CN1554806A - Micro arc oxidation treating process for aluminium alloy cylinder inner surface - Google Patents
Micro arc oxidation treating process for aluminium alloy cylinder inner surface Download PDFInfo
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- CN1554806A CN1554806A CNA2003101189099A CN200310118909A CN1554806A CN 1554806 A CN1554806 A CN 1554806A CN A2003101189099 A CNA2003101189099 A CN A2003101189099A CN 200310118909 A CN200310118909 A CN 200310118909A CN 1554806 A CN1554806 A CN 1554806A
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Abstract
During the micro arc oxidizing treatment of aluminum alloy cylinder inner surface, alkali electrolyte solution is made to flow through the cylinder and circulate via the solution circulating and cooling system; and power supply is applied across the stainless steel tube connected to the negative pole and the outer cylinder wall connected to the positive pole; so as to form one compact Al2O3 ceramic layer on the inner surface of the cylinder. The ceramic layer has blind micropores distributed homogeneously, and under friction reducing condition, one continuous oil film is formed on the surface to raise the wear resistance of the surface of the cylinder. In addition, the inner surface ceramic layer with heat insulating property results in raised combustor heat utilization while the outer surface of the cylinder maintains its heat dissipating performance.
Description
Technical field
The invention belongs to aluminium alloy cylinder surface hardening treatment process technology, particularly aluminium alloy cylinder internal surface microarc oxidation treatment process.
Technical background
Aluminium alloy becomes one of main consumptive material of vapour (bavin) oil turbine because of characteristics such as its lightweight and easy-formations, but wear resistance, antifraying property are relatively poor, limited it and on engine cylinder-body, directly used, must carry out suitable internal surface hardening treatment or inlay wear resisting cylinder jacket as friction pair.
Hardening process for aluminum alloy surface, obtained great development in recent years, as hard anodizing, thermospray etc., obtained using widely in industrial community, micro-arc oxidation process is a kind of non-ferrous metal (as aluminium, magnesium, titanium etc.) process of surface treatment that development in recent years is got up, especially since nineteen nineties, this technology has become the research focus of domestic academia, and obtains the approval of industrial community gradually.Especially the surface by micro-arc oxidation hardening treatment of aluminium alloy is because the high rigidity of alumina-ceramic layer and surface are uniform-distribution with the oil storage characteristic of a large amount of blind property micropores, so only be applicable under the antifriction condition and use.
Summary of the invention
The object of the present invention is to provide and a kind ofly can improve the heat dispersion of aluminium alloy and the thermal insulation of ceramic layer, the aluminium alloy cylinder internal surface microarc oxidation treatment process of wear resisting property.
The solution that realizes aluminium alloy cylinder internal surface microarc oxidation treatment process is, with pending aluminium alloy cylinder as anode, built-in stainless steel tube as negative electrode, the alkaline electrolysis solution that will be main component with phosphoric acid salt enters cylinder body by stainless steel tube, and alkaline electrolysis solution flows out from the solution thrust-augmenting nozzle of the other end of cylinder body.Alkaline electrolysis solution compares with cumulative volume by weight: by Sodium hexametaphosphate 99 10g/L-20g/L, and water glass 5g/L-10g/L, Sodium orthomolybdate 10g/L-15g/L, yellow soda ash 5g/L-8g/L, sodium wolframate 2g/L-5g/L forms.The pH value scope of alkaline electrolysis solution: 8～12.
With the aluminium diecast alloy cylinder body of alkaline electrolysis solution after an end of cylinder body is input to honing, alkaline electrolysis solution flows out from the solution thrust-augmenting nozzle of the other end of cylinder body, and alkaline electrolysis solution circulates in cylinder body by the solution circulated cooling system.
Built-in stainless steel tube is connect the negative pole of power supply, and outer wall of cylinder block connects the positive pole of power supply, by power supply cylinder body is applied voltage, and magnitude of voltage is at 600V-650V, and the time is 30～60min.Described power supply adopts direct current pulse power source.
The present invention be with pending aluminium alloy cylinder as anode, built-in stainless steel tube as negative electrode, application is that the alkaline electrolysis solution of main component enters cylinder body by stainless steel tube with phosphoric acid salt, electrolytic solution flows out from the other end of cylinder body, only to the inner surface of cylinder block potteryization, keep intact in the outside, both improved the utilization ratio of cylinder interior combustion chamber heat, the thermal diffusivity not influence again to cylinder body itself has improved the wear resistance between piston ring and cylinder body.
Description of drawings
Accompanying drawing is an aluminium alloy cylinder internal surface differential arc oxidation structure iron of the present invention.
Embodiment
A kind of aluminium alloy cylinder internal surface microarc oxidation treatment process, with pending aluminium alloy cylinder 1 as anode, built-in stainless steel tube 4 as negative electrode, the alkaline electrolysis solution that with phosphoric acid salt is main component enters cylinder body 1 by built-in stainless steel tube 4, alkaline electrolysis solution flows out from the solution thrust-augmenting nozzle 3 of cylinder body 1 the other end, and its concrete treatment process carries out according to the following steps:
1) preparation alkaline electrolysis solution:
Alkaline electrolysis solution is that hexametaphosphate is an electrolytic solution, and alkaline electrolysis solution compares with cumulative volume by weight:
By Sodium hexametaphosphate 99 10g/L-20g/L, water glass 5g/L-10g/L, Sodium orthomolybdate 10g/L-15g/L, yellow soda ash 5g/L-8g/L, sodium wolframate 2g/L-5g/L forms.Alkaline electrolysis pH value of solution value scope: 8～12.
2) with the alkaline electrolysis solution that the prepares aluminium diecast alloy cylinder body 1 after an end of cylinder body 1 is input to honing, alkaline electrolysis solution flows out from the solution thrust-augmenting nozzle 3 of the other end of cylinder body 1, and alkaline electrolysis solution circulates in cylinder body 1 by solution circulated cooling system 6;
3) built-in stainless steel tube 4 is connect the negative pole of power supply 5, outer wall of cylinder block connects the positive pole of power supply 5; Apply voltage by 5 pairs of cylinder bodies of power supply; Pressurization 600V-650V, time 30～60min will be at the Al of inner surface of cylinder block growth in situ one deck densification
2O
3Ceramic layer.Power supply 5 adopts direct current pulse power source.
The present invention has the following advantages:
(1) change pending the surface treatment mode of putting into solution, because solution only touches inner surface of cylinder block, and outside surface is not oxidized, has reduced the processing area of unit workpiece, has saved the energy.
(2) owing to oxidizing reaction is only carried out at the internal surface of cylinder body, therefore generate alumina-ceramic layer in cylinder interior with heat insulating ability and wear resistance, and the heat dispersion of outside surface is unaffected, therefore when improving thermo-efficiency, has reduced the thermal distortion of aluminium alloy cylinder.
The present invention is only to aluminium alloy cylinder internal surface potteryization, and keeping intact in the outside, has both improved the utilization ratio of cylinder interior combustion chamber heat, and the thermal diffusivity to aluminium alloy cylinder itself does not influence again.Under the DC pulse electric field action, make the aluminum alloy surface in-situ oxidation become to satisfy the alumina-ceramic layer of different performance requirement.
Embodiments of the invention one: alkaline electrolysis solution is that hexametaphosphate is an electrolytic solution, with the cumulative volume ratio, gets Sodium hexametaphosphate 99 15g/L by weight, water glass 8g/L, Sodium orthomolybdate 13g/L, yellow soda ash 7g/L, sodium wolframate 3g/L preparation alkaline electrolysis solution.The alkaline electrolysis pH value of solution value scope for preparing is transferred between 8-12, and alkaline electrolysis solution enters cylinder body 1 by built-in stainless steel tube 4, and alkaline electrolysis solution flows out from the solution thrust-augmenting nozzle 3 of the other end of cylinder body 1.Alkaline electrolysis solution circulates in cylinder body 1 by solution circulated cooling system 6; Built-in stainless steel tube 4 is connect the negative pole of power supply 5, outer wall of cylinder block connects the positive pole of power supply 5 again; Apply voltage by 5 pairs of cylinder bodies of power supply, pressurization 600V-650V, time 45min will be at the Al of inner surface of cylinder block growth in situ one deck densification
2O
3Ceramic layer.
Embodiments of the invention two: alkaline electrolysis solution is that hexametaphosphate is an electrolytic solution, with the cumulative volume ratio, gets Sodium hexametaphosphate 99 12g/L by weight, water glass 6g/L, Sodium orthomolybdate 12g/L preparation, yellow soda ash 6g/L, sodium wolframate 3g/L preparation alkaline electrolysis solution.The alkaline electrolysis pH value of solution value scope for preparing is transferred between 8-12, enter cylinder body 1 by built-in stainless steel tube 4, alkaline electrolysis solution flows out from the solution thrust-augmenting nozzle 3 of the other end of cylinder body 1.Alkaline electrolysis solution circulates in cylinder body 1 by solution circulated cooling system 6; Built-in stainless steel tube 4 is connect the negative pole of power supply 5, and outer wall of cylinder block connects the positive pole of power supply 5; Apply voltage by 5 pairs of cylinder bodies of power supply, pressurization 600V-650V, time 55min will be at the Al of inner surface of cylinder block growth in situ one deck densification
2O
3Ceramic layer.
Embodiments of the invention three: alkaline electrolysis solution is that hexametaphosphate is an electrolytic solution, with the cumulative volume ratio, gets Sodium hexametaphosphate 99 19g/L by weight, water glass 9g/L, Sodium orthomolybdate 14g/L preparation, yellow soda ash 8g/L, sodium wolframate 5g/L preparation alkaline electrolysis solution.The pH value scope of the alkaline electrolysis solution for preparing is transferred between 8-12, enter cylinder body 1 by built-in stainless steel tube 4, alkaline electrolysis solution flows out from the solution thrust-augmenting nozzle 3 of the other end of cylinder body 1, and alkaline electrolysis solution circulates in cylinder body 1 by solution circulated cooling system 6; Built-in stainless steel tube 4 is connect the negative pole of power supply 5, and outer wall of cylinder block connects the positive pole of power supply 5; Apply voltage by 5 pairs of cylinder bodies of power supply, pressurization 600V-650V, time 50min will be at the Al of inner surface of cylinder block growth in situ one deck densification
2O
3Ceramic layer.
Claims (6)
1, aluminium alloy cylinder internal surface microarc oxidation treatment process, it is characterized in that: with pending aluminium alloy cylinder (1) as anode, built-in stainless steel tube (4) as negative electrode, enter cylinder body (1) with alkaline electrolysis solution by built-in stainless steel tube (4), alkaline electrolysis solution flows out from the solution thrust-augmenting nozzle (3) of cylinder body (1) the other end.
2, aluminium alloy cylinder internal surface microarc oxidation treatment process according to claim 1, it is characterized in that, said alkaline electrolysis solution compares with cumulative volume by weight: by Sodium hexametaphosphate 99 10g/L-20g/L, water glass 5g/L-10g/L, Sodium orthomolybdate 10g/L-15g/L, yellow soda ash 5g/L-8g/L, sodium wolframate 2g/L-5g/L forms.
3, aluminium alloy cylinder internal surface microarc oxidation treatment process according to claim 1 and 2 is characterized in that: said alkaline electrolysis pH value of solution value scope is 8～12.
4, aluminium alloy cylinder internal surface microarc oxidation treatment process according to claim 1, it is characterized in that: with the aluminium diecast alloy cylinder body (1) of alkaline electrolysis solution after an end of cylinder body (1) is input to honing, alkaline electrolysis solution flows out from the solution thrust-augmenting nozzle (3) of the other end of cylinder body (1), and alkaline electrolysis solution circulates in cylinder body (1) by solution circulated cooling system (6).
5, aluminium alloy cylinder internal surface microarc oxidation treatment process according to claim 1, it is characterized in that: the negative pole that built-in stainless steel tube (4) is connect power supply (5), cylinder body (1) outer wall connects the positive pole of power supply (5), by power supply (5) cylinder body (1) is applied voltage, magnitude of voltage is at 600V-650V, and the time is 30-60min.
6, aluminium alloy cylinder internal surface microarc oxidation treatment process according to claim 1 or 5 is characterized in that: described power supply (5) adopts direct current pulse power source.
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| CNB2003101189099A CN1243133C (en) | 2003-12-23 | 2003-12-23 | Micro arc oxidation treating process for aluminium alloy cylinder inner surface |
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| CN1554806A true CN1554806A (en) | 2004-12-15 |
| CN1243133C CN1243133C (en) | 2006-02-22 |
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| CN100334244C (en) * | 2005-07-22 | 2007-08-29 | 敬康林 | Manufacturing method of metal ceramic power machinery product |
| CN100465355C (en) * | 2005-05-20 | 2009-03-04 | 中国科学院物理研究所 | Pipe surface ceramizing treatment process |
| CN101210336B (en) * | 2006-12-31 | 2011-05-18 | 比亚迪股份有限公司 | Surface treatment method for light metal material |
| CN101298200B (en) * | 2007-04-30 | 2012-03-28 | 比亚迪股份有限公司 | Magnesium alloy composite material and preparation thereof |
| CN102691086A (en) * | 2012-06-18 | 2012-09-26 | 哈尔滨工业大学 | Cylinder hole ceramic-forming treatment method for aluminum alloy engine cylinder body |
| CN102966241A (en) * | 2012-11-26 | 2013-03-13 | 中联重科股份有限公司 | Hopper, manufacturing method thereof and pumping system |
| CN103088384A (en) * | 2011-11-04 | 2013-05-08 | 和淞科技股份有限公司 | valve metal plasma electrolytic oxidation surface treatment method |
| CN103775333A (en) * | 2014-01-24 | 2014-05-07 | 哈尔滨工业大学 | Three-screw pump machine barrel and ceramic treatment method of inner surface of three-screw pump machine barrel |
| CN104948332A (en) * | 2015-06-16 | 2015-09-30 | 中国科学院力学研究所 | Cylinder barrel of total-aluminum engine cylinder body and preparation method for ceramic protective layer |
| CN105369317A (en) * | 2015-12-10 | 2016-03-02 | 苏州市嘉明机械制造有限公司 | Preparation technology of insulating thrust runner collar with long service life |
| CN105483792A (en) * | 2015-12-10 | 2016-04-13 | 苏州市嘉明机械制造有限公司 | Manufacturing technology of hot-pressing-resisting insulation mirror plate |
| CN107236979A (en) * | 2016-03-29 | 2017-10-10 | 长城汽车股份有限公司 | Multicylinder engine cylinder holes ceramic fixture and device and ceramming processes |
| CN107338464A (en) * | 2017-06-20 | 2017-11-10 | 中国科学院力学研究所 | A kind of all-aluminium engine inboard wall of cylinder block ceramic fixture |
| CN107587181A (en) * | 2017-09-26 | 2018-01-16 | 西南石油大学 | A kind of titanium alloy pipe inwall micro-arc oxidation device and its differential arc oxidation treatment method |
| CN108368633A (en) * | 2015-09-03 | 2018-08-03 | 美特倍股份有限公司 | Form the improved method of the pipeline coatings of cylinder cover and thus obtained cylinder cover |
| CN109402699A (en) * | 2018-11-01 | 2019-03-01 | 中国科学院兰州化学物理研究所 | A kind of aluminum alloy surface acid resistance corrosion function ceramic membrane preparation process |
| CN110965100A (en) * | 2019-11-29 | 2020-04-07 | 中国航发沈阳黎明航空发动机有限责任公司 | Micro-arc oxidation and hard anodization process method for forged aluminum alloy cylinder |
| CN111893536A (en) * | 2019-12-23 | 2020-11-06 | 中国航发长春控制科技有限公司 | Tool clamp for micro-arc oxidation of inner cavity of double-cylinder actuator cylinder |
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- 2003-12-23 CN CNB2003101189099A patent/CN1243133C/en not_active Expired - Fee Related
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN100465355C (en) * | 2005-05-20 | 2009-03-04 | 中国科学院物理研究所 | Pipe surface ceramizing treatment process |
| CN100334244C (en) * | 2005-07-22 | 2007-08-29 | 敬康林 | Manufacturing method of metal ceramic power machinery product |
| CN101210336B (en) * | 2006-12-31 | 2011-05-18 | 比亚迪股份有限公司 | Surface treatment method for light metal material |
| CN101298200B (en) * | 2007-04-30 | 2012-03-28 | 比亚迪股份有限公司 | Magnesium alloy composite material and preparation thereof |
| CN103088384A (en) * | 2011-11-04 | 2013-05-08 | 和淞科技股份有限公司 | valve metal plasma electrolytic oxidation surface treatment method |
| CN102691086A (en) * | 2012-06-18 | 2012-09-26 | 哈尔滨工业大学 | Cylinder hole ceramic-forming treatment method for aluminum alloy engine cylinder body |
| CN102966241A (en) * | 2012-11-26 | 2013-03-13 | 中联重科股份有限公司 | Hopper, manufacturing method thereof and pumping system |
| CN103775333B (en) * | 2014-01-24 | 2017-02-08 | 哈尔滨工业大学 | Three-screw pump machine barrel and ceramic treatment method of inner surface of three-screw pump machine barrel |
| CN103775333A (en) * | 2014-01-24 | 2014-05-07 | 哈尔滨工业大学 | Three-screw pump machine barrel and ceramic treatment method of inner surface of three-screw pump machine barrel |
| CN104948332A (en) * | 2015-06-16 | 2015-09-30 | 中国科学院力学研究所 | Cylinder barrel of total-aluminum engine cylinder body and preparation method for ceramic protective layer |
| CN108368633A (en) * | 2015-09-03 | 2018-08-03 | 美特倍股份有限公司 | Form the improved method of the pipeline coatings of cylinder cover and thus obtained cylinder cover |
| CN105483792A (en) * | 2015-12-10 | 2016-04-13 | 苏州市嘉明机械制造有限公司 | Manufacturing technology of hot-pressing-resisting insulation mirror plate |
| CN105369317A (en) * | 2015-12-10 | 2016-03-02 | 苏州市嘉明机械制造有限公司 | Preparation technology of insulating thrust runner collar with long service life |
| CN107236979A (en) * | 2016-03-29 | 2017-10-10 | 长城汽车股份有限公司 | Multicylinder engine cylinder holes ceramic fixture and device and ceramming processes |
| CN107338464A (en) * | 2017-06-20 | 2017-11-10 | 中国科学院力学研究所 | A kind of all-aluminium engine inboard wall of cylinder block ceramic fixture |
| CN107338464B (en) * | 2017-06-20 | 2019-04-02 | 中国科学院力学研究所 | A kind of all-aluminium engine inboard wall of cylinder block ceramic fixture |
| CN107587181A (en) * | 2017-09-26 | 2018-01-16 | 西南石油大学 | A kind of titanium alloy pipe inwall micro-arc oxidation device and its differential arc oxidation treatment method |
| CN109402699A (en) * | 2018-11-01 | 2019-03-01 | 中国科学院兰州化学物理研究所 | A kind of aluminum alloy surface acid resistance corrosion function ceramic membrane preparation process |
| CN110965100A (en) * | 2019-11-29 | 2020-04-07 | 中国航发沈阳黎明航空发动机有限责任公司 | Micro-arc oxidation and hard anodization process method for forged aluminum alloy cylinder |
| CN111893536A (en) * | 2019-12-23 | 2020-11-06 | 中国航发长春控制科技有限公司 | Tool clamp for micro-arc oxidation of inner cavity of double-cylinder actuator cylinder |
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| CN1243133C (en) | 2006-02-22 |
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Assignee: Xi'an forever Technology Development Co., Ltd. Assignor: Changan Univ. Contract fulfillment period: 2003.12.23 to 2013.12.23 contract change Contract record no.: 2009610000057 Denomination of invention: Micro arc oxidation treating process for aluminium alloy cylinder inner surface Granted publication date: 20060222 License type: Exclusive license Record date: 20091125 |
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Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2003.12.23 TO 2013.12.23; CHANGE OF CONTRACT Name of requester: XI AN HENGJIU ST DEVELOPMENT CO., LTD. Effective date: 20091125 |