CN1536031A - Polycrystalline state composite and its preparation method - Google Patents

Abstract

The present invention relates to a polycrystalline state complex composite which can be used in the field of rubber processing technology. It adopts the powder which can be commonly used in rubber filling agent and reinforcing agent as nuclear body material, after the nuclear body material surface is undergone the processes of covering with mixed crystal and special physical-chemical modification treatment, it can be prepared into the polycrystalline state complex composite whose nuclear body material surface has polycrystalline state compound and mixture like 'small file' form. The composition formula of said polycrystalline state complex composite is [sigma aiAi.sigma biBi.ZH2O].sigma niDi, in which Ai is inorganic and non-meltable low-ash nuclear body material, Bi is polycrystalline state inorganic salt compound and mixture formed by reaction in liquid phase, Di is organic material, and Sigma ai, Sigma bi, Z and Sigma ni are molar coefficients.

Description

A kind of polycrystalline state compound composition and preparation method thereof

Technical field

The present invention is from the field of rubber processing aids, a kind of polycrystalline state mixture with the application of multiple field and preparation method thereof has been proposed, relate to Rubber processing used additives, sorbent material, weighting agent, pigment, powder fire extinguishing agent, fire retardant, abrasive material etc., belong to fields such as rubber processing aids, the manufacturing of inorganic chemical industry product.

Background technology

As everyone knows, in the Rubber processing industry, carry out smoothly, adopt various processing aids, make the physicochemical property of sizing material that useful transformation take place in order to make the course of processing.As, make rubber size softening, will in sizing compound formula, add plasticity processing aids such as oil, ester, wax, soap, activator, promotor; In waste vulcanized rubber is pulverized, in the processing of " normal temperature cutterhead method " superfine grinding sulfuration waste rubber that develops rapidly in recent years,, use powders such as stone flour, light calcium carbonate to do the barrier property processing aid usually especially in order to prevent the rubber powder conglomeration.Yet there are many shortcomings that are difficult to overcome in existing many kind rubber processing aids, and can't satisfy the user and the producer's demand.At present the Rubber processing used additives exist environmental pollution serious and cost an arm and a leg, shortcoming such as cost height, concrete detailed being shown in Table 1.

Therefore, the urgent hope of Rubber processing industry can have a kind of tasteless, pollution-free, nonflammable, applied range, good, the cheap new processing aid of effect to occur; Rubber ingredients preparation industry also needs a kind of getting to expect conveniently, produces easily free of contamination processing aid product.In order to overcome many shortcomings of existing rubber processing aids, the present invention's development provides a kind of New Polycrystalline attitude compound composition and preparation method thereof, this polycrystalline state mixture is not only the desirable processing aid of Rubber processing industry, and be the good auxiliary agent of plastics, coating, paper industry, also there is good prospects for application in the fields such as modification utilization of this external sorbent material, pigment, fire retardant, " three wastes " thing.

When using processing aid always, uses and shortcoming table 1 rubber

Summary of the invention

The objective of the invention is, adopt and do the main body core material as the powdered material of rubber filler and strengthening agent etc. usually, by the chemical technique means main body powdered material is carried out materialization and handle to form the coprecipitated or/and amorphous of surperficial mixed crystal and coat, thereby be prepared into the polycrystalline state compound composition that can make the rubber plasticizing and also have wide application prospects to promote the technical progress of Auxiliaries Industry in other field.

The design of polycrystalline state compound composition that the present invention proposes and preparation method thereof is as follows:

1, adopts and can be used as rubber packing strengthening agent etc. usually, vapour pressure is zero (or being destitute of smell) under the Rubber processing temperature condition, does not burn, and security is good, the source is wide, and the powdered material that price is low is done the main body core material or the parent material of polycrystalline state compound composition of the present invention.

2, main body powdered material surface is coated mixed crystal or/and imperfect crystal formation, be processed into miniature " the little file " of polycrystalline state.When Rubber processing, these miniature " little files " enter in the polymer network chain of rubber, and shuttle in sizing material by the mechanical force of milling machine, and file cuts the part network chain key of rubber, thereby increase chain rupture free radical formation speed, and then make the rubber plasticizing.

3, carry out the materialization processing on main body powdered material surface and form coprecipitated mixed crystal, be prepared into the technology of the compound composition of miniature " little file " shape polycrystalline state or/and imperfect crystal formation coats:

A, at first, adopt acid molten or alkaline etching or calcining method, calcine some powder materials that can (or part can) be dissolved in acid or alkali and acid or alkali effect or some powder materials that contain the non-refractory component, make its formation just as the crude surface of coal scoriform; Certainly also can directly select the crude material fine powder in surface for use;

B, secondly, mix the method that generates by the polymorphic throw out, to have the composition on crude surface or the mixture powder core material multiple material different or/and one or more unformed material mixes with newly-generated crystal formation in liquid phase, pass through physical reaction, will generate the crude layer of imperceptible many crystallizations on powder nucleome surface, thereby obtain that (surface has the polycrystalline state compound, mixture) primary particle of whole particulate, the sterie configuration complexity of particle repeatedly, surface recombination have indenting hard polycrystalline state compound, mixture is just as the polycrystalline state compound composition of miniature " little file ".

C, in order to be prepared into " a little file " small as far as possible, prevent solution bumping in the preparation process, and save material in dried grinding and processing operation sequence, add rubber, mould organic materials commonly used in the processing, prevent separant and solution reaction defoamer that " little file " crystal is reunited.

When 4, preparing the polycrystalline state compound composition, the least possible water in the technology is to save the filter operation operation.In the time of must water, institute's water (or filtrate) be reused.Like this, both can eliminate the discharging of waste liquid contaminate environment, the material pick-up rate is risen.

5, last, the made rubber plastifying that makes miniature " little file " shape polycrystalline state compound composition again with rubber, mould or/and it processes usual auxiliaries mixes, carry out special physics and chemistry modification, obtain having the more compound composition of extensive use.

The method that the present invention proposes polycrystalline state compound composition and preparation thereof is as follows:

The available general formula of the composition of polycrystalline state compound composition of the present invention: [∑ a _iA _i∑ b _iB _iZH ₂O] ∑ n _iD _iExpression, the ∑ a in the formula _i, ∑ b _i, Z, ∑ n _iBe the mole indeterminate coefficient, [the ∑ a in the general formula _iA _i∑ b _iB _iZH ₂O] weight percent is 〉=50%, ∑ n _iD _iWeight percent is＜50%.The expanded formula of general formula is:

[a ₁A ₁A ₂A ₂A _nA _nB ₁B ₁B ₂B ₂B _mB _mZH ₂O] n ₁D ₁N ₂D ₂N _hD _hOr

$[\underset{i=1~n}{\mathrm{\Σ}}{a}_i(A_1,A_2\·\·\·\·\·\·\mathrm{An})\·\underset{i=1~m}{\mathrm{\Σ}}{b}_i(B_1,B_2\·\·\·\·\·\·B_m)\·Z{H}_{2}O]\·\underset{i=1~b}{\mathrm{\Σ}}{n}_i(D_1,D_2\·\·\·\·\·\·D_h).$

" [∑ a in the general formula _iA _i∑ b _iB _iZH ₂O] " be the foundation stone composition of polycrystalline state compound composition of the present invention, " ∑ n _iD _i" be the perfect and expansion that polycrystalline state compound composition of the present invention is formed.When polycrystalline state compound composition of the present invention prepares, get one or more composition batchings A among the following powder thing A earlier _i:

Selected A batching size requires: can not be consoluet by acid or alkali lye, and particle diameter is the smaller the better, generally will be narrower than or equal 200 orders; Can be then thick as far as possible by the material of acid or alkali dissolution fully, generally be not coarser than 5 orders; The Ai batching particle diameter that carries out calcination processing all requires to be narrower than or to equal 200 orders.Selected batching A _iAfter, with A _iMaterial one step or substep place water, add in sulfuric acid, phosphoric acid, hydrochloric acid, hydrofluoric acid, the carbonic acid (carbonic acid gas entry) one or more acid add caustic soda or and soda ash, react, also the Ai material can be carried out calcination processing.For selected A _iMaterial is soluble in acid, and the acid of adding needn't be excessive.To selected A _iMaterial will heat concentrated acid could be partly soluble, and the sour available bases of reacting excessive is neutralized.The neutralization bases of selecting for use can be the alkalescence batching among the above-mentioned A, also can select soda ash (Na else ₂CO ₃), caustic soda (NaOH), bubble flower alkali (Na ₂OXSiO ₂), sodium sulphite (Na ₂S), lime (CaO), slaked lime (Ca (OH) ₂), lime carbonate (CaCO ₃), ironic hydroxide (Fe (OH) ₃) etc.; The Ai material is carried out alkaline purification, and alkali all can be excessive slightly, and the alkali after excessive can filter or add aforesaid acid and be removed after alkaline purification.The potential of hydrogen of solution reaction terminal point is controlled at PH=1～10 scopes.In the processing reaction, A _iBeing dissolved fully by acid or alkali of having of prototype material (can make ∑ a in the products therefrom _iA _iBe zero), what have is then lost into the littler surperficial crude particle of particle diameter, the B in the general formula by acid or alkali or high temperature _iCombination for following one or more substance Bs of in solution, generating:

