CN1530430A - Perfume composition for hard-surface abstergent - Google Patents
Perfume composition for hard-surface abstergent Download PDFInfo
- Publication number
- CN1530430A CN1530430A CNA2004100084380A CN200410008438A CN1530430A CN 1530430 A CN1530430 A CN 1530430A CN A2004100084380 A CNA2004100084380 A CN A2004100084380A CN 200410008438 A CN200410008438 A CN 200410008438A CN 1530430 A CN1530430 A CN 1530430A
- Authority
- CN
- China
- Prior art keywords
- oil
- ester
- acetate
- methyl
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Fats And Perfumes (AREA)
- Detergent Compositions (AREA)
Abstract
To obtain a perfume composition for hard surface detergents having an aroma different from that of citrus base, giving no problem such as of swelling containers and injuring plastics, and having an excellent masking effect on pharmaceutical smells, excellent perfuming effect when washing and a little remaining smell after washing. This perfume composition for hard surface detergents contains not less than 10 mass % of an esterification compound having the boiling point of not more than 200 [deg.]C based on the amount of an aroma component.
Description
Technical field
The present invention relates to be applicable to the washing composition of the crust of the plastics class that contains fibre reinforced plastics, ceramic tile, stainless steel, enamel, pottery, glass etc., just relate to the flavor compositions that is used for hard surface detergent.
Background technology
Generally, the dirt that adheres on the crust of the employed plastics class that contains fibre reinforced plastics such as the ground in bathing pool, the bathroom, wall and apparatus class, ceramic tile, stainless steel, pottery, glass etc. is the mixture of the inorganics of the organism of nitrogenous compound, free fatty acids, glyceride type, fatty acid metal salt (soap slag) etc. of protein etc. and mud etc.
In the past, the fragrance of being given in the hard surface detergent of removing such dirt nearly all was the oranges and tangerines type, had not had happy sense and feeling of freshness.In addition, the main fragrance component of the fragrance of oranges and tangerines type is limonene (for example patent documentation 1), but when using limonene, exists the problem of the swelling of container and damage plastics class etc.
In addition, the fragrance release property is good when just requiring the sheltering of preparation flavor and washing for hard surface detergent with flavor compositions, and the few type of residual perfume (or spice) during flushing.
Patent documentation 1
The open communique of Japan 2000-87098 patent of invention
Summary of the invention
The present invention is in view of above-mentioned problem in the past etc., these problems propose in order to solve, its purpose is to provide the hard surface detergent flavor compositions, it has the fragrance different with the oranges and tangerines type, there are not problems such as container swelling and damage plastics class, the fragrance release property is good when the sheltering of preparation flavor and flushing, and the residual fragrance during flushing is few.
The present invention includes following invention.
(1) hard surface detergent flavor compositions is characterized in that in fragrance component, contains the above boiling point of 10 quality % at the ester cpds below 200 ℃.
(2) allocated the hard surface detergent compositions of the flavor compositions of above-mentioned (1) being put down in writing, it is characterized in that this hard surface detergent compositions is filled in the shaped container.
Embodiment
Discharge flavour ingredient, mid-term early stage and discharge flavour ingredient and later stage when discharging flavour ingredient in that spices is categorized into, be used for the ester cpds of boiling point of the present invention below 200 ℃ and be equivalent to discharge early stage flavour ingredient.
