CN1528721A - Plateau windbreak match - Google Patents
Plateau windbreak match Download PDFInfo
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- CN1528721A CN1528721A CNA2003101018606A CN200310101860A CN1528721A CN 1528721 A CN1528721 A CN 1528721A CN A2003101018606 A CNA2003101018606 A CN A2003101018606A CN 200310101860 A CN200310101860 A CN 200310101860A CN 1528721 A CN1528721 A CN 1528721A
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Abstract
The invention discloses a plateau windproof match, composed of matchstick, drug coat adhering to the matchstick and drug head coat adhering to the surface on the end of the drug coat, where: the drug coat is prepared of the components in weight share: potassium chlorate 50-53, sodium nitrate or potassium nitrate 6-9, sulfur 1-2, cornstarch or celluloid 8-11, skin glue 9-11, formaldehyde 3-5, zinc oxide 2-4, filling agent 10-15 and corresponding colorant 0-10; drug head coat prepared of the components in weight share: potassium chlorate 47-50, sulfur 3-5, boracic acid 0.5, skin glue 9-11, zinc oxide 1-2, filling agent 30-35, plaster 1-3 and corresponding colorant 0-10. It is environmental-protection and applied on plateau anoxic condition, able to resist 9-10 level wind, quickly igniting, where when it ignites, its drug coat can uniformly combust for 8-11 seconds.
Description
Technical field
The present invention relates to a kind of match, be specifically related to a kind of have wind resistance, moisture-proof function, the match that can in altitude environment, use and medicine layer formula thereof.
Background technology
Storm match is that a kind of still can the wiping in high wind and wet environment drawn the match of getting angry, and belongs to extraordinary match, is adapted at carrying out under the weather complex conditions personnel's use of work, as navigation, fishing and hunting, the hydrology, geological prospecting etc.Existing storm match, its match wood is generally with phosphoric acid or ammonium dihydrogen phosphate dipping, the medicine head is formulated with Potcrate 50～53%, sulphur 8～9%, starch 3～4%, zinc oxide 5～6%, potassium bichromate 1.5%, glass powder 10～18%, hide glue 9～10%, and medicine layer length is at 30 millimeters; Be to improve match and wipe and draw a sensitivity, can adopt the method for being stained with head for twice, be stained with the higher little medicine head of a sensitivity, by the burning of the little medicine head storm match medicine head that ignites at the medicine cephalic par of being stained with.But in the above-mentioned storm match medicine head, sulfur consumption is bigger, and still use chromic salts as tanning agent, do not meet environment protection requirement, on the other hand, under altitude environment, because high altitude anoxia, various matches or portfire all can run into the difficult problem of getting angry, above-mentioned storm match is no exception, it is out of condition that it issues fire in altitude environment, wipes combustion back match medicine head, the burning of medicine stalk is ineffective, and the medicine stalk is only smoldered and misfired and extinguish very soon, can't play the effect of igniting, the wind resistance effect is undesirable.
Summary of the invention
The purpose of this invention is to provide a kind of plateau environmental protection storm match that under hypoxic plateau environment, can use for the personnel of army or other field works.
For achieving the above object, the present invention takes following design:
The invention provides a kind of plateau storm match, it by match wood, attach the medicine layer on match wood and attach and form at the medicine head layer of medicine layer end surface, wherein:
Described medicine layer is formed by following component assembly:
Potcrate 50～53 weight parts;
Oxygenant II 6～9 weight parts, described oxygenant II is SODIUMNITRATE or saltpetre;
Sulphur 1～2 weight part;
Incendiary material II 8～11 weight parts, described incendiary material II are to be selected from a kind of in W-Gum, the zylonite;
Hide glue 9～11 weight parts;
Formaldehyde 3～5 weight parts;
Zinc oxide 2～4 weight parts;
Weighting agent 10～15 weight parts, described weighting agent are to be selected from ground silica, quartz sand or the talcum powder one or more;
Medicine layer tinting material 0～10 weight part, described tinting material are selected from a kind of in red iron oxide, carbon black, Manganse Dioxide and titanium dioxide, lithopone and other pigment or the dyestuff;
Described medicine head layer is formed by following component assembly:
Potcrate 47～50 weight parts;
Sulphur 3～5 weight parts;
Boric acid 0.5 weight part;
Hide glue 9～11 weight parts;
Zinc oxide 1～2 weight part;
Weighting agent 30～35 weight parts, described weighting agent are to be selected from ground silica, quartz sand or the talcum powder one or more;
Gypsum 1～3 weight part; And
Medicine head layer tinting material 0～10 weight part, described tinting material are to be selected from a kind of in red iron oxide, carbon black, Manganse Dioxide and titanium dioxide, lithopone and other pigment or the dyestuff.
In the storm match of above-mentioned plateau, described medicine head layer tinting material and medicine layer tinting material are selected material not of the same race for use.
In the storm match of above-mentioned plateau, described match wood length is 60 millimeters, and described medicine layer length is 45 millimeters.
Adopt technique scheme, advantage of the present invention is:
1, innovation has used nitrate as oxygenant in the storm match medicine layer of plateau of the present invention, and rational allocation oxygenant, incendiary material equal proportion, make match of the present invention after wiping combustion, with 5～7 millimeters speed burning p.s., and kept this speed homogeneous combustion 8～11 seconds, can anti-storm power;
2, do not contain dichromate in the storm match medicine layer of plateau of the present invention, and only contain Determination of Trace Sulfur, compliance with environmental protection requirements;
3, plateau of the present invention storm match, except general moist, have in the wind environment and use, can also in altitude environment, use.
4, plateau of the present invention storm match gets medicine layer length and is increased to 45 millimeters, and the medicine layer can not extinguish in perfect combustion, has strengthened result of use.
Description of drawings
Fig. 1 is a plateau of the present invention storm match structural representation.
Embodiment
Storm match of the present invention is mainly considered from following several respects:
One, match specification
More common match, the match wood normal length of storm match is 60 millimeters, and area of section is 2.3 * 2.3 millimeters, and the medicine layer has a segment length, and diameter is about 5～6 millimeters, and the medicine layer thickness is 1.2～1.6 millimeters, and the medicine layer is a cigar shape.The storm match structure can be referring to Fig. 1, and 11 is match wood, and 12 is the medicine layer, and 13 is medicine head layer.
In the present invention, for adapting to the assembly of medicine layer, adapt to the medicine grate firing and burn speed and adjust the medicine grate firing burning time, medicine layer length of the present invention increases to 45 millimeters.
On the other hand, the present invention adopts secondary to be stained with the mode of head, attaches medicine head layer again at medicine layer cross cut end (of a beam), and medicine head layer length has the 2-5 millimeter to get final product, and being mainly used in increases the sensitivity of wiping combustion.
Two, the assembly of storm match medicine head
The prescription of match medicine head is generally suited measures to local conditions, but in the match assembly, comprises several components substantially:
Oxygenant: Potcrate commonly used, by adjusting the consumption of Repone K, can adjust the power of medicine hair firepower;
Among the present invention, use single Potcrate as oxygenant, its ignition quality is not good, thus add nitrate (saltpetre or SODIUMNITRATE) as oxygenant, and adjust its proportioning according to test.
Incendiary material: sulphur commonly used, also can mix rosin or needle antimony.The use of incendiary material can improve the heat energy of getting angry sensitivity and burning and producing.Among the present invention, for reaching environmental requirement, only use the sulphur of trace, other incendiary material of blending simultaneously, the present invention is referred to as incendiary material II, can be W-Gum, rosin, zylonite or boric acid.
Tackiness agent: generally select gelatin for use.Select hide glue among the present invention for use.The emulsifying capacity of the moisture resistance performance of the consumption of hide glue and quality influence medicine head and medicine slurry is to the knot slurry typing of medicine slurry with to be stained with a difficulty or ease all influential.The present invention selects for use hide glue and consumption thereof can guarantee the quality of medicine head well, and adapts to the match process requirements.