Calcium sulfate (CaSO₄), calcium monohydrogen phosphate (CaHPO₄), calcium phosphate (Ca₃(PO ₄) ₂), calcirm-fluoride (CaF₂) strontium fluoride (SrF₂), barium fluoride (BaF₂), magnesium fluoride (MgF₂), magnesium hydroxide (Mg (OH)₂), magnesium carbonate (MgCO₃), magnesium monohydrogen phosphate (MgHPO₄), silicic acid (H₂SiO ₃Or SiO₂·nH ₂O), magnesium silicate (MgOXSiO₂), calcium silicates (CaOXSiO₂), strontium silicate (SrOXSiO₂), barium silicate (BaOXSiO₂), alumina silicate (Al₂O ₃·XSiO ₂), zinc silicate (ZnOXSiO₂), zinc carbonate (ZnCO₃), basic zinc carbonate (ZnCO₃·2Zn(OH) ₂), trbasic zinc phosphate (Zn₃(PO ₄) ₂), basic zinc sulfate (ZnSO₄·4Zn(OH) ₂), zinc sulphide (ZnS), zinc hydroxide (Zn (OH)₂), aluminium hydroxide (Al (OH)₃), iron hydroxide (Fe (OH)₃), alkali formula iron chloride (FeCl (OH)₂、FeCl ₂(OH)), ferric subsulfate (FeSO₄(OH)), strontium sulfate (SrSO₄), barium sulfate (BaSO₄), sodium chloride crystallization (NaCl), sulfate crystal (Na₂SO ₄), sodium phosphate (Na₃PO ₄), sodium hydrogen phosphate crystallization (Na₂HPO ₄), potassium chloride crystallization (KCl), potassium sulfate crystallization (K₂SO ₄), potassium phosphate crystallization (K₃PO ₄), dipotassium hydrogen phosphate crystallization (K₂HPO ₄), potassium fluoride crystallization (KF), ferrous sulfate crystallization (FeSO₄·nH ₂O), zinc sulfate crystallization (ZnSO₄·nH ₂O), metatitanic acid (TiO₂·XH ₂O), (without what calcine) lithopone (aZnSbBaSO₄), the ferrous crystallization (FeHPO of phosphoric acid hydrogen₄·nH ₂O), frerrous chloride crystallization (FeCl₂·nH ₂O), zinc chloride crystallization (ZnCl₂·nH ₂O), cerium hydroxide (Ce (OH)₃), cerous phosphate (CePO₄), Kocide SD (Cu (OH)₂), cupric phosphate (Cu₃(PO ₄) ₂), nickel hydroxide (Ni (OH)₂), nickelous carbonate (NiCO₃), boric acid (H₃BO ₃), metaboric acid (HBO₂), sodium tetraborate (Na₂B ₄O ₇·nH ₂O), Firebrake ZB (XZnOYB₂O ₃·ZH ₂O), magnesium sulfate (MgSO₄·7H ₂O), Sodium Aluminium Carbonate Basic (NaAl (OH)₂CO ₃), basic lead carbonate (2PbCO₃·Pb(OH) ₂), sodium acid carbonate (NaHCO₃), titanyl sulfate (TiOSO₄), aluminium dihydrogen phosphate (Al (H₂PO ₄) ₃), potassium titanate (K₂TiO ₃), ammonium magnesium phosphate (MgNH₄PO ₄·6H ₂O), PTPP (K₅P ₃O ₁₀), barium metaphosphate (Ba (PO₃) ₂), kodalk (Na₂B ₂O ₄), potassium pentaborate (KB₅O ₈·4H ₂O), aluminium borate (2Al₂O ₃·B ₂O ₃·3H ₂O), bismoclite (BiOCl), aluminum phosphate (AlPO₄), calcium molybdate (CaMoO₄), ammonium molybdate (NH₄) ₆Mo ₇O ₂₄·4H ₂O), orthophosphoric acid iron (FePO₄·2H ₂O), potassium ferric oxalate (KFe (C₂O ₄) ₂), ferrous oxalate (FeC₂O ₄), stannic acid zinc (ZnSnO₃·4H ₂O), calcium citrate (Ca₃(C ₆H ₅O ₇) ₂), calcium lactate (CaC₃H ₅O ₃), calcium oxalate (CaC₂O ₄), calper calcium peroxide (CaO₂), hydrogen peroxide calcium sulfate adduct (CaSO₄·nH ₂O ₂), hydrogen peroxide sulfate crystal (Na₂SO ₄·nH ₂O ₂), hydrogen peroxide cupric sulphate crystal (CuSO₄·nH ₂O ₂), calcium sulfite (CaSO₃), sodium sulfite crystallization (Na₂SO ₃), sodium pyrosulfite (potassium) crystallization (Na₂S ₂O ₅Or/and (K₂S ₂O ₅)), sodium dithionite (potassium) crystallization (Na₂S ₂O ₄Or/and (K₂S ₂O ₄)), sodium bisulphite formaldehyde crystallization (NaHSO₂CH ₂O·2H ₂O), zinc oxalate crystallization (ZnC₂O ₄·nH ₂O), ferrous oxalate zinc crystallization (FeC₂O ₄·ZnC ₂O ₄·nH ₂O), ferrous sulfate zinc crystallization (FeSO₄·ZnSO ₄·nH ₂O), zinc dithionite crystallization (ZnS₂O ₄), basic magnesium carbonate (MgCO₃·Mg(OH) ₂), sodium thiosulfate (potassium) crystallization (Na₂S ₂O ₃Or/and (K₂S ₂O ₃)), ferrous sulfate copper crystallization (FeSO₄·nH ₂O), the ferrous zinc crystallization of phosphoric acid hydrogen (ZnHPO₄·FeHPO ₄·nH ₂O), the ferrous copper crystallization of phosphoric acid hydrogen (CuHPO₄·FeHPO ₄·nH ₂O), chromium hydroxide (Cr (OH)₃), metatitanic acid (H₂TiO ₃), iron oxide black (Te₃O ₄), barba hispanica (Fe₄[Fe(CN) ₆] ₃·K ₄Fe(CN) ₆, or Fe₄[Fe(CN) ₆] ₃·(NH ₄) ₄Fe(CN) ₆), iron oxide yellow (Fe₂O ₃·H ₂O), iron oxide red (Fe₂O ₃), medium chrome yellow (PbCrO₄/PbSO ₄/Al(OH) ₃), molybdate red (aPbCrO₄·bPbMoO ₄·cPbSO ₄), chrome yellow (PbCrO₄Or PbSO₄·X[PbCrO ₄·Pb(OH) ₂]), cadmium red (CdS/CdSe), cadmium yellow (CdS/ZnS), G cadmium scarlet (CdS/HgS), cupric silicate (CuOXSiO₂), antimony oxide (Sb₂O ₃), ultramarine (Na₆Al ₄Si ₆S ₄O ₂), bright red, the benzidine yellow of phthalocyanine blue, phthalocyanine green, alkaline royal blue color lake, Fast Malachite Blue lake, lithol rubine, toluidines, the husky Huang of the Chinese, the bright red LC of rubber, golden red antimony etc., Bi is except obtaining also can making from other liquid phase reactor approach from the Ai processing reaction.

When Ai handles and after subsequently Bi polycrystalline state thing deposition reaction finishes, solution carries out processed through ageing a few hours.Processed obtains material ∑ b _iB _iComponent itself or ∑ b _iB _iComponent and ∑ a _iA _iWhat component combined together again is surperficial crude, just as miniature " little file " powder of file shape.For the powder that makes miniature file shape generates as far as possible for a short time, entering the rubber network chain, to cut the chain effect better, also in order to prevent solution bumping in the preparation process, and can be at selected A _iIn the dry powder formulation of component, generate B _iIn the reaction solution of component, add following one or more materials earlier and make separant and defoamer: rosin, staybelite, dimethylbenzene Gum Rosin, special octyl phenol urea formaldehyde, coumarone, Persea cubeba (Jiao) oil, alizarin assistant, Yatall MA, Stockholm tar, oleum gossypii seminis, rape seed oil, soybean oil, plam oil, Cai spend seed oil, sweet oil, machine oil, white oil, aromatic hydrocarbon oil, naphthenic oil, paraffin oil, third fractional oil, six line oil, (giving up) rubber hot tearing oil, (giving up) plastics hot tearing oil, (mixing) oleic acid etc.

Above-mentioned these organic materialss are D in the composition formula of compound composition of the present invention _iThe class component.Add above-mentioned D _iBehind the component material, not only can make miniature " little file " powder of generation thinner, and when reaction solution also be difficult for bumping; After the material dewatering drying, do not need to pulverize especially; With compounding rubber, material feeding is fast, no dust from flying.

In the preparation process of the present invention, after solution reaction stopped, reaction solution obtained being compound composition slurry mud, cake mud, elementary core product " [the ∑ a of dry powder again through operations such as ageing, filtrations _iA _i∑ b _iB _iZH ₂O] ∑ n _iD _i"; Simultaneously, the filtrate that produces in the technological process is returned use, has both eliminated pollution, has also improved the pick-up rate of product.In addition, polycrystalline state compound composition [the ∑ a for the present invention is prepared _iA _i∑ b _iB _iZH ₂O] ∑ n _iD _iCan be multi-direction, be applied even more extensively in the Rubber processing industry, also can carry out multiple deep processing to elementary core product of the present invention again, to obtain the rubber processing aids of multiple formulation:

First kind is, the slurry mud that contains more free-water again be narrower than or equal 200 purpose powder A _iThan 1.5: 8.5～8: 2 ratio mixs, make cake mud material, the dry material of loose shape in butt.Processing can be removed the filter operation operation from like this;

Second kind is, the cake mud shape material that contains free-water and the D of volume more _iThe class material further mixes in proportion, and blending ratio is: the deduction free-water is disregarded " [∑ a _iA _i∑ b _iB _iZH ₂O] " weight of material per-cent is greater than 50, " ∑ n _iD _i" weight of material per-cent is less than 50, obtains aqueous greasy filth shape polycrystalline state compound composition [∑ a after the mixing _iA _i∑ b _iB _iZH ₂O] ∑ n _iD _iThis primary product compound composition and/or greasy filth shape compound composition are suitable for the pulverizing and the regenerated rubber of vulcanized rubber very much, the processing of natural " rubber " etc.;

The third is to be obtained by primary product polycrystalline state compound composition drying and dehydrating.Become a kind of [∑ a that does (powder, grain, piece) shape behind the primary product polycrystalline state compound composition drying and dehydrating _iA _i∑ b _iB _iZH ₂O] ∑ n _iD _iMaterial is suitable for the plasticizing of conventional rubber, mixing processing;

The 4th kind is, the primary product that the third deep processing is obtained do (powder, piece, grain) shape material again with above-mentioned separant and defoamer or/and following one or more materials (also belonging to the Di class component in the general formula composition) further mix or mixed kneading:

C _4～18Lipid acid, Vaseline, paraffin, halogenated paraffin, pitch, dark substitute, white factice, styrene resin, low molecular polyethylene, resol, polyisobutene, polybutene, stearic acid, sodium stearate, calcium stearate, Magnesium Stearate, barium stearate, Zinic stearas, ethylenediamine tetraacetic acid (EDTA) (Asia) iron, sylvic acid is ferrous, zinc abietate, the ferrous zinc of sylvic acid, Ferrous Gluconate zinc, amylalcohol, hexanol, enanthol, octanol, decyl alcohol, lauryl alcohol, tetradecyl alcohol, hexadecanol, stearyl alcohol, cyclopentanol, hexalin, phenylcarbinol, ethylene glycol, propylene glycol, glycerol, 2-Ethylhexyl Alcohol, sec-n-octyl alcohol, lauryl alcohol, Terpineol 350, high carbon number (C _7～18) mixed fatty alcohol, tetramethylolmethane, Xylitol, dipropylene glycol, dioctyl phthalate (DOP), dibutyl phthalate, diisobutyl phthalate, dialphanyl phthalate, tributyl phosphate, triethyl phosphate, triphenylphosphate, Tritolyl Phosphate, pentabromodiphenyl oxide, the tetrabromo cyclooctane, two bromotrifluoromethane dibromo-cyclohexanes, decabromodiphynly oxide, pentabromotoluene, hexabromocyclododecane, tetrabromo-bisphenol s two (2, the 3-dibromopropyl) ether, Brominated Polystyrene (high molecular), poly-Dowspray 9, Brominated Polystyrene (lower molecular weight), tetrabromophthalate diesters/glycol, the tetrabromo Dipentaerythritol, bromine ethene, 2, the 3-dibromo-propanol, tricresyl phosphate (2-chloroethyl) ester, tricresyl phosphate (1,3-two chloro-2-propyl group) ester, tricresyl phosphate (1-chloro-2-propyl group) ester, dimethyl methyl phosphonate, diethyl ethylphosphate, the oligomeric chloroformate ethyl phosphonate, ammonium polyphosphate (APP), the terephthalic acid dibutyl ester, the hexanodioic acid dibutyl ester, hexanodioic acid two-2-(ethyl hexyl) ester, sebacic acid two-2-(ethyl hexyl) ester, two-[3-triethoxyl silane propyl group] tetrasulfide, r-sulfydryl propyl trimethoxy silicane, dimethyldimethoxysil,ne, methyltrimethoxy silane, methyl triacetoxysilane, Union carbide A-162, tetramethoxy-silicane, tetraethoxysilane, dimethyldiethoxysilane, the 2-thiol benzothiazole, curing Dibenzo thiazole, 2-thiol benzothiazole zinc salt, N, N-diethylbenzene a pair of horses going side by side thiazole-2-sulphenamide, N-cyclohexyl benzothiazole sulfonamide, N, N-dicyclohexyl-2-benzothiazole sulfonamide, N-oxygen diethylene-2-benzothiazole sulfonamide, natural rubber; styrene-butadiene rubber(SBR); cis-1,4-polybutadiene rubber; polyisoprene rubber; (halogenation) isoprene-isobutylene rubber; paracril; ethylene-propylene rubber(EPR); chloroprene rubber; urethanes; regenerated rubber; (sulfuration) rubber powder; salicylic acid; citric acid; oxalic acid; lactic acid; tartrate; glucose; vitamins C; titanic acid ester etc.Blending ratio also is " [∑ a _iA _i∑ b _iB _iZH ₂O] " material＞50%, " ∑ n _iD _i" material＜50%.Mix like this or mixed kneading after, obtain the piece, granular of bulky powder shape, oil loam shape, oil-containing, wax etc., the blob of viscose micelle shape, mixing gelationus multiple formulation [the ∑ a that contain rubber, mould etc. _iA _i∑ b _iB _iZH ₂O] ∑ n _iD _iThe polycrystalline state compound composition.

The present invention has following advantage and positive technique effect: polycrystalline state compound composition of the present invention at first is suitable for the kinds of processes and the application direction of Rubber processing, can be used as separant and preparation low mooney viscosity rubber, the odorless regenerated rubber, best in quality, cheap; Add in the zinc oxide that rubber ingredients use and can make mixing, the compound polycrystalline state compound composition that contains zinc oxide, can increase the dispersiveness of zinc oxide and mould, the plasticity-of glue stuff compounding; Add rubber, mould, can increase the dispersiveness of pigment in rubber, plastics with in colour batch or the pigment; Add rubber, mould, can increase the speed that powder " is eaten into " by rubber, plastics material with in the reinforcing fillers such as carbon black, white carbon black, potter's clay, lime carbonate; Add aqueous rubber in addition, mould with anti-aging agent, rubber and use in the vulcanization accelerator, can be used as absorption carrier.Certainly, polycrystalline state compound composition of the present invention also can be applied in others, as ∑ n _iD _iBe tending towards at 0 o'clock, can be used as the purifying adsorbent of water surface sump oil, paper weighting agent etc.In addition, the polycrystalline state compound composition of gained miniature " little file " core material [the ∑ a according to the present invention _iA _i∑ b _iB _iZH ₂O] mould when mixing with rubber, to rubber to mould the effect of separating identical with higher alcohols, metallic soap class etc.Because the core material is tasteless, the overwhelming majority is not fired, and after core material and D class auxiliary material were mixed, the processing aid of gained was compared with the processing aid for preparing with pure organism, and its smell and combustion heat value are all little over half.The raw material that the inventive method prepares compound composition is easy to get, and method is simple, steady quality, and gained sizing material peculiar smell is little.Polycrystalline state compound composition of the present invention and preparation method thereof, opened main employing inorganics, the low ash thing of melting property does not prepare the beginning that rubber is moulded separating property auxiliary agent, with the polycrystalline state compound composition auxiliary agent of the inventive method preparation, is applied to the Rubber processing industry, more practical, more progressive.And the sorrow of all not having " three wastes " processing in preparation and the use.

Embodiment

Further specify content of the present invention below by preferred embodiment.

Embodiment 1

Get and be narrower than or equal 200 purpose fiber snake--asbestos (Mg ₆[(OH) ₈| Si ₄O ₁₀]), krocodylite (Na ₂Fe ₃ ^(II)Fe ₂ ^(III)[O, OH] ₂[Si ₈O ₂₂], amosite asbestos [Fe ^(II) _5.5Mg _1.5Si ₈O ₂₄H ₂], Tremoliteor Tremoliteasbestos cotton (Na ₂(a ₄[Mg, Fe] ₁₀[(OH) ₂O ₂| Si ₆O ₁₄]), crocidolite (Na, K, Ca) _3-4MgFe ^(II)(Fe ^(II), Al) _3-4[(OH) ₄| Si ₁₆O ₄₄]), each 20 parts place in the acid-resistant container, add water and stir for 2000 parts, under agitation condition, add saturated hydrofluoric acid (HF) contain 30% above industrial waste sulfuric acid (H ₂SO ₄) acid solution, add-on is 105～110% of reactional equation metering, stirring reaction dripped an amount of milk of lime neutralization after 1 hour, stopped reaction when solution acid alkalinity PH=8～10.When material is the thickness pulpous state, filter, filtrate recycle is in the cotton powder of fossil, and it is about 60～70% that the filter cake mud after the filtration contains free-water, and the component of filter cake mud compound composition consists of:

∑ a _i(be insoluble to the resistates A of acid in the asbestos _i) ∑ b _i[Mg (OH) ₂, CaSO ₄, CaF ₂, MgF ₂, Fe (OH) ₃, Al (OH) ₃, SiO ₂] ZH ₂O.Moisture filter cake mud compound composition material through 110 ℃ of dry a few hours, is done (powder, piece, grain) shape compound composition, and at this moment some soluble salts are also separated out, these soluble salts mix on a small quantity in compound composition to rubber mould separate useful.The polycrystalline state compound composition that obtains after the drying is:

∑ a _i(be insoluble to the resistates A of acid in the asbestos _i) ∑ b _i[Na ₂SO ₄, K ₂SO ₄, Mg (OH) ₂,

| _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ porous surface is crude _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ | | _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ CaSO ₄, CaF ₂, FeSO ₄, MgF ₂, Fe (OH) ₃, Al (OH) ₃, SiO ₂] ZH ₂O._ _ _ _ _ _ _ _ _ polycrystalline state composite junction crystal _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ |

Embodiment 2

Get 400 order manganolite (3CaOMgO2SiO ₂), wollastonite (CaOSiO ₂), silicon stirs for 500 parts, adds assorted oleic acid of 0.5-49 part or machine oil under agitation condition, 75 part 98% vitriol oil H ₂SO ₄, react and drip an amount of lime carbonate suspension liquid (400 order lime carbonate: water=1: 1) end to not bubbling after 2 hours again.This moment, feed liquid became heavy-gravity slurry mud, added 300 parts of 400 purpose kaolin again and starched the cake mud that the mud mix becomes to contain free-water about 40%.Cake mud obtains containing D after 120 ℃ of dryings _iWeight percent 0.1～10%, easily dispersive is done (powder, grain) shape polycrystalline state compound composition:

[∑ a _i(can not be dissolved in silicate, lime carbonate, the kaolin A of acid _i) ∑ b _i[(CaSO ₄, SrSO ₄,

| _ _ _ _ _ _ _ _ _ _ _ _ surperficial crude _ _ _ _ _ _ _ _ _ _ _ _ | | _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Zn (OH) ₂, MgOSiO ₂, SiO ₂) ZH ₂O] ∑ n _i(assorted oleic acid or machine oil D _i)._ _ _ _ _ _ _ _ _ _ _ _ _ _ _ polycrystalline state composite junction crystal _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ | the oil-absorption(number) of this dried (powder, grain) shape polycrystalline state compound composition ( ^DOPml/ _{The 100g compound composition})=40～250.(annotate: DOP is an octyl phthalate).

Embodiment 3

Get barium silicate (BaOXSiO ₂) 100 parts place acid-resistant container, add water and stir for 450 parts, drip the acid of sulfonation sulfur waste while stirring and o'clock end to solution acid alkalinity PH=7～8.This moment, feed liquid was slurry mud shape, and adding is narrower than or equals respectively 121 parts of 200 purpose bamboo powders, (mixing) wood dust, (giving up) activity charcoal powder, tree bark powder, and mix becomes loose cake mud shape.Again cake mud is tedded to moisture about 20%, was configured in than 60: 40 by butt with natural rubber and mixingly in the Banbury mixer becomes mixing gluey polycrystalline state compound composition:

[∑ a _i(bamboo powder, (mixing) wood dust, (giving up) activity charcoal powder, tree bark powder A _i) ∑ b _i(BaSO ₄,

| _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ surperficial crude _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ | | _ _ _ _ _ _ _ _ _ many SiO ₂) ZH ₂O] n ₁(natural rubber D ₁) n ₂(assorted sulfonation class thing D ₂).

Crystalline state composite junction crystal _ _ _ _ _ _ |

Embodiment 4

Get 200 order wollastonite powder and place acid-resistant container for 87 parts, adding water stirs for 400 parts, 93 parts of stirring reactions of strong phosphoric acid of dropping 80% are after about 1 hour, when the pH value of solution adds 470 parts of wood charcoal powders greater than 1 the time again in the material that is slurry mud shape, mix takes out to loose cake mud and teds (ageing), the pH value of material rises, pH value rises to more than 5, contain free-water 15～20% o'clock, material and Stockholm tar, Yatall MA, dark substitute etc. be mixed into the polycrystalline state compound composition in butt than the ratio heat greater than 1: 1:

[a ₁(be insoluble to the remaining A of wollastonite of acid ₁) a ₂(wood charcoal powder A ₂) b ₁CaHPO ₄B ₂SiO ₂ZH ₂O]

| _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ surperficial crude _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ | | _ _ _ _ _ _ polycrystalline state composite junction crystal _ _ _ _ _ _ |

N ₁(Stockholm tar D ₁) n ₂(Yatall MA D ₂) n ₃(dark substitute D ₃) n ₄(...).

Embodiment 5

Get 400 purpose iron calcium aluminate (XCaOYAl ₂O ₃ZFe2O ₃) 10 parts, amarantite (Fe ₂O ₃2SO ₃7H ₂O) 10 parts, 200 purpose zinc silicate (ZnOXSiO ₂) 30 parts, 300 parts in water places acid-resistant container, adds 0.5 part of white oil, the vitriol oil (98%H ₂SO ₄) 80 parts, successively add 60 parts of 200 purpose wollastonite powder and an amount of milk of lime again, react, stop during to the potential of hydrogen PH=1 of solution.This moment, material was thickness slurry mud shape, admixed 300 parts in 400 purpose potter's clay, was prepared into the cake mud shape polycrystalline state compound composition that contains free-water about 45%.The component of polycrystalline state compound composition consists of:

[a ₁(the acid non-soluble substance A in the iron calcium aluminate ₁) a ₂(the acid non-soluble substance A in the wollastonite ₂) a ₃(potter's clay A ₃)

| _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ surperficial crude _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ |

B ₁FeSO ₄(OH) b ₂ZnSO ₄B ₃CaSO ₄B ₄H ₂SiO ₃B ₅Al (OH) ₃ZH ₂O] n ₁(white oil

| _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ polycrystalline state composite junction crystal _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ | D ₁)].

Embodiment 6

Get 400 purpose wilkinite (Al ₂O ₃4SiO ₂2H ₂O) 100 parts place acid-resistant container, add water and stir for 2000 parts, add strong phosphoric acid (80%H under agitation condition ₃PO ₄) 40 parts, the vitriol oil (98%H ₂SiO ₄) 45 parts, react after 1 hour, add again by about 200 parts of the slurry of 1: 1 synthetic 400 purpose wollastonite powder and water, continued stirring reaction about 1 hour, and stopped to stir when the pH value of feed liquid rises to 4, feed liquid is still aging, the pH value of material continues to rise at 5 o'clock, thick the solidifying of material knot.At this moment, material is taken out, centrifuge dehydration obtains the polycrystalline state compound composition filter mud of solid content 25～40%:

[a ₁(wilkinite acid non-soluble substance A ₁) a ₂(wollastonite acid non-soluble substance A ₂) b ₁CaHPO ₄B ₂CaSO ₄

| _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ surperficial crude _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ | | _ _ _ _ _ _ polycrystalline state composite junction crystal

·b ₃SiO ₂·ZH ₂O]。

___________________________|

This compound composition filter mud tedded or heat drying after pulverize, the powder compound composition is except that being directly used in the Rubber processing, be more suitable in the oil product decolorizing purification, usage is identical with atlapulgite, but in technological process, there is not spent acid to discharge, and after the oil purification, the slag mud of formation is still the polycrystalline state compound composition of the present invention that is used for Rubber processing:

[a ₁(wilkinite acid non-soluble substance A ₁) a ₂(wollastonite acid non-soluble substance A ₂) b ₁CaHPO ₄B ₂CaSO ₄

| _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ surperficial crude _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ | | _ _ _ _ _ _ _ _ _ polycrystalline state composite junction crystal _ _ _

B ₃SiO ₂ZH ₂O] ∑ ni (mineral oil, vegetables oil, animal oil, solid paraffin D _i)._____________________|

The pH value of present embodiment dry powder product can be by the add-on control of wollastonite powder water slurry, and pH value is 5～7 o'clock, helps the polycrystalline state compound composition and do the sorbent material use.The oil-absorption(number) of polycrystalline state compound composition ( ^DOPml/ _{100 compound compositions})=120～180.In addition, polycrystalline state compound composition dry powder product also can replace white carbon black to add aqueous rubber, moulds anti-aging agent, in the vulcanization accelerator etc., making absorption carrier uses, or dye the adsorption removal agent as water oil stain and use, or make the filler of coating, paper, or make polish abrasive, powder fire extinguishing fire retardant, uses such as lagging material.

Embodiment 7

Get dry mash and the Rubber processing zinc oxide of embodiment 6, mix by 1～2: 4～3 weight ratio, be prepared into a kind of have chew the modified zinc oxide polycrystalline state compound composition of separating rubber hydrocarbon chain performance.Modified zinc oxide polycrystalline state compound composition has the minimizing zinc oxide dosage, reduces the rubber mass mooney viscosity, improves advantages such as sizing material extrusion property.Concrete enforcement: 25～40% filter muds and the zinc oxide dry powder admittedly of containing of getting embodiment 6; by butt than 1～2: 4～3 puddle mutually; and then fluidisation or expansion drying, obtain chewing of rubber hydrocarbon chain separated better modified zinc oxide particle of effect or dry powder polycrystalline state compound composition:

[a ₁(wilkinite acid non-soluble substance A ₁) a ₂(wollastonite acid non-soluble substance A ₂) a ₃(zinc oxide A ₃)

| _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ surperficial crude _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ |

·b ₁CaHPO ₄·b ₂CaSO ₄·b ₃SiO ₂·ZH ₂O]。

| _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ the polycrystalline state composite crystal _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ | substitute zinc oxide with this polycrystalline state compound composition and be used for the vulcanization of rubber, consumption is 2～5 parts, but its zinc oxide content only is 50～70%, and common zinc oxide is used for the vulcanization of rubber, consumption is 5 parts, and zinc oxide content is not less than 90%.

