CN1534744A - Field effect transistor structure possessing strain silicon germanium layer beaping crystal and its manufacturing method - Google Patents

Field effect transistor structure possessing strain silicon germanium layer beaping crystal and its manufacturing method Download PDF

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CN1534744A
CN1534744A CNA031079725A CN03107972A CN1534744A CN 1534744 A CN1534744 A CN 1534744A CN A031079725 A CNA031079725 A CN A031079725A CN 03107972 A CN03107972 A CN 03107972A CN 1534744 A CN1534744 A CN 1534744A
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strain
layer
silicon
heap
stone
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CN1277296C (en
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杨育佳
林俊杰
杨富量
胡正明
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Taiwan Semiconductor Manufacturing Co TSMC Ltd
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Taiwan Semiconductor Manufacturing Co TSMC Ltd
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Abstract

A FET structure with epitaxial strain Si-Ge layer is prepared through providing a Si substrate, epitaxially growing a Si buffer layer and a strain Si(1-x)Ge(x) channel layer under the dual-axis compression strain, generating a grid insulating layer, generating a grid, and generating source/drain at both sides of grid.

Description

Have strain silicon germanium layer brilliant field-effect transistor structure and manufacture method thereof of heap of stone
Technical field
The present invention relates to a kind of field-effect transistor, be meant a kind of field-effect transistor structure and manufacture method thereof especially with strain silicon germanium layer brilliant (epitaxy) of heap of stone.
Background technology
Along with the downsizing of grid assembly size, make mos field effect transistor (MOSFET) assembly can be under low operating voltage, having tend to act electric current and performance at a high speed of height is suitable difficulty.Therefore, many people are in the method for making great efforts to seek to improve the performance of mos field effect transistor assembly.
The band structure modification of utilizing strain to cause increases the mobility of carrier, to increase the electric current of tending to act of field-effect transistor, can improve the performance of field effect transistor element, and this kind method has been applied in the various assemblies.The silicon channel of these assemblies is in the situation of biaxial stretch-formed strain.
Increase mobility (the K.Ismail et al. of electronics in the situation that existing research is pointed out to utilize the silicon passage to be in biaxial stretch-formed strain, " Electron transport properties in Si/SiGe heterostructures:Measurements and device applications ", Appl.Phys.Lett.63, pp.660,1993.), and utilize the SiGe passage is in increases the hole in the situation of biaxial compressive strain mobility (D.K.Nayaket al., " Enhancement-mode quantum-well GeSi PMOS ", IEEE Elect.Dev.Lett.12, pp.154,1991.).Yet, be difficult to finish in conjunction with the NMOSFETs of silicon passage and the CMOS manufacturing technology of PMOSFETs with SiGe passage of biaxial compressive strain with biaxial stretch-formed strain.Many strained layer manufacture methods (K.Ismail et al. such as utilizing thick resilient coating or complex multilayer is arranged in transistorized manufacturing, IBM, Jul.1996, Complementary metal-oxide semiconductortransistor logic using strained Si/SiGe heterostructure layers, U.S.PatentNo.5534713.), these a little methods are not readily integrated in traditional CMOS operation.
Therefore, have the tend to act mos field effect transistor assembly of electric current and performance at a high speed of height, suddenly treat to seek the road of improvement at the problems referred to above in order to make.
Summary of the invention
In view of this, the purpose of this invention is to provide a kind of have strain silicon germanium layer brilliant field-effect transistor structure and manufacture method thereof of heap of stone, it utilizes to form has strained silicon Germanium channel layer (Y.-C.Yeo et al., " Enhanced performance in sub-100nm CMOSFETs using strained epitaxialsilicon-germanium ", IEEE International Electron Device Meeting TechnicalDigest, pp.753-756, San Francisco, CA, Dec.2000.), with the increase electric current of tending to act.
For achieving the above object, the present invention proposes a kind of manufacture method, comprise the following steps: to provide a silicon base with field-effect transistor of strain silicon germanium layer brilliant (epitaxy) of heap of stone; Building crystal to grow one silicon buffer layer and strain Si (1-x) Ge (x) channel layer on this silicon base, wherein this strain Si (1-x) Ge (x) channel layer is under the biaxial compressive strain situation; On this strain Si (1-x) Ge (x) channel layer, form a gate insulator; On this gate insulator, form a gate electrode; And in this gate electrode both sides formation source.
The present invention has also proposed a kind of manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone in addition, comprises the following steps: to provide a silicon base; Building crystal to grow three composite beds that do not mix on this silicon base, this three composite bed is by a silicon buffer layer, a strain Si (1-x)Ge (x)A channel layer and a silicon covering layer are formed, wherein this strain Si (1-x)Ge (x)Channel layer is under the biaxial compressive strain situation; On this silicon covering layer, form a gate insulator; On this gate insulator, form a gate electrode; And in this gate electrode both sides formation source.
The present invention also provides a kind of manufacture method with CMOS of strain silicon germanium layer crystalline substance of heap of stone, comprises the following steps: to provide a silicon base, and this substrate isolates active region by insulation and has a p-well area and a n-well area; Building crystal to grow three composite beds that do not mix on this silicon base, this three composite bed is by a silicon buffer layer, a strain Si (1-x)Ge (x)A channel layer and a silicon covering layer are formed, wherein this strain Si (1-x)Ge (x)Channel layer is under the biaxial compressive strain situation; On this silicon covering layer, form a gate insulator; On this gate insulator, form a gate electrode; Implement n type and p type ion doping to define a PMOS assembly and a NMOS assembly for this p-well area and n-well area; And in this gate electrode both sides formation source.
The present invention proposes a kind of strain silicon germanium layer brilliant field-effect transistor structure of heap of stone that has in addition, is applicable to a silicon base, comprising: a silicon buffer layer, and building crystal to grow is on the active region of this silicon base; One strain Si (1-x)Ge (x)Channel layer, building crystal to grow on this resilient coating, this strain Si wherein (1-x)Ge (x)Channel layer is under the biaxial compressive strain situation; One gate insulator is formed at this strain Si (1-x)Ge (x)On the channel layer; One gate electrode is formed on this gate insulator; And source, be formed at this gate electrode both sides.
For above-mentioned purpose of the present invention, feature and advantage can be become apparent, preferred embodiment cited below particularly, and conjunction with figs. are described in detail below.
Description of drawings
Fig. 1 to Fig. 7 represents to have manufacturing process's profile that strain silicon germanium layer is built brilliant field-effect transistor according to an embodiment of the invention;
Fig. 8 represents a kind of process profile that strain silicon germanium layer is built the metal silicide layer of brilliant field-effect transistor that has;
Fig. 9 represents that another kind has the process profile that strain silicon germanium layer is built the metal silicide layer of brilliant field-effect transistor;
Figure 10 represents that another kind has the process profile that strain silicon germanium layer is built the metal silicide layer of brilliant field-effect transistor.
Wherein, description of reference numerals is as follows:
10~silicon base; 12~fleet plough groove isolation structure;
14,50~silicon buffer layer; 16,52~strain Si (1-x)Ge (x)Channel layer;
18,54~silicon covering layer; 20~extended source/drain region;
22~gate insulator (or silicon oxide layer); 24~V-type groove;
26~dielectric layer; 28~gate electrode; 30~clearance wall;
32~metal silicide layer; S/D~source/drain electrode; 34~silicon layer.
Embodiment
The invention provides a kind of have strain silicon germanium layer brilliant field-effect transistor structure and manufacture method thereof of heap of stone.And in the present invention that atomic size is big than silicon element (for example germanium) imports in the silicon layer, has the channel layer of strain with making.
As shown in Figure 1, provide a silicon base 10, silicon base 10 is with fleet plough groove isolation structure (shallowtrench isolation, STI) 12 definition active regions.The present invention can be applicable to PMOS assembly, NMOS assembly and cmos component, is to illustrate with cmos component in Fig. 1, so demonstrate p-well (p-well) zone and n-well (n-well) zone among the figure.Then as shown in Figure 2, building crystal to grow (epitaxy) three composite beds that do not mix comprise on silicon base 10: a silicon buffer layer 14, a strain Si (1-x)Ge (x)Channel layer 16, an and silicon covering layer 18.Three composite beds of growing up for example utilize selectivity brilliant method of heap of stone to be formed at the active region of silicon base 10.The thickness of silicon buffer layer 14 is as much as possible little, is preferably less than 10nm.Strain Si (1-x)Ge (x)The not ear rate x of Ge in the channel layer 16 is between 0.1 to 0.5, and during as if x=0.25, the critical thickness of strain SiGe layer is 10nm.Thickness Design for the strain SiGe layer of component design is not to be large enough to hold most reversed charge, but too thick and surpass critical thickness and make that the SiGe thin layer is metastable (metastable), and metastable thin layer can relax when high-temperature process.Building crystal to grow three composite beds that do not mix can utilize the high vacuum chemical vapour deposition process (ultra-high-vacuum chemicalvapor deposition UHVCD) forms.Strain Si wherein (1-x)Ge (x)Channel layer 16 is under the biaxial compressive strain situation.Above-mentioned building crystal to grow does not mix the step of three composite beds also can only first building crystal to grow silicon buffer layer 14 and strain Si (1-x)Ge (x)Channel layer 16 is asked for an interview following explanation.
As shown in Figure 6, the thickness of the silicon covering layer 18 of being grown up be depend on its target final thickness and the thickness of the grid oxic horizon that forms of the thermal oxidation of wanting, with these silicon covering layer 18 oxidations, make the top layer of silicon covering layer 18 transfer silicon oxide layer 22 to afterwards, remaining silicon layer then is denoted as 18a.The thickness of the silicon covering layer 18 of being grown up is decided by the thickness of its last remaining thickness and thermal oxidation rear oxidation silicon layer 22.Usually, after step of thermal oxidation, if the thickness tox of silicon oxide layer 22, then the thickness of silicon covering layer 18 can consume about 0.46tox.Suppose that wish that the silicon oxide layer 22 that step of thermal oxidation forms is 10 dusts (), the predetermined thickness of silicon layer 18a is 5 dusts, then needs the silicon layer 18 of growth 9.6 dusts before carrying out step of thermal oxidation.This silicon covering layer 18 provides a good interface quality, and can avoid silicon oxide layer 22 directly to grow up at Si (1-x)Ge (x)Channel layer 16 surfaces, silicon covering layer 18 must cover the edge (as shown in Figure 2) of SiGe layer 16 to avoid the causing oxidation of SiGe layer when thermal oxidation is grown up.The preferable thickness of silicon layer 18a after the thermal oxidation is 2~6 atom level layers (atomic layers), promptly about 5~15 Izod right sides.This silicon covering layer 18 provides a good interface quality, and can avoid silicon oxide layer 22 directly to grow up at Si (1-x)Ge (x)Channel layer 16 surfaces, the germanium concentration that can guarantee silicon covering layer 18a, silicon oxide layer 22 interfaces are lower than 5% and make silicon oxide layer 22 that good quality be arranged.The more important thing is that the existence of this thin silicone layer 18a can guarantee that reversed charge density is collected at Si in the N channel transistor (1-x)Ge (x)In the channel layer 16, and make most movable carrier (for example electronics) be positioned at Si (1-x)Ge (x)In the channel layer 16, so will help and benefit strain Si (1-x)Ge (x)The band structure modification of channel layer.Therefore, can promote transistorized performance again.Moreover because the ultra-thin silicon cover layer can cause pin hole, therefore silicon covering layer in the past is thicker, yet among the present invention, can obtain the thinnest silicon covering layer and the thickest grid oxic horizon with the formed grid oxic horizon of the method, can the actual problem that solves pin hole.
The formation of gate insulator 22 also can be selected other method, utilizes chemical vapour deposition technique in strain Si (1-x)Ge (x)Deposition of aluminium oxide, hafnium oxide or zirconia on the channel layer 16.
As shown in Figure 3, form three composite beds that do not mix and also have another kind of method, be to use non-selective brilliant method of heap of stone, comprise a silicon buffer layer 50 in comprehensive formation of silicon base 10 as the brilliant method of liquid built; One strain Si (1-x)Ge (x) Channel layer 52, and three composite beds of a silicon covering layer 54.Formation method, condition and the thickness of this three composite bed is identical with aforementioned person, and unique difference is to be that these a little thin layers are to form with non-selective brilliant method of heap of stone.
As shown in Figure 4, etching is removed in the part of isolated area and is stayed silicon buffer layer 50, strain Si on active region again (1-x)Ge (x)Channel layer 52, and three lamination layer structures of silicon covering layer 54.
Then, as shown in Figure 5, after forming three composite beds that do not mix and before the growth grid oxic horizon, optionally on the V-shaped groove 24 at active region edge, form dielectric layer 26, to solve the more weak grid oxic horizon insulating properties of transistor side.Dielectric layer 26 for example uses chemical vapour deposition technique to form silicon oxide layer.
Then, please as shown in Figure 6, on gate insulator 22, form gate electrode 28.
Afterwards, please as shown in Figure 7, carry out n type and p type ion doping respectively at p-well (p-well) zone and n-well (n-well) zone of gate electrode 28 both sides again, and form clearance wall 30 at the sidewall of gate electrode 18, for example use chemical vapour deposition technique to form silicon nitride layer as clearance wall 30.And carry out rapid thermal annealing processing procedure (RTA) and do not causing Si (1-x)Ge (x)Activation n type and p type ion doping under the situation of channel layer 16 strain relaxations, to form expansion source electrode S/ drain D district 20, wherein the temperature of rapid thermal annealing processing procedure (RTA) is approximately between 950 ℃ to 1050 ℃.
Form metal silicide (silicide) layer at last, and in source S/drain D and gate electrode 28 surfaces.Its formation method have following three kinds available.
First method as shown in Figure 8, is used traditional method, with the Si in source S/drain D (1-x)Ge (x)The metal silication reaction is carried out to form metal silicide (silicide) layer 32 in channel layer 16 top layers.Meaning promptly deposits layer of metal, and for example titanium then utilizes high temperature, makes titanium and Si (1-x)Ge (x)The metal silication reaction is carried out on channel layer 16 top layers, utilizes wet etching to remove unreacted titanium at last.
Second method as shown in Figure 9, is before carrying out the metal silication reaction, removes the Si that exposes (1-x)Ge (x)Channel layer 16 makes in the metal silicide layer 32 of formation not contain any germanium atom.
The third method as shown in figure 10, is the Si in source S/drain D (1-x)Ge (x)The surface selectivity of channel layer 16 is built brilliant one deck silicon layer 34, the metal silication reaction is occurred in the silicon layer 34, and can not occur in Si (1-x)Ge (x)Channel layer 16, as shown in figure 10.
The present invention proposes a kind of strain silicon germanium layer brilliant field-effect transistor structure of heap of stone that has, and as shown in Figure 7, is applicable to a silicon base 10, and this field-effect transistor structure has following assembly.First assembly is 14 layers of a silicon bufferings, uses the said method building crystal to grow on the active region of silicon base 10.
Second assembly is a strain Si (1-x)Ge (x)Channel layer 16 uses the said method building crystal to grow on resilient coating 14, strain Si (1-x)Ge (x)Channel layer 16 is under the biaxial compressive strain situation.
This field-effect transistor structure still also has following assembly: a gate insulator 22 is formed at strain Si (1-x)Ge (x)On the channel layer 16; One gate electrode 28 is formed on the gate insulator 22; And one source pole S/ drain D, be formed at gate electrode 28 both sides.
Field-effect transistor structure with strain silicon germanium layer crystalline substance of heap of stone of the present invention also comprises silicon shoe cap rock 18, is formed at strain Si (1-x)Ge (x)Between channel layer 16 and the gate pole insulating barrier 22.
The present invention also proposes a kind of strain silicon germanium layer brilliant field-effect transistor structure of heap of stone that has, and as shown in Figure 8, is applicable to a silicon base 10, and this field-effect transistor structure has following assembly.First assembly is 14 layers of a silicon bufferings, uses the said method building crystal to grow on the active region of silicon base 10.
Second assembly is a strain Si (1-x)Ge (x)Channel layer 16 uses the said method building crystal to grow on resilient coating 14, strain Si (1-x)Ge (x)Channel layer 16 is under the biaxial compressive strain situation.
This field-effect transistor structure still has following assembly: a gate insulator 22 is formed at strain Si (1-x)Ge (x)On the channel layer 16; One gate electrode 28 is formed on the gate insulator 22; One source pole S/ drain D is formed at gate electrode 28 both sides; And a metal suicide source/drain electrode 32, be formed on the silicon buffer layer 14 of source S/drain D.
The present invention proposes a kind of strain silicon germanium layer brilliant field-effect transistor structure of heap of stone that has again, as shown in Figure 9, is applicable to a silicon base 10, and this field-effect transistor structure has following assembly.First assembly is 14 layers of a silicon bufferings, uses the said method building crystal to grow on the active region of silicon base 10.
Second assembly is a strain Si (1-x)Ge (x)Channel layer 16 uses the said method building crystal to grow on resilient coating 14, strain Si (1-x)Ge (x)Channel layer 16 is under the biaxial compressive strain situation.
This field-effect transistor structure also has following assembly: a gate insulator 22 is formed at strain Si (1-x)Ge (x)On the channel layer 16; One gate electrode 28 is formed on the gate insulator 22; One source pole S/ drain D is formed at gate electrode 28 both sides, and a metal suicide source/drain electrode 32, is formed in source S/drain electrode.
The present invention also proposes a kind of strain silicon germanium layer brilliant field-effect transistor structure of heap of stone that has, as shown in figure 10, be applicable to a silicon base 10, this field-effect transistor structure has following assembly: first assembly is 14 layers of a silicon bufferings, uses the said method building crystal to grow on the active region of silicon base 10.
Second assembly is a strain Si (1-x)Ge (x)Channel layer 16 uses the said method building crystal to grow on resilient coating 14, strain Si (1-x)Ge (x)Channel layer 16 is under the biaxial compressive strain situation.
This field-effect transistor structure also has following assembly: a gate insulator 22 is formed at strain Si (1-x)Ge (x)On the channel layer 16; One gate electrode 28 is formed on the gate insulator 22; One source pole S/ drain D is formed at gate electrode 28 both sides; And a metal suicide source/drain electrode 32, be formed at the strain Si of source S/drain D (1-x)Ge (x)On the channel layer 16.
Though the present invention discloses as above with preferred embodiment, but be not in order to restriction the present invention, any those skilled in the art, without departing from the spirit and scope of the present invention, the equivalent structure transformation of having done all is included in the claim of the present invention.

Claims (48)

1. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone is characterized in that, comprises the following steps:
One silicon base is provided;
Building crystal to grow one silicon buffer layer and a strain Si on this silicon base (1-x)Ge (x)Channel layer, wherein this strain Si (1-x)Ge (x)Channel layer is under the biaxial compressive strain situation;
At this strain Si (1-x)Ge (x)Form a gate insulator on the channel layer;
On this gate insulator, form a gate electrode; And
Form source in these gate electrode both sides.
2. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 1 is characterized in that this strain Si (1-x)Ge (x)Channel layer, wherein x is between 0.1 to 0.5.
3. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 1 is characterized in that this strain Si (1-x)Ge (x)The critical thickness of channel layer is 10nm.
4. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 1 is characterized in that the thickness of this silicon buffer layer is less than 10nm.
5. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 1 is characterized in that this gate insulator is a silicon oxide layer.
6. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 5 is characterized in that the formation method of this gate insulator comprises:
At this strain Si (1-x)Ge (x)Form a silicon layer on the channel layer; And
This silicon layer of oxidation makes the top layer of this silicon layer transfer this silicon oxide layer to.
7. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 1 is characterized in that the formation method of this gate insulator is to utilize chemical vapour deposition technique, at this strain Si (1-x)Ge (x)Deposition one deck is selected from the set that aluminium oxide, hafnium oxide and zirconia form on the channel layer.
8. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 1 is characterized in that, is included in before this silicon buffer layer of building crystal to grow, forms a fleet plough groove isolation structure in this silicon base.
9. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 1 is characterized in that, also is included in and forms after this source/drain this strain Si in this source/drain (1-x)Ge (x)The metal silication reaction is carried out on the top layer of channel layer, to form a metal silicide.
10. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 1 is characterized in that, also comprises forming after this source/drain, removes this strain Si in this source/drain (1-x)Ge (x)Channel layer carries out the metal silication reaction, again to form a metal silicide.
11. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 1 is characterized in that, also is included in to form after this source/drain, selectivity is built this strain Si of a brilliant silicon layer in this source/drain (1-x)Ge (x)The metal silication reaction is carried out, again to form a metal silicide in the channel layer surface.
12. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 1 is characterized in that this silicon buffer layer of building crystal to grow and this strain Si (1-x)Ge (x)Channel layer is to use selectivity to build brilliant method.
13. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 1 is characterized in that this silicon buffer layer of this building crystal to grow and this strain Si (1-x)Ge (x)Channel layer comprises the following steps:
Use non-selective brilliant method of heap of stone grow up this silicon buffer layer and this strain Si (1-x)Ge (x)Channel layer; And
This silicon buffer layer and this strain Si of part removed in etching (1-x)Ge (x)Channel layer and stay part on active region.
14. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone is characterized in that, comprises the following steps:
One silicon base is provided;
Building crystal to grow three composite beds that do not mix on this silicon base, this three composite bed is by a silicon buffer layer, a strain Si (1-x)Ge (x)A channel layer and a silicon covering layer are formed, wherein this strain Si (1-x)Ge (x)Channel layer is under the biaxial compressive strain situation;
On this silicon covering layer, form a gate insulator;
On this gate insulator, form a gate electrode; And
Form source in these gate electrode both sides.
15. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 14 is characterized in that this strain Si (1-x)Ge (x)Channel layer, wherein x is between 0.1 to 0.5.
16. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 14 is characterized in that this strain Si (1-x)Ge (x)The critical thickness of channel layer is 10nm.
17. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 14 is characterized in that the thickness of this silicon buffer layer is less than 10nm.
18. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 14 is characterized in that this gate insulator is a silicon oxide layer.
19. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 18 is characterized in that the formation method of this gate insulator is this silicon covering layer of thermal oxidation, makes the top layer of this silicon covering layer transfer this silicon oxide layer to.
20. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 14, it is characterized in that, the formation method of this gate insulator is to utilize chemical vapour deposition technique, and deposition one deck is selected from the set that aluminium oxide, hafnium oxide and zirconia form on this silicon covering layer.
21. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 14, peculiar levying is, is included in before this silicon buffer layer of building crystal to grow, forms a fleet plough groove isolation structure in this silicon base.
22. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 14 is characterized in that, is included in and forms after this source/drain this strain Si in this source/drain (1-x)Ge (x)The metal silication reaction is carried out on the top layer of channel layer, to form a metal silicide.
23. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 14 is characterized in that, is included in to form after this source/drain, removes this strain Si in this source/drain (1-x)Ge (x)Channel layer carries out the metal silication reaction, again to form a metal silicide.
24. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 14 is characterized in that, is included in to form after this source/drain, selectivity is built a brilliant silicon layer this strain Si in this source/drain (1-x)Ge (x)The metal silication reaction is carried out, again to form a metal silicide in the channel layer surface.
25. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 14 is characterized in that this three composite bed of building crystal to grow is to use selectivity to build brilliant method.
26. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 14 is characterized in that this three composite bed of this building crystal to grow comprises the following steps:
Use non-selective brilliant method of heap of stone this three composite bed of growing up; And
Etching is removed this three composite bed of part and is stayed part on active region.
27. the manufacture method with CMOS of strain silicon germanium layer crystalline substance of heap of stone comprises the following steps:
One silicon base is provided, and this substrate isolates active region by insulation and has a p-well area and a n-well area;
Building crystal to grow three composite beds that do not mix on this silicon base, this three composite bed is by a silicon buffer layer, a strain Si (1-x)Ge (x)A channel layer and a silicon covering layer are formed, wherein this strain Si (1-x)Ge (x)Channel layer is under the biaxial compressive strain situation;
On this silicon covering layer, form a gate insulator;
On this gate insulator, form a gate electrode;
Implement n type and p type ion doping to define a PMOS assembly and a NMOS assembly for this p-well area and n-well area; And
Form source in these gate electrode both sides.
28. the manufacture method with CMOS of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 27 is characterized in that this strain Si (1-x)Ge (x)Channel layer, wherein x is between 0.1 to 0.5.
29. the manufacture method with CMOS of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 27 is characterized in that this strain Si (1-x)Ge (x)The critical thickness of channel layer is 10nm.
30. the manufacture method with CMOS of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 27 is characterized in that the thickness of this silicon buffer layer is less than 10nm.
31. the manufacture method with CMOS of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 27 is characterized in that this gate insulator is a silicon oxide layer.
32. the manufacture method with field-effect transistor of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 31 is characterized in that the formation method of this gate insulator is this silicon covering layer of thermal oxidation, makes the top layer of this silicon covering layer transfer this silicon oxide layer to.
33. the manufacture method with CMOS of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 27 is characterized in that, before this silicon buffer layer of building crystal to grow, also is included in the step that forms a fleet plough groove isolation structure in this silicon base.
34. the manufacture method with CMOS of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 27 is characterized in that, also is included in and forms after this source/drain this strain Si in this source/drain (1-x)Ge (x)The metal silication reaction is carried out on the top layer of channel layer, to form a metal silicide.
35. the manufacture method with CMOS of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 27 is characterized in that, more is included in to form after this source/drain, removes this strain Si in this source/drain (1-x)Ge (x)Channel layer carries out the metal silication reaction, again to form a metal silicide.
36. the manufacture method with CMOS of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 27 is characterized in that, also is included in to form after this source/drain, selectivity is built this strain Si of a brilliant silicon layer in this source/drain (1-x)Ge (x)The metal silication reaction is carried out, again to form a metal silicide in the channel layer surface.
37. the manufacture method with CMOS of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 27 is characterized in that this three composite bed of building crystal to grow is to use selectivity to build brilliant method.
38. the manufacture method with CMOS of strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 27 is characterized in that this three composite bed of this building crystal to grow comprises the following steps:
Use non-selective brilliant method of heap of stone this three composite bed of growing up; And
Etching is removed this three composite bed of part and is stayed part on active region.
39. one kind has strain silicon germanium layer brilliant field-effect transistor structure of heap of stone, is applicable to a silicon base, it is characterized in that, comprising:
One silicon buffer layer, building crystal to grow is on the active region of this silicon base;
One strain Si (1-x)Ge (x)Channel layer, building crystal to grow on this resilient coating, this strain Si wherein (1-x)Ge (x)Channel layer is under the biaxial compressive strain situation;
One gate insulator is formed at this strain Si (1-x)Ge (x)On the channel layer;
One gate electrode is formed on this gate insulator; And
Source is formed at this gate electrode both sides.
40. the field-effect transistor structure with strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 39 is characterized in that this strain Si (1-x)Ge (x)Channel layer, wherein x is between 0.1 to 0.5.
41. the field-effect transistor structure with strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 39 is characterized in that this strain Si (1-x)Ge (x)The critical thickness of channel layer is 10nm.
42. the field-effect transistor structure with strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 39 is characterized in that the thickness of this silicon buffer layer is less than 10nm.
43. the field-effect transistor structure with strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 39 is characterized in that this gate insulator is a silicon oxide layer.
44. as claimed in claim 39 have a strain silicon germanium layer field-effect transistor structure of heap of stone brilliant, it is characterized in that, this gate insulator is selected from the set that aluminium oxide, hafnium oxide and zirconia form.
45. the field-effect transistor structure with strain silicon germanium layer crystalline substance of heap of stone as claimed in claim 39 is characterized in that, also comprises a silicon covering layer, is formed at this strain Si (1-x)Ge (x)Between channel layer and this gate insulator.
46. one kind has strain silicon germanium layer brilliant field-effect transistor structure of heap of stone, is applicable to a silicon base, it is characterized in that, comprising:
One silicon buffer layer, building crystal to grow is on the active region of this silicon base;
One strain Si (1-x)Ge (x)Channel layer, building crystal to grow on this resilient coating, this strain Si wherein (1-x)Ge (x)Channel layer is under the biaxial compressive strain situation;
One gate insulator is formed at this strain Si (1-x)Ge (x)On the channel layer;
One gate electrode is formed on this gate insulator;
Source is formed at this gate electrode both sides; And
One metal suicide source/drain electrode is formed on this silicon buffer layer of this source/drain.
47. one kind has strain silicon germanium layer brilliant field-effect transistor structure of heap of stone, is applicable to a silicon base, it is characterized in that, comprising:
One silicon buffer layer, building crystal to grow is on the active region of this silicon base;
One strain Si (1-x)Ge (x)Channel layer, building crystal to grow on this resilient coating, this strain Si wherein (1-x)Ge (x)Channel layer is under the biaxial compressive strain situation;
One gate insulator is formed at this strain Si (1-x)Ge (x)On the channel layer;
One gate electrode is formed on this gate insulator;
Source is formed at this gate electrode both sides; And
One metal suicide source/drain electrode is formed on this source/drain.
48. one kind has strain silicon germanium layer brilliant field-effect transistor structure of heap of stone, is applicable to a silicon base, it is characterized in that, comprising:
One silicon buffer layer, building crystal to grow is on the active region of this silicon base;
One strain Si (1-x)Ge (x)Channel layer, building crystal to grow on this resilient coating, this strain Si wherein (1-x)Ge (x)Channel layer is under the biaxial compressive strain situation;
One gate insulator is formed at this strain Si (1-x)Ge (x)On the channel layer;
One gate electrode is formed on this gate insulator;
Source is formed at this gate electrode both sides; And
One metal suicide source/drain electrode is formed at this strain Si of this source/drain (1-x)Ge (x)On the channel layer.
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