CN1554493A - Recovering and treating method for glass fibre reinforced plastic waste - Google Patents
Recovering and treating method for glass fibre reinforced plastic waste Download PDFInfo
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- CN1554493A CN1554493A CNA2003101228106A CN200310122810A CN1554493A CN 1554493 A CN1554493 A CN 1554493A CN A2003101228106 A CNA2003101228106 A CN A2003101228106A CN 200310122810 A CN200310122810 A CN 200310122810A CN 1554493 A CN1554493 A CN 1554493A
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Abstract
The recovering and treating method of waste glass fiber reinforced plastic is to treating waste glass fiber reinforced plastic into grains and to utilize the grains as the stuffing for sheet molding compound (SMC). The said method solves the problem of compatibility and adhesion of the waste with resin, reinforcing material and other components and makes SMC possess excellent mechanical performance.
Description
Background technology
The invention belongs to technical field of composite materials, be specifically related to a kind of recovery and treatment method of glass reinforced plastic waste.
Background technology
In decades, glass reinforced plastic has been widely used in all trades and professions with the characteristic of its high-strength light, many excellences such as corrosion-resistant.But along with glass reinforced plastic is used the increase of time and the continuous growth of output in China, the amount of scrap stock that produce in the production process and old glass fiber reinforced plastics product the like waste increases gradually, add the corrosion-resistant of glass reinforced plastic, be difficult for the nature weathering, at present its waste is handled as building waste or consumer waste filling and embedding mostly, and the pollution problem of environment is become increasingly conspicuous.For the recovery of glass reinforced plastic waste with utilize problem to put on agenda day by day.
Present domestic glass reinforced plastic waste is handled as building waste or consumer waste filling and embedding mostly, abroad the method that also has burning adopted or cracking to handle.Also there is the glass reinforced plastic of employing waste to pulverize material in the document and makes permanent water drain well lid (Wang Jinxi, Chinese patent application number 01115069), also there is the glass reinforced plastic of employing waste to pulverize material and makes glass filament reinforced plastics burning into sand pipe RPM (Gao Yongfei etc., glass reinforced plastic/matrix material, 2001,1:19).
Can reclaim and utilize by suitable method glass reinforced plastic waste, the glass reinforced plastic waste might reclaim and utilizes by following approach: (1) is with the burning that acts as a fuel of glass reinforced plastic waste; (2) Pintsch process extracts useful chemical ingredients; (3) mechanical disintegration, particle reclaims.Because present most of glass fiber reinforced plastics products require to have fire retardancy, and most glass fiber reinforced plastics product all contains a large amount of mineral fillers and strongthener, and the burning that acts as a fuel is unsatisfactory.Same content owing to resin in most of glass fiber reinforced plastics products is limited, adds the facility investment costliness, complex process, and the chemical that Pintsch process can extract is very limited, also is not best selection at least at present.
Summary of the invention
The objective of the invention is to propose a kind of technology simple, handle the recovery and treatment method of glass reinforced plastic waste easily, and realize innoxious, recycling.A kind of product of recycling glass waste is proposed simultaneously.
The glass reinforced plastic waste recovery and treatment method that the present invention proposes is that the glass reinforced plastic waste is ground into powder, then as the stopping composition of slice plastic (SMC); The diameter of glass reinforced plastic waste pulverized particles is not more than 2mm, and staple length is not more than 6mm, in the sheet molding compound, is 100 weight parts in unsaturated polyester resin, and the consumption of glass reinforced plastic waste is 60-120 part.
Usually generally to add the talcum powder of a great deal of or lime carbonate in the sheet molding compound (SMC) as stopping composition.And all contain a large amount of mineral fillers and strongthener in the glass fiber reinforced plastics product, and after pulverizing, its waste contains the inorganic components of a large amount of similar talcum powder or lime carbonate, and therefore, the present invention adopts mechanical means that the glass reinforced plastic waste is pulverized the stopping composition of back as SMC.Realized the recycling of waste.