Embodiment 8

Get 600 order wollastonite powder and place acid-resistant container for 100 parts, add water and stir for 2000 parts, the Witco 70 of first Dropwise 5 part chloride 30% slowly adds the 75 parts of vitriol oil (98%H again under agitation condition ₂SO ₄), insulation reaction after 2 hours still aging about 4 hours after material solidifies, is taken out centrifuge dehydration, moisture about 60～75% filter cake mud, the clear liquid that dehydration leaches can be back to the present embodiment material.Filter cake mud is formed component: [a ₁(the acid non-soluble substance A in the wollastonite ₁) b ₁CaSO ₄B ₂SiO ₂ZH ₂O] n ₁(chlorinated paraffinic oil D ₁).Then, again the newly-generated water-aluminum hydroxide that contains, in 400 parts of butt materials mix with it, the cake mud after being mixed is dry in flasher, obtains polycrystalline state compound composition dry material:

[a ₁(wollastonite acid non-soluble substance A ₁) b ₁CaSO ₄B ₂SiO ₂B ₃Al (OH) ₃ZH ₂O] n ₁(chlorine

| _ _ _ _ _ _ _ _ _ surperficial crude _ _ _ _ _ _ _ _ _ | | _ _ _ _ _ _ _ _ _ the polycrystalline state composite crystal _ _ _ _ _ _ _ _ _ | fossil wax oil D ₁).

The pH value of this polycrystalline state compound composition is between 5.2～7.5, and proportion is less than 2.4, oil-absorption(number) ( ^DOPml/ _{100 compound compositions}) 〉=100 not only can be used as Rubber processing and chew and separate softening agent, and are more suitable for doing the fire extinguishing flame retardant filler in rubber, the plastics, also can be used as polish abrasive, and insulation is coated with (mud) material etc.

Embodiment 9

Get moisture about 60% dihydrate gypsum (CaSO ₄2H ₂O) cake mud and moisture about 80% silicate hydrate (SiO ₂NH ₂O) cake mud and moisture about 70% zinc subcarbonate (ZnCO ₃2Zn (OH) ₂) cake mud, by weight CaSO ₄: SiO ₂: ZnO=1.25: 1.25: 2.5～0.5: 0.5: 4 scope batching, mix and pinch evenly.Then blended cake mud drying and dehydrating, roast, 500～550 ℃ of roasting drop temperatures.In the roasting process, component A _iWith component B _iIn the non-refractory composition, be oxidized to corresponding oxide compound, crystal water [ZH ₂O] and organism ∑ n _iD _iThen be converted into gas evolution.Obtain the polycrystalline state compound composition at last:

a ₁CaSO ₄·b ₁SiO ₂·b ₂ZnO。

| the surface is crude | | _ _ _ the polycrystalline state composite crystal _ _ _ | this polycrystalline state compound composition has to chew to rubber separates and activates promotion sulfuration function, and the usage quantity in rubber compounding is 3～6 parts.

Embodiment 10

Get 200 order wollastonite powder and place acid-resistant container for 100 parts, add 2500 parts in water, stir, and under agitation condition, slowly add 75-80 part vitriol oil (98%H ₂SO ₄).When reaction terminating, pH value is 1-5.0, and the silicic acid in the solution can not precipitate, if the pH value of solution will be continued raise, precipitation of silica is come out, and can add 0.5 part of soluble inorganic salt again (as K in solution ₂SO ₄, MgSO ₄Deng) or drip small amount of alkali (as KOH, Mg (OH) ₂Deng).When the pH value of material when PH=5.0 is elevated to PH=10, take out slurries filtration, obtain the filtrate that contains silicic acid or silicon sol of PH=1-10, filtrate can be used as the raw material of multi-usage silicic acid (salt) series products such as preparation si-enriched colloidal sol, white carbon black.Filtration obtains, the filter cake mud of PH=1-10, and the drying dehydration is prepared into the polycrystalline state compound composition:

a ₁(be insoluble to the wollastonite powder A of acid ₁) b ₁CaSO ₄B ₂SiO ₂ZH ₂O.

| _ _ _ _ _ _ _ _ _ _ _ _ surface crude _ _ _ _ _ _ _ _ _ _ _ _ | | _ _ _ _ _ _ the polycrystalline state composite crystal _ _ _ _ _ _ _ _ _ | as with this polycrystalline state compound composition again with compounding rubber, have and well eat powder speed, the Mooney viscosity of gained sizing material is also little.Wherein, the compound composition of PH=1-5 has very strong anti-vulcanized rubber incipient scorch characteristic; The polycrystalline state compound composition of PH=9-10 has pair vulcanized rubber sulfuration to promote characteristic; The outer compound composition characteristic of two kinds of above PH=5-9 scopes is only managed unsatisfactory, but as reducing rubber Mooney viscosity filler good application prospects is arranged separately.

Embodiment 11

Get and contain Fe ₂O ₃% is less than 0.6 be narrower than and equal 400 order kaolin (Al ₂O ₃2SiO ₂2H ₂O) 120 parts, put it and in calcining kiln, burn to 800～1200 ℃, the assorted burn off that gives of the organic look that wherein is mingled with, move to a band insulation or heating is arranged and have in the stirring tank of steam outlet stand-by calcining being removed look assorted kaolin heat material; Other gets 10 parts and contains Fe ₂O ₃% is less than 0.2 be narrower than and equal 400 order wollastonite powder in acid-resistant container, adds water earlier and is stirred to uniform suspension for 30 parts, (contains H slowly adding 7.5 parts of vitriol oils ₂SO ₄98%), when the ropy material pH value is tending towards 4～4.5, can stop to stir, this is not separated out SiO as yet ₂NH ₂The sticky material of O slowly drops in the aforementioned stirring tank that fills about 1000 ℃ kaolin material; mix while adding; at this moment the water in the dope of Jia Ruing can be steamed by hot kaolin; hot kaolin powder can be diminished by extremely cold back powder in fragmentation; the cooling fast of whole material; add that solute (silicic acid, calcium sulfate) in the pan feeding is all separated out and separate out the surface of the calcium sulfate in dope attached to kaolin and previous big portion; when but steam drains temperature of charge just discharging when reducing to 100～110 ℃, obtain pulverous polycrystalline state compound composition:

a ₁(calcined kaolin) a ₂(acid does not have molten most wollastonite) a ₃(calcium sulfate of separating out earlier)

| _ _ _ _ _ _ _ _ _ be heated, acute cold, the molten effect of acid back particle fragmentation diminish surperficial crude _ _ _ _ _ _ _ _ _ |

B ₁(CaSO ₄2H ₂O) b ₂(SiO ₂NH ₂O) 120 parts.

| _ _ _ _ _ _ _ _ _ polycrystalline state composite junction crystal _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ | the whiteness of this routine product is not less than 90%, and pH value is in 5～7 scopes.This routine product is compared with existing calcined kaolin products, is added in rubber, the plastics, and the sizing material processing characteristics that adds this routine product is splendid; Be added on paper, it is fabulous that its anti-printing ink seal is worn performance; Its resistance to sinking can be not low; This routine method for making has utilized kaolin calcined waste heat to steam to remove moisture content to have more economic implications than the scheme that existing kaolin calcined waste heat is used to heat domestic water.Calcined kaolin among this embodiment also can change A such as calcining wilkinite, calcined diatomite, calcining perlite into, obtains corresponding white polycrystalline state compound composition at last:

a ₁(calcining wilkinite) a ₂(acid does not have molten most wollastonite) a ₃(calcium of separating out earlier) calcium

·b ₁(CaSO ₄·2H ₂O)·b ₂(SiO ₂·nH ₂O)、

a ₁(calcined diatomite) a ₂(acid does not have molten most wollastonite) a ₃(calcium sulfate of separating out earlier) calcium

·b ₁(CaSO ₄·2H ₂O)·b ₂(SiO ₂·nH ₂O)、

a ₁(calcining perlite) a ₂(acid does not have molten most wollastonite) a ₃(calcium sulfate of separating out earlier) calcium

B ₁(CaSO ₄2H ₂O) b ₂(SiO ₂NH ₂O) etc.,

Product also can be used as sorbent material, lagging material etc., but they have utilized waste heat, and production cost can descend, and three-waste free discharge.Also can be used on CaSO newly-generated in the water among this embodiment ₄2H ₂O2Al (OH) ₃, CaSO ₄2H ₂OZn (OH) ₂Moisture filter cake mud add respectively in A such as calcined kaolin, calcined diatomite, the calcining perlite material of heat, obtain corresponding white polycrystalline state compound composition at last:

a ₁(calcined kaolin) a ₂(calcium sulfate of separating out earlier) b ₁(CaSO ₄NH ₂O) b ₂(Al ₂O ₃),

a ₁(calcined diatomite) a ₃(calcium sulfate of separating out earlier) b ₁(CaSO ₄NH ₂O) b ₂(Al ₂O ₃),

a ₁(calcining perlite) a ₃(calcium sulfate of separating out earlier) b ₁(CaSO ₄NH ₂O) b ₂(Al ₂O ₃),

a ₁(calcined kaolin) a ₂(calcium sulfate of separating out earlier) b ₁(CaSO ₄) b ₂(ZnO),

a ₁(calcined diatomite) a ₃(calcium sulfate of separating out earlier) b ₁(CaSO ₄NH ₂O) b ₂(ZnO),

a ₁(calcining perlite) a ₃(calcium sulfate of separating out earlier) b ₁(CaSO ₄NH ₂O) b ₂(ZnO) etc.

Embodiment 12

Get 25 parts in the waste active carbon powder that the glucose bleaching workshop section dumps, 25 parts in the waste active carbon powder that the vitamins C bleaching workshop section dumps, each 25 parts in useless bleaching clay that grease-decolor workshop section dumps and waste active carbon powder, 100 parts of containers that place a band to stir of newly-generated moisture 70% amorphous silicic acid zinc clay, mix and stir add again after ageing half an hour 100 parts in machine oil stir evenly the polycrystalline state compound composition:

∑ a _i(various waste active carbon powder, useless bleaching clay) b ₁(ZnOXSiO ₂) (CaSO ₄) b ₃(SiO ₂)

| _ _ _ _ _ _ _ _ _ surperficial crude _ _ _ _ _ _ _ _ _ _ | | _ _ _ _ _ _ the polycrystalline state composite crystal _ _ _ _ _ _ _ _ _ |

∑ D _i(glucose, vitamins C, grease, machine oil),

This routine polycrystalline state compound composition is used for waste rubber regeneration and with regeneration such as pure machine oil, pitches good equally regeneration effect is arranged, but the foreign odor of gained sizing material flavor is much smaller; This example has been utilized useless discoloring agent slag charge.

Need to prove that in above embodiment and aforesaid A, B, the D material, the water soluble salt component appears in many places, this class water soluble salt component in polycrystalline state compound composition of the present invention, generally 15% of unsuitable overweight.Because water soluble salt content is no more than at 15% o'clock, in polycrystalline state compound composition great majority of the present invention are used, do not influence Rubber processing and use, the abnormal metal of wherein some, heavy metal etc. also have the effect of redox and heat resistanceheat resistant decomposition.The dewatered cake for preparing in the polycrystalline state compound composition technological process of the present invention generally can not washed, and filtrate is also reusable.Behind the filtration cakes torrefaction, be deposited in the water soluble salt crystallisate in the polycrystalline state compound composition, also can become the mixed crystal component of miniature " little file ", file broken height molecule chain link is contributed to some extent, and contain the polycrystalline state compound composition material sponginess of small amounts of water soluble salt component, in sizing material, be easy to disperse.

Embodiment 13

To natural rubber, regenerated rubber adopts polycrystalline state compound composition of the present invention to reduce the mooney viscosity fusion test, and it is as described in Table 2 to contrast organic quasi-tradition peptizer FL result.

