Carbon/carbon composite material oxidation-proof coating
Affiliated technical field
The present invention relates to a kind of carbon/carbon composite material oxidation-proof coating.
Background technology
Since the C/C matrix material temperature be higher than 370 ℃ oxygen atmosphere is arranged the time just begin to take place oxidizing reaction, make the physicals and the rapid deterioration of mechanical property of material, when oxidation weight loss reaches 10%, will have a strong impact on the performance of material.Concerning airplane carbon brake disc, will influence braking efficiency, even cause brake to be lost efficacy, thereby, carbon/carbon brake disc is carried out effective antioxidation treatment, guarantee aircraft brake safety, be gordian technique in the airplane carbon brake disc manufacturing processed.
Among the Chinese patent authorization notification number CN1062961 a kind of aircraft C/C composite material brake disc inoxidzable coating that is used for has been described, it is made up of have the physical barriers layer (being formed by the rare earth borosilicate) from bridging function and chemical barrier layer and metallurgical diffusion layer of densification, and the rare earth borosilicate is not less than 85% in inoxidzable coating.Chinese patent application publication number CN1415669 discloses a kind of airplane carbon/carbon brake disc inoxidzable coating and coating processes thereof that be used for, adopt presoak (boric acid, phosphoric acid salt and distilled water) and coating (silicon carbide, boron and boride, silica flour etc.), warp is to operations such as the dip-coating of carbon dish, thermal treatments, make carbon dish each position except that surface of friction all adhere to presoak and coating, its thickness finally forms 0.05~0.1mm.Though these two patent applications all in various degree raising the resistance of oxidation and the humidity-proof ability of C/C composite material brake disc, its technology more complicated, resistance of oxidation is still waiting to improve when high temperature.
Summary of the invention
Technology of the present invention is dealt with problems and is: overcome the deficiencies in the prior art, provide a kind of technology simple, when high temperature the high carbon/carbon composite material oxidation-proof coating of resistance of oxidation.
Technical solution of the present invention is as follows: a kind of carbon/carbon composite material oxidation-proof coating, and its characteristics are: comprise following component (weight percent); Silicon 10%~15%, boron 10%~15%, phosphoric acid salt 60%~70%, aluminum oxide 5%~10%.
Above four kinds of materials are mixed and stir, after brush on the carbon/carbon composite surface,, brush and high-temperature heat treatment process is under atmospheric pressure implemented in 800 ℃~900 ℃ following thermal treatments 2~3 hours (nitrogen atmosphere).
The advantage that the present invention compared with prior art has is as follows:
(1) adopts resistance to oxidation component such as Si, make the outside surface of charcoal/raw material of wood-charcoal material form fine and close protective layer, can effectively stop the scattering and permeating of oxygen molecule.
(2) have and the close thermal expansivity of C/C matrix material body; B component in the coating generates boron trioxide B under oxidizing atmosphere
2O
3, B
2O
3It is dynamic at high temperature to form melt-flow, and the micropore of the coating itself that healed and at high temperature because the tiny crack that difference produced of coefficient of thermal expansion between coating and carbon matrix makes coating have the ability of self-healing anti-oxidation has stoped the erosion of oxygen molecule effectively.The carbon/carbon composite oxidation resistant coating has good oxidation-resistance among the present invention in 500 ℃~700 ℃ scopes.
(3) the present invention has good thermal shock resistance, through behind the high temperature impact, can keep good resistance of oxidation.
(4) technology is simple, is applicable to the oxidation resistant coating of airplane carbon brake disc.
Embodiment
Embodiment 1, with silicon 10%, and boron 15%, phosphoric acid salt 70%, aluminum oxide 5% (weight percent) mixes and stirs, after brush on the carbon/carbon composite surface, in 900 ℃ of following thermal treatments 2 hours (nitrogen atmosphere), brushing and high-temperature heat treatment process are under atmospheric pressure implemented again.
Embodiment 2, with silicon 15%, and boron 10%, phosphoric acid salt 65%, aluminum oxide 10% (weight percent) mixes and stirs, after brush on the carbon/carbon composite surface, in 800 ℃ of following thermal treatments 3 hours (nitrogen atmosphere), brushing and high-temperature heat treatment process are under atmospheric pressure implemented again.
Embodiment 3, with silicon 15%, and boron 15%, phosphoric acid salt 60%, aluminum oxide 10% (weight percent) mixes and stirs, after brush on the carbon/carbon composite surface, in 850 ℃ of following thermal treatments 2.5 hours (nitrogen atmosphere), brushing and high-temperature heat treatment process are under atmospheric pressure implemented again.
The raw material of wood-charcoal material of sample is selected Boeing-757 carbon/carbon brake disc material for use among the present invention, the sample of machine addition 10mm * 10mm * 10mm, and the surface brush coating layer makes after high-temperature heat treatment.At 500 ℃, after the 100h oxidation test, it only is 6.01% through rate of weight loss after the 20h oxidation test that rate of weight loss only is 1.25%, 700 ℃.900 ℃ only is 6.17% through rate of weight loss after the 5h oxidation test.
Sample is warming up to 500 ℃, is cooled to room temperature then rapidly, carry out 50 circulations; Be warming up to 700 ℃, carry out 5 circulations; Be warming up to 1100 ℃, carry out 3 circulations after, the oxidative mass loss of test sample, sample are through after the thermal shocking repeatedly, oxidation weight loss only is 2.65%.