CN1544252A - Waterproof high light ink jet printing medium - Google Patents
Waterproof high light ink jet printing medium Download PDFInfo
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- CN1544252A CN1544252A CNA2003101153256A CN200310115325A CN1544252A CN 1544252 A CN1544252 A CN 1544252A CN A2003101153256 A CNA2003101153256 A CN A2003101153256A CN 200310115325 A CN200310115325 A CN 200310115325A CN 1544252 A CN1544252 A CN 1544252A
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Abstract
The invention relates to an ink jet printing medium, especially relating to a waterproof strong-light ink jet printing medium, which includes supporter and ink-absorbing layer, and its characteristic: the ink-absorbing layer contains inorganic pigment and adhesive at particle size 8-15 nanometer and specific surface area 150-200 sq m/g, and it can both absorb dye ink and both pigment ink, and has high glossiness surface, and after printing, it dries rapidly, waterproof, and anti-blotting.
Description
Technical field
The present invention relates to a kind of ink-jet printing media, particularly a kind of waterproof glossy ink-jet printing media.
Technical background
In recent years, because the development in an all-round way of electronic technology, the digitized video storage capacity also progressively increases, and the colour print image also increases thereupon, and the technology of colour print image has also obtained developing rapidly.
Inkjet technology is because characteristics such as its colorize is easy, noise is low, pollution-free, low price, popularizes gradually in the color print image field in recent years and enlarges day by day.Along with the raising of ink-jet technology, the ink droplet of ink-jet printer is more and more littler, and resolution ratio is more and more higher, and the picture quality of printing moves closer to the level of silver salt photo, and for raising the efficiency, print speed is more and more faster.In order to satisfy above-mentioned feature, high-gloss surface is necessary, and print image is water-fast, fast light.For the China ink head that prevents to cause after the ink dried stops up, must use to be difficult for dry ink.In order to obtain the ink of above-mentioned feature, generally in ink, add polyalcohol, adhesive etc., this causes easily prints the dry slow result in back, and because polyalcohol is not volatile, and hygroscopicity is arranged, and causes after the print image drying moisture absorption again, and causing spreads and sinks in oozes.
Disclose a kind of high lustre ink-jetting recording material among the Chinese patent CN1283723, these recording materials are coating ink-receiver layer and cover layers on body paper, and it is 0.01～1.0 micron aluminium oxide and silica that ink-receiver layer contains particle diameter.Because contain hydrophilic gelatin in the cover layer, this recording materials water proofing property is relatively poor.
A kind of like this ink-jet recording sheet is disclosed among the Chinese patent CN1393346, this documentary film is coating ink-receiver layer and a glossiness adjustment layer on base material, ink-receiver layer contains metal salts of organic acids and cationic fixing agent, improve light resistance and ozone resistance, but glossiness and printing back rate of drying are not described.
A kind of ink jet recording materials is disclosed among the Chinese patent CN1388008, this material is the ink-receiver layer of two-layer or multilayer on anti-water carrier and the back coating that mainly contains organic polymer, wherein to contain predecessor be 3～30 nanometers to receiving layer, and to add the average grain greater particle size be that 1～5 micron and mean particle size are that 5～20 microns fine grained improves the transmission property, owing to add oarse-grained fine grained on the top layer, cause surface gloss to reduce easily and be full of cracks.
Chinese patent CN1348868 discloses a kind of recording medium and has used its formation method, this recording medium is coated with two-layer ink absorbing layer on the base material with barium sulfate layer, ink absorbing layer comprises aluminium base pigment, the specific area of the aluminium base pigment in upper strata is greater than lower floor, and this patent is to glossiness and print the not description of back rate of drying.
Summary of the invention
The purpose of this invention is to provide have high-gloss surface, print the back fast drying, have waterproof, the waterproof glossy ink-jet printing media of anti-the oozing property of spreading and sinking in.
Technical scheme of the present invention is: a kind of waterproof glossy ink-jet printing media, comprise support and ink absorbing layer, and it is characterized in that containing particle diameter in the wherein said ink absorbing layer is that 8～15 nanometers, specific area are 150～200m
2The inorganic pigment of/g and adhesive.