Table 2 (embodiment 13)

Annotate: FL is the first upright corporate agent's in Taiwan a German product in the table 2, and its chemical constitution is: metallic soap class, the mixing of high boiling point alcohols and fatty acid

Thing.

Embodiment 14

Polycrystalline state compound composition of the present invention is applied in " natural rubber～fine particle calcium carbonate " sizing material, compares with " soap class～high boiling point alcohols～fatty acid " rubber processing aids " FL ", and the result is as described in Table 3.

Embodiment 15

Table 3 (embodiment 14)

Use polycrystalline state compound composition of the present invention and prepare regenerated rubber, the result sees table 4 for details.

Embodiment 16

As the separant of normal temperature method superfine grinding vulcanized rubber powder, polycrystalline state compound composition application result of the present invention sees table 5 for details.

In addition, utilize compound composition of the present invention to have the characteristic that reduces the sizing material mooney viscosity, can improve the dispersiveness of various auxiliary agent components in rubber, plastics material, and then minimizing component consumption, as pigment, when preparation look mother rubber unvulcanizate, 30～75% pigment that white compound composition dry powder can substitute among the look mother by weight 1: 1, next embodiment has just illustrated this point.

Embodiment 17

With the polycrystalline state compound composition among the embodiment 11:

a ₁(Al ₂O ₃2SiO ₂[calcined kaolin]) a ₂(CaSiO ₃[acid does not have molten most wollastonite]) a ₃(CaSO ₄) b ₁(CaSO ₄) b ₂(SiO ₂NHO ₂)

Table 4 (embodiment 15)

Table 5 embodiment 16

Prescription/example number	????1		????2	????3	????4	????5	????6	????7	????8	????9
											The tire micelle (5 order) that contains butadiene-styrene rubber	100 parts		100 parts	100 parts	-	-	-	-	-	-
(natural～along fourth) class tire micelle	-		-	-	(5 order) 100 parts	(5 order) 100 parts	(5 order) 100 parts	-	-	-
											(natural gum) white bottle stopper micelle	-		-	-	-	-	-	(5 order) 100 parts	(5 order) 100 parts	(5 order) 100 parts
(separant) lightweight charcoal acid calcium	-		-	-	10 parts	-	-	-	10 parts	-
											(separant) carbon black	-		3 parts	-	-	3 parts	-	-	-	-
Compound composition	-		-	3 parts (example 1 or example 5)	-	-	3 parts (example 2 or example 5)	-	-	3 parts (example 1 or example 2)
											The time output (Kg/h) of normal temperature method superfine grinding (device parameter: 110Kw, cutter diameter 300mm)		120 (40-120 orders)	180 (40-120 orders)	180 (40-120 orders)	160 (40 orders)	160 (40 orders)	160 (40 orders)	140 (40 orders)	200 (40 orders)	200 (40 orders)
Estimate		Yield poorly	Carbon pollution	Pollution-free	The ash height	Carbon pollution	Pollution-free	Yield poorly	The ash height	Pollution-free

Replace titanium dioxide, phthalocyanine blue pigment system white, blue rubber at 1: 1 with weight ratio, the result who substitutes is as follows: (seeing table 6 for details).

Execute example 18:

Make pigment with the polycrystalline state compound composition, establish the polycrystalline state compound composition and be following multiple array configuration:

a ₁(Al ₂O ₄SiO ₂2H ₂O) b ₁(CaSO ₄2H ₂OSiO ₂NH ₂O) b ₂(CdS/CdSe or CdS/Hg ₃S)---red or

a ₁(Al ₂O ₃2SiO ₂2H ₂O) b ₁(CaSO ₄2H ₂OSiO ₂NH ₂O) b ₂(lithol rubine or Tolylamine are bright red)---red or

Table 6 embodiment 17

Prescription/enforcement numbering	1	2	3	4	5	6	7	8	9	10
											Natural rubber (3#)	100 parts	100 parts	100 parts	100 parts	100 parts	100 parts	100 parts	100 parts	100 parts	100 parts
Titanium dioxide	20	15	10	5	5	/	/	/	/	/
											Phthalocyanine blue	/	/	/	/	/	2	1.5	1	0.5	0.5
Embodiment 11	0	5	10	15	0	0	0.5	1	1.5	0
											Irrelevant component	Constant	Constant	Constant	Constant	Constant	Constant	Constant	Constant	Constant	Constant
Prescription adds up to (part)	300	300	300	300	295	300	300	300	300	295
											Save pigment %	0	25	50	75	75	0	25	50	75	75
Tensile strength (MPa)	11.1	11.3	10.5	9.9	9.0	/	/	/	/	/
											Tensile yield (%)	783	800	780	775	760	/	/	/	/	/
Hardness (Shao Er A)	58	59	61	58	62	/	/	/	/	/
											Estimated aberration the same day	The 1# reference white	More close with 1# than extremely	Compare no color differnece with 2#	Compare no color differnece with 2#	Obviously dark than 1 #, 2 # looks	6# benchmark blueness	Compare no color differnece with 6#	Compare no color differnece with 6#	More close with 6# than extremely	Obviously dark than 6# look
Estimate aberration after 3 years	(1#) reference color	Compare no color differnece with (1#)	Compare no color differnece with (1#)	Compare no color differnece with (1#)	Obviously look dark than (1#)	(6#) reference color	Compare no color differnece with (6#)	Compare no color differnece with (6#)	Compare no color differnece with (6#)	Obviously dark than (6 #) look

a ₁(Al ₂O ₃2SiO ₂2H ₂O) or/and Mg ₅[Si ₄O ₁₀] ₂(HO) ₂4H ₂O is or/and CaSiO ₃CaCO ₃CaSO ₄15H ₂O) b ₁(ferric oxide) b ₂(Fe ₄[Fe (CN) ₆] ₃K ₄Fe (CN) ₆Or Fe ₄[Fe (CN) ₆] ₃(NH ₄) ₄Fe (CN) ₆) b ₃(Al (OH) ₃B ₄(CaSO ₄2H ₂OSiO ₂N2H ₂O)---blue or

a ₁(CaSiO ₃) a ₂(KMg ₃(AlSi ₃O ₁₀) (OH) ₂A ₃(CuSiO ₃NH ₂O) b ₁(CaSO ₄2H ₂OSiO ₂NH ₂O) b ₂(CuOxSiO ₂Or/and Na ₆Al ₄Si ₆S ₄O ₂)---blue or

a ₁(Mg ₄[(H ₂O) ₃| (OH) ₃| Si ₆O ₁₅] 3H ₂O) a ₂(CaSiO ₃) b ₁(CaSO ₄SiO ₂NH ₂O) b ₂(Fe ₂O ₃H ₂O or PbCrO ₄/ PbSO ₄/ Al (OH) ₃)-yellow or

a ₁(Mg ₄[(H ₂O) ₃| (OH) ₃| Si ₆O ₁₅] 3H ₂O) a ₂(CaSiO ₃) b ₁(CaSO ₄SiO ₂NH ₂O) b ₂(Fe ₂O ₃H ₂O or PbCrO ₄/ PbSO ₄/ Al (OH) ₃)---yellow or

a ₁(8Al ₂O ₃3SiO ₂3H ₂O) a ₂(CaSiO ₃CaCO ₃CaSO ₄15H ₂O) b ₁(Al (OH) ₃) b ₂a ₁(Al ₂O ₃2SiO ₂2H ₂O) or/and Mg ₅[Si ₄O ₁₀] ₂(HO) ₂4H ₂O is or/and (CaSO ₄2H ₂OSiO ₂NH ₂O) b ₃(diarylide yellow or the Chinese husky yellow)---yellow or

a ₁(3MgO4SiO ₂H ₂O) a ₂(CaSiO ₃) b ₁(CaSO ₄) b ₂(SiO ₂) b ₃(aPbCrO ₄BPbMoO ₄CPbSO ₄)---orange or

a ₁(SiO ₂NH ₂O) a ₂(KAl ₂(AlSi ₃O ₁₀) b ₁(TiO ₂) b ₂(Al (OH) ₃) b ₃(CaSO ₄0.5H ₂OSiO ₂NH ₂O)---the pearly-lustre look or

a ₁(Al ₂O ₃2SiO ₂) a ₂(Al ₂O ₃4SiO ₂) a ₃(SiO ₂) a ₄(CaSiO ₃) TiO ₂Invest the inside and outside surperficial b of ∑ aiAi ₁(TiO ₂) b ₂(CaSO ₄) b ₃(SiO ₂)---white, or the like, and the granularity of establishing these polycrystalline state compound composition pigment is narrower than and equals 400 orders, set polycrystalline state compound composition pigment they to have quality fluffy, be easy in the preparation filter and drying operation; The knot that set multiple array configuration design can reduce and eliminate the chromophoric group particulate gathers is convenient to make hyaluronic; The proportion of set polycrystalline state compound composition pigment is suitable, is assigned in to be difficult for layering in the coating; The same with aforesaid principle, set polycrystalline state compound composition pigment has file shape surface, and it very easily disperses rubber, in moulding; Make core pigment with the polycrystalline state compound composition that the present invention proposes, having broken through core pigment is the limitation of examining with few several materials such as mica, zinc sulfide white, resin only; It is abundant widely to coat array mode and select materials scope.

Embodiment 19

Make fire retardant with the polycrystalline state compound composition, establish the polycrystalline state compound composition and be following multiple array configuration:

(1) .a ₁(r-Al (OH) ₃) a ₂(Mg (OH) ₂) a ₃(CaSiO ₃CaCO ₃CaSO ₄15H ₂O) b ₁(Al (OH) ₃) b ₂(Sb ₂O ₃) b ₃(FeC ₂O ₄) b ₄(CaSO ₄2H ₂OSiO ₂NH ₂O), (material PH=5～9) or

(2) .a. ₁(Mg (OH) ₂) b ₁(Al (OH) ₃) b ₂(CaSO ₄2H ₂OSiO ₂NH ₂O), (material PH＞5) or

(3) .a ₁(Al (OH) ₃) a ₂(CaSiO ₃CaCO ₃CaSO ₄15H ₂O) b ₁CaSO ₄2H ₂O) b ₂(SiO ₂NH ₂O) b ₃(Al (OH) ₃), (material PH＞5) or

(4) .a ₁(Al ₂O ₃2SiO ₂) a ₂(Al ₂O ₃3H ₂O) b ₁(Al (OH) ₃) b ₂(CaSO ₄) b ₃(SiO ₂NH ₂O) n ₁(ammonium polyphosphate is or/and P contained compound and phosphorus～nitrogen compounds such as phosphoric acid fat, phosphonates, phosphites), (material PH=6～8) or

(5) .a ₁(P ₄) a ₂(Al ₂O ₃2SiO ₂) b ₁(Al (OH) ₃) b ₂(CaSO ₄) b ₃(SiO ₂) n ₁(tricresyl phosphate (2,3 dibromopropyl) ester etc. contains halophosphate and contains phosphonic acid ester), (material PH=6～7) or

Or the like, they all are rich in crystal water above-mentioned (1)～(6) formula polycrystalline state compound composition, can with the rapid reaction of hydrogen halide smog, the surface is polycrystalline state, adds rubber, plastic rubber material can both finely disperse.

Certainly, also can mix the polycrystalline state compound composition of preparation method's preparation of the present invention in the reinforcing fillers such as carbon black, white carbon black, potter's clay, lime carbonate, increase powder and " eaten into " speed by rubber, plastics material, the ratio of mixing in the reinforcing filler is reinforcing filler: compound composition dry powder=10: 1～2; Can also utilize the wide characteristic of compound composition pH value variable range of the present invention, reach and reduce the purpose of rubber with promotor, scorch retarder consumption.What be worth mentioning at last is that polycrystalline state compound composition of the present invention and preparation method thereof also can have application prospect in other field of chemical industry.

Claims (8)

1, a kind of polycrystalline state compound composition is characterized in that, described polycrystalline state compound composition can be used general formula [Σ a _iA _iΣ b _iB _iZH ₂O] Σ n _iD _iExpression,

A wherein _iBe following listed one or more the combination of powdered material A:

Chrysotile-asbestos (Mg₆[(OH) ₈/Si ₄O ₁₀]), crocidolite (Na₂Fe ₃ ^(II)Fe ₂ ^(III)[O，OH] ₂[Si ₈O ₂₂]), actinolite-asbestos (Na₂Ca ₄[Mg，Fe] ₁₀[(OH) ₂O ₂/Si ₆O ₁₄]), amosite (Fe^(II) _5.5Mg _1.5Si ₈O ₂₄H ₂), crocidllite ((Na, K, Ca)_3-4Mg ₆Fe ^(II)(Fe ^(II)，Al) _3-4[(OH) ₄/Si ₁₆O ₄₄]), the white tremolite-asbestos (Ca₂(Mg，Fe) ₅[(OH)/Si ₄O ₁₁] ₂), aluminite (Al₂[(OH) ₄/SO ₄]·7H ₂O), alunogen (Al₂[SO ₄] ₃·18H ₂O), alunite (KAl₃[(OH) ₆/(SO ₄) ₂]), basic aluminite (2Al₂O ₃·SO ₃·10H ₂O), iron alum stone (FeOAl₂O ₃·4SO ₃·22H ₂O), natroalunite (NaAl₃[(OH) ₆/(SO ₄) ₂]), pickeringite stone (MgOAl₂O ₃·4SO ₃·22H ₂O), bauxite (main composition: Al₂O ₃、SiO ₂Deng), diaspore (Al₂O ₃·nH ₂O), allophane (Al₂O ₃·SiO ₂·nH ₂O，3Al ₂O ₃·SiO ₂·15H ₂O), trolleite (Al₂(PO ₄)(OH) ₃·5H ₂O), zirlite (r-Al (OH)₃), augelite (Al₂[(OH) ₃/PO ₄]), useless bleaching clay (main composition: H₂Al ₂(SiO ₃) ₄·nH ₂O, (mixing) oils), aluminium ash (Al₂O ₃、 Al、Na ₃AlF ₆Deng), kaolin (Al₂O ₃·2SiO ₂·2H ₂O), calcined kaolin (Al₂O ₃·2SiO ₂), Emathlite (H₂Al ₂[SiO ₃] ₄·nH ₂O), bentonite (Al₂O ₃·4SiO ₂·2H ₂O), calcining bentonite (Al₂O ₃·4SiO ₂), potter's clay (main composition: Al₂O ₃·2SiO ₂·2H ₂O), attapulgite (Mg₅[Si ₄O ₁₀] ₂(OH) ₂·4H ₂O), earth (main composition: Al₂O ₃·2SiO ₂·2H ₂O、Fe ₂O ₃, organic matter), serpentine (Mg₆[Si ₄O ₁₀](OH) ₈), kolskite (5MgO4SiO₂·4H ₂O), magnesia cerolite (MgOSiO₂·H ₂O), the magnesia cerolite of nickel ((Mg, Ni)₃(OH) ₂(Si ₄O ₁₄)·H ₂O), hampdenite (Mg₃[OH] ₄[Si ₂O ₅]), cerolite (4MgOSiO₂·H ₂O), talcum (3MgO4SiO₂·H ₂O), attapulgite (5MgO8SiO₂·9H ₂O), clinoenstatite (α-MgOSiO₂), enstatite (β-MgOSiO₂), forsterite (2MgOSiO₂), enstatite (Mg₂[Si ₂O ₆]), hydrotalcite (Mg₆Al ₂[(OH) ₁₆/CO ₃]·4H ₂O), foliated talc (Mg₃[(OH) ₂/Si ₄O ₁₀], cordierite (2MgO2Al₂O ₃·5SiO ₂), palygorskite (Mg_2.5[(H ₂O) ₂|OH|Si ₄O ₁₀]·2H ₂O), diopside (CaOMgO2SiO₂), monticellite (CaOMgOSiO₂), manganolite (3CaOMgO2SiO₂)、Fe ₂O ₃·3SiO ₂·5H ₂O (chloropal), Al₂O ₃·SiO ₂·5H ₂O (allophane), 8Al₂O ₃·3SiO ₂·3H ₂O (schroetterite), 3MgO2Al₂O ₃·12SiO ₂·8H ₂O (lineae ablicantes stone), (Al, Fe)₂O ₃·2SiO ₂·2H ₂O (yellow kaolin), Mg₄Al(OH) ₂(SiO ₃) ₅·14H ₂O (saponite), 5MgO6SiO₂·4H ₂O (spadaite), (Ca, Na₂)Si ₂O ₅(silico-calcium sodium stone), (K₂，Ba)Al ₂(SiO ₂) (baryta feldspar), BaAl₂Si ₂O ₈(baryta fledspar), CaAl₂Si ₂O ₈(anorthite), Na₂O·2CaO·3Al ₂O ₃·9SiO ₂(carnegieite), 4MgO3SiO₂·6H ₂O (hydroserpentine), CaFe (SiO₃) (hedenbergite), Na₂O·Fe ₂O ₃·4SiO ₂(achmatite achmite), H₂(Ca，Mg) ₂·Si ₂O ₇(jurupaite), Ca₂ZnSi ₂O ₇(zinc scapolite), 7MgO8Al₂O ₃·10SiO ₂·14H ₂O (rumpfite), K₂O·Al ₂O ₃·3SiO ₂(kaliophilite), 4 (NaK) CaAl₃(SiO ₄) ₃·4(NaK)Cl·(Na，K)SiO ₄(buttress shaft nepheline), Na₄(AlCl)Al ₂(SiO ₄) ₃(sodalite), Na₂Ca(NaSO ₄Al)Al ₂(SiO ₄) ₃(hauynite), Na₄(NaSO ₄Al)Al ₂(SiO ₄) ₃(noselite), Mg₃Al ₂(SiO ₄) ₃(pyrope garnet), Fe₃Al ₂(SiO ₄) ₃(iron aluminium garnet), 3CaOFe₂O ₃·3SiO ₂(brownmillerite garnet), 2 (Mg, Fe) OSiO₂(chrysolite), 2FeOSiO₂(fayalite), Zn₂SiO ₄(willemite), H₂Cu ₇(CuOH) ₃(SiO ₃) ₁₂(fiber copper silicon ore deposit), Ca₄Al ₆Si ₆O ₂₅(meionite), Na₄Al ₂Si ₉O ₂₄Cl (marialite), (Ca, Na₂) ₃Al ₂(SiO ₄) ₃(sarcolite), Na₂(Ca，Mg) ₁₁(Al，Fe) ₄(SiO ₄) ₉(scapolite), Ca₃Al ₂Si ₂O ₁₀(gehetinite), Al₂SiO ₅(sillimanite), (H, K, Na)₂(Mg，Ca)(Al，Fe) ₂(Si ₂O ₅) ₅₉H ₂O (melilite), HCa₂Al ₃Si ₃O ₁₃(clinozoisite), H₄CaAl ₂Si ₂O ₁₀(lawsonite), 2 (Ca, Mg) O5 (Al, Fe)₂O ₃·6SiO ₂(sial calcium magnesite), 8Al₂O ₃·B ₂O ₃·6SiO ₂·H ₂O (dumortierite), (AlO)₄(AlOH)Fe(SiO ₄) ₄(staurolite), MgOAl₂O ₃·SiO ₂(kornerupine), Ca₂SiO ₄·H ₂O (okenite), H₂CaSi ₂O ₆·H ₂O (silicoglaserite), H₂Ca ₂Si ₃O ₉·H ₂O (gyrolite), 4H₂CaSiO ₄·3H ₂O (monocline silicoglaserite), 2CaSiO₅·H ₂O (riversideite), 3 (Ca, Mg) O2 (Al, Fe)₂O ₃·4SiO ₂·2H ₂O (beryl), K₂O·8CaO·16SiO ₂·16H ₂O (fish-eye stone), 3 (Ca, K₂，Na ₂)Si ₁₀O ₂₄·2OH ₂O (modenite), H₄(Sr，Ba，Ca)Al ₂(SiO ₃) ₆·3H ₂O (brewsterite) H₄CaAl ₂(SiO ₃) ₆·3H ₂O (stripping zeolite), (K₂Ba)Al ₂Si ₅O ₁₄·5H ₂O (barium staurolite), (K₂Ca)Al ₂(SiO ₄) ₃·4H ₂O (phillipsite), (Ca, Na) Al₂Si ₄O ₁₂·6H ₂O (tiltedly analcime), (Na₂，Ca)Al ₂Si ₄O ₁₂·6H ₂O (the oblique zeolite of sodium), Ca₂Al ₃O ₁₀·5H ₂O (the oblique zeolite of calcium), Na₂Al ₂Si ₃O ₁₀·2H ₂O (sodalite), Na₂Ca ₂Al ₅(SiO ₄) ₅·5H ₂O (karphostilibite), (Ca, Na₂)O·2Al ₂O ₃·3SiO ₂·4H ₂O (porcelain laubanite), CaAl₂Si ₇O ₁₈·7H ₂O (light thin zeolite), Na₈Ca ₄Si ₂₄Al ₁₆O ₂₈·28H ₂O (erionite), Ca₃Al ₂(SiO ₃) ₆·H ₂O (single zeolite), 4CaO3Al₂O ₃·6SiO ₂·H ₂O (zoisite), thaumasite (CaSiO₃·CaCO ₃·CaSO ₄·15H ₂O), wollastonite (CaOSiO₂), okenite (Ca₁₂[(OH) ₁₄|Si ₆O ₁₇]), Hydrogrossular (Ca₃Al ₂[SiO ₄] ₃), hibschite (Ca₃Al ₂[OH] ₄[SiO ₄] ₂), heulandite (Ca[Al₂Si ₇O ₁₈]·6H ₂O), analcime (Na[AlSi₂O ₆]·H ₂O), scolecite (Ca[Al₂Si ₃O ₁₀]·3H ₂O), foresite (Ca[Al₂Si ₇O ₁₈]·7H ₂O), antiedrite (Ba[Al₂Si ₃O ₁₀]·3H ₂O), desmine (Ca[Al₂Si ₇O ₁₈]·7H ₂O), laumontite (Ca[AlSi₁₂O ₆] ₂·4H ₂O), zeolite (Na₂O·Al ₂O ₃·2SiO ₂·nH ₂O), aksaite (Mg[B₆O ₇(OH) ₂]·4H ₂O), boromagnesite (Mg₂[B ₂O ₄(OH)] (OH)), carbon boron-calcium-magnesium stone (4CaOMgO2B₂O ₃·2CO ₂·3H ₂O), calciborite (Ca[BO₂] ₂), datolite (CaB[OH|SiO₄]), pinnoite (Mg[B₂O(OH) ₆], Ke's hydrotalcite (Mg₁₀Fe ₂(CO ₃)(OH) ₂₄·2H ₂O), the tremolite (Ca₂(Mg·Fe ₈) ₅(OH/Si ₄O ₁₁) ₂), hypersthene ((Fe, Mg)₂[Si ₂O ₆]), iron sepiolite ((MG, Fe^(III)，Fe ^(II)) _≤4[(H ₂O) ₃|(OH) ₂|Si ₆O ₁₅]·3H ₂O), lazulite ((Mg, Fe^(II)Al ₂[OH|PO ₄] ₂, vermiculite ((Mg, Fe^(II)，Fe ^(III)) ₃[(Si，Al) ₄O ₁₀](OH) ₂·H ₂O), bronzite ((Mg, Fe)₂[Si ₂O ₆]), chlorite ((Mg, Fe)_6-2X(Al，Fe) _2X[OH] ₈{Si _4-2XAl _2XO ₁₀), nephrite (Ca₂(Mg，Fe) ₅[OH] ₂[Si ₈O ₂₂]), sepiolite (Mg₄[(H ₂O) ₃|(OH) ₂|Si ₆O ₁₅]·3H ₂O), iron magnesium amphibole ((Mg, Fe)₁₄[(OH) ₄|Si ₁₆O ₄₄]), breunnerite ((Fe, Mg) CO₃), pictoamesite ((Mg, Fe)₄Al ₂[OH] ₈{Si ₂Al ₂O ₁₀), vesuvian (Ca₁₀(Mg，Fe) ₂Al[(OH) ₄|(SiO ₄) ₅|Si ₁₂O ₇]), actinolite (Na₂Ca ₄[Mg，Fe] ₁₀[(OH) ₂O ₂|Si ₁₀O ₄₄]), fine magnesite (MgCO₃·Mg(OH) ₂·3H ₂O), shepardite (Mg (OH)₂), anhydrous smooth halogen, Bai Shi (KClMgCl₂), Dou chlorite ((Mg, Al)₃[(OH) ₂|AlSi ₃O ₁₀]Mg ₃(OH) ₆), dolomite ((CaCO₃·MgCO ₃), ankerite (CaFe[CO₃] ₂), gypsum (CaSO₄·1/2H ₂O or CaSO₄·2H ₂O), calcium phosphate (Ca₃(PO ₄) ₂), calcite (CaCO₃), cancrinite ((Na, Ca)₄[CO ₃|(H ₂O) _0-2|(AlSiO ₄) ₆]), brushite (CaH[PO₄]·2H ₂O), prehnite (Ca₂Al ₂[(OH) ₂|Si ₃O ₁₀]), aspidelite (CaTiOSiO₄), zoisite (Ca₂Al ₂[O|OH|SiO ₄|Si ₂O ₇]), allochite (Ca₂(Al，Fe ^(III)Al ₂[O|OH|SiO ₄|Si ₂O ₇]), callainite (Al[PO₄]·2H ₂O), galapectite (Al₂SiO ₅(OH) ₄·2H ₂O), andalusite (AlOAl[SiO₄]), pyrophyllite (Al₂O ₃·4SiO ₂·H ₂O), iron galapectite ((Al, Fe)₂O ₃·2SiO ₂·nH ₂O), illite (K_＜1(Al，Fe) ₂(OH) ₂{AlSi ₃O ₁₀}·nH ₂O, chamosite (Fe₄Al ₂[OH] ₈{Si ₃AlO ₁₀), feldspar (Na, K, Al₂SiO ₃), Juanyingshi (K₂O·3Al ₂O ₃·6SiO ₂·2H ₂O), montmorillonite ((Al_1.67，Mg _0.33)[(OH) ₂|Si ₄O ₁₀]Na _0.33(H ₂O) ₄), albite (Na{AlSi₃O ₈), orthoclase (K[AlSi₃O ₈]), ararantite (Fe₂O ₃·2SO ₃·7H ₂O), monocline natrojarosite (Na₂O·Fe ₂O ₃·4SO ₃·12H ₂O), delvauxite (Fe₂ ^(III)(OH) ₃PO ₄·nH ₂O), ilmenite (FeTiO₃), steel-making slag powder (Main Ingredients and Appearance: Fe, Fe₂O ₃、SiO ₂Deng), steel mill's chimney soot (main composition: Fe₂O ₃、SiO ₂Deng), monheimite (ZnFe (CO₃) ₂), zinc～botryogen (2ZnOFe₂O ₃·4SiO ₃·15H ₂O), carbon sodium silicoglaserite (KNaCa₄Si ₈O ₁₈(CO ₃) ₄(Fe，OH)H ₂O), zincocopiapite (ZnO2Fe₂O ₃·6SO ₃·21H ₂O), sauconite ((Zn, Mg, Al, Fe)₃(OH) ₂(Si，Al) ₄O ₁₀), smithsonite (ZnCO₃), marionite (Zn₅[(OH) ₃|CO ₃] ₂), aurichalcite ((Zn, Cu)₅[(OH) ₃|CO ₃] ₂), chessy copper (Cu₃[OH|CO ₃] ₂), warringtonite (Cu₄(OH) ₆SO ₄), chrysocolla (CuSiO₃·nH ₂O), oblique side's malachite (Cu₅(OH) ₄(PO ₄) ₂·nH ₂O), dioptase (Cu₆[Si ₆O ₁₈]·6H ₂O), blue stone (CuSO₄·5H ₂O), cerine ((Ce, Ca)₄(Al，Mg，Fe) ₆[OH] ₂O ₃[Si ₂O ₇]), rinkolite (CeNa₂Ca ₄Ti[Si ₄O ₁₅F ₃]), nepouite (3 (Ni, Mg)_0.2SiO ₂·2H ₂O), the chlorite ((Mg, Ni) that rises_3.6Al ₂[OH] ₈{Si ₃(Al，Si)O ₁₀), phosphorus aluminium strontium alum ((Sr, Ca, Mg)₃Al ₁₂[PO ₄] ₄[SO ₄] ₂(OH) ₂₆), perlite or foam powder (acid glassy lava master composition: SiO₂、 Al ₂O ₃、K ₂O、CaO、Fe ₂O ₃), assorted cullet (main composition: Na₂O、K ₂O、CaO、SiO ₂Deng), assorted waste ceramic (main composition: Al₂O ₃、SiO ₂Deng), opal (SiO₂·nH ₂O), diatomite (main composition: SiO₂·nH ₂O), calcining diatomite (main composition: SiO₂), potassium silicate (K₂O·XSiO ₂), sodium metasilicate (Na₂O·XSiO ₂), calcium silicates (CaOXSiO₂), strontium silicate (SrOXSiO₂), barium silicate (BaOXSiO₂), alumina silicate (Al₂O ₃·XSiO ₂), zinc silicate (ZnOXSiO₂), zinc oxide (ZnO), zinc gray (ZnO, Zn etc.), flyash (main composition: SiO₂、Al ₂O ₃、Fe ₂O ₃Deng), zinc molybdate (ZnMoO₄), molybdenum sesquioxide (MoO₃), cement (main composition: Al₂O ₃·XSiO ₂、CaO·XSiO ₂、Fe ₂O ₃Deng), waste active carbon (C), strontium carbonate (SrCO₃), brium carbonate (BaCO₃), muscovite (KAl₂(AlSi ₃O ₁₀)(OH) ₃), biotite (K (Mg, Fe)₃(Al Si ₃O ₁₀)·(OH) ₂), phlogopite (KMg₃(AlSi ₃O ₁₀)(OH) ₂), calcium aluminate (CaOXAl₂O ₃), iron calcium aluminate (XCaOYAl₂O ₃·ZFe ₂O ₃), (carried the residue of gained after boron by the boron rock pruinescence, main composition is boron mud: CaO, MgO, SiO₂Deng), (salt electrolyte is discharged in the removal of impurities process slag mud, main composition is electrolysis melt cinder mud: BaSO₄、SiO ₂、 Al ₂O ₃Deng), flower bulb alkaline residue mud (from the slag mud that the sodium silicate solution purification section is discharged, main composition: Na₂O·XSiO ₂、Al ₂O ₃、Fe ₂O ₃、CaO·XSiO ₂Deng), (generated through sulfuric acid acidation organic acid processed time institute by organic acid calcium, main composition is organic acid (as citric acid, lactic acid) gypsum tailings: CaSO₄·2H ₂O, active carbon, organic acid etc.), the barium slag (mainly contains BaSiO by carrying the melt slag that barium sulphide produces₃、BaCO ₃, BaS etc.), the strontium slag (mainly contains strontium sulfide SrS, SrCO by carrying the melt slag that strontium sulfide produces₃、SrSiO ₃Deng), coal dust (C), colliery powder (C, SiO₂), red (red) body refuse (aCaObMgOcNa of alumina producer₂O·dK ₂O·eSiO ₂·fAl ₂O ₃·gFe ₂O ₃·hTiO ₂·nOH·mH ₂O), shell is or/and coral powder (CaCO₃), Si-Al molecular sieve, bone meal, charcoal powder, wood chip powder, rice husk powder, peanut hull meal, (oak) bark powder, coconut palm palm fibre (wood) silk powder, (crops) tangerine bar powder, (giving up) phenol-formaldehyde resin powder, bamboo powder, paper scrap powder, (fabric) fiber powder, red phosphorus (P₄)；

B _iThe combination of newly-generated substance B in solution for following listed one or more:

Calcium sulfate (CaSO₄·nH ₂O), calcium monohydrogen phosphate (CaHPO₄), calcium phosphate (Ca₃(PO ₄) ₂), calcirm-fluoride (CaF₂) strontium fluoride (SrF₂), barium fluoride (BaF₂), magnesium fluoride (MgF₂), magnesium hydroxide (Mg (OH)₂), magnesium carbonate (MgCO₃), magnesium monohydrogen phosphate (MgHPO₄), silicic acid (H₂SiO ₃Or SiO₂·nH ₂O), magnesium silicate (MgOXSiO₂), calcium silicates (CaOXSiO₂), strontium silicate (SrOXSiO₂), barium silicate (BaOXSiO₂), alumina silicate (Al₂O ₃·XSiO ₂), zinc silicate (ZnOXSiO₂), zinc carbonate (ZnCO₃), basic zinc carbonate (ZnCO₃·2Zn(OH) ₂), trbasic zinc phosphate (Zn₃(PO ₄) ₂), basic zinc sulfate (ZnSO₄·4Zn(OH) ₂), zinc sulphide (ZnS), zinc hydroxide (Zn (OH)₂), aluminium hydroxide (Al (OH)₃), iron hydroxide (Fe (OH)₃), alkali formula iron chloride (FeCl (OH)₂、FeCl ₂(OH)), ferric subsulfate (FeSO₄(OH)), strontium sulfate (SrSO₄), barium sulfate (BaSO₄), sodium chloride crystallization (NaCl), sulfate crystal (Na₂SO ₄), sodium phosphate (Na₃PO ₄), sodium hydrogen phosphate crystallization (Na₂HPO ₄), potassium chloride crystallization (KCl), potassium sulfate crystallization (K₂SO ₄), potassium phosphate crystallization (K₃PO ₄), dipotassium hydrogen phosphate crystallization (K₂HPO ₄), potassium fluoride crystallization (KF), ferrous sulfate crystallization (FeSO₄·nH ₂O), zinc sulfate crystallization (ZnSO₄·nH ₂O), metatitanic acid (TiO₂·XH ₂O), (without what calcine) lithopone (aZnSbBaSO₄), the ferrous crystallization (FeHPO of phosphoric acid hydrogen₄·nH ₂O), frerrous chloride crystallization (FeCl₂·nH ₂O), zinc chloride crystallization (ZnCl₂·nH ₂O), cerium hydroxide (Ce (OH)₃), cerous phosphate (CePO₄), Kocide SD (Cu (OH)₂), cupric phosphate (Cu₃(PO ₄) ₂), nickel hydroxide (Ni (OH)₂), nickelous carbonate (NiCO₃), boric acid (H₃BO ₃), metaboric acid (HBO₂), sodium tetraborate (Na₂B ₄O ₇·nH ₂O), Firebrake ZB (XZnOYB₂O ₃·ZH ₂O), magnesium sulfate (MgSO₄·7H ₂O), Sodium Aluminium Carbonate Basic (NaAl (OH)₂CO ₃), basic lead carbonate (2PbCO₃·Pb(OH) ₂), sodium acid carbonate (NaHCO₃), titanyl sulfate (TiOSO₄), aluminium dihydrogen phosphate (Al (H₂PO ₄) ₃), potassium titanate (K₂TiO ₃), ammonium magnesium phosphate (MgMH₄PO ₄·6H ₂O), PTPP (K₅P ₃O ₁₀), barium metaphosphate (Ba (PO₃) ₂), kodalk (Na₂B ₂O ₄), potassium pentaborate (KB₅O ₈·4H ₂O), aluminium borate (2Al₂O ₃·B ₂O ₃·3H ₂O), bismoclite (BiOCl), aluminum phosphate (AlPO₄), calcium molybdate (CaMoO₄), ammonium molybdate (NH₄) ₆Mo ₇O ₂₄·4H ₂O), orthophosphoric acid iron (FePO₄·2H ₂O), potassium ferric oxalate (KFe (C₂O ₄) ₂), ferrous oxalate (FeC₂O ₄), stannic acid zinc (ZnSnO₃·4H ₂O), calcium citrate (Ca₃(C ₆H ₅O ₇) ₂), calcium lactate (CaC₃H ₅O ₃), calcium oxalate (CaC₂O ₄), calper calcium peroxide (CaO₂), hydrogen peroxide calcium sulfate adduct (CaSO₄·nH ₂O ₂), hydrogen peroxide sulfate crystal (Na₂SO ₄·nH ₂O ₂), hydrogen peroxide cupric sulphate crystal (CuSO₄·nH ₂O ₂), calcium sulfite (CaSO₃), sodium sulfite crystallization (Na₂SO ₃), sodium pyrosulfite (potassium) crystallization (Na₂S ₂O ₅Or/and (K₂S ₂O ₅)), sodium dithionite (potassium) crystallization (Na2S₂O ₄Or/and (K₂S ₂O ₄)), sodium bisulphite formaldehyde crystallization (NaHSO₂CH ₂O·2H ₂O), zinc oxalate crystallization (ZnC₂O ₄·nH ₂O), ferrous oxalate zinc crystallization (FeC₂O ₄·ZnC ₂O ₄·nH ₂O), ferrous sulfate zinc crystallization (FeSO₄·ZnSO ₄·nH ₂O), zinc dithionite crystallization (ZnS₂O ₄), basic magnesium carbonate (MgCO₃·Mg(OH) ₂), sodium thiosulfate (potassium) crystallization (Na₂S ₂O ₃Or/and (K₂S ₂O ₃)), ferrous sulfate copper crystallization (FeSO₄·nH ₂O), the ferrous zinc crystallization of phosphoric acid hydrogen (ZnHPO₄·FeHPO ₄·nH ₂O), the ferrous copper crystallization of phosphoric acid hydrogen (CuHPO₄·FeHPO ₄·nH ₂O), chromium hydroxide (Cr (OH)₃), metatitanic acid (H₂TiO ₃), iron oxide black (Te₃O ₄), barba hispanica (Fe₄[Fe(CN) ₆] ₃·K ₄Fe(CN) ₆, or Fe₄[Fe(CN) ₆] ₃·(NH ₄) ₄Fe(CN) ₆), iron oxide yellow (Fe₂O ₃·H ₂O), iron oxide red (Fe₂O ₃), medium chrome yellow (PbCrO₄/PbSO ₄/Al(OH) ₃), molybdate red (aPbCrO₄·bPbMoO ₄·cPbSO ₄), chrome yellow (PbCrO₄Or PbSO₄·X[PbCrO ₄·Pb(OH) ₂]), cadmium red (CdS/CdSe), cadmium yellow (CdS/ZnS), G cadmium scarlet (CdS/HgS), cupric silicate (CuOXSiO₂), antimony oxide (Sb₂O ₃), ultramarine (Na₆Al ₄Si ₆S ₄O ₂), bright red, the benzidine yellow of phthalocyanine blue, phthalocyanine green, alkaline royal blue color lake, Fast Malachite Blue lake, lithol rubine, toluidines, the husky Huang of the Chinese, the bright red LC of rubber, golden red antimony;