Be used for the ester cpds of boiling point of the present invention below 200 ℃, can enumerate ethyl formate, propyl formate, butyl formate, pentyl formate, isoamyl formate, hexyl formate, formic acid cis-3-hexene ester, octyl formate, methyl acetate, ethyl acetate, propyl acetate, isopropyl acetate, butylacetate, isobutyl acetate, sec-butyl acetate, tert.-butyl acetate, pentyl acetate, Isoamyl Acetate FCC (acetate 3-methyl isophthalic acid-butyl ester), hexyl acetate, acetate cis-3-hexene ester, acetate is trans-2-hexene ester, prenyl acetate, 2-ethyl hexyl ethanoate, heptyl acetate, acetate 3-monooctyl ester, acetate octene ester, acetate furfuryl group ester, the acetic ester of acetate tetrahydro furfuryl ester etc.; Ethyl propionate, propyl propionate, allyl propionate, butyl propionate, isobutyl propionate, isoamyl propionate, n-hexyl propionate, propionic acid cis-3-hexene ester, propionic acid be trans-propionic ester of 2-hexene ester etc.; Methyl-butyrate, ethyl butyrate, propyl butyrate, isopropyl butyrate, butyl butyrate, isobutyl butyrate, the secondary butyl ester of butyric acid, tert-butyl acetate, pentyl butyrate, isoamyl butyrate, allyl butyrate, butyric acid cis-3-hexene ester, butyric acid is trans-2-hexene ester, methyl isobutyrate, ethyl isobutyrate, propyl isobutyrate, isopropyl isobutyrate, isobutyl isobutyrate, isoamyl isobutyrate, the own ester of isopropylformic acid, isopropylformic acid cis-3-hexene ester, methyl 2-methylbutyrate, ethyl 2-methylbutyrate, the butyric acid of 2-Methyl Butyric Acid-2-methyl butyl ester etc., isobutyrate; The valerate of methyl valerate, Valeric acid ethylester, butyl valerate, isobutyl isovalerate, the secondary butyl ester of valeric acid, the valeric acid tert-butyl ester, oil of apple, valeric acid cis-3-hexene ester etc.; The isopentanoate of methyl isovalerate, Ethylisovalerate, propyl isovalerate, isopropyl isovalerate, butyl isovalerate, isobutyl isovalerate, isoamyl isovalerate, allyl isovalerate, isovaleric acid cis-3-hexene ester etc.; The capronate of methyl caproate, ethyl hexanoate, propyl hexanoate, isopropyl hexylate, caproic acid allyl ester etc.; The heptanoate of Methylheptanoate, oil of cognac etc.; Methyl caprylate, methyl aceto acetate, methyl benzoate, tiglic acid, ethyl tiglate, angelicic acid, isobutyl angelate, isoamyl angelate, ethyl propenoate, butenoic acid ethyl, methyl lactate, ethyl lactate, n-Butyl lactate, Pyruvic Acid Ethyl ester, methylfuroate, ethyl furoate, diethyl malonate, dimethyl succinate, preferably ethyl acetate, Isoamyl Acetate FCC (acetate 3-methyl isophthalic acid-butyl ester), butylacetate, isoamyl isovalerate.
Hard surface detergent of the present invention is with in the flavor compositions, and the allotment ratio of the above-mentioned ester cpds of boiling point below 200 ℃ in fragrance component, need be more than the 10 quality %.During above-mentioned allotment ratio less than 10 quality %, be difficult to cover the base-material flavor, not only reduce frank sense, and the fragrance after the washing left behind easily.Above-mentioned allotment ratio is 30～50 quality % preferably.
Hard surface detergent of the present invention is with in the flavor compositions, also can allocate the fragrance component except above-mentioned boiling point is ester below 200 ℃.List as the employed perfume base of spices is published on various documents, for example, " Perfume and FlavorChemicals ", Vol.I and II, Steffen Arctander, Allured Pub.Co. (1994), " synthetic perfume science and knowledge of goods ", seal rattan unit one work, chemical industry day newspaper office (1996), " Perfume and Flavor Materials of Natural Origin ", SteffenArctander, Allured Pub.Co. (1994), " spices encyclopaedia ", Japan's fragrance association is compiled, towards storehouse bookstore (1989) and " Flower oils and Floral Compounds InPerfumery ", Danute Lajaujis Anonis, Allured Pub.Co. (1993).Quote these respectively, can be used as the disclosed part of this specification sheets.These fragrance components, can be individually or the composition more than 2 kinds be used in combination, in the fragrance component of flavor compositions of the present invention, can be deployed into below the 90 quality %.
As discharging flavour ingredient early stage, can enumerate limonene, the p-cymene, α-Pai Xi, beta-pinene, the terpin diene, cis-blatter alcohol, trans-the 2-hexenol, 1-amylene-3-alcohol, 1-octene-3-alcohol, 2,6-dimethyl heptane-2-alcohol, myrcenol, dihydromyrcenol, the 1-menthol, p-tolyl methyl ether, hexanal, trans-the 2-hexenoic aldehyde, octanal, aldehyde C-9, sinensal, methylheptanone, 1, the 4-Terpane, 1, the 8-Terpane, the limonene oxide compound, 8-sulfydryl piperitone, lemon oil, mandarin oil, lime oil, sarcodactylis oil fu, eucalyptus oil, tangerine oil etc.Above-mentioned volatile oil also can be the shape of tree type, pure type, coagulation type etc.
As discharging flavour ingredient mid-term, can enumerate the 3-phenyl propanol, α-fenchone, 9-decen-1-ol, dimethyl octanol, geraniol, Geraniol, tetrahydrochysene laurine dimethyl acetal, linalool (3,7-dimethyl-1,6-octadiene-3-alcohol), Tetrahydrolinalool, vernol, Ethyl linalool, terpinol, tetrahydrogeraniol, Tetrahydromyrcenol, α-fenchol, methyl eugenol, Eugenol, dimethylbenzylcarbinol, 3,5-dimethylphenyl Ethylbenzyl methyl alcohol, diphenyl ether, citronellyl formate, Geranyl Formate, jasmal, acetate dimethyl benzyl hydrocarbon methyl esters, Linalyl acetate, neryl acetate, acetate 2-tertiary butyl cyclohexyl, cyclohexyl fluoroacetic acid allyl ester, acetate turnip ester, citronellyl acetate, meraneine, tetrahydrogeranyl acetate, the acetate terpenoid, acetate dihydro terpenoid, the acetate iso-bornyl ester, acetate 1-menthyl ester, nonyl acetate, verdy acetate, acetate p-methylphenyl ester, acetate 2-phenylethylester, acetate 3-phenyl propyl ester, acetate styryl ester, acetate 3,5-dimethylphenyl ethyl hydrocarbon methyl esters, acetate 1-ethynyl cyclohexyl, the enanthic acid allyl ester, isobutyl propionate, propionic acid 2-phenylethylester, propionic acid citronellyl ester, benzyl propionate, tricyclo decenyl propionate, butyric acid cis-3-hexenyl ester, cyclohexyl butyrate, isopropylformic acid 3-phenyl propyl ester, dimethylbenzyl carbinyl butyrate, geranyl propionate, the propionic acid allyl ester, cyclohexyl butyric acid allyl ester, anthranilic acid cis-3-hexenyl ester, the phenylacetic acid isobutyl ester, isonefolia, Whitfield's ointment 2-phenyl chlorocarbonate, the heptyne carboxylic acid methyl ester, the octyne carboxylic acid methyl ester, sad p-cresol ester, phenylformic acid cis-3-hexenyl ester, allyl group amyl group glycol ester, the beta-phenyl ethyl alcohol, benzyl alcohol, pmethoxybenzyl alcohol, Geraniol, citral, neral, capraldehyde, the undecyl aldehyde, the 10-undecenal, lauric aldehyde, cyclocitral, isocyclocitral, aubepine, phenyl acetaldehyde, hydratropaldehyde, laurine, wheat is drawn aldehyde, all wheat is drawn aldehyde, 2-methyl-3-(p-methoxyphenyl) propionic aldehyde, Ling Lanquan, 2-amyl group cyclopentanone, the 1-Karvon, piperitone, geranyl acetone, p-methyl aceto phenone, geranial, citronellyl oxygen acetaldehyde, the dimethyl tetrahydro phenyl aldehyde, methyl phenyl ethylglycidate, the laurine dimethylacetal, phenyl acetaldehyde dimethylacetal, the methyl nonyl acetaldehyde dimethylacetal, acetaldehyde 2-phenyl-2,4-pentanediol acetal, the methyl aceto acetate propylene glycol acetal, hydrogenation aritox aldehyde dimethylacetal, hydrogenation aritox aldehyde Glycol Acetal, estragole, o-hydroxyanisole, the p-propenylanisole, p-cresol, the geranyl nitrile, the citronellyl nitrile, indoles, the sulfo-Geraniol, wintergreen oil, white oil of camphor, linaloe oil etc.Above-mentioned volatile oil also can be the shape of pure type, resin type, coagulation type etc.
As later stage release flavour ingredient, can enumerate Patchoulicalcohol, patchone, styryl carbinol, β-caryophyllene, guaiol acetate, acetate cinnyl ester, geranyl butyrate, citronellyl butyrate, the phenylacetic acid ester, orchidae, Salicylate Isomyl, the Whitfield's ointment benzyl ester, Whitfield's ointment cis-3-hexene ester, n-Hexyl salicylate, methyl oaminobenzoate, the N-methyl methylanthranilate, phenylformic acid benzyl ester, diethyl phthalate, phenoxyethyl isobutanoate, geranyl isobutyrate, the isovaleric acid geraniol ester, TRANSCINNAMIC ACID cinnyl ester, ethyl phenylacrylate, the phenylacetic acid citronellyl acrylate, phenylacetic acid p-cresol ester, the phenylacetic acid phenyl chlorocarbonate, phenylacetic acid Syzygium aromaticum alcohol ester, the aromatic ester of phenylacetic acid isobutyl, the different ketone that comes into leaves, methyl anthranilic acid ester, four capraldehyde, α-Wu Jirouguiquan, hydrocinnamic aldehyde, Xian Kelaiquan, lyral (trade(brand)name), tree lucerne ketone, isojasmone, cis-jasmone, Vanillin, vanillal, piperitol, piperonylaldehyde, α-n-hexyl aubepine, aurantiol, ionone class [α-Zi Luotong, β-ionone (β-ring citrylidene acetone; β-cyclocitrylideneacetone), γ-ionone], methyl violet sieve ketone, the acetyl cedrene, the sub-sesame oil phenol of isobutyl, methyl clove(bud)oil phenol, the sub-sesame oil phenol of methyl isobutyl, the sub-sesame oil phenol of benzyl isobutyl, Beta-methyl naphthyl ketone, methyl, the betanaphthyl ethyl ether, 2-methyl undecyl aldehyde dimethylacetal, 2-methyl-3-(p-p-methoxy-phenyl) propyl alcohol, vernol, maltol, ethyl maltol, γ-Xin Neizhi, γ-hendecoic acid lactone, γ-decalactone, γ-Ren Neizhi, δ-Shi Erneizhi, methyl dihydro jasmonyl, different-E-super, cdear ylmethyl ether, Isobutylquinoline, rose oxygen, the rose benzophenone, longifolene, oak moss oil, opopanax oil, the copaiba fatty oil, santal wood oil, deodar cedarwood oil, Tolu balsam oil, Peru balsam oil, benzoin oil, the vanilla wet goods.Above-mentioned volatile oil also can be the shape of pure type, coagulation type, resin type etc.
In addition, as early stage with discharge the natural perfume that flavour ingredient has mixed mid-term, can enumerate the natural essence oil that Pinus pumilio oil, almond oil, hemp oil, chamomile oil, safflower vegetable oil, Gu meet face cream oil, lucerne sagebrush oil, cumin oil, Coriandrum sativumL oil, Du's pinaster seed oil, Oleum Menthae Rotundifoliae, sage oil, Oils, Apium graveolens, thyme oil, sagebrush oil, ucuhuba oil (nutmeg oil), basil oil, oil of hyssop, petitgrain oil, the withered oil of cloth, pennyroyal oil, spearmint oil, Semen Myristicae caul-fat (mace oil), oleum lavendulae, rosemary oil, levisticum oil, bay wet goods.
Discharge the natural perfume that flavour ingredient has mixed as mid-term and later stage, can enumerate the natural essence oil of sandal oil, olive sesame oil, Oleum Cinnamomi, guaiac wood oil, Syzygium aromaticum stem oil, styrax oil, Herba Erodii oil, mandarin oil, patchouli oil, vetiver oil, ladanum oil, oleum graminis citrati, Radix Angelicae Sinensis oil, Japan cypress oil, Chinese juniper leaf oil, lemongrass wet goods.
Discharge the natural perfume that flavour ingredient has mixed as mid-term in early stage and later stage, can enumerate the natural essence oil of fennel seed oil, ylang-ylang oil, Salvia Sclare L.oil, Oleum Cinnamomi, star aniseed oil, cananga oil, red currant wet goods.
The allotment ratio of the fragrance component in the flavor compositions of the present invention, for example, can use discharge early stage flavour ingredient be discharge that flavour ingredient is that the above 90 quality % of 0 quality % are following in 10～100 quality %, mid-term, the later stage, to discharge flavour ingredient be the following scopes of the above 90 quality % of 0 quality %, but preferred range is, discharges flavour ingredient early stage and be that to discharge flavour ingredient in 30～50 quality %, mid-term be that 40～70 quality %, later stage to discharge flavour ingredient be 0～10 quality %.
Flavor compositions of the present invention in order to prevent the deterioration of fragrance component, can add known natural or synthetic antioxidant, anti-light degradation as required.
Can moderately add solvent (ethanol, ethylene glycol, propylene glycol), known natural pigment and synthetic colour, known emulsifying agent, solvating agent, preservatives and fixer, toughener etc. in case of necessity.
Flavor compositions of the present invention by mixing above-mentioned composition, can be made with usual method.Its agent shape has no particular limits, and can make aqueous, gluey, aerosol shape.
Flavor compositions of the present invention is suitable to the washing composition of the crust of the plastics class that is used to contain fibre reinforced plastics, ceramic tile, stainless steel, enamel, pottery, glass etc.
Flavor compositions of the present invention is to the allotment ratio of washing composition, normally 0.001～0.5 quality %.
In addition, the hard surface detergent compositions of having allocated flavor compositions of the present invention is filled into washing composition in the shaped container, than the easier release fragrance of the hard surface detergent that is filled into bottle container.
As shaped container, can enumerate that use was in the past, for example flip-over type, the extrusion type, pump type, but when using easy aspect, the preferably flip-over type of cleaning more.As the mechanism of the divider of flip-over type, can enumerate and be documented in the open communique of Japanese 1998-316157 patent of invention etc.As can enumerating of extrusion type be documented in Japanese 1987-042785 utility model bulletin communique, Japanese 1987-042786 utility model bulletin communique, Japanese 1987-042787 utility model bulletin communique or according to its standard, in addition, as can enumerating of the type of pumping be documented in the open communique of Japanese 1995-315463 patent of invention, the open communique of Japanese 1996-230961 patent of invention or according to its standard.These containers have more bubble in order to reach, and in export department net are installed mostly, and the dictyosome of 1～2 piece 100～300 sieve apertures wherein also can be installed.
By utilizing these shaped container, flavor compositions of the present invention can more easily discharge fragrance, not only can reduce the remaining fragrance behind the hard surface detergent, and, the perfume compound that uses after also can not influencing or the fragrance of bath shampoo.
Embodiment
Below enumerate embodiment and comparative example specifically describes the present invention.
(embodiment 1～3 and comparative example 1～2)
According to table 1～3, preparation flavor compositions 1 (embodiment 1), flavor compositions 2 (embodiment 2) and flavor compositions 3 (embodiment 3).
In addition, with independent limonene as a comparative example 1, the flavor compositions shown in the table 4 as a comparative example 2.
Table 1
| Spices 1 (strawberry type) | Allotment amount (mass parts) |
| Ethyl acetate | ????10 |
| Ethyl butyrate | ????30 |
| Valeric acid ethylester | ????5 |
| Cis-3-hexenol | ????5 |
| Linaool | ????15 |
| The acetate benzyl ester | ????10 |
| Acetate o-tert-butyl cyclohexyl | ????20 |
| γ-hendecoic acid lactone | ????5 |
| Add up to | ????100 |
Table 2
| Spices 2 (apple shape) | Allotment amount (mass parts) |
| Hexyl acetate | ????4 |
| Ethyl butyrate | ????5 |
| Oil of apple | ????25 |
| Pentyl butyrate | ????15 |
| Linalool | ????15 |
| Meraneine | ????10 |
| Acetate o-tert-butyl cyclohexyl | ????20 |
| N-Hexyl salicylate | ????6 |
| Add up to | ????100 |
Table 3
| Spices 3 (pineapple type) | Allotment amount (mass parts) |
| Ethyl acetate | ????15 |
| Ethyl butyrate | ????20 |
| Ethyl hexanoate | ????5 |
| Linalool | ????15 |
| Meraneine | ????10 |
| Acetate o-tert-butyl cyclohexyl | ????20 |
| The enanthic acid allyl ester | ????10 |
| Vanillin | ????5 |
| Add up to | ????100 |
Table 4
| Spices 4 (orange type) | Allotment amount (mass parts) |
| Mandarin oil | ????15 |
| Limonene | ????45 |
| The dihydro methyl jasmonate | ????20 |
| Linalool | ????5 |
| Meraneine | ????5 |
| Acetate o-tert-butyl cyclohexyl | ????5 |
| Galaxolide | ????5 |
| Add up to | ????100 |
Test example 1
Use the spices of embodiment 1～3 and comparative example 1～2, make the washing composition of prescription shown in the table 5.When obtaining the tax perfume rate of shelter need,, carry out the sense test with 20 people overseers.
In addition, according to following method and standard, observe container and have or not swelling.
(method)
The container of clean polypropylene system is divided into suitable size block, makes test piece.This test piece is immersed in 4 weeks in the reagent under 40 ℃.Measure before the dipping and the changes in weight behind the dipping.
(benchmark)
Swelling is arranged: velocity of variation is more than 1%
No problem: velocity of variation is lower than 1%
The result is illustrated in table 6.
Table 5
| Composition | Allotment amount (mass parts) |
| Moisture | Residual amount |
| Spices | In right amount |
| Diethylene glycol monobutyl ether | ????5 |
| Na soap | ????1.5 |
| The fatty acid distribution of coconut oil diglycollic amide | ????1.0 |
| The polyoxyethylene Sodium Lauryl Sulphate BP/USP | ????2.5 |
| Phenylformic acid Na | ????0.5 |
| EDTA-4?Na | ????8 |
| Add up to | ????100 |
Table 6
| Use spices | The fragrant rate of the tax that the shelter needs | Tester (n=20) | Chamber test | ||
| Like (%) | Not (%) | Dislike (%) | |||
| It is limonene (comparative example 1) | ????0.4 | ????30 | ????40 | ??30 | Swelling is arranged |
| Spices 4 (comparative example 2) | ????0.1 | ????50 | ????40 | ??10 | Swelling is arranged |
| Spices 1 (embodiment 1) | ????0.05 | ????70 | ????30 | ??0 | Out of question |
| Spices 2 (embodiment 2) | ????0.1 | ????80 | ????20 | ??0 | Out of question |
| Spices 3 (embodiment 3) | ????0.05 | ????75 | ????20 | ??5 | Out of question |
(test example 2)
The flavor compositions (spices 1) of use embodiment 1, independent limonene (comparative example 1) and the flavor compositions (spices 4) of comparative example 2 are mixed with the hard surface detergent compositions of filling a prescription shown in the table 5.Fill it into flip-over type shaped container A, and outpouring a shaped container B that mouth has the extrusion type of sieve aperture structure, and general bottle container C in, respectively to 1m
2Unit bath face spray about 5ml, by special juror the degree of the release of fragrance is carried out functional evaluation.
Its result is illustrated in the table 7.
Table 7
| The washing composition of the table 5 of the flavor compositions of use embodiment 1 | The washing composition of the table 5 of the flavor compositions of use comparative example 1 | The washing composition of the table 5 of the flavor compositions of use comparative example 2 | |
| Container A | ????◎ | ????× | ????△ |
| Container B | ????◎ | ????× | ????× |
| Container C | ????○ | ????× | ????× |
◎: fragrance discharges very good, does not have residual perfume (or spice)
Zero: fragrance discharges, and residual perfume (or spice) is arranged slightly
△: fragrance discharges bad, and residual perfume (or spice) is arranged
*: fragrance discharges very bad, and is residual fragrant severe
As can be seen from Table 7, flavor compositions of the present invention by using shaped container, can further improve the fragrance release, reduces residual perfume (or spice).
According to the present invention, the hard surface detergent flavor compositions can be provided, and it has the fragrance that is different from citrus, does not have the swelling of container and the problem of injury plastics etc., and the release property of the shielding of preparation flavor and the fragrance when cleaning is good, and the residual perfume (or spice) when not washing.In addition, the hard surface detergent compositions of having allocated flavor compositions of the present invention is filled into the interior washing composition of shaped container, and is better than the release property of the hard surface detergent that is filled into bottle container.