A kind of preferred version, wherein said inorganic pigment are silica, aluminium oxide, calcium carbonate, barium sulfate, magnesium sulfate, diatomite or titanium dioxide.
A kind of preferred version, wherein said inorganic pigment be shaped as parallelogram, ball-type, needle-like or unformed.
A kind of preferred version, wherein said inorganic pigment are its aluminium oxide that is shaped as parallelogram.
A kind of preferred version, wherein said adhesive are polyvinyl alcohol.
A kind of preferred version, wherein said adhesive are the mixture of polyvinyl alcohol and polyvinyl acetate, and the weight ratio of polyvinyl alcohol and polyvinyl acetate is 10: 1～14: 1.
A kind of preferred version, wherein said polyvinyl alcohol are with silicomethane alcohol modified polyethylene alcohol.
A kind of preferred version, the degree of polymerization of wherein said polyvinyl alcohol are 1700～4000.
A kind of preferred version, wherein said inorganic pigment and bonding agent ratio are 9: 1～16: 1 (weight ratio).
A kind of preferred version also contains curing agent or waterproofing agent in the wherein said ink absorbing layer.
A kind of preferred version, wherein said curing agent are ethanol, isopropyl alcohol, acetone, melamine, lactic acid titanium or melamine resin.
A kind of preferred version, wherein said waterproofing agent are boric acid, borate or melamine resin.
A kind of preferred version, wherein said support are plastic-coated paper-based.
Among the present invention, the fine particulate inorganic pigment in the ink absorbing layer can be selected silica, aluminium oxide, calcium carbonate, barium sulfate, magnesium sulfate, diatomite or titanium dioxide for use; The grain shape of inorganic pigment can be parallelogram, ball-type, needle-like or unformed, and preferred particulates is shaped as the aluminium oxide of parallelogram.
Fine particulate inorganic pigment in the print media of the present invention in the ink absorbing layer, its particle diameter are 8～15 nanometers, if less than 8 nanometers, can cause absorbency to descend; If greater than 15 nanometers, cause glossiness to descend; Specific area is 150～200m
2/ g is if specific area is less than 150m
2/ g, blotting quantity not sufficient then, specific area is greater than 200m
2/ g causes print image color density low, and color is not bright-coloured.
Among the present invention, the adhesive that uses in the ink absorbing layer can be selected from water-soluble or the water miscible adhesive of part, as polyvinyl alcohol, gelatin, polyvinylpyrrolidone, polyvinyl acetate, cellulose, modified polyvinylalcohol, polyacrylic acid or its mixture, the mixture of preferably polyethylene alcohol, polyvinyl alcohol and polyvinyl acetate, silicomethane alcohol modified polyethylene alcohol, wherein the degree of polymerization of polyvinyl alcohol is 1700～4000, and the weight ratio of polyvinyl alcohol and polyvinyl acetate can be 10: 1～14: 1.
Among the present invention, the fine grain inorganic pigment in the ink absorbing layer and the part by weight of adhesive are 9: 1～16: 1, if greater than 16: 1, binder dosage is very few, and cementitiousness descends, and causes the coating be full of cracks, print the back ink and spread, cause image quality decrease along crackle; If less than 9: 1, binder dosage increases, and forms dense coating, and it is slower to make medium print the back rate of drying, will cause the accumulation of ink, makes the picture quality variation.