With the sheet molding compound of glass reinforced plastic waste as stopping composition, (SMC) its moiety is as follows:
100 parts of unsaturated polyester resins (weight)
Vinylbenzene 0-30 part (weight)
Initiator 0.5-2 part (weight)
Stopping composition 60-120 part (weight)
Thickening material 1-3 part (weight)
Shrinking agent 5-20 part (weight)
Coupling agent 0-1 part (weight)
Remover 1-5 part (weight)
Strongthener 20-50 part (weight)
In the above-mentioned materials, described unsaturated polyester resin is to contain the cinnamic commercially produced product that can be used for making SMC.
Described initiator is azo-initiator or peroxide initiator, has suitable thermal initiation temperature and thermal initiation time.
Described stopping composition is the mixture that the pulverizing material of glass reinforced plastic waste or this type of are pulverized material and talcum powder, lime carbonate.The pulverizing material particle diameter of glass reinforced plastic waste is not more than 2mm, and staple length is not more than 6mm.
Described thickening material is the inorganic powder of similar magnesium oxide one class, and thickening material has certain surfactivity.
Described low shrinkage additive is thermoplasticity class plastics, has the suitable polymerization degree, and has appropriate solvability in vinylbenzene.
Described coupling agent is a silane coupling agent, can promote the adhesive property of resin and glass fibre.
Described remover is the stearic acid material, is used to help the demoulding of SMC goods.
Described strongthener is an alkali free glass fibre, and the length of glass fibre is 3-6cm.
Compared with prior art, the present invention adopts mechanical means that the glass reinforced plastic waste is ground into diameter and is not more than 2mm, staple length is not more than the particle of 6mm, control well and pulverize the particle size of expecting, with its part or all of talcum powder that replaces in the SMC moulding compound, solve the glass reinforced plastic waste simultaneously and pulverized material and resin, strongthener and other compatibility between components and adhesive property problem, obtained good mechanical property and economy.
Embodiment
Further specify the present invention by the following examples.Do not violating under the purport of the present invention, the present invention should be not limited to the content that following examples are specifically expressed.
The used starting material of embodiment are as follows:
(1) unsaturated polyester (UP) resin, Xinhua Resin Factory, Shanghai
(2) the alkali free glass fibre silk (170 * 15WJ-1), Yaohua Glass-making Plant, Shanghai
(3) talcum powder, the Huzhou City building material factory
(4) light magnesium oxide (chemical pure), Dunhuang Chenical Plant, Shanghai
(5) Zinc Stearate, oceangoing voyage chemical plant, Shanghai
(6) vinylbenzene, chemical reagents corporation of Chinese Medicine group
(7) dicumyl peroxide, coupling agent, polystyrene (PS) etc. are commercially available commercially produced product.
The preparation of SMC moulding compound
Press the weighing of prescription shown in the table 1 unsaturated polyester in beaker, add components such as low shrinkage additive, stopping composition, Zinc Stearate, dicumyl peroxide, coupling agent successively, after stirring, add light magnesium oxide, use the agitator high-speed stirring again, it is mixed, and the material that will prepare takes out from beaker then, places on the previously prepd mylar.The short glass fiber of drying, being about 5cm with shearing mixes with resin paste, makes resin thorough impregnation glass fibre, is pressed into sheet, and sealing is placed.
SMC prescription (weight ratio) among table 1 embodiment
| Component | Prescription 1 | Prescription 2 | Prescription 3 |
| Resin | ????100 | ????100 | ????100 |
| Vinylbenzene | ????15 | ????15 | ????15 |
| Initiator | ????1 | ????1 | ????1 |
| Glass fiber reinforced plastic wastes | ????120 | ????0 | ????60 |
| Talcum powder | ????0 | ????120 | ????60 |
| Thickening material | ????3 | ????3 | ????3 |
| Shrinking agent | ????20 | ????20 | ????20 |
| Coupling agent | ????1 | ????1 | ????1 |
| Remover | ????3 | ????3 | ????3 |
| Strongthener | ????30 | ????30 | ????30 |
The compression moulding of SMC sheet material and sample preparation
The placement of SMC moulding compound after 3-5 days, is got an amount of material and placed mould, and both sides cover with film.Precompressed at normal temperatures earlier, compression moulding under the pressure of 135 ℃ and 150MPa then, during put once gas every one minute, exit 2-3 time pressurize at last 10 minutes altogether.Mould is taken out from press, treat its cooling curing after, board product is taken out, make the shape and size of the required batten of Mechanics Performance Testing with omnipotent sampling machine.
