CN1528943A - Low-temperature vacuum plasma sulfurizing process - Google Patents
Low-temperature vacuum plasma sulfurizing process Download PDFInfo
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- CN1528943A CN1528943A CNA031350011A CN03135001A CN1528943A CN 1528943 A CN1528943 A CN 1528943A CN A031350011 A CNA031350011 A CN A031350011A CN 03135001 A CN03135001 A CN 03135001A CN 1528943 A CN1528943 A CN 1528943A
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- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The invention refers to metal surface process technology field, especially a process of low temperature vacuum plasma sulfurizing for wearing resisting of metal surface. The principle is using ion to strike, makes the surface of piece form the FeS, and realizes sulfurizing. The concrete method is: the pieces are put on the negative board in low vacuum container, the shell of vacuum container is jointed with positive pole, adds in a little sulfur. Powers a direct current voltage to the negative and positive ends, when the voltage reach a fixed value, the sulfur is ionized into sulfur ion by the effect of electricity field, the positive ion moves to the negative pole, it is accelerated by the negative pressured decreasing near the negative pole, the ion with high speed strikes metal surface, and enters the metal base body, forms the sulfurizing layer. The sulfurizing process temperature is low, it can save energy sources, and it is stable.
Description
Relate to the field
The present invention relates to field of metal surface treatment technology, especially a kind of processing method that is used for the wear-resistant cryogenic vacuum plasma body sulfurizing of metallic surface anti-attrition.
Background technology
Electrolytic process is adopted in external sulfurizing more, owing to produce prussiate, pollutes greatly, also has shortcomings such as the surface accuracy of change and surfaceness.Denomination of invention is that ionitrocarburizing and middle temperature ion sulfurization compounding method, the patent No. are 97125869.4, the patent of invention of Granted publication CN1049252C discloses a kind of nitriding, carbon, sulphur are the method for finishing in a step, wherein the temperature of sulfurizing technology workpiece is 200-400 ℃, vacuum tightness 600-800Pa, this processes expend energy height, and when heat, the workpiece easy deformation reduces yield rate.
Summary of the invention
The purpose of this invention is to provide a kind of cryogenic vacuum plasma body sulfurizing technology method, this processing method does not change roughness, precision, hardness and the structure of processed workpiece, ion enters and forms self-lubricating layer and matrix one integrated mass in the workpiece surface, and the bite-resistant performance is good.
Cryogenic vacuum plasma sulpurizing principle: utilize ion bombardment, make workpiece surface form FeS, reach the sulfurizing purpose.Concrete grammar is that workpiece is placed on the negative plate of rough vacuum container, with the outer shell joint anode of vacuum vessel, adds a small amount of sulphur.Add a direct current voltage at the anode and cathode two ends, when voltage reaches a certain numerical value, sulphur this moment direct ionization under electric field action becomes sulfonium ion, gained positive ion behind the ionization of gas, to cathode motion the time, near negative electrode, be subjected to rapid cathode drop effect and quicken the ion bombardment metallic surface of this high-speed motion, enter in the metallic matrix, form sulphide layer.
Cryogenic vacuum plasma body sulfurizing technology method comprises the following steps:
1. treat that the sulfurizing workpiece at first carries out pre-treatment, i.e. cleaning, greasy dirt and the impurity of method to remove the sulfurizing face for the treatment of of employing gasoline and kerosene cleaning and ultrasonic cleaning, operations such as non-sulfurizing face will cover, shielding;
2. treat to put into the large industrialized synthetic furnace after the sulfurizing workpiece cleaning, workpiece is a negative electrode, and furnace shell is an anode, intensification also is evacuated to 50Pa, and logical ammonia and hydrogen sulfide in stove keep vacuum not to be higher than 50Pa, boosted voltage extremely rises till the aura, after temperature is raised to preset temperature, begins insulation;
3. after insulation finishes, stop air feed and bleed, cut off the aura power supply, part is furnace cooling in sulfurizing atmosphere, treats that part is reduced to below 60 ℃ can come out of the stove, and the back oil removing in time of coming out of the stove is antirust.
4. main technical details:
1) anode and cathode is under antivacuum state, insulation resistance≤4 * 10
6Ω;
2) under antivacuum state, bear power-frequency voltage 2V between the anode and cathode
0No punch-through that+1000V is withstand voltage;
3) final vacuum 〉=6.7Pa;
4) be extracted into highest attainable vacuum required time≤30 minute at empty stove state 3m stove normal atmosphere, 4m stove≤40 minute;
5) under working gas peak flow situation, vacuum pump should guarantee at desired vacuum tightness 50-10Pa;
6) specified line voltage 380V ± 10%;
7) the specified 1000V of rectifier output voltage when 200V is above, does not have the kick phenomenon when adjusting continuously;
8) direct current output rated current is 45A, and can be adjustable continuously;
9) exchange rated output 60KW;
10) sulfurizing internal tank top temperature is 250 ℃;
11) quenching time 10
-4S;
12) water consumption 400Kg/h.
Advantage of the present invention is: compare with the ion nitrogen carbon method have vacuum tightness require low, the sulfurizing technology temperature is low, saves advantages such as the energy, working reliability are strong, product reliability and life-span are improved 3-5 doubly after the sulfurizing.Comparing fused salt with electrolytic process does not have prussiate, healthy favourable with environmental protection to the operator, and workpiece dimensional accuracy, roughness are not changed, and sulphide layer is controlled, does not influence basic unit's hardness, does not change to ooze the part size.
Embodiment
Cryogenic vacuum plasma body sulfurizing technology method is operated as follows:
1. workpiece cleaning; Treat that the sulfurizing workpiece at first carries out pre-treatment, i.e. cleaning, greasy dirt and the impurity of method to remove the sulfurizing face for the treatment of of employing gasoline and kerosene cleaning and ultrasonic cleaning, operations such as non-sulfurizing face will cover, shielding;
2. vulcanisation operation;
1) treat to put into the large industrialized synthetic furnace after the sulfurizing workpiece cleaning, workpiece is a negative electrode, and furnace shell is an anode, and the power turn-on master switch is opened vacuum pump, opens manually-operated gate gradually.When treating that vacuum is extracted into 50Pa, turn off vacuum pump, logical ammonia is turned off ammonia when vacuum drops to 10Pa in stove, stops 10 minutes, continues to vacuumize again.
2) treat that vacuum is extracted into 50Pa with the interior high-voltage switch gear of opening, keep vacuum not to be higher than 50Pa.
3) current switch I shelves are opened, adjusted high voltage potential meter gradually, boosted voltage extremely rises till the aura.
4) beat situations such as arc, aura, temperature and vacuum according to workpiece in the stove, adjust high voltage potential meter.
5) according to the degree of cleaning of different workpiece and workpiece, select current switch I-IV shelves, before gear shift, high voltage potential meter must be transferred to minimum, gear shift then.
6) after temperature is raised to preset temperature, begin insulation, shutdown after a hour.Come out of the stove oiling packing of naturally cooling, workpiece.Forbid high temperature to be come out of the stove.
7) the shutdown trends of the times will high voltage potential meter transfer to minimumly, turn off current gear then, turn off high-voltage switch gear at last.
Claims (1)
1. a cryogenic vacuum plasma body sulfurizing technology method is characterized in that comprising the following steps:
1. treat that the sulfurizing workpiece at first carries out pre-treatment, i.e. cleaning, greasy dirt and the impurity of method to remove the sulfurizing face for the treatment of of employing gasoline and kerosene cleaning and ultrasonic cleaning, operations such as non-sulfurizing face will cover, shielding;
2. treat to put into the large industrialized synthetic furnace after the sulfurizing workpiece cleaning, workpiece is a negative electrode, and furnace shell is an anode, intensification also is evacuated to 50Pa, and logical ammonia and hydrogen sulfide in stove keep vacuum not to be higher than 50Pa, boosted voltage extremely rises till the aura, after temperature is raised to preset temperature, begins insulation;
3. after insulation finishes, stop air feed and bleed, cut off the aura power supply, part is furnace cooling in sulfurizing atmosphere, treats that part is reduced to below 60 ℃ can come out of the stove, and the back oil removing in time of coming out of the stove is antirust;
4. main technical details:
1) anode and cathode is under antivacuum state, insulation resistance≤4 * 10
6Ω;
2) under antivacuum state, bear power-frequency voltage 2V between the anode and cathode
0No punch-through that+1000V is withstand voltage;
3) final vacuum 〉=6.7Pa;
4) be extracted into highest attainable vacuum required time≤30 minute at empty stove state 3m stove normal atmosphere, 4m stove≤40 minute;
5) under working gas peak flow situation, vacuum pump should guarantee at desired vacuum tightness 50-10Pa;
6) specified line voltage 380V ± 10%;
7) the specified 1000V of rectifier output voltage when 200V is above, does not have the kick phenomenon when adjusting continuously;
8) direct current output rated current is 45A, and can be adjustable continuously;
9) exchange rated output 60KW;
10) sulfurizing internal tank top temperature is 250 ℃;
11) quenching time 10
-4S;
12) water consumption 400Kg/h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03135001 CN1216179C (en) | 2003-09-30 | 2003-09-30 | Low-temperature vacuum plasma sulfurizing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03135001 CN1216179C (en) | 2003-09-30 | 2003-09-30 | Low-temperature vacuum plasma sulfurizing process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1528943A true CN1528943A (en) | 2004-09-15 |
| CN1216179C CN1216179C (en) | 2005-08-24 |
Family
ID=34286253
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 03135001 Expired - Fee Related CN1216179C (en) | 2003-09-30 | 2003-09-30 | Low-temperature vacuum plasma sulfurizing process |
Country Status (1)
| Country | Link |
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| CN (1) | CN1216179C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101914748A (en) * | 2010-08-13 | 2010-12-15 | 中国人民解放军装甲兵工程学院 | Process for preparing high-quality FeS film through supersonic microparticle bombardment and low temperature ion sulphurizing complex treatment |
| CN101956155A (en) * | 2010-09-30 | 2011-01-26 | 北京天马轴承有限公司 | Gas plasma sulfurizing process |
| CN102505106A (en) * | 2011-12-30 | 2012-06-20 | 瓦房店轴承集团有限责任公司 | Surface treatment process for wind power generation spindle bearing |
| CN105951033A (en) * | 2016-05-13 | 2016-09-21 | 青岛普雷斯马微波科技有限公司 | Microwave plasma diffusion sulfur plating technology |
| CN108640114A (en) * | 2018-05-16 | 2018-10-12 | 合肥工业大学 | A kind of catamaran type activated carbon vacuum sulfurizing device and its application method |
-
2003
- 2003-09-30 CN CN 03135001 patent/CN1216179C/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101914748A (en) * | 2010-08-13 | 2010-12-15 | 中国人民解放军装甲兵工程学院 | Process for preparing high-quality FeS film through supersonic microparticle bombardment and low temperature ion sulphurizing complex treatment |
| CN101956155A (en) * | 2010-09-30 | 2011-01-26 | 北京天马轴承有限公司 | Gas plasma sulfurizing process |
| CN102505106A (en) * | 2011-12-30 | 2012-06-20 | 瓦房店轴承集团有限责任公司 | Surface treatment process for wind power generation spindle bearing |
| CN105951033A (en) * | 2016-05-13 | 2016-09-21 | 青岛普雷斯马微波科技有限公司 | Microwave plasma diffusion sulfur plating technology |
| CN105951033B (en) * | 2016-05-13 | 2018-03-23 | 青岛普雷斯马微波科技有限公司 | A kind of microwave plasma plating sulphur technique |
| CN108640114A (en) * | 2018-05-16 | 2018-10-12 | 合肥工业大学 | A kind of catamaran type activated carbon vacuum sulfurizing device and its application method |
| CN108640114B (en) * | 2018-05-16 | 2021-04-13 | 合肥工业大学 | Double-body type active carbon vacuum sulfurizing device and using method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1216179C (en) | 2005-08-24 |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20050824 Termination date: 20091030 |