Can also contain various auxiliary agents in the ink absorbing layer of the present invention, as dispersant, crosslinking agent, plasticizer, surfactant, bleeding agent, defoamer, brightening agent, anticorrisive agent, PH conditioning agent etc.Dispersant can be organic acid, inorganic acid, monoacid, binary acid, ternary acid, calgon, lauryl sodium sulfate or polypropylene acid etc., preferred acetic acid, calgon or lauryl sodium sulfate; In order to make the coating waterproof, a kind of preferred version is to add curing agent in ink accepting layer, the optional known ethanol of curing agent, isopropyl alcohol, acetone, melamine, lactic acid titanium, melamine resin etc., preferred lactic acid titanium; Another kind of preferred scheme is to add waterproofing agent, the optional boric acid of waterproofing agent, borate or melamine resin, preferred boric acid or melamine resin in ink accepting layer.In order to make picture have resistance to water, can add color-fixing agent in the coating, the optional known polyamine class color-fixing agent of color-fixing agent, dicyandiamide, fragrant same clan color-fixing agent, acrylic compounds color-fixing agent, preferred acrylic compounds, the JK-330 that becomes chemical company to produce as name.The optional cationic surfactant of surfactant, anion surfactant, non-ionic surface active agent, fluorine surfactant or silicon are surfactant etc.
Coating weight of the present invention with dry weight basis, can be 25～60 gram/rice
2, preferred 30～45 gram/rice
2If, less than 25 gram/rice
2, the blotting quantity not sufficient of coating then causes the problem of print image quality difference easily; If greater than 60 gram/rice
2, then can cause the coating be full of cracks, print quality is descended.
Coating method on base material of the present invention can use the coating method of any conventional, as coating methods such as dip-coating, roller coat, air knife, scraper, wave current extruding, still, and for flatness and the glossiness that guarantees coating, preferred wave current extrusion coated mode.
Support among the present invention is a plastic-coated paper-based.
Waterproof glossy ink-jet printing media of the present invention is to make like this:
At first prepare PVA solution, dispersed alumina then, a certain amount of deionized water of weighing is added to the water fine grain inorganic pigment and dispersant, stirs, and at first carries out pre-dispersedly, and then shears dispersion, makes pigment slurry; Then slurry is mixed with PVA solution, other adhesives, add color-fixing agent, surfactant, curing agent, waterproofing agent, make coating fluid; At last, coating fluid is coated on the plastic-coated paper-based, drying obtains the waterproof glossy ink-jet printing media.
The specific embodiment
The present invention is further illustrated below in conjunction with specific embodiment.
Embodiment 1
Prescription:
PVA (degree of polymerization 1700, complete hydrolysis) 2.6g
Aluminium oxide 23.40g
(particle diameter 8 nanometers, specific area 180m
2/ g, grain shape is a parallelogram)
Acetic acid 0.02g
JK-330 (trade names, name become chemical company to produce) 6.4g
Boric acid 0.05g
Silicon is surfactant L-7604 (trade names, Konica company produces) 0.03g
Deionized water 67.50g
Operation:
Claim the deionized water of 13.65g, join in the stainless steel cask, under agitation the PVA of 2.6g is sprinkled in the water then, continue to stir 1 hour, begin to be warming up to 93 ℃, kept 1 hour, be cooled to room temperature, obtain PVA solution; , join in the stainless steel cask balance of deionized water (53.85g) by prescription, add 0.02g acetic acid, stir, add the 23.40g aluminium oxide, continue to stir pre-dispersed 1 hour, use high speed shear disperser (IKA company's T 25) to disperse again 2 hours, make slurry; PVA solution and slurry are mixed, and adding 6.4g JK-330,0.05g boric acid, 0.03g silicon are surfactant L-7604, stir, and make coating fluid, static froth breaking; Coating fluid is applied on the plastic-coated paper-based with the wheat rod, and the coating dry measure is 40g/m
2Dry: 50 ℃, dry 20 minutes; 120 ℃, dry 2 minutes; Obtain product, survey its performance (seeing Table).
Embodiment 2
Prescription:
PVA?????????????????????????????????????????????2.3g
(degree of polymerization 2400, complete hydrolysis, the modification of silicomethane alcohol)
Silica 23.0g
(particle diameter 10 nanometers, specific area 150m
2/ g, grain shape is a ball-type)
Calgon 0.02g
JK-330 (trade names, name become chemical company to produce) 6.4g
Melamine resin 0.05g
L-7604 (silicon is surfactant) 0.03g
Lactic acid titanium 0.05g
Water 68.15g
Operation:
Claim the deionized water of 12.07g, join in the stainless steel cask, under agitation the PVA of 2.3g is sprinkled in the water then, continue to stir 1 hour, begin to be warming up to 95 ℃, kept 1 hour, be cooled to room temperature, obtain PVA solution; , join in the stainless steel cask balance of deionized water (56.08g) by prescription, add the 0.02g calgon, stir, add 23g silica, continue to stir pre-dispersed 1 hour, use high speed shear disperser (IKA company's T 25) to disperse again 2 hours, make slurry; PVA solution and slurry are mixed, and adding 6.4g JK-330,0.05g melamine resin, 0.05g lactic acid titanium, 0.03g silicon are surfactant L-7604, stir, and make coating fluid, static froth breaking; Coating fluid is applied on the plastic-coated paper-based with the wheat rod, and the coating dry measure is 40g/m
2Dry: 50 ℃, dry 20 minutes; 120 ℃, dry 2 minutes; Obtain product, survey its performance (seeing Table).
Embodiment 3
Prescription:
PVA (degree of polymerization 4000, complete hydrolysis) 2.4g
Aluminium oxide 36.0g
(particle diameter 15 nanometers, specific area 200m
2/ g, grain shape is a parallelogram)
Acetic acid 0.03g
JK-330 (trade names, name become chemical company to produce) 6.4g
Boric acid 0.05g
Silicon is surfactant L-7604 0.03g
Lactic acid titanium 0.05g
Water 54.04g
Operation:
Claim the deionized water of 12.6g, join in the stainless steel cask, under agitation the PVA of 2.4g is sprinkled in the water then, continue to stir 1 hour, begin to be warming up to 90 ℃, kept 1 hour, be cooled to room temperature, obtain PVA solution; , join in the stainless steel cask balance of deionized water (42.44g) by prescription, add 0.03g acetic acid, stir, add the 36g aluminium oxide, continue to stir pre-dispersed 1 hour, use high speed shear disperser (IKA company's T 25) to disperse again 2 hours, make slurry; PVA solution and slurry are mixed, and adding 6.4g JK-330,0.05g boric acid, 0.05g lactic acid titanium, 0.03g silicon are surfactant L-7604, stir, and make coating fluid, static froth breaking; Coating fluid is applied on the plastic-coated paper-based with the wheat rod, and the coating dry measure is 40g/m
2Dry: 50 ℃, dry 20 minutes; 120 ℃, dry 2 minutes; Obtain product, survey its performance (seeing Table).
Table one:
| Glossiness | Absorbency 1 | Absorbency 2 | Drying time | |
| Embodiment 1 | ?48 | ?A | ?A | ＜10 seconds |
| Embodiment 2 | ?47 | ?A | ?A | ＜10 seconds |
| Embodiment 3 | ?53 | ?A | ?A | ＜10 seconds |
Embodiment 4
Prescription:
PVA (degree of polymerization 1700, complete hydrolysis, the modification of silicomethane alcohol) 1.64g
Aluminium oxide 26.24g
(particle diameter 15 nanometers, specific area 190m
2/ g, grain shape is a parallelogram)
Acetic acid 0.46g
JK-330 (trade names, name become chemical company to produce) 1.96g
Melamine resin 0.05g
Silicon is surfactant L-7604 0.2g
Water 69.46g
Operation:
Claim the deionized water of 8.61g, join in the stainless steel cask, under agitation the PVA of 1.64g is sprinkled in the water then, continue to stir 1 hour, begin to be warming up to 95 ℃, kept 1 hour, be cooled to room temperature, obtain PVA solution; , join in the stainless steel cask balance of deionized water (60.85g) by prescription, add 0.46g acetic acid, stir, add the 26.24g aluminium oxide, continue to stir pre-dispersed 1 hour, use high speed shear disperser (IKA company's T 25) to disperse again 2 hours, make slurry; PVA solution and slurry are mixed, and adding 1.96g JK-330,0.05g melamine resin, 0.2g silicon are surfactant L-7604, stir, and make coating fluid, static froth breaking; Coating fluid is applied on the plastic-coated paper-based with the wheat rod, and the coating dry measure is 40g/m
2Dry: 50 ℃, dry 20 minutes; 120 ℃, dry 2 minutes; Obtain product, survey its performance (seeing Table two, three).