The performance test of SMC sheet material:
(1) density: with reference to the determination of test method of GB1033-86 regulation.
(2) tensile strength: with reference to the determination of tensile test method of GB/T1040-92 regulation.
(3) shock strength: the impact test method with reference to the GB/T1043-93 regulation is measured.
(4) flexural strength and modulus in flexure: with reference to the bending property determination of test method of GB1042-79 regulation;
(5) shrinking percentage: actual shrinking percentage is the percentage ratio of the ratio of the difference of respective straight size of same temperature bed die and goods and mould straight-line dimension.Measure the straight-line dimension of room temperature bed die and goods in the experiment with vernier callipers respectively, can calculate the sample shrinking percentage.
(6) water-absorbent: respectively get a pat earlier and in baking oven, dry, put into 25 ℃ water-bath then to constant weight, the quality after the different time takes by weighing the sample suction respectively, until constant weight, sample suction at this moment reaches equilibrium state, can calculate the sample water-intake rate.
The performance of SMC sheet material is as shown in table 2 among the embodiment.
The performance of SMC sheet material among table 2 embodiment
| Performance index | Prescription 1 | Prescription 2 | Prescription 3 |
| Outward appearance | Even no obvious impurity | Even inclusion-free | Even no obvious impurity |
| Thickness (mm) | ??2.1 | ??2.0 | ????2.0 |
| Substance (Kg/m 2) | ??3.3 | ??3.3 | ????3.2 |
| Relative density | ??1.70 | ??1.80 | ????1.75 |
| Flexural strength (MPa) | ??161 | ??155 | ????158 |
| Modulus in flexure (MPa) | ??11.6 | ??11.1 | ????11.3 |
| Shock strength (KJ/m 2) | ??86.3 | ??82.1 | ????83.9 |
| Tensile strength (MPa) | ??72 | ??74 | ????75 |
| Shrinking percentage (%) | ??≤0.05 | ??≤0.05 | ????≤0.05 |
| Water-intake rate (%) | ??≤0.2 | ??≤0.2 | ????≤0.2 |
Claims (10)
1, a kind of glass reinforced plastic waste recovery and treatment method is characterized in that the glass reinforced plastic waste is ground into particle, as the stopping composition of sheet molding compound; Glass reinforced plastic waste particulate diameter is not more than 2mm, and staple length is not more than 6mm; Major ingredient unsaturated polyester resin in sheet molding compound is 100 weight parts, and the consumption of glass reinforced plastic waste is 60-120 part.
2, a kind ofly it is characterized in that the weight share meter with the sheet molding compound of glass reinforced plastic waste as stopping composition, its composition is as follows:
100 parts of unsaturated polyester resins
Vinylbenzene 0-30 part
Initiator 0.5-2 part
Stopping composition 60-120 part
Thickening material 1-3 part
Shrinking agent 5-20 part
Coupling agent 0-1 part
Remover 1-5 part
Strongthener 20-50 part
3, sheet molding compound according to claim 2 is characterized in that described resin is to contain the cinnamic commercially produced product that can be used for making SMC.
4, sheet molding compound according to claim 2 is characterized in that described initiator is azo-initiator or peroxide initiator.
5, sheet molding compound according to claim 2, it is characterized in that stopping composition is the mixture that the pulverizing material of glass reinforced plastic waste or this type of are pulverized material and talcum powder, lime carbonate, the pulverizing material particle diameter of glass reinforced plastic waste is not more than 2mm, and staple length is not more than 6mm.
6, sheet molding compound according to claim 1 is characterized in that described thickening material is the inorganic powder of magnesium oxide one class.
7. sheet molding compound according to claim 2 is characterized in that described low shrinkage additive is thermoplasticity class plastics.
8, sheet molding compound according to claim 2 is characterized in that described coupling agent is a silane coupling agent.
9, sheet molding compound according to claim 2 is characterized in that described remover is the stearic acid material.
