oxime antioxygenic stablizer in carved gravure, etching plate, special look plano-convex version, special look deep-etch plate printing ink, oximes complexing stablizer is a methyl ethyl ketoxime.All the other are with embodiment 1.
Embodiment 5
The application of oxime antioxygenic stablizer in carved gravure, etching plate, special look plano-convex version, special look deep-etch plate printing ink, oximes complexing stablizer is a butyraldehyde oxime.All the other are with embodiment 1.
Embodiment 6
The application of oxime antioxygenic stablizer in carved gravure, etching plate, special look plano-convex version, special look deep-etch plate printing ink, oximes complexing stablizer is the combination of methyl ethyl ketoxime and butyraldehyde oxime.All the other are with embodiment 1.
Embodiment 7
The method of pressing embodiment 1 adds methyl ethyl ketoxime and butyraldehyde oxime in carved gravure, etching plate, special look plano-convex version, the special look deep-etch plate printing ink, and compares with common ink:
The prescription of table 1 common ink and effect:
Table 2 carved gravure, etching plate, specially look plano-convex version, the specially prescription and the effect of look deep-etch plate printing ink:
The printing ink of the A in the table 2, B, C, D look all can be used for the printing ink of carved gravure, etching plate, special look plano-convex version, special look deep-etch plate, and the material class number in the table 2 can search and buy in seal paper money coinage main office.
Its address is: the No. 143 A, Xizhimen Outside Avenue, Xicheng District, Beijing City.
With the printing ink of the same race of A, B, C, D look, contain four groups of different printing ink of dry oil mass ratio and test, by the financial industry standard JR/TXXXXX-XXXX of the People's Republic of China (PRC) and ASTMD1640 " organic coating dry solidification film forming test method under the room temperature) ", discovery is under 80 ℃ of conditions, add with the drying time that does not add the oximes stablizer and do not have difference, but the dry and comfortable of surperficial conjunctiva slightly had any different, the ink pellet surface conjunctiva that adds the oximes stablizer is dry and comfortable, does not add the slightly sticking hand of ink pellet surface conjunctiva of oximes stablizer.Infiltration 23 ℃ of simulate press conditions all will be faster than the printing ink that does not add the oximes stablizer from doing the printing ink air-drying time that adds the oximes stablizer as can be seen, and this has just reached quick-drying purpose on paper.And not having infiltration under the condition of doing at 23 ℃ of simulate press ink fountains, the printing ink air-drying time that adds the oximes stablizer all will be slower than the printing ink that does not add the oximes stablizer, has reached dry slow purpose on machine.Table 3
Carry out anti-materialization check with the above eight groups printing ink that add the oximes stablizer by the capable standard of issuing of financial JY/T4203-1998, it is excellent all to have reached highest ranking.Quality test sees Table 4:
Experiment shows that methyl ethyl ketoxime, butyraldehyde oxime addition are lower than 0.5%, be not enough to carved gravure, etching plate, specially look plano-convex version, specially the composite metal in the look deep-etch plate printing ink is urged the abundant complexing of dried salt.Effect is undesirable.Select for use the printing ink of the same race of D look to compare experiment, the results are shown in Table 5:
Embodiment 8
The application of a kind of oxime antioxygenic stablizer in carved gravure, etching plate, special look plano-convex version, special look deep-etch plate printing ink, the oximes complexing stablizer of adding 0.55% in printing ink, oximes complexing stablizer is R
1C (=NOH) R
2, R wherein
1=C
2-C
3Carbochain, R
2=H or CH
3Oximes complexing stablizer slowly added to stir in the printing ink get final product.All the other are with embodiment 7.
Embodiment 9
The application of a kind of oxime antioxygenic stablizer in carved gravure, etching plate, special look plano-convex version, special look deep-etch plate printing ink, the oximes complexing stablizer of adding 1.5% in printing ink, oximes complexing stablizer is R
1C (=NOH) R
2, R wherein
1=C
2-C
3Carbochain, R
2=H or CH
3Oximes complexing stablizer slowly added to stir in the printing ink get final product.All the other are with embodiment 7.
Embodiment 10
The application of a kind of oxime antioxygenic stablizer in carved gravure, etching plate, special look plano-convex version, special look deep-etch plate printing ink, the oximes complexing stablizer of adding 1.1% in printing ink, oximes complexing stablizer is R
1C (=NOH) R
2, R wherein
1=C
2-C
3Carbochain, R
2=H or CH
3Oximes complexing stablizer slowly added to stir in the printing ink get final product.All the other are with embodiment 7.
Embodiment 11
The application of oxime antioxygenic stablizer in carved gravure, etching plate, special look plano-convex version, special look deep-etch plate printing ink, the methyl ethyl ketoxime of adding 0.77% in the printing ink that contains siccative 0.4%.All the other are with embodiment 10.
Embodiment 12
The application of oxime antioxygenic stablizer in carved gravure, etching plate, special look plano-convex version, special look deep-etch plate printing ink, the butyraldehyde oxime of adding 1.2% in the printing ink that contains siccative 1.5%.All the other are with embodiment 10.
Embodiment 13
The application of oxime antioxygenic stablizer in carved gravure, etching plate, special look plano-convex version, special look deep-etch plate printing ink, the methyl ethyl ketoxime of adding 0.6% and 0.6% butyraldehyde oxime in the printing ink that contains siccative 0.6%.All the other are with embodiment 10.