Claims (2)
1. a hard surface detergent flavor compositions is characterized in that in fragrance component, contains the above boiling point of 10 quality % at the ester cpds below 200 ℃.
2. a hard surface detergent compositions has wherein been allocated flavor compositions as claimed in claim 1, it is characterized in that this hard surface detergent compositions is filled in the shaped container.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP065461/2003 | 2003-03-11 | ||
| JP2003065461A JP2004269791A (en) | 2003-03-11 | 2003-03-11 | Perfume composition for hard surface detergent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1530430A true CN1530430A (en) | 2004-09-22 |
Family
ID=33126478
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2004100084380A Pending CN1530430A (en) | 2003-03-11 | 2004-03-10 | Perfume composition for hard-surface abstergent |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP2004269791A (en) |
| CN (1) | CN1530430A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106235934A (en) * | 2015-06-11 | 2016-12-21 | 天津市地文高科技发展有限公司 | A kind of bathroom cleaning wet tissue |
| CN108531298A (en) * | 2018-04-10 | 2018-09-14 | 上海应用技术大学 | A kind of washing powder and preparation method thereof containing gold bergamot essential oil microcapsules |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5328084B2 (en) * | 2005-08-05 | 2013-10-30 | ライオン株式会社 | Liquid softener composition |
| WO2008018186A1 (en) * | 2006-08-07 | 2008-02-14 | Lion Corporation | Liquid softener composition |
-
2003
- 2003-03-11 JP JP2003065461A patent/JP2004269791A/en active Pending
-
2004
- 2004-03-10 CN CNA2004100084380A patent/CN1530430A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106235934A (en) * | 2015-06-11 | 2016-12-21 | 天津市地文高科技发展有限公司 | A kind of bathroom cleaning wet tissue |
| CN108531298A (en) * | 2018-04-10 | 2018-09-14 | 上海应用技术大学 | A kind of washing powder and preparation method thereof containing gold bergamot essential oil microcapsules |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2004269791A (en) | 2004-09-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| WO2007002478A2 (en) | Carrier foam to enhance liquid functional performance | |
| EP0521899A1 (en) | Liquid hand-cleansing agent | |
| EP2678411A1 (en) | Wc gel | |
| CN1530430A (en) | Perfume composition for hard-surface abstergent | |
| JP2003176497A (en) | Cleanser composition for glass | |
| JP2003183697A (en) | Detergent composition for rest room | |
| DE2043341B2 (en) | Use of p-menthan-8-thiol-3-one as a fragrance | |
| DE102012215536A1 (en) | Toilet Gel | |
| JP3677675B2 (en) | Antifouling detergent composition for hard surfaces | |
| CN1359418A (en) | Aqueous cleaning compositions | |
| US5424001A (en) | Graphic ink remover composition containing dibasic ester and method of removing ink | |
| JP2003183698A (en) | Detergent composition for bathroom | |
| EP0174689B1 (en) | Fragrant liquid cleaning compositions | |
| EP1780258B1 (en) | Perfume composition | |
| AT525502B1 (en) | Mixtures containing enantiomerically pure Ambrocenide® | |
| DE2652452A1 (en) | CYCLOHEXENESTER, THE PROCESS FOR THEIR PRODUCTION AND THEIR USE IN FRAGRANCE COMPOSITIONS | |
| TWI814920B (en) | Gel-like detergent composition, method for suppressing decrease in gel strength of gel-like detergent composition | |
| DE60203748T2 (en) | 1,3-oxathiane as fragrance or flavoring | |
| JPH05331047A (en) | Aqueous composition | |
| JP2003239000A (en) | Liquid detergent composition | |
| DE2757559C2 (en) | Use of the 3,5,5-trimethylhexanoic acid esters as fragrances and fragrance compositions containing them | |
| DE102010042805A1 (en) | Self-adhesive sanitary agent | |
| JP2020002242A (en) | Gelatinous detergent composition | |
| US20020193281A1 (en) | Use of fatty acid lower alkyl esters as wetting additives | |
| EP2904078B1 (en) | Flavor and fragrance formulation (vi) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |