CN1541940A - Production and reproduction method of seamless active carbon articles and products produced thereby - Google Patents

Production and reproduction method of seamless active carbon articles and products produced thereby Download PDF

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Publication number
CN1541940A
CN1541940A CNA031183379A CN03118337A CN1541940A CN 1541940 A CN1541940 A CN 1541940A CN A031183379 A CNA031183379 A CN A031183379A CN 03118337 A CN03118337 A CN 03118337A CN 1541940 A CN1541940 A CN 1541940A
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China
Prior art keywords
active carbon
product
temperature
heat
seamless
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CNA031183379A
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Chinese (zh)
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CN100364886C (en
Inventor
成如山
李韬
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Individual
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Individual
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Priority to CNB031183379A priority Critical patent/CN100364886C/en
Priority to PCT/CN2004/000202 priority patent/WO2004096706A1/en
Publication of CN1541940A publication Critical patent/CN1541940A/en
Application granted granted Critical
Publication of CN100364886C publication Critical patent/CN100364886C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/30Active carbon
    • C01B32/354After-treatment
    • C01B32/36Reactivation or regeneration
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/30Active carbon
    • C01B32/312Preparation
    • C01B32/318Preparation characterised by the starting materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

The present invention is the production, regeneration process and product of seamless active carbon product. The production process of the active carbon product includes setting timber or bamboo material inside one sealed container with exhaust port, raising temperature in certain rate gradually up to 600 deg.c, maintaining for certain time, lowering temperature in the same rate to room temperature to obtain the seamless active carbon product. The regeneration process is basically the same as the production process but has highest temperature of 400 deg.c and vacuum degree of 0.7-0.9 Pa maintained inside the container. The product may be further produced into artistic work through further processing, coloring and other steps and may be used in adsorbing harmful gas in air.

Description

The production of product of seamless active carbon and renovation process and products thereof
Technical field
The present invention relates to the production and the renovation process of gac goods and have finishing, decoration, art, the handicraft product of adsorption function.
Background technology
In the prior art, though people begin to utilize the adsorption function of gac already, it utilizes scope very little, is mainly used in special type protection and laboratory etc.
On the other hand; along with The development in society and economy; it is important further that environment protection seems, the various obnoxious flavoures that hotel guest-room, household's house fitting material discharge, the smog that smoking causes, indoor vitiated air etc. all have a strong impact on the healthy of people, demand urgently purifying.
Summary of the invention
The technical problem to be solved in the present invention is, problem at the prior art existence, a kind of production of product of seamless active carbon and renovation process and products thereof are proposed, utilize described method to produce seamless active carbon and it is regenerated and reuse, goods such as prepared finishing, decoration, art had both had ornamental aesthetic feeling, possessed adsorption function again, significantly decontamination chamber's inner air and outer air, thereby the raising environmental quality is safeguarded HUMAN HEALTH.
One of technical scheme of the present invention, the step of promptly described product of seamless active carbon production method is:
(1) timber or bamboo wood are placed the sealed metal container that is provided with venting port, with the heat-up rate of 0.15-0.3 ℃ of per minute rising by room temperature slowly the described material of heating be incubated 0.5-2 hour to 38-45 ℃; For as the wet feed down, that bamboo is expected of lumbering just, in this intensification and holding stage must be with described containers, be evacuated to 0.8-1.5Pa vacuum tightness;
(2) continue to continue to heat up with above-mentioned identical heat-up rate, the every rising 30-50 of temperature ℃, be incubated 0.5-1 hour, the highlyest rise to 600 ℃; If heat-up rate is lower than 0.15 ℃/min, then need not be incubated;
(3) after the top temperature constant temperature scheduled time, slowly lower the temperature with the speed identical with above-mentioned heat-up rate, temperature is reduced to room temperature in metal vessel, takes out material, promptly gets product of seamless active carbon.
In the said process, can before charing, will treat that carbonated material (timber, bamboo wood) is processed into desired structure shape (as ornament, handicraft model), carries out described charing again; Also can after described charing is finished, carbide be processed into desired structure, shape.
Two of technical scheme of the present invention, the step of promptly described product of seamless active carbon renovation process is:
(1) will treat that the regeneration activity carbon product places the sealed metal container that is provided with venting port, speed with 0.15-0.3 ℃ of per minute rising slowly heats described goods to 80-100 ℃ by room temperature, be incubated 0.5-2 hour, simultaneously described metal vessel be evacuated to 0.7-0.9Pa;
(2) continue to heat up with above-mentioned identical speed and bleed to make and keep described vacuum tightness in this metal vessel, promotion to 400 ℃;
(3) after 400 ℃ of insulation and keeping described vacuum tightness 0.5-2 hour, with above-mentioned identical speed cooling, and continue to bleed to make and keep described vacuum tightness in this metal vessel, temperature is reduced to room temperature in metal vessel, stop to bleed, treat to recover in the container to take out regeneration feed behind the normal pressure, promptly finish regenerative process.
Three of technical scheme of the present invention is, with described product of seamless active carbon carry out forming process, painted, and make up processing, make have finishing, decoration, technology class and have the seamless active carbon product of obnoxious flavour in the absorbed air, air purification function.
In the production method of product of seamless active carbon of the present invention (comprising section bar), the concrete heat-up rate that is warming up to 38-42 ℃ by room temperature is determined that by wet degree of doing of employed wood, bamboo wood and volume or weight thereof common humidity is less, volume or weight the greater can heat up slightly hurry up.When smoldering (about 300 ℃ of beginning charings), then heat-up rate can slow down.The top temperature of finishing charing is by the diameter or the thickness decision of seeds and single blocks, usually arborescence hard, diameter or thickness is big, it is high that its top temperature is wanted.After finishing carbonization process, reducing to room temperature, take out carbide, with boring method inspection all charings whether, whether the crack is arranged with the lens examination goods.When with five times of lens examination goods leakless, be seamless active carbon of the present invention.
Among the present invention, for charing person after the first moulding, available graduating with cutter or iron the type of being carved into; For first charing aftershaping person, generally use the graduating with cutter moulding; For extraordinary product or precious product then with photoetching or iron the type of being carved into.Product in actual use, adsorb saturated after, carry out desorption with described technical scheme two, promptly regeneration (resurrection).
As known from the above, the present invention is production and the renovation process and the activated carbon product thereof of product of seamless active carbon, and described method can be produced satisfactory product of seamless active carbon, and described product had both had decorative aesthetics, but the active adsorption indoor harmful gas significantly improves the room air condition again.After testing, product adsorption rate of the present invention reaches standard activity charcoal adsorption rate; Because of product is that seamless active carbon is sturdy and durable, indeformable, be not subjected to burn into to be difficult for catching fire; Raw material sources are extensive, sufficient, and available various wood, bamboo wood (comprising artificial material and matrix material) are produced, and material shape is also unrestricted, and post, tube, piece, plate, the root and stem of certain plants, root etc. all can.
Embodiment
Embodiment 1: do raw material with dry Chinese catalpa timber, the animal that graduating with cutter Cheng Gaowei is 30 centimetres " hawk " moulding places metal (as the steel) container that is provided with venting port, slowly is heated to 40 ℃ with raise 0.2 ℃ speed of per minute by room temperature, is incubated 0.5 hour; Continue gradation again and heat up, heat up 40 ℃ at every turn, be incubated 0.5 hour; Promotion to 400 ℃ is incubated after 1 hour with identical speed cooling, and temperature is reduced to room temperature in metal vessel, in taking out in material, be product of seamless active carbon.When heat-up rate be controlled at 0.15 ℃/when min is following, sustainable intensification and needn't gradation heating up and insulation.
Embodiment 2: the artificial timber board with long 50cm, thick 2.5cm is done raw material, puts into the metal vessel of venting port, slowly is heated to 40 ℃ with raise 0.25 ℃ heat-up rate of per minute by room temperature, is incubated 1 hour; Persistently overheating with described speed again to 400 ℃, be incubated after 1 hour and lower the temperature with described speed, temperature is reduced to room temperature in container, and middle material in taking out is processed into carbide the artwork (as the engraving plate picture) that can hang appreciation on the wall with the graduating with cutter method.
Embodiment 3: with the hawk surface finish of silk with the charing moulding, again according to the color of eagle each several part, the colored powder of silicon (on-liquid) that will have an adsorption function with writing brush is coated in the characteristic portion of hawk, again with the silk polishing, beautiful eagle artwork.
Embodiment 4: with the early-products of the maiden of the rural area Tujia moulding of charing moulding,, white rubber powder is coated on the face with writing brush its face and straw hat polishing with silk, and with the silk polishing, draws face again; With the colored powder of silicon straw hat is painted pattern; Make scarf and clothes, opotism with the flower silk, and make up on one's body the maiden.
Embodiment 5: the sheet material of moulding is carved in charing, painted with the method for the foregoing description 3, again around it with aluminium alloy or add lacquer timber or mould firmly and make framework, so that hang on the wall; Or make skeleton frame, be convenient to pendulum on the table.

Claims (5)