Embodiment 5
Prescription:
PVA (degree of polymerization 2400, complete hydrolysis) 1.96g
Titanium dioxide 24.5g
(particle diameter 15 nanometers, specific area 190m
2/ g, grain shape is a ball-type)
Lauryl sodium sulfate 0.03g
JK-330 (trade names, name become chemical company to produce) 2g
Boric acid 0.05g
JK-330 (trade names, name become chemical company to produce) 3g
Silicon is surfactant L-7604 0.3g
Deionized water 68.16g
Operation:
Claim the deionized water of 10.29g, join in the stainless steel cask, under agitation the PVA of 1.96g is sprinkled in the water then, continue to stir 1 hour, begin to be warming up to 90 ℃, kept 1 hour, be cooled to room temperature, obtain PVA solution; , join in the stainless steel cask balance of deionized water (57.87g) by prescription, add the 0.03g lauryl sodium sulfate, stir, add 24.5g titanium dioxide, continue to stir pre-dispersed 1 hour, use high speed shear disperser (IKA company's T 25) to disperse again 2 hours, make slurry; PVA solution and slurry are mixed, and adding 3g JK-330,0.05g boric acid, 0.3g silicon are surfactant L-7604, stir, and make coating fluid, static froth breaking; Coating fluid is applied on the plastic-coated paper-based with the wheat rod, and the coating dry measure is 40g/m
2Dry: 50 ℃, dry 20 minutes; 120 ℃, dry 2 minutes; Obtain product, survey its performance (seeing Table two, three).
Embodiment 6
Prescription:
PVA (degree of polymerization 3500, partial hydrolysis) 2.44g
Aluminium oxide 23.5g
(particle diameter 15 nanometers, specific area 200m
2/ g, grain shape is a parallelogram)
Acetic acid 0.28g
JK-330 (trade names, name become chemical company to produce) 3g
Boric acid 0.05g
Silicon is surfactant L-7604 0.3g
Lactic acid titanium 0.05g
Deionized water 70.38g
Operation:
Claim the deionized water of 12.81g, join in the stainless steel cask, under agitation the PVA of 2.44g is sprinkled in the water then, continue to stir 1 hour, begin to be warming up to 95 ℃, kept 1 hour, be cooled to room temperature, obtain PVA solution; , join in the stainless steel cask balance of deionized water (57.57g) by prescription, add 0.28g acetic acid, stir, add the 23.5g aluminium oxide, continue to stir pre-dispersed 1 hour, use high speed shear disperser (IKA company's T 25) to disperse again 2 hours, make slurry; PVA solution and slurry are mixed, and adding 3g JK-330,0.05g boric acid, 0.05g lactic acid titanium, 0.3g silicon are surfactant L-7604, stir, and make coating fluid, static froth breaking; Coating fluid is applied on the plastic-coated paper-based with the wheat rod, and the coating dry measure is 40g/m
2Dry: 50 ℃, dry 20 minutes; 120 ℃, dry 2 minutes; Obtain product, survey its performance (seeing Table two, three).
Embodiment 7
Prescription:
PVA (degree of polymerization 3500, partial hydrolysis) 2.5g
Polyvinyl acetate 0.2g
Aluminium oxide 25.0g
(particle diameter 15 nanometers, specific area 200m
2/ g, grain shape is a parallelogram)
Lauryl sodium sulfate 0.03g
JK-330 (trade names, name become chemical company to produce) 6.4g
Boric acid 0.05g
Silicon is surfactant L-7604 0.3g
Lactic acid titanium 0.05g
Deionized water 67.47g
Operation:
Claim the deionized water of 14.18g, join in the stainless steel cask, under agitation PVA and the 0.2g polyvinyl acetate of 2.5g is sprinkled in the water then, continue to stir 1 hour, begin to be warming up to 95 ℃, kept 1 hour, be cooled to room temperature, obtain PVA solution; , join in the stainless steel cask balance of deionized water (50.29g) by prescription, add the 0.03g lauryl sodium sulfate, stir, add the 25g aluminium oxide, continue to stir pre-dispersed 1 hour, use high speed shear disperser (IKA company's T 25) to disperse again 2 hours, make slurry; PVA solution and slurry are mixed, and adding 6.4g JK-330,0.05g boric acid, 0.05g lactic acid titanium, 0.3g silicon are surfactant L-7604, stir, and make coating fluid, static froth breaking; Coating fluid is applied on the plastic-coated paper-based with the wheat rod, and the coating dry measure is 40g/m
2Dry: 50 ℃, dry 20 minutes 120 ℃, dry 2 minutes; Obtain product, survey its performance (seeing Table two, three).
Embodiment 8
Prescription:
PVA (degree of polymerization 3500, partial hydrolysis) 2.6g
Polyvinyl acetate 0.2g
Diatomite 28.0g
(particle diameter 14 nanometers, specific area 190m
2/ g, grain shape is a parallelogram)
Acetic acid 0.03g
JK-330 (trade names, name become chemical company to produce) 6.4g
Melamine resin 0.05g
Silicon is surfactant L-7604 0.3g
Deionized water 62.42g
Operation:
Claim the deionized water of 19.95g, join in the stainless steel cask, under agitation PVA and the 0.2g polyvinyl acetate of 2.6g is sprinkled in the water then, continue to stir 1 hour, begin to be warming up to 95 ℃, kept 1 hour, be cooled to room temperature, obtain PVA solution; , join in the stainless steel cask balance of deionized water (42.47g) by prescription, add 0.03g acetic acid, stir, add 28g diatomite, continue to stir pre-dispersed 1 hour, use high speed shear disperser (IKA company's T 25) to disperse again 2 hours, make slurry; PVA solution and slurry are mixed, and adding 6.4g JK-330,0.05g boric acid, 0.3g silicon are surfactant L-7604, stir, and make coating fluid, static froth breaking; Coating fluid is applied on the plastic-coated paper-based with the wheat rod, and the coating dry measure is 40g/m
2Dry: 50 ℃, dry 20 minutes; 120 ℃, dry 2 minutes; Obtain product, survey its performance (seeing Table two, three).
Embodiment 9
Prescription:
PVA (degree of polymerization 3500, partial hydrolysis) 2.3g
Polyvinyl acetate 0.2g
Aluminium oxide 40.0g
(particle diameter 15 nanometers, specific area 150m
2/ g, grain shape is a parallelogram)
Acetic acid 0.03g
Lactic acid titanium 0.05g
Silicon is surfactant L-7604 0.3g
Deionized water 57.12g
Operation:
Claim the deionized water of 13.13g, join in the stainless steel cask, under agitation PVA and the 0.2g polyvinyl acetate of 2.3g is sprinkled in the water then, continue to stir 1 hour, begin to be warming up to 95 ℃, kept 1 hour, be cooled to room temperature, obtain PVA solution; , join in the stainless steel cask balance of deionized water (44.99g) by prescription, add 0.03g acetic acid, stir, add the 40g aluminium oxide, continue to stir pre-dispersed 1 hour, use high speed shear disperser (IKA company's T 25) to disperse again 2 hours, make slurry; PVA solution and slurry are mixed, and adding 0.05g lactic acid titanium, 0.3g silicon are surfactant L-7604, stir, and make coating fluid, static froth breaking; Coating fluid is applied on the plastic-coated paper-based with the wheat rod, and the coating dry measure is 40g/m
2Dry: 50 ℃, dry 20 minutes; 120 ℃, dry 2 minutes; Obtain product, survey its performance (seeing Table two, three).
Comparative example 1
Last layer formula:
Polyvinylpyrrolidone, 95g
Quaternary ammonium salt 5g
The bottom prescription:
Silica (0.2-0.3 micron, internal pore volume 0.7-1.0cm3/g) 84g
PVA (complete hydrolysis, viscosity 62-72cp, 4% aqueous solution) 12g
Methacrylic acid ammonia methyl esters 3g
Boric acid 1g
Operation:
Preparation bottom masking liquid is applied to the front of body paper with it, behind the heat drying, obtains bottom, and the coating dry measure is 35 gram/rice
2Preparation upper strata coating fluid is applied to it on bottom, and the coating dry measure is 1 gram/rice
2, behind the heat drying, obtain a record material, survey its performance (seeing Table two).
Table two:
| Absorbency | Water proofing property | Spread and sink in and ooze | Glossiness | |
| Embodiment 4 | ?A | ?A | ?A | ?52 |
| Embodiment 5 | ?A | ?A | ?A | ?52 |
| Embodiment 6 | ?A | ?A | ?A | ?50 |
| Embodiment 7 | ?A | ?A | ?A | ?50 |
| Embodiment 8 | ?A | ?A | ?A | ?50 |
| Embodiment 9 | ?A | ?A | ?A | ?50 |
| Comparative example | ?A | ?C | ?C | ?25 |
Light resistance:
| Black | Yellow | Product | Blue or green | |
| Embodiment 4 | ??2.8％ | ??1.5％ | ??3.1％ | ??5.6％ |
| Embodiment 5 | ??1.8％ | ??1.8％ | ??1.8％ | ??4.33％ |
| Embodiment 6 | ??2.3％ | ??1.9％ | ??2.9％ | ??4.8％ |
| Embodiment 7 | ??3.8％ | ??1.3％ | ??3.4％ | ??5.1％ |
| Embodiment 8 | ?2.1％ | 2.1％ | 1.9％ | 4.4％ |
| Embodiment 9 | ?2.3％ | 2.4％ | 3.2％ | 4.9％ |
Evaluation method:
Ink absorption 1:
Use the EPSON890 printer, these four kinds of colors are tested with yellow, magenta, cyan, black.Described printer Design is that the ink of water-soluble dye prints.
A: do not have and pile up
B: the slight accumulation
C: pile up
Ink absorption 2:
Use the EPSON2100 printer, these four kinds of colors are tested with yellow, magenta, cyan, black.Described printer Design is that the ink of water-soluble pigment prints.
A: do not have and pile up
B: the slight accumulation
C: pile up
Drying time:
Under the condition of environment temperature (23 ± 2) ℃, relative humidity (55 ± 10) %, on the test specimen page, print test chart drying time., by 1.5cm * 1.5cm color lump that 100% green grass or young crops (C), 100% product (M), 100% Huang (Y), 100% black (K) four looks China ink superposition form, use the above-mentioned color lump of EPSON890 printer prints,
After print media goes out machine, put the clean scraps of paper successively according to the time that each color lump is demarcated, on the paper piece, add ballast (weight is the piece of stainless steel of 2.5cm * 2.5cm * 8mm, and the weight of each bloom is identical) then.Treat that weight is pressed in color lump after last 3 minute, take off and observe its pollution condition.The free of contamination pairing shortest time of paper piece is the drying time of this medium.
Glossiness:
With model is that PG-160 ° hand-held glossometer is measured.Sample is positioned on the horizontal table top, again instrument is placed on the tested sample surface, press the corresponding button and measure.Because vertical, the horizontal glossiness of specimen page has certain difference, gets 4 different directions for a sample and measures, every survey is once rotated 45 with sample, and the glossiness value is 4 mean values of measuring.
Water proofing property:
100% green grass or young crops (C), 100% product (M), 100% Huang (Y), 100% are deceived (K) four looks 1.5cm * 1.5cm color lump, after EPSON890 prints above-mentioned color lump, wash 30 minutes with circulating water under tap, dab with have gentle hands and smear, and observe the surface and become dirty situation
A: surperficial constant dirt
B: the surface is slight to become dirty
C: the surface becomes dirty
Spreading and sinking in of image oozed:
100% green grass or young crops (C), 100% product (M), 100% Huang (Y), 100% color lump of deceiving 2.5 centimetres of 2.5 centimetres of * of (K) four looks, horizontal, vertical two groups of white lines are all distributing on each color lump, each is organized lines and is arranged by the fine rule of 7 different in width and form, the width of lines is followed successively by 1,2,4,6,8,10,12 from fine to coarse, and unit is a pixel.After EPSON890 prints above-mentioned color lump, print image is put into ageing oven (50 ℃ of temperature, humidity 80%) 72 hours, observe white lines.
A; 1,2 is clear
B:4,6 is clear
C:8,10,12 is clear
Light resistance:
Print 100% Huang, 100% product, 100% green grass or young crops, 100% black block density D 0 with EPSON890 with the densitometer side, uviol lamp (wavelength 2537A, power 26W) down irradiation survey density D 1 after 68 hours, (D0-D1)/D1 is with the data that draw.
Beneficial effect:
Data can be found out from table, the water proofing property of product of the present invention, spread and sink in ooze, the performance such as glossiness is significantly better than the properties of open product, obtained having high-gloss surface, print after the waterproof glossy ink-jet printing media of fast drying, waterproof, anti-the oozing property of spreading and sinking in.
Claims (13)
1. a waterproof glossy ink-jet printing media comprises support and ink absorbing layer, it is characterized in that, containing particle diameter in the wherein said ink absorbing layer is that 8～15 nanometers, specific area are 150～200m
2The inorganic pigment of/g and adhesive.
2. waterproof glossy ink-jet printing media according to claim 1 is characterized in that, wherein said inorganic pigment is silica, aluminium oxide, calcium carbonate, barium sulfate, magnesium sulfate, diatomite or titanium dioxide.
3. waterproof glossy ink-jet printing media according to claim 2 is characterized in that, wherein said inorganic pigment be shaped as parallelogram, ball-type, needle-like or unformed.
4. according to claim 2 or 3 described waterproof glossy ink-jet printing medias, it is characterized in that wherein said inorganic pigment is its aluminium oxide that is shaped as parallelogram.
5. waterproof glossy ink-jet printing media according to claim 1 is characterized in that, wherein said adhesive is a polyvinyl alcohol.
6. waterproof glossy ink-jet printing media according to claim 1 is characterized in that, wherein said adhesive is the mixture of polyvinyl alcohol and polyvinyl acetate, and the weight ratio of polyvinyl alcohol and polyvinyl acetate is 10: 1～14: 1.
7. according to claim 5 or 6 described waterproof glossy ink-jet printing medias, it is characterized in that wherein said polyvinyl alcohol is with silicomethane alcohol modified polyethylene alcohol.
8. according to claim 5 or 6 described waterproof glossy ink-jet printing medias, it is characterized in that the degree of polymerization of wherein said polyvinyl alcohol is 1700～4000.
9. waterproof glossy ink-jet printing media according to claim 1 is characterized in that, wherein said inorganic pigment and adhesive ratio are 9: 1～16: 1 (weight ratio).
10. waterproof glossy ink-jet printing media according to claim 1 is characterized in that, also contains curing agent or waterproofing agent in the wherein said ink absorbing layer.
11. waterproof glossy ink-jet printing media according to claim 10 is characterized in that, wherein said curing agent is ethanol, isopropyl alcohol, acetone, melamine, lactic acid titanium or melamine resin.
12. waterproof glossy ink-jet printing media according to claim 10 is characterized in that, wherein said waterproofing agent is boric acid, borate or melamine resin.
13. waterproof glossy ink-jet printing media according to claim 1 is characterized in that, wherein said support is a plastic-coated paper-based.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2003101153256A CN1544252A (en) | 2003-11-19 | 2003-11-19 | Waterproof high light ink jet printing medium |
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| Application Number | Priority Date | Filing Date | Title |
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| CNA2003101153256A CN1544252A (en) | 2003-11-19 | 2003-11-19 | Waterproof high light ink jet printing medium |
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| CN1544252A true CN1544252A (en) | 2004-11-10 |
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| CNA2003101153256A Pending CN1544252A (en) | 2003-11-19 | 2003-11-19 | Waterproof high light ink jet printing medium |
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