Tanning agent: the tanning agent that uses of tradition is potassium bichromate, can be to tanning of colloid, and helpful to match medicine head moisture resistance power and sensitivity, after burning, match medicine head can prevent that ashes from dispersing.Because potassium bichromate belongs to highly toxic substance, match incendiary chromium cpd can be invaded human body by respiratory tract with flue gas and be worked the mischief, and therefore, does not use potassium bichromate as tanning agent among the present invention, and with formaldehyde as tanning agent.Formaldehyde can play superimposed effect with colloid in storm match, thereby changes the gelationus solvability, and colloid viscosity is increased, and has tanning and anticorrosion dual function; In addition, formaldehyde also can react with glutin, generates methylene compound and makes two adjacent peptide bonds crosslinked, thereby make gelatin molecule structural strengthening reduce water absorbing properties, improves match moisture resistance power.Formaldehyde has certain volatility, and the residual unreacting acetal in the match medicine head can volatilize in the short period, and its residual quantity is very low when match uses, and is very little to the harm of human body.
Solubility promoter: use boric acid as solubility promoter, the B that it is melt into 300 ℃ of dehydration decomposition
2O
3Can the weighting material in the medicine head be bonded together, form a complete grey structure, complete ashes are arranged after the burning, and can prevent to drip fire, can strengthen the stability of medicine head again; In addition, boric acid is to prolonging medicine head combustion time, makes match get angry the stable good result that has.
Stablizer: use zinc oxide, its consumption changes can adjust medicine head combustionvelocity.
Tinting material: as the black medicine is first with Manganse Dioxide as tinting material, add carbon black in case of necessity and make color burn; Brown medicine head adopts red iron oxide to make tinting material, can add Manganse Dioxide and regulate the brown depth; White medicine head uses zinc oxide, titanium dioxide, lithopone etc. to make tinting material; Colored medicine head is made colour based on white medicine head at interpolation pigment or fuel.In the present invention, the inessential composition of tinting material can selectivity adds, when using tinting material, and its color and select for use the amount of tinting material to add according to the practical situation allotment.The color of medicine layer and medicine head layer is preferably different colours, is beneficial to distinguish.
Weighting agent: weighting agent commonly used is silica powder, glass powder, diatomite and talcum powder etc.Above-mentioned weighting agent the present invention all can use.
Three, the difference of medicine layer and medicine head layer proportioning
In the present invention, the technology that adopts secondary to be stained with head is made the plateau storm match, considers each factor such as gas volume in ignition situation, combustionvelocity, combustion time, medicine pulp density and the medicine slurry during apolegamy of medicine layer each component.According to repetition test, Chinese traditional medicine layer of the present invention assembly preferably is: Potcrate 50～53 weight parts; Oxygenant II6～9 weight parts; Sulphur 1～2 weight part; Incendiary material II8～11 weight parts; Hide glue 9～11 weight parts; Formaldehyde 3～5 weight parts; Zinc oxide 2～4 weight parts; Weighting agent 10～15 weight parts; Medicine layer tinting material 0～10 weight part.
Mainly consider medicine head layer ignition sensitivity during the apolegamy of medicine head layer each component.The medicine head layer assembly preferably that the present invention selectes is: Potcrate 47～50 weight parts; Sulphur 3～5 weight parts; Boric acid 0.5 weight part; Hide glue 9～11 weight parts; Zinc oxide 1～2 weight part; Weighting agent 30～35 weight parts; Gypsum 1～3 weight part; Medicine head layer tinting material 0～10 weight part.In this proportioning, sulfur consumption wants big than the medicine layer, but because in whole storm match, medicine head layer consumption is less, the concentration of sulfurous gas compliance with environmental protection requirements still during the match end burning; Added the gypsum composition in the medicine head layer proportioning, its effect is the combustionvelocity of regulating the medicine head, and charge head volume increases medicine dosing port hardness, improves the anti-wiping of medicine head and draws ability.
Four, raw materials used quality standard among the present invention
Potcrate: moisture is no more than 5/1000ths, and purity is not less than 99.5%, and water-insoluble is no more than 3/1000ths, and muriate is no more than 4/10000ths, and fineness is fully by 120 orders; Routine inspection muriate, fineness, Potcrate purity in the production.
Sulphur: yellow fine powder, content is not less than 95%, and fineness is all by 120 orders, and free acid (with sulphur acid meter) is no more than 5/1000ths.
Hide glue: yellow fine powder, fineness is passed through 2.36 millimeters square hole (per inch 8 holes) fully, moisture 14～18%, 6 ° of E～525 ° E of viscosity, rubber cement power is not less than 200 grams, molten point is not less than 25 ℃, spumescence: population is long-pending to be no less than 22 milligrams, and the time that colloid surface is raised to more than 13 milliliters is no less than 4 minutes, and ash content is no more than 3%, muriate is no more than 1%, solution time: the glue sample soaks into the back fully with 4.634 times of cold water (below 20 ℃) and dissolved 60 ℃ of water-soluble last 30 minutes.
Ground silica: white, little yellow or light fine powder, carbonate is no more than 1%, and the water solubles is no more than 1%, and oxide compound is no more than 4/10000ths, and fineness is fully by 120 orders.
Zinc oxide: another name (lead powder used in cosmetics, zinc white, zinc white) white fine powder, purity: contain zinc oxide and be not less than 80%, fineness is fully by 120 orders; Routine inspection is volume coefficient and purity.
Gypsum: white powder, crystal water is not less than 3%, is no more than 9%, and calcium sulphate content is more than 80%, and setting time: mix with cold water, setting time is no more than 3 minutes, and fineness is fully by 120 orders.
Boric acid: molecular formula H
3BO
3Outward appearance is 185 ℃ of flakey band gloss crystalline density 1.435 (15 ℃) fusing points of white crystals or three clinopinacoids, i.e. decomposition, odorless, water soluble, ethanol, glycerine simultaneously, and the aqueous solution is the slightly acidic reaction, dehydration becomes boric anhydride in the time of 300 ℃, boric anhydride content 99%.
Saltpetre: call native nitre, nitre, nitre; Molecular formula: KNO
3Water white transparency crystallization or white powder have saline taste, and be inflammable, 337 ℃ of fusing points, proportion 2.10P (16 ℃), water-soluble at 400 ℃ of time-division liberation oxygen, be insoluble to alcohol and ether, be that strong oxidizer contacts in inflammable substance, organism, can cause combustion explosion, and take place poisonous and irritating smell.
W-Gum: molecular formula (C
6H
10D
5)
nBe trickle granular, white powder, main component is a carbohydrate, and its composition is roughly moisture 13.31%, crude protein 1.2%, crude fat 0.01%, robust fibre vestige, ash 0.37%, starch 85.11%, be slightly soluble in water, in hot water (50 ℃), can expand into certain temperature (58 ℃～77 ℃) gelatinization of will breaking, meet iodine solution and be blue reaction heating disappearance, it is blue that cooling is again, is the ins and outs of starch.
Specific embodiment explanation the present invention below is provided.
Embodiment one
The medicine layer: get Potcrate 51 grams, SODIUMNITRATE 8 grams, sulphur 1 gram, zylonite 10 grams, hide glue 10 grams, formaldehyde 4 grams, zinc oxide 4 grams, ground silica 12 grams, titanium dioxide 2 grams, veridian 1 gram modulation patent medicine slurry is standby.
Medicine head layer: get Potcrate 48 grams, sulphur 4 grams, boric acid 0.5 gram, hide glue 10 grams, gypsum 2 grams, zinc oxide 1.5 grams, quartz sand 34 grams, red iron oxide 7 gram modulation patent medicine slurries are standby.
Get the match wood (long 60 millimeters) that makes, flood in 1% phosphoric acid, baking is after 15 minutes down at 100 ℃, and match wood is stained with wax, afterwards, attach the above-mentioned medicine layer medicine slurry that modulates at match wood one end, medicine layer length is 45 millimeters, after toasting 50 minutes about 45 ℃, attach the above-mentioned medicine head layer medicine slurry that modulates on the top of medicine layer, about 45 ℃,, promptly obtain plateau of the present invention storm match, can be used for step packing down oven dry 30 minutes.
Embodiment two to embodiment six
Adopt following table 1 assembly, make the plateau storm match according to the method for embodiment one.
Table 1: embodiment two to embodiment six
| Component (g) | Embodiment two | Embodiment three | Embodiment four | Embodiment five | Embodiment six | |
| The assembly of medicine layer | Potcrate | 50 | 51 | 52 | 53 | 51 |
| Oxygenant II | SODIUMNITRATE 9 | Saltpetre 8 | Saltpetre 7 | SODIUMNITRATE 6 | Saltpetre 7 | |
| Sulphur | 2 | 1 | 1.5 | 1 | 1.2 | |
| Incendiary material II | Zylonite 9 | W-Gum 10 | Rosin 11 | Zylonite 9 | W-Gum 10 | |
| Hide glue | 10 | 9 | 10 | 9.5 | 11 | |
| Formaldehyde | 4 | 3 | 4 | 3.5 | 5 | |
| Zinc oxide | 2 | 3 | 3 | 4 | 4 | |
| Weighting agent | Ground silica 10 | Quartz sand 13 | Glass powder 12 | Diatomite 11 | Sliding diamond stone 15 | |
| Tinting material | - | Titanium dioxide/basket 2/1 | Lithopone/ash 2/2 | - | Red iron oxide 9 | |
| The assembly of medicine head layer | Potcrate | 47 | 48 | 49 | 50 | 48 |
| Sulphur | 3 | 4 | 5 | 5 | 4 | |
| Boric acid | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | |
| Hide glue | 10 | 9 | 10 | 9.5 | 11 | |
| Gypsum | 1 | 2 | 3 | 2 | 2.5 | |
| Zinc oxide | 1 | 2 | 1.5 | 1.5 | 1 | |
| Weighting agent | Quartz sand 30 | Ground silica 31 | Diatomite 32 | Glass powder 34 | Sliding diamond stone 35 | |
| Tinting material | Manganse Dioxide 8 | Titanium dioxide 2 | Red iron oxide 9 | Lithopone/red 2/1 | - | |
Storm match to the foregoing description manufacturing carries out wind resistance and combustionproperty detection, result such as table 2 under altitude environment:
Table 2: match wind resistance and combustionproperty detected result
| Five | ????10 | Rapidly | ????4 | ????11 |
| Six | ????10 | Rapidly | ????5 | ????9 |
| Common match | ????0 | Do not fire | ????- | ????- |
| Common storm match | ????5 | But ignition has cigarette not have fire | ????- | The time 3s of being fuming |
In the above-mentioned detection, altitude environment detects in Lhasa urban district and height above sea level the Yangbajing mountain area 4600 meters or more of Tibet plateau height above sea level more than 3700 meters on the spot; Wind resistance rank detection method is: during according to the wind conditions of testing local weather forecast on the same day and army's field training the on-the-spot wind-force of method evaluation test is declared in the simple and easy survey of wind direction.Situation determination methods standard on fire is: the match that detects by an unaided eye is wiped whether to produce visible flame after the combustion or blank sheet of paper is put in the storm match top and is observed and whether light vestige at blank sheet of paper edge, match burning back and judge.Combustion time and combustionvelocity detection method are: test with stopwatch combustion time, and the starting point of test is wiped combustion constantly for the medicine head, and terminal point is the moment that match flame extinguishes; Combustionvelocity is the ratio of match burning length and combustion time.
According to above table, as can be seen, storm match of the present invention is suitable for using under altitude environment, can resist 9～storm, and ignition is rapid, but medicine layer homogeneous combustion behind the ignition, and the time length can be at 8～11 seconds.And in the comparative example, common match can not use, and common storm match ignition is fuming and is just extinguished about 3 seconds, can't play the effect of igniting.
Claims (5)
1, a kind of plateau storm match, it by match wood, attach the medicine layer on match wood and attach and form at the medicine head layer of medicine layer end surface, it is characterized in that, wherein:
Described medicine layer is formed by following component assembly:
Potcrate 50～53 weight parts;
Oxygenant II 6～9 weight parts, described oxygenant II is SODIUMNITRATE or saltpetre;
Sulphur 1～2 weight part;
Incendiary material II 8～11 weight parts, described incendiary material II are to be selected from a kind of in W-Gum, the zylonite;
Hide glue 9～11 weight parts;
Formaldehyde 3～5 weight parts;
Zinc oxide 2～4 weight parts;
Weighting agent 10～15 weight parts, described weighting agent are to be selected from ground silica, quartz sand or the talcum powder one or more;
Medicine layer tinting material 0～10 weight part, described tinting material are selected from a kind of in red iron oxide, carbon black, Manganse Dioxide and titanium dioxide, lithopone and other pigment or the dyestuff;
Described medicine head layer is formed by following component assembly:
Potcrate 47～50 weight parts;
Sulphur 3～5 weight parts;
Boric acid 0.5 weight part;
Hide glue 9～11 weight parts;
Zinc oxide 1～2 weight part;
Weighting agent 30～35 weight parts, described weighting agent are to be selected from ground silica, quartz sand or the talcum powder one or more;
Gypsum 1～3 weight part; And
Medicine head layer tinting material 0～10 weight part, described tinting material are to be selected from a kind of in red iron oxide, carbon black, Manganse Dioxide and titanium dioxide, lithopone and other pigment or the dyestuff.
2, plateau according to claim 1 storm match, it is characterized in that: described medicine layer is formed by following component assembly:
Potcrate 51 weight parts;
SODIUMNITRATE 8 weight parts;
Sulphur 1 weight part;
Zylonite 10 weight parts;
Hide glue 10 weight parts;
Formaldehyde 4 weight parts;
Zinc oxide 4 weight parts;
Ground silica 12 weight parts;
3, plateau according to claim 1 and 2 storm match, it is characterized in that: described medicine head layer is formed by following component assembly:
Potcrate 48 weight parts;
Sulphur 4 weight parts;
Boric acid 0.5 weight part;
Hide glue 10 weight parts;
Zinc oxide 1.5 weight parts;
Quartz sand 34 weight parts;
Gypsum 2 weight parts; And
Red iron oxide 7 weight parts.
4, plateau according to claim 1 storm match, it is characterized in that: described medicine head layer tinting material and medicine layer tinting material are selected material not of the same race for use.
5, plateau according to claim 1 storm match, it is characterized in that: described match wood length is 60 millimeters, described medicine layer length is 45 millimeters.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310101860 CN1235840C (en) | 2003-10-21 | 2003-10-21 | Plateau windbreak match |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310101860 CN1235840C (en) | 2003-10-21 | 2003-10-21 | Plateau windbreak match |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1528721A true CN1528721A (en) | 2004-09-15 |
| CN1235840C CN1235840C (en) | 2006-01-11 |
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ID=34304220
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200310101860 Expired - Fee Related CN1235840C (en) | 2003-10-21 | 2003-10-21 | Plateau windbreak match |
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| Country | Link |
|---|---|
| CN (1) | CN1235840C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111205148A (en) * | 2018-11-21 | 2020-05-29 | 赵长新 | Novel process for making match suitable for personal customization |
-
2003
- 2003-10-21 CN CN 200310101860 patent/CN1235840C/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111205148A (en) * | 2018-11-21 | 2020-05-29 | 赵长新 | Novel process for making match suitable for personal customization |
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| Publication number | Publication date |
|---|---|
| CN1235840C (en) | 2006-01-11 |
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Granted publication date: 20060111 Termination date: 20101021 |