D _iCombination for the organism D of following listed one or more:

Rosin, staybelite, dimethylbenzene Gum Rosin, special octyl phenol urea formaldehyde, coumarone, Persea cubeba (Jiao) oil, alizarin assistant, Yatall MA, Stockholm tar, oleum gossypii seminis, rape seed oil, soybean oil, plam oil, Cai spend seed oil, sweet oil, machine oil, white oil, aromatic hydrocarbon oil, naphthenic oil, paraffin oil, third fractional oil, six line oil, (giving up) rubber hot tearing oil, (giving up) plastics hot tearing oil, (mixing) oleic acid, C _4～18Lipid acid, Vaseline, paraffin, halogenated paraffin, pitch, dark substitute, white factice, styrene resin, low molecular polyethylene, resol, polyisobutene, polybutene, stearic acid, sodium stearate, calcium stearate, Magnesium Stearate, barium stearate, Zinic stearas, ethylenediamine tetraacetic acid (EDTA) (Asia) iron, sylvic acid is ferrous, zinc abietate, the ferrous zinc of sylvic acid, Ferrous Gluconate zinc, amylalcohol, hexanol, enanthol, octanol, decyl alcohol, lauryl alcohol, tetradecyl alcohol, hexadecanol, stearyl alcohol, cyclopentanol, hexalin, phenylcarbinol, ethylene glycol, propylene glycol, glycerol, 2-Ethylhexyl Alcohol, sec-n-octyl alcohol, lauryl alcohol, Terpineol 350, high carbon number (C _7～18) mixed fatty alcohol, tetramethylolmethane, Xylitol, dipropylene glycol, dioctyl phthalate (DOP), dibutyl phthalate, diisobutyl phthalate, dialphanyl phthalate, tributyl phosphate, triethyl phosphate, triphenylphosphate, Tritolyl Phosphate, pentabromodiphenyl oxide, the tetrabromo cyclooctane, two bromotrifluoromethane dibromo-cyclohexanes, decabromodiphynly oxide, pentabromotoluene, hexabromocyclododecane, tetrabromo-bisphenol s two (2, the 3-dibromopropyl) ether, Brominated Polystyrene (high molecular), poly-Dowspray 9, Brominated Polystyrene (lower molecular weight), tetrabromophthalate diesters/glycol, the tetrabromo Dipentaerythritol, bromine ethene, 2, the 3-dibromo-propanol, tricresyl phosphate (2-chloroethyl) ester, tricresyl phosphate (1,3-two chloro-2-propyl group) ester, tricresyl phosphate (1-chloro-2-propyl group) ester, dimethyl methyl phosphonate, diethyl ethylphosphate, the oligomeric chloroformate ethyl phosphonate, ammonium polyphosphate (APP), the terephthalic acid dibutyl ester, the adipic acid dibutyl ester, hexanodioic acid two-2-(ethyl hexyl) ester, sebacic acid two-2-(ethyl hexyl) ester, two-[3-triethoxyl silane propyl group] tetrasulfide, r-sulfydryl propyl trimethoxy silicane, dimethyldimethoxysil,ne, methyltrimethoxy silane, methyl triacetoxysilane, Union carbide A-162, tetramethoxy-silicane, tetraethoxysilane, dimethyldiethoxysilane, the 2-4 thiol benzothiazole, curing Dibenzo thiazole, 2-thiol benzothiazole zinc salt, N, N-diethylbenzene a pair of horses going side by side thiazole-2-sulphenamide, N-cyclohexyl benzothiazole sulfonamide, N, N-dicyclohexyl-2-benzothiazole sulfonamide, N-oxygen diethylene-2-benzothiazole sulfonamide, natural rubber; styrene-butadiene rubber(SBR); cis-1,4-polybutadiene rubber; polyisoprene rubber; (halogenation) isoprene-isobutylene rubber; paracril; ethylene-propylene rubber(EPR); chloroprene rubber; urethanes; regenerated rubber; (sulfuration) rubber powder; salicylic acid; citric acid; oxalic acid; lactic acid; tartrate; glucose; vitamins C; titanic acid ester; Σ ai, Σ b, Z, Σ ni are mole coefficient; [Σ a _iA _iΣ b _iB _iZH ₂O] material 〉=50%, " Σ n _iD _i" material＜50%; Contain polycrystalline state compound composition [Σ a _iA _iΣ b _iB _iZH ₂O] PH=1～10 of 10% aqueous solution; Described polycrystalline state compound composition, its formulation are dry powder or grain or piece, contain Σ n _iD _iBe oil loam shape or blob of viscose shape or micelle shape or mixing glue more for a long time.

2, polycrystalline state compound composition as claimed in claim 1, its preparation method is characterised in that:

A, choose one or more A powder constituent batching A _i

B, employing acid molten or alkaline etching or calcining method are with A _iBatching is processed into just as the crude table of coal scoriform

The face composition;

C, with above-mentioned composition with crude surface or mixture powder as core material Σ a _iA _iWith in the different various materials of the newly-generated crystal formation of aqueous phase or/and the file shape shell Σ b that one or more unformed material is formed _iB _iZH ₂O mixes and carries out physical reaction generation crude hard polycrystalline state compound composition [the Σ a in surface _iA _iΣ b _iB _iZH ₂O];

D, at selected Σ a _iA _iIn the dry material of component batching or generate Σ b _iB _iZH ₂In the reaction soln of O component, add the defoamer and the separant Σ n that prevent the solution bumping _iD _i, generate more small polycrystalline state compound composition xln [Σ a _iA _iΣ b _iB _iZH ₂O] Σ n _iD _i

The water of on a small quantity necessary usefulness in e, the preparation process leaches the back and reuses;

F, again with polycrystalline state compound composition [the Σ a that makes _iA _iΣ b _iB _iZH ₂O] or [Σ a _iA _iΣ b _iB _iZH ₂O] Σ n _iD _iWith rubber, mould or with its processing usual auxiliaries mix, carry out special physics and chemistry modification, further prepare purposes polycrystalline state compound composition widely.

3, polycrystalline state compound composition according to claim 1 is characterized in that: the polycrystalline state compound composition adds rubber and can be used as separant and preparation low mooney viscosity rubber and odorless regenerated rubber; Add in the zinc oxide that rubber ingredients use and can make mixing, the compound polycrystalline state compound composition that contains zinc oxide, can increase the dispersiveness of zinc oxide and mould, the plasticity-of glue stuff compounding; Add rubber, mould the mixing, the compound polycrystalline state compound composition that contain pigment with making in colour batch or the pigment, can increase dispersing of pigments and delamination resistance; Add aqueous rubber, mould with anti-aging agent, rubber and use in the vulcanization accelerator, can be used as absorption carrier; Add in the reinforcing fillers such as carbon black, white carbon black, potter's clay, kaolin, lime carbonate, can increase the speed that powder " is eaten into " by rubber, plastic rubber material; Add and can be used as weighting agent and coating pigment in the paper; Can make sorbent material, powder fire extinguishing agent, fire retardant, abrasive material.

4, according to the preparation method of the described polycrystalline state compound composition of claim 2, it is characterized in that A _iThe size of powder ingredients is: can not be narrower than or equal 200 orders by acid or the consoluet material particular diameter of alkali lye; Can be coarser than 5 orders by the material particular diameter of acid or alkali dissolution fully, the Ai batching particle diameter that carries out calcination processing all requires to be narrower than or to equal 200 orders.

5, according to the preparation method of the described polycrystalline state compound composition of claim 2, it is characterized in that, in and the alkali used of excess acid can be alkalescence batching among the A, also can be soda ash (Na ₂CO ₃), caustic soda (NaOH), bubble flower alkali (Na ₂OXSiO ₂), sodium sulphite (Na ₂S), lime (CaO), slaked lime (Ca (OH) ₂), lime carbonate (CaCO ₃), ironic hydroxide (Fe (OH) ₃); The Ai material is carried out the molten processing of alkali, and alkali all can be excessive slightly, and excessive alkali can filter or add acid and be removed after alkaline purification.

6, according to the preparation method of the described polycrystalline state compound composition of claim 2, it is characterized in that, the material that contains the more amount free-water [Σ a _iA _iΣ b _iB _iZH ₂O] or Σ b _iB _iZH ₂O or [Σ a _iA _iΣ b _iB _iZH ₂O] Σ n _iD _iOr Σ b _iB _iZH ₂O Σ n _iD _iSlurry mud again be narrower than or equal 200 purpose powder Σ a _iA _i, become to remove from loose shape cake mud material or the dry material that filters operation than 1.5: 8.5～8: 2 ratio mixs in butt.

7, according to claim 1,2 described polycrystalline state compound compositions and preparation method thereof, it is characterized in that, by blending ratio be: [Σ a _iA _iΣ b _iB _iZH ₂O] or Σ b _iB _iZH ₂O material＞50%, " Σ n _iD _i" material＜50%, [the Σ a that contains free-water or dried (powder, grain, piece) shape _iA _iΣ b _iB _iZH ₂O] or Σ b _iB _iZH ₂O material and organism Σ n _iD _iMix, obtain bulky powder shape, oil loam shape, blob of viscose shape, micelle shape, mixing gelationus multiple formulation polycrystalline state compound composition [Σ a _iA _iΣ b _iB _iZH ₂O] Σ n _iD _iOr Σ b _iB _iZH ₂O _iΣ n _iD.

8, according to claim 1 and 2 described polycrystalline state compound compositions and preparation method thereof, it is characterized in that, can starch the mud drying and dehydrating to compound composition and make dried (powder, grain, piece) shape polycrystalline state compound composition [Σ a _iA _iΣ b _iB _iZH ₂O] Σ n _iD _iOr Σ b _iB _iZH ₂O Σ n _iD _iOr Σ a _iA _iΣ b _iB _iZH ₂O or Σ b _iB _iZH ₂O, roast obtain dehydration polycrystalline state compound composition [Σ a _iA _iΣ b _iB _i] or Σ b _iB _iAnd A _i, B _iBecome corresponding anhydrous salt or oxide compound.