Claims (6)
1, a kind of oxime antioxygenic stablizer is characterized in that in carved gravure, etching plate, specially look plano-convex version, the specially application in the look deep-etch plate printing ink: add 0.55～1.5% oximes complexing stablizer in printing ink, oximes complexing stablizer is R
1C (=NOH) R
2, R wherein
1=C
2-C
3Carbochain, R
2=H or CH
3
2, oxime antioxygenic stablizer according to claim 1 is characterized in that in carved gravure, etching plate, specially look plano-convex version, the specially application in the look deep-etch plate printing ink: add 0.55～1.5% oximes complexing stablizer in the printing ink that contains siccative 0.4～1.5%.
3, oxime antioxygenic stablizer according to claim 1 is characterized in that in carved gravure, etching plate, specially look plano-convex version, the specially application in the look deep-etch plate printing ink: add 1.1～1.5% oximes complexing stablizer in printing ink.
4, the application of oxime antioxygenic stablizer according to claim 1 in carved gravure, etching plate, special look plano-convex version, special look deep-etch plate printing ink, it is characterized in that: oximes complexing stablizer is a methyl ethyl ketoxime.
5, the application of oxime antioxygenic stablizer according to claim 1 in carved gravure, etching plate, special look plano-convex version, special look deep-etch plate printing ink, it is characterized in that: oximes complexing stablizer is a butyraldehyde oxime.
6, the application of oxime antioxygenic stablizer according to claim 1 in carved gravure, etching plate, special look plano-convex version, special look deep-etch plate printing ink, it is characterized in that: oximes complexing stablizer is the combination of methyl ethyl ketoxime and butyraldehyde oxime.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410012804 CN1234784C (en) | 2004-02-27 | 2004-02-27 | Application of oxime antioxygenic stabilizing agent in printing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410012804 CN1234784C (en) | 2004-02-27 | 2004-02-27 | Application of oxime antioxygenic stabilizing agent in printing ink |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1560145A true CN1560145A (en) | 2005-01-05 |
| CN1234784C CN1234784C (en) | 2006-01-04 |
Family
ID=34440104
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410012804 Expired - Fee Related CN1234784C (en) | 2004-02-27 | 2004-02-27 | Application of oxime antioxygenic stabilizing agent in printing ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1234784C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101450559B (en) * | 2007-12-07 | 2011-11-02 | 海德堡印刷机械股份公司 | Method for drying printing ink and printing ink |
| CN104830143A (en) * | 2015-04-17 | 2015-08-12 | 陆开云 | Environment-friendly antioxidant used for printing ink |
| CN113480888A (en) * | 2021-07-08 | 2021-10-08 | 杭华油墨股份有限公司 | Compound anti-skinning agent and preparation method and application thereof |
-
2004
- 2004-02-27 CN CN 200410012804 patent/CN1234784C/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101450559B (en) * | 2007-12-07 | 2011-11-02 | 海德堡印刷机械股份公司 | Method for drying printing ink and printing ink |
| CN104830143A (en) * | 2015-04-17 | 2015-08-12 | 陆开云 | Environment-friendly antioxidant used for printing ink |
| CN113480888A (en) * | 2021-07-08 | 2021-10-08 | 杭华油墨股份有限公司 | Compound anti-skinning agent and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1234784C (en) | 2006-01-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106062098B (en) | Active energy ray-curable flexographic ink composition and its printed article | |
| CN1800225A (en) | Latex type hydroxy acryl acid resin possessing core-shell configuration | |
| CN103756496A (en) | Environment-friendly printed matter oil polish | |
| CN103540240A (en) | UV (Ultraviolet)-compound laser coating composition | |
| CN1234784C (en) | Application of oxime antioxygenic stabilizing agent in printing ink | |
| CN103073658A (en) | Photoinitiator mixture of novel aromatic hydroxyl ketone and acylphosphine oxide, and composite system of photoinitiator mixture and photoabsorber | |
| CN1712465A (en) | Water soluble printing ink and production thereof | |
| CN111619256A (en) | Water transfer printing holographic anti-counterfeiting stained paper and printing method thereof | |
| CN101864245A (en) | Alcohol-soluble printing varnish and preparation method thereof | |
| JP2023547688A (en) | UV-VIS radiation-curable security ink for creating dichroic security features | |
| CN1222866A (en) | Abrasion-removable coating and method of application | |
| CN102899960B (en) | A kind of synthetic calcium silicate adds the surface treatment method filling out offset printing paper | |
| US20200354596A1 (en) | Ink composition and printed matter | |
| CN1907725A (en) | Novel technique of producing laser paper | |
| CN104710855A (en) | Novel new formula PVC decorative material gravure printing ink | |
| CN103666053B (en) | A kind of UV curing transfer ink and preparation method thereof | |
| CN101486856B (en) | Light storage printing ink and preparation method thereof | |
| CN113910794B (en) | UV etching printing process capable of displaying large-area image-text gold stamping and controllable in brightness | |
| CN103254689B (en) | Gravure ink for aluminium foil and preparation method of gravure ink | |
| CN110128903B (en) | Benzene-free imaging layer for deep-color laser electrochemical aluminum and preparation method thereof | |
| CN101892609B (en) | Water mist resistant ultraviolet curing varnish capable of gold stamping | |
| US3048100A (en) | Method of producing a watermark design on paper | |
| CN106978013A (en) | The ink, its preparation method and application of different fluorescence are produced at different temperatures | |
| JP2023547687A (en) | UV-VIS radiation-curable security ink for creating dichroic security features | |
| CN101722753B (en) | Color-developing agent for carbonless copying paper |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |