CN1552824A - Liquid fuel and producing method thereof - Google Patents

Liquid fuel and producing method thereof Download PDF

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Publication number
CN1552824A
CN1552824A CNA031281044A CN03128104A CN1552824A CN 1552824 A CN1552824 A CN 1552824A CN A031281044 A CNA031281044 A CN A031281044A CN 03128104 A CN03128104 A CN 03128104A CN 1552824 A CN1552824 A CN 1552824A
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China
Prior art keywords
liquid fuel
potassium permanganate
modification
ferrocene
acetone
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Pending
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CNA031281044A
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Chinese (zh)
Inventor
宋志荣
蔡植如
廖志华
张宗利
叶鹤皋
张凤文
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Individual
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Priority to CNA031281044A priority Critical patent/CN1552824A/en
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  • Liquid Carbonaceous Fuels (AREA)
  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)

Abstract

A clean and cheap liquid fuel and its production are disclosed. The fuel consists of (by weight) light hydrocarbon (C5/C6) 50-65, methanol 0-15, alcohol 10-25, modified C12 20-25,, mineral chameleon 0-0.006, hydrogen peroxide 0-0.008, ferrocene 0.002-0.006, acetone 0.3-0.7, n-butyl alcohol 0.04-0.08, acetic acid matte 0-0.007, and isoamyl acetate 0-0.08. The fuel is prepared from byproducts of refineries, such as C5, C6 and C12 hydrocarbons, with high thermal value above 8000 kilocalorie/Kg and stable flame. Its advantages include simple production and use, no odd smell, easy and complete combustion, explosion-resistance, cheap, safety and stability, no environmental pollution and harmless to human beings.

Description

A kind of liquid fuel and production method thereof
Technical field
The present invention relates to a kind of liquid fuel.
Background technology
At present, many hotels of catering trade, restaurant and large stall adopt the oil liquefied gas cooking to cook, and boil water with electric water boiler.The deficiency that exists is: consumption is big, price is high.For reducing cost, many managers use diesel oil instead and do fuel, but the dry sound of diesel range is big, oil smoke is many, environmental pollution is serious, and consequently the big and medium-sized cities that have have banned use of diesel oil to do fuel, therefore, the development and use novel energy, then imperative.
Summary of the invention
The object of the present invention is to provide that a kind of raw material is easy to get, of fine quality, cheap, energy-saving and environmental protection, safe in utilization, liquid fuel easily.
The present invention also aims to provide a kind of production method of above-mentioned liquid fuel.
Technical program of the present invention lies in this liquid fuel and comprise following component composition: (weight part)
Lighter hydrocarbons (C 5/ C 6) 50~65 methyl alcohol, 0~15 ethanol, 10~25 modification C 1220~25
Potassium permanganate 0~0.006 hydrogen peroxidase 10~0.008 ferrocene 0.002~0.006
Acetone 0.3~0.7 propyl carbinol 0.04~0.08 glacial acetic acid 0~0.007 Isoamyl Acetate FCC 0~0.08
The component of liquid fuel of the present invention consists of: (weight part)
Lighter hydrocarbons (C 5/ C 6) 55~64 methyl alcohol, 5~10 ethanol, 10~20 modification C 1220~22
Potassium permanganate 0.003~0.004 hydrogen peroxidase 10 .004~0.006 ferrocene 0.003~0.005
Acetone 0.5~0.7 propyl carbinol 0.05~0.07 glacial acetic acid 0.02~0.06
Isoamyl Acetate FCC 0.004~0.008
The said modification C of the present invention 12Be C 12Form with perfect combustion catalyzer is composite, wherein: C 12Be 99.8%, perfect combustion catalyzer is 0.2%.(C 12Claim fusel again)
When potassium permanganate uses, be dissolved in water, its proportioning is a potassium permanganate: water=1: 9.
Said lighter hydrocarbons contain normal paraffin 47.1%, isoparaffin 39.48%, naphthenic hydrocarbon 11.08%, alkene 0.18%, aromatic hydrocarbons 2.16%.
The production method of liquid fuel of the present invention is:
1. with lighter hydrocarbons the 1# material;
2. with C 12Be mixed in proportion composition modification C with perfect combustion catalyzer 12Be the 2# material;
3. after potassium permanganate being dissolved in water, add methyl alcohol, add hydrogen peroxide again and mix, be the 3# material;
4. 1# material and 2# material are added in the reactor mixing and stirring;
5. the 3# material is inserted in the aforesaid reaction vessel mixing and stirring;
6. ferrocene, acetone, propyl carbinol, glacial acetic acid, Isoamyl Acetate FCC, ethanol are added in the aforesaid reaction vessel successively mixing and stirring;
7. filtration, can.
The present invention is composite by raw material combination, can thorough mixing with immiscible raw material, both improved the calorific value of fuel of the present invention, increased the stability of fuel again, remove toxicity, again because the use of perfect combustion catalyzer and catalyzer ferrocene makes this fuel combustion more complete.
Seasonings, cover the adding of worn-out agent Isoamyl Acetate FCC, can remove and cover the peculiar smell in the worn-out fuel.Glacial acetic acid is a reodorant.
Used starting material wide material sources of the present invention, abundant, buying easily, the C of its main raw material 5, C 6, C 12Be the byproduct of refinery, the calorific value height.Methyl alcohol can adopt the product of paying in fertilizer plant, chemical plant, and raw material is extensive, with low cost and burning cleaning fully.
The present invention is a kind of cleaning and cheap liquid fuel, and manufacture method is simple, also has following advantage:
1, calorific value height, firepower manganese.Calorific value can reach 8000 kilocalories/more than the Kg, do not have tempering and flame-out phenomenon during burning, and flame size can arbitrarily be adjusted, flame stabilization;
2, safe and reliable, the nontoxic no specific peculiar smell of the present invention, inflammable non-explosive, be convenient to transportation and storage;
3, easy to use, used kitchen range and fuel oil kitchen range are basic identical, and with the burning torch igniting, the industrial improvement slightly gets final product, and refuel is convenient;
4, the invention belongs to environmentfriendly products, harmless, sufficient combustion does not have any impurity;
5, low price, the present invention is lower than oil liquefied gas and the diesel-fuel price of selling on the market.
(trade name of the present invention is " green No. one ", detects through Hubei Province Bureau of Technical Supervision and Hubei Province Environmental Protection Agency, and every technical indicator all reaches state-set standard.)
Description of drawings
Accompanying drawing is a process flow sheet of the present invention.
Embodiment
Embodiment 1
It forms proportioning following (weight part) liquid fuel of the present invention
Lighter hydrocarbons (C 5/ C 6) 58 methyl alcohol (90%) 9
Modification carbon 12 (C 12) 22 potassium permanganate (technical pure) 0.004
Hydrogen peroxide (technical pure) 0.005 ferrocene (technical pure) 0.004
Acetone (technical pure) 0.7 propyl carbinol (technical pure) 0.06
Glacial acetic acid (technical pure) 0.04 Isoamyl Acetate FCC (technical pure) 0.006
Ethanol (90%) (technical pure) 10.2
In said ratio, oxidant potassium permanganate (solid) needs to press following proportioning preparation (weight %): potassium permanganate 10%, hot water (90 ℃) 90% with hot water (90 ℃) dissolving before synthetic.
In said ratio, modification C 12Be C 12Perfect combustion catalyzer is composite forms with super despot, and (super despot's perfect combustion catalyzer is that Huangshi city Kang Fu chemical machinery institute produces), by following proportioning preparation (weight %):
Carbon 12 (C 12) 99.8%, super despot's perfect combustion catalyzer 0.2%.
Detect through the Ministry of Aerospace 42, calorific value is up to more than 8000 kilocalories.Detect through Hubei Province Bureau of Technical Supervision and Hubei Province Environmental Protection Agency, every technical indicator all reaches state-set standard.
Technological process: (seeing process flow sheet)
1, raw materials used must can the application through quality examination is qualified, various Chemicals chemical reagent must have regular producer and work certificate.
2, various raw materials are by forming the proportioning strict measurement.With lighter hydrocarbons is the 1# material; With C 12Be mixed in proportion composition modification C with perfect combustion catalyzer 12Be the 2# material, after potassium permanganate is dissolved in water, add methyl alcohol, add hydrogen peroxide again and mix, be the 3# material.
3, press the process flow sheet order, 1# and 2# material are inserted reactor mixing stirring 10 minutes.
4, placing reactor to mix in the 3# material stirred 10 minutes.
5, ferrocene, acetone, propyl carbinol, glacial acetic acid, Isoamyl Acetate FCC, ethanol being placed successively reactor mix stirred 30 minutes.(in stirring, adding successively)
6, filter through strainer.
7, extracting finished product from strainer send the laboratory to detect.
8, product detects qualified back canning and warehousing.
Store after 24 hours behind the products production and can use.
Embodiment 2
It forms proportioning following (weight part) liquid fuel of the present invention
Lighter hydrocarbons (C 5/ C 6) 63 modification carbon, 12 (C 12) 22
Ferrocene (technical pure) 0.003 acetone (technical pure) 0.6
Propyl carbinol (technical pure) 0.07 glacial acetic acid (technical pure) 0.03
Isoamyl Acetate FCC (technical pure) 0.005 ethanol (90%) (technical pure) 14.3
In said ratio, modification C 12Be C 12Perfect combustion catalyzer is composite forms with super despot, and (super despot's perfect combustion catalyzer is that Huangshi city Kang Fu chemical machinery institute produces), by following proportioning preparation (weight %):
Carbon 12 (C 12) 99.8%, super despot's perfect combustion catalyzer 0.2%.
Detect through the Ministry of Aerospace 42, calorific value is up to more than 10,000 kilocalories.Detect through Hubei Province Bureau of Technical Supervision and Hubei Province Environmental Protection Agency, every technical indicator all reaches state-set standard.
Technological process:
1, raw materials used must can the application through quality examination is qualified, various Chemicals chemical reagent must have regular producer and work certificate.
2, various raw materials are by forming the proportioning strict measurement.With lighter hydrocarbons is the 1# material; With C 12Be mixed in proportion composition modification C with perfect combustion catalyzer 12Be the 2# material,
3, press the process flow sheet order, 1# and 2# material are inserted reactor mixing stirring 10 minutes.
4, ferrocene, acetone, propyl carbinol, glacial acetic acid, Isoamyl Acetate FCC, ethanol being placed successively reactor mix stirred 30 minutes.(in stirring, adding successively)
5, filter through strainer.
6, extracting finished product from strainer send the laboratory to detect.
7, product detects qualified back canning and warehousing.
Store after 24 hours behind the products production and can use.
Embodiment 3
It forms proportioning following (weight part) liquid fuel of the present invention
Lighter hydrocarbons (C 5/ C 6) 64 methyl alcohol (90%) 5
Modification carbon 12 (C 12) 20 potassium permanganate (technical pure) 0.003
Hydrogen peroxide (technical pure) 0.004 ferrocene (technical pure) 0.003
Acetone (technical pure) 0.6 propyl carbinol (technical pure) 0.07
Ethanol (90%) (technical pure) 10.3
In said ratio, oxidant potassium permanganate (solid) needs to press following proportioning preparation (weight %): potassium permanganate 10%, hot water (90 ℃) 90% with hot water (90 ℃) dissolving before synthetic.
In said ratio, modification C 12Be C 12Perfect combustion catalyzer is composite forms with super despot, and (super despot's perfect combustion catalyzer is that Huangshi city Kang Fu chemical machinery institute produces), by following proportioning preparation (weight %):
Carbon 12 (C 12) 99.8%, super despot's perfect combustion catalyzer 0.2%.
Detect through the Ministry of Aerospace 42, calorific value is up to more than 10,000 kilocalories.Detect through Hubei Province Bureau of Technical Supervision and Hubei Province Environmental Protection Agency, every technical indicator all reaches state-set standard.
Technological process:
1, raw materials used must can the application through quality examination is qualified, various Chemicals chemical reagent must have regular producer and work certificate.
2, various raw materials are by forming the proportioning strict measurement.With lighter hydrocarbons is the 1# material; With C 12Be mixed in proportion composition modification C with perfect combustion catalyzer 12Be the 2# material, after potassium permanganate is dissolved in water, add methyl alcohol, add hydrogen peroxide again and mix, be the 3# material.
3, press the process flow sheet order, 1# and 2# material are inserted reactor mixing stirring 10 minutes.
4, placing reactor to mix in the 3# material stirred 10 minutes.
5, ferrocene, acetone, propyl carbinol, ethanol being placed successively reactor mix stirred 30 minutes.(in stirring, adding successively)
6, filter through strainer.
7, extracting finished product from strainer send the laboratory to detect.
8, product detects qualified back canning and warehousing.
Store after 24 hours behind the products production and can use.
Embodiment 4
It forms proportioning following (weight part) liquid fuel of the present invention
Lighter hydrocarbons (C 5/ C 6) 57 methyl alcohol (90%) 5
Modification carbon 12 (C 12) 22 potassium permanganate (technical pure) 0.004
Hydrogen peroxide (technical pure) 0.005 ferrocene (technical pure) 0.004
Acetone (technical pure) 0.7 propyl carbinol (technical pure) 0.06
Glacial acetic acid (technical pure) 0.04 Isoamyl Acetate FCC (technical pure) 0.006
Ethanol (90%) (technical pure) 15.2
In said ratio, oxidant potassium permanganate (solid) needs to press following proportioning preparation (weight %): potassium permanganate 10%, hot water (90 ℃) 90% with hot water (90 ℃) dissolving before synthetic.
In said ratio, carbon 12 (C 12) before synthetic, need add excess of imports despot perfect combustion catalyzer (Huangshi city Kang Fu chemical machinery institute product), prepare (weight %) by following proportioning:
Carbon 12 (C 12) 99.8%, super despot's perfect combustion catalyzer 0.2%.
Detect through the Ministry of Aerospace 42, calorific value is up to more than 8000 kilocalories.Detect through Hubei Province Bureau of Technical Supervision and Hubei Province Environmental Protection Agency, every technical indicator all reaches state-set standard.
Technological process:
1, raw materials used must can the application through quality examination is qualified, various Chemicals chemical reagent must have regular producer and work certificate.
2, various raw materials are by forming the proportioning strict measurement.With lighter hydrocarbons is the 1# material; With C 12Be mixed in proportion composition modification C with perfect combustion catalyzer 12Be the 2# material, after potassium permanganate is dissolved in water, add methyl alcohol, add hydrogen peroxide again and mix, be the 3# material.
3, press the process flow sheet order, 1# and 2# material are inserted reactor mixing stirring 10 minutes.
4, placing reactor to mix in the 3# material stirred 10 minutes.
5, ferrocene, acetone, propyl carbinol, glacial acetic acid, Isoamyl Acetate FCC, ethanol being placed successively reactor mix stirred 30 minutes.(in stirring, adding successively)
6, filter through strainer.
7, extracting finished product from strainer send the laboratory to detect.
8, product detects qualified back canning and warehousing.Store after 24 hours behind the products production and can use.

Claims (6)

1, a kind of liquid fuel is characterized in that: this fuel comprises following component composition: (weight part)
Lighter hydrocarbons (C 5/ C 6) 50~65, methyl alcohol 0~15, ethanol 10~25, modification C 1220~25,
Potassium permanganate 0~0.006, hydrogen peroxidase 10~0.008, ferrocene 0.002~0.006,
Acetone 0.3~0.7, propyl carbinol 0.04~0.08, glacial acetic acid 0~0.007, Isoamyl Acetate FCC 0~0.08.
2, liquid fuel according to claim 1 is characterized in that: the component of this fuel consists of: (weight part)
Lighter hydrocarbons (C 5/ C 6) 55~64, methyl alcohol 5~10, ethanol 10~20, modification C 1220~22,
Potassium permanganate 0.003~0.004, hydrogen peroxidase 10 .004~0.006, ferrocene 0.003~0.005,
Acetone 0.5~0.7, propyl carbinol 0.05~0.07, glacial acetic acid 0.02~0.06,
Isoamyl Acetate FCC 0.004~0.008.
3, liquid fuel according to claim 1 and 2 is characterized in that: said modification C 12Be C 12Form with perfect combustion catalyzer is composite, wherein: C 12Be 99.8%, perfect combustion catalyzer is 0.2%.
4, liquid fuel according to claim 1 and 2 is characterized in that: when potassium permanganate uses, be dissolved in water, its proportioning is a potassium permanganate: water=1: 9.
5, liquid fuel according to claim 1 and 2 is characterized in that: said lighter hydrocarbons contain normal paraffin 47.1%, isoparaffin 39.48%, naphthenic hydrocarbon 11.08%, alkene 0.18%, aromatic hydrocarbons 2.16%.
6, the production method of a kind of claim 1 or 2 described liquid fuels is characterized in that:
1. with lighter hydrocarbons the 1# material;
2. with C 12Be mixed in proportion composition modification C with perfect combustion catalyzer 12Be the 2# material;
3. after potassium permanganate being dissolved in water, add methyl alcohol, add hydrogen peroxide again and mix, be the 3# material;
4. 1# material and 2# material are added in the reactor mixing and stirring;
5. the 3# material is inserted in the aforesaid reaction vessel mixing and stirring;
6. ferrocene, acetone, propyl carbinol, glacial acetic acid, Isoamyl Acetate FCC, ethanol are added in the aforesaid reaction vessel successively mixing and stirring;
7. filtration, can.
CNA031281044A 2003-06-03 2003-06-03 Liquid fuel and producing method thereof Pending CN1552824A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102373100A (en) * 2010-08-13 2012-03-14 中国石油化工股份有限公司 Preparation method for biodiesel, and biodiesel prepared by the same
CN102559336A (en) * 2012-02-24 2012-07-11 洛阳万山高新技术应用工程有限公司 Automobile exhaust PM2.5 pollutant treatment agent
CN104194845A (en) * 2014-08-06 2014-12-10 贵州黔晟新能源实业有限公司 Method for preparing high-quality fuel oil blended with alcohol-containing fuel
CN105889907A (en) * 2016-05-13 2016-08-24 河南心连心化肥有限公司 Circulating fluidized bed boiler ignition device and ignition control method thereof
CN106147888A (en) * 2016-08-11 2016-11-23 王浩 A kind of biomass alcohol oil and preparation method thereof
CN108865290A (en) * 2017-05-08 2018-11-23 柳宏国 A kind of Novel clean-fuel
CN109536218A (en) * 2018-12-26 2019-03-29 福建贵福新能源科技有限公司 A kind of environment-friendly type alcohol-based fuel and preparation method thereof
CN110499194A (en) * 2019-08-13 2019-11-26 王则平 A kind of high cleanness methanol diesel that boat diesel engine uses
CN112940803A (en) * 2021-01-28 2021-06-11 浙江百盟能源科技有限公司 Industrial fuel and preparation method thereof
CN113621413A (en) * 2021-08-12 2021-11-09 安徽醇生新能源科技有限公司 High-efficiency alcohol-based gasoline fuel additive

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102373100B (en) * 2010-08-13 2014-12-03 中国石油化工股份有限公司 Preparation method for biodiesel, and biodiesel prepared by the same
CN102373100A (en) * 2010-08-13 2012-03-14 中国石油化工股份有限公司 Preparation method for biodiesel, and biodiesel prepared by the same
CN102559336A (en) * 2012-02-24 2012-07-11 洛阳万山高新技术应用工程有限公司 Automobile exhaust PM2.5 pollutant treatment agent
CN104194845A (en) * 2014-08-06 2014-12-10 贵州黔晟新能源实业有限公司 Method for preparing high-quality fuel oil blended with alcohol-containing fuel
CN104194845B (en) * 2014-08-06 2016-10-05 贵州黔晟新能源实业有限公司 A kind of blend the method that alcohol fuel prepares high-quality fuel oil
CN105889907B (en) * 2016-05-13 2018-06-29 河南心连心化肥有限公司 A kind of ignition device of circulating fluidized bed boiler and its ignition control method
CN105889907A (en) * 2016-05-13 2016-08-24 河南心连心化肥有限公司 Circulating fluidized bed boiler ignition device and ignition control method thereof
CN106147888A (en) * 2016-08-11 2016-11-23 王浩 A kind of biomass alcohol oil and preparation method thereof
CN108865290A (en) * 2017-05-08 2018-11-23 柳宏国 A kind of Novel clean-fuel
CN109536218A (en) * 2018-12-26 2019-03-29 福建贵福新能源科技有限公司 A kind of environment-friendly type alcohol-based fuel and preparation method thereof
CN110499194A (en) * 2019-08-13 2019-11-26 王则平 A kind of high cleanness methanol diesel that boat diesel engine uses
CN112940803A (en) * 2021-01-28 2021-06-11 浙江百盟能源科技有限公司 Industrial fuel and preparation method thereof
CN113621413A (en) * 2021-08-12 2021-11-09 安徽醇生新能源科技有限公司 High-efficiency alcohol-based gasoline fuel additive

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