10, sheet molding compound according to claim 2 is characterized in that described strongthener is no first alkali containing glass fibre, and staple length is 3-6cm.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2003101228106A CN1554493A (en) | 2003-12-25 | 2003-12-25 | Recovering and treating method for glass fibre reinforced plastic waste |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2003101228106A CN1554493A (en) | 2003-12-25 | 2003-12-25 | Recovering and treating method for glass fibre reinforced plastic waste |
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| CN1554493A true CN1554493A (en) | 2004-12-15 |
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| CNA2003101228106A Pending CN1554493A (en) | 2003-12-25 | 2003-12-25 | Recovering and treating method for glass fibre reinforced plastic waste |
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Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101113230B (en) * | 2007-08-08 | 2010-08-18 | 华南理工大学 | Method for preparing unsaturated polyester cross-linking waste mold plastic |
| CN101157794B (en) * | 2007-09-07 | 2011-05-18 | 常熟东南塑料有限公司 | Melamine resin modified unsaturated polyester mould plastic |
| CN102453302A (en) * | 2010-10-19 | 2012-05-16 | 冀州市华信玻璃钢有限责任公司 | Recycle method of glass fiber-reinforced plastic waste |
| CN102899116A (en) * | 2012-10-24 | 2013-01-30 | 杜振华 | Power-generating fuel |
| CN103122153A (en) * | 2013-03-27 | 2013-05-29 | 武城县新时代玻璃钢厂 | Resin based composite |
| CN103172934A (en) * | 2013-03-09 | 2013-06-26 | 扬州市邗江扬子汽车内饰件有限公司 | Crumb rubber toughened thermoplastic glass steel scrap reinforced FRTP material and its preparation method |
| CN104292748A (en) * | 2013-07-18 | 2015-01-21 | 张运泉 | Epoxy resin synthesized SMC like material |
| CN104591632A (en) * | 2015-01-15 | 2015-05-06 | 黑龙江工程学院 | Preparation method of waste glass fiber reinforced plastic powder toughened concrete composite |
| CN105175969A (en) * | 2015-08-10 | 2015-12-23 | 南通德瑞森复合材料有限公司 | Recycling method of old glass fiber reinforced plastics |
| CN105754312A (en) * | 2016-03-18 | 2016-07-13 | 广东溢达纺织有限公司 | Environment-friendly unsaturated polyester resin button and preparation method thereof |
| CN105984558A (en) * | 2015-02-02 | 2016-10-05 | 福建省泉州海丝船舶评估咨询有限公司 | Method for disassembling fiberglass reinforced plastic ship |
| CN106140775A (en) * | 2015-03-08 | 2016-11-23 | 福建省泉州海丝船舶评估咨询有限公司 | A kind of 3D moulding material manufacture method based on glass fibre reinforced plastic waste and system |
| CN106140774A (en) * | 2015-03-08 | 2016-11-23 | 福建省泉州海丝船舶评估咨询有限公司 | A kind of method and system of glass fibre reinforced plastic waste regeneration |
| CN109366796A (en) * | 2018-11-13 | 2019-02-22 | 蒋遂安 | A kind of scrap glass steel processing equipment for recycling |
| CN109605618A (en) * | 2018-11-13 | 2019-04-12 | 蒋遂安 | A kind of scrap glass steel recycling processing method |
| CN109895479A (en) * | 2017-12-11 | 2019-06-18 | 上海越科新材料股份有限公司 | A kind of method and system using discarded composite material production structural member |
| CN111057387A (en) * | 2019-12-04 | 2020-04-24 | 江苏华昇新材料科技有限公司 | Bulk molding compound prepared from recycled glass fiber reinforced plastic crushed materials |
| CN111112300A (en) * | 2020-01-08 | 2020-05-08 | 山东虎力机械有限公司 | Solid waste resource utilization method |
| CN112724647A (en) * | 2020-12-29 | 2021-04-30 | 刘伟 | Waste regenerated glass fiber reinforced plastic and preparation method thereof |
| CN114276694A (en) * | 2021-11-03 | 2022-04-05 | 天津市龙宝节能科技有限公司 | Filling master batch containing glass fiber reinforced plastics and application thereof |
| CN116694098A (en) * | 2023-08-01 | 2023-09-05 | 国能龙源环保有限公司 | Glass plastic tray and preparation method thereof |
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2003
- 2003-12-25 CN CNA2003101228106A patent/CN1554493A/en active Pending
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101113230B (en) * | 2007-08-08 | 2010-08-18 | 华南理工大学 | Method for preparing unsaturated polyester cross-linking waste mold plastic |
| CN101157794B (en) * | 2007-09-07 | 2011-05-18 | 常熟东南塑料有限公司 | Melamine resin modified unsaturated polyester mould plastic |
| CN102453302A (en) * | 2010-10-19 | 2012-05-16 | 冀州市华信玻璃钢有限责任公司 | Recycle method of glass fiber-reinforced plastic waste |
| CN102899116A (en) * | 2012-10-24 | 2013-01-30 | 杜振华 | Power-generating fuel |
| CN103172934B (en) * | 2013-03-09 | 2015-06-03 | 扬州市邗江扬子汽车内饰件有限公司 | Crumb rubber toughened thermoplastic glass steel scrap reinforced FRTP material and its preparation method |
| CN103172934A (en) * | 2013-03-09 | 2013-06-26 | 扬州市邗江扬子汽车内饰件有限公司 | Crumb rubber toughened thermoplastic glass steel scrap reinforced FRTP material and its preparation method |
| CN103122153A (en) * | 2013-03-27 | 2013-05-29 | 武城县新时代玻璃钢厂 | Resin based composite |
| CN104292748A (en) * | 2013-07-18 | 2015-01-21 | 张运泉 | Epoxy resin synthesized SMC like material |
| CN104591632A (en) * | 2015-01-15 | 2015-05-06 | 黑龙江工程学院 | Preparation method of waste glass fiber reinforced plastic powder toughened concrete composite |
| CN105984558A (en) * | 2015-02-02 | 2016-10-05 | 福建省泉州海丝船舶评估咨询有限公司 | Method for disassembling fiberglass reinforced plastic ship |
| CN106140774A (en) * | 2015-03-08 | 2016-11-23 | 福建省泉州海丝船舶评估咨询有限公司 | A kind of method and system of glass fibre reinforced plastic waste regeneration |
| CN106140775A (en) * | 2015-03-08 | 2016-11-23 | 福建省泉州海丝船舶评估咨询有限公司 | A kind of 3D moulding material manufacture method based on glass fibre reinforced plastic waste and system |
| CN105175969A (en) * | 2015-08-10 | 2015-12-23 | 南通德瑞森复合材料有限公司 | Recycling method of old glass fiber reinforced plastics |
| CN105754312A (en) * | 2016-03-18 | 2016-07-13 | 广东溢达纺织有限公司 | Environment-friendly unsaturated polyester resin button and preparation method thereof |
| CN109895479A (en) * | 2017-12-11 | 2019-06-18 | 上海越科新材料股份有限公司 | A kind of method and system using discarded composite material production structural member |
| CN109366796A (en) * | 2018-11-13 | 2019-02-22 | 蒋遂安 | A kind of scrap glass steel processing equipment for recycling |
| CN109605618A (en) * | 2018-11-13 | 2019-04-12 | 蒋遂安 | A kind of scrap glass steel recycling processing method |
| CN111057387A (en) * | 2019-12-04 | 2020-04-24 | 江苏华昇新材料科技有限公司 | Bulk molding compound prepared from recycled glass fiber reinforced plastic crushed materials |
| CN111112300A (en) * | 2020-01-08 | 2020-05-08 | 山东虎力机械有限公司 | Solid waste resource utilization method |
| CN112724647A (en) * | 2020-12-29 | 2021-04-30 | 刘伟 | Waste regenerated glass fiber reinforced plastic and preparation method thereof |
| CN114276694A (en) * | 2021-11-03 | 2022-04-05 | 天津市龙宝节能科技有限公司 | Filling master batch containing glass fiber reinforced plastics and application thereof |
| CN116694098A (en) * | 2023-08-01 | 2023-09-05 | 国能龙源环保有限公司 | Glass plastic tray and preparation method thereof |
| CN116694098B (en) * | 2023-08-01 | 2023-10-27 | 国能龙源环保有限公司 | Glass plastic tray and preparation method thereof |
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