1, a kind of production method of product of seamless active carbon the steps include:
(1) timber or bamboo wood are placed the sealed metal container that is provided with venting port, with the heat-up rate of 0.15-0.3 ℃ of per minute rising by room temperature slowly the described material of heating be incubated 0.5-2 hour to 38-45 ℃; For as the wet feed down, that bamboo is expected of lumbering just, in this intensification and holding stage must be with described containers, be evacuated to 0.8-1.5Pa vacuum tightness;
(2) continue to continue to heat up with above-mentioned identical heat-up rate, the every rising 30-50 of temperature ℃, be incubated 0.5-1 hour, the highlyest rise to 600 ℃; If heat-up rate is lower than 0.15 ℃/min, then need not be incubated;
(3) after the top temperature constant temperature scheduled time, slowly lower the temperature with the speed identical with above-mentioned heat-up rate, temperature is reduced to room temperature in metal vessel, takes out material, promptly gets product of seamless active carbon.
2, the production method of seamless active carbon according to claim 1 is characterized in that, before charing, will treat that carbonated material is processed into required structure, shape.
3, the production method of seamless active carbon according to claim 1 is characterized in that, after charing is finished, carbide is processed into desired structure, shape.
4, a kind of renovation process of product of seamless active carbon the steps include:
(1) will treat that the regeneration activity carbon product places the sealed metal container that is provided with venting port, speed with 0.15-0.3 ℃ of per minute rising slowly heats described goods to 80-100 ℃ by room temperature, be incubated 0.5-2 hour, simultaneously described metal vessel be evacuated to 0.7-0.9Pa;
(2) continue to heat up with above-mentioned identical speed and bleed to make and keep described vacuum tightness in this metal vessel, promotion to 400 ℃;
(3) after 400 ℃ of insulation and keeping described vacuum tightness 0.5-2 hour, with above-mentioned identical speed cooling, and continue to bleed to make and keep described vacuum tightness in this metal vessel, temperature is reduced to room temperature in metal vessel, stop to bleed, treat to recover in the container to take out regeneration feed behind the normal pressure, promptly finish regenerative process.
5, a kind of seamless active carbon product that makes through the described method of claim 1, it is characterized in that, it comprise with described goods through forming process, painted, woman's persona, make have finishing, decoration, technology class and can absorbed air in the seamless active carbon product that gas arranged, purify air.
CNB031183379A 2003-04-29 2003-04-29 Production and reproduction method of seamless active carbon articles and products produced thereby Expired - Fee Related CN100364886C (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CNB031183379A CN100364886C (en) 2003-04-29 2003-04-29 Production and reproduction method of seamless active carbon articles and products produced thereby
PCT/CN2004/000202 WO2004096706A1 (en) 2003-04-29 2004-03-15 The processes for producing and regenerating the seamless activated carbon and products obtained by the said processes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB031183379A CN100364886C (en) 2003-04-29 2003-04-29 Production and reproduction method of seamless active carbon articles and products produced thereby

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Publication Number Publication Date
CN1541940A true CN1541940A (en) 2004-11-03
CN100364886C CN100364886C (en) 2008-01-30

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WO (1) WO2004096706A1 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100391591C (en) * 2005-08-17 2008-06-04 黎伯忠 Novel adsorptive material for treating air pollution and its preparing method
CN100577562C (en) * 2007-01-08 2010-01-06 长沙文象环保科技有限公司 Activation furnace for producing and reproducing block-shaped active carbon
CN101450306B (en) * 2008-12-10 2011-12-14 南华大学 Depressurization desorption regeneration device and method of radon-absorption active carbon
CN116637607A (en) * 2023-05-22 2023-08-25 山东一清环保设备有限公司 Continuous solid waste regeneration process method

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102398904B (en) * 2011-10-20 2013-07-17 江西省七星炭材科技有限公司 Preparation of fuel oil recovery special active carbon by taking mao bamboo leftovers as raw material and method thereof
CN107129813B (en) * 2017-06-26 2023-12-19 农业部规划设计研究院 Carbonization heat preservation and sealing carbon discharging system of rotary pyrolysis furnace

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85100619B (en) * 1985-04-02 1986-11-26 中国市政工程西北设计院 Forced discharge regeneration method and device for used active carbon
CN1098701A (en) * 1993-08-11 1995-02-15 梁黎利 powdered activated carbon regeneration technology and device
CN1150118A (en) * 1996-09-25 1997-05-21 谢仁智 Active carbon regenerating process
JP2001247303A (en) * 2000-03-01 2001-09-11 Hitachi Ltd Device for regenerating activated carbon and method for activation treatment of activated carbon
RU2159706C1 (en) * 2000-05-04 2000-11-27 Кутьев Анатолий Анатольевич Method of and device for charcoal regeneration
CN1381305A (en) * 2001-04-16 2002-11-27 谢仁智 Process for regenerating activated carbon
CN1128100C (en) * 2001-09-04 2003-11-19 郑兴福 Method for preparing activated char from bamboo material
CN1406867A (en) * 2001-09-06 2003-04-02 何弘鑫 Preparation of activated carbon from bamboo
CN1382625A (en) * 2002-06-09 2002-12-04 陈文照 Process for preparing activated carbon from bamboo

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100391591C (en) * 2005-08-17 2008-06-04 黎伯忠 Novel adsorptive material for treating air pollution and its preparing method
CN100577562C (en) * 2007-01-08 2010-01-06 长沙文象环保科技有限公司 Activation furnace for producing and reproducing block-shaped active carbon
CN101450306B (en) * 2008-12-10 2011-12-14 南华大学 Depressurization desorption regeneration device and method of radon-absorption active carbon
CN116637607A (en) * 2023-05-22 2023-08-25 山东一清环保设备有限公司 Continuous solid waste regeneration process method

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Publication number Publication date
CN100364886C (en) 2008-01-30
WO2004096706A1 (en) 2004-11-11

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Granted publication date: 20080130

Termination date: 20140429