CN1513663A - Ultrasonic processing resin transfer moulding method and used apparatus - Google Patents
Ultrasonic processing resin transfer moulding method and used apparatus Download PDFInfo
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- CN1513663A CN1513663A CNA031324304A CN03132430A CN1513663A CN 1513663 A CN1513663 A CN 1513663A CN A031324304 A CNA031324304 A CN A031324304A CN 03132430 A CN03132430 A CN 03132430A CN 1513663 A CN1513663 A CN 1513663A
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Abstract
An ultrasonic treating method for resin transfer moulding (RTM) features that the fibres and resin in the cavity of mould are treated by ultrasonic waves for decreasing the porosity. Its apparatus is composed of air storage tank, resin storage tank, mould resin collecting tank, vacuumizing pump, and ultrasonic unit.
Description
Technical field: the method and the device that the present invention relates to a kind of resin transfer moulding.
Background technology: resin transfer moulding (RTM) technology is little with its environmental pollution, and production efficiency height, equipment simply reach the mould small investment, but characteristics such as large and complex structure goods one-shot forming obtain application more and more widely at home and abroad.RTM technology be with resin system under certain pressure, inject in the closed mould cavity of the good fibre reinforcement of lay in advance, resin soaks into curing molding behind the fibre reinforced materials in die cavity.Resin is an important ring to the infiltration of fibre reinforcement in the RTM technological forming process, because air is difficult for draining in forming process, thereby easily make in the RTM forming composite and produce defective, particularly (loop bonding strengthens body in fibrous composite, braiding strengthens body) particularly evident, this will reduce performance of composites greatly, according to the porosity of document announcement composite in 5%, every increase by 1%, just cause 30% bending strength, 3% hot strength, the loss of 8% impact strength, interlaminar strength descends 7%, thereby resin is extremely important to the wellability and the minimizing porosity of fiber in the raising forming process.
Summary of the invention:, the invention provides a kind of ultrasonic-processing resin transfer molding method and used device for solving the problem that air is difficult for draining in the RTM technological forming process.Ultrasonic-processing resin transfer molding method of the present invention is: in resin transfer molding (RTM) process fiber in the dies cavity and resin are carried out ultrasonic processing.Described ultrasonic frequency is 40～60KHz, and the best is 45～55KHz.The used device of ultrasonic-processing resin transfer molding of the present invention comprises air accumulator 1, storage glue jar 2, mould 3, collection glue jar 4 and vavuum pump 5, and be connected above each the device between glue conveying box, the present invention also includes ultrasonic unit 7, the ultrasonic wave that Vltrasonic device 7 produces is towards mould 3, Vltrasonic device 7 is arranged on the position near mould 3, and be positioned at mould 3 the side, above or below.Principle of the present invention: ultrasonic treatment technology mainly is that the localized hyperthermia, the high pressure effect that produce when utilizing ultrasonic wave to cause collapse of bubbles in liquid cause that resin improves the wellability of fiber.The ultrasonic effect that glue is mainly produced is the activity that helps improving glue, improves the processes characteristic; Utilize ultrasonic cavitation to eliminate unnecessary bubble in the glue.The present invention has following function: (1) sound cavitation effect: acoustic cavitation is meant that the small complex in the liquid is activated under the high-strength ultrasonication of low frequency, show as concussion, growth, the contraction of complex and collapse a series of dynamic processes, the HTHP that around cavitation bubble, produces in the utmost point short time of cavitation bubble collapse, theoretical calculating shows, maximum temperature can reach 5000K, and maximal pressure can reach 5 * 10
7Pa.The cavitation effect of cavitation bubble has produced the percussive pressure of moment, causes the high-speed motion of molecule.And then in liquid, produced local high temperature, high pressure, bring out a series of effect (comprising atomizing, peptizaiton, physics chemical action etc.).(2) acoustic streaming effect: the acoustic streaming effect is meant that ultrasonic finite amplitude decay in liquid makes the certain acoustic pressure gradient that forms in the liquid, thereby makes liquid make the stable phenomenon that circulates.If ultrasonication in liquid, is utilized this acoustic streaming effect, can realize that not only each component in the mixing material is disperseed more evenly, can be made the abundant refinement of component, dispersion in the liquid, and can reach the effect of the breakdown of emulsion in the emulsion.The present invention has following effect: in the RTM forming process, resin improves the wellability of fibre reinforcement through ultrasonic processing, and wet-out rate improves about 30%; Ultrasonic processing can improve the interface performance of RTM forming composite, and power value during the unsticking 50% of interface improves about 36% than untreated samples; Interlaminar shear strength improves about 10% than untreated samples.The present invention improves resin in the RTM forming process to the wellability of fiber with reduce the composite porosity, and then improves the interface performance of composite.
Description of drawings: Fig. 1 is the structural representation of the specific embodiment one, and Fig. 2 is the A-A cutaway view of Fig. 1.
The specific embodiment one: the used device of the ultrasonic-processing resin transfer molding of present embodiment is made up of air accumulator 1, storage glue jar 2, mould 3, collection glue jar 4, vavuum pump 5, ultrasonic unit 7 and glue conveying box.Between air accumulator 1 and storage glue jar 2, be connected with glue conveying box 6-1, on glue conveying box 6-1, be provided with pressure regulator valve 6-2.Between storage glue jar 2 and mould 3, be connected with glue conveying box 6-3.Between mould 3 and collection glue jar 4, be connected with glue conveying box 6-4.Between collection glue jar 4 and vavuum pump 5, be connected with glue conveying box 6-5.Vltrasonic device 7 be arranged on mould 3 under and be close to mould 3.The Vibration Box 7-1 of Vltrasonic device 7 is towards mould 3, and the floor space of mould 3 inner chamber 3-1 is less than the area on the last plane of Vibration Box 7-1, even the ultrasonic wave that all can receive Vibration Box 7-1 generation everywhere in the mould 3 inner chamber 3-1.Mould 3 is that the tool metal is made, and steel preferably are as 45
#Steel or A
3Steel.Described Vltrasonic device 7 is to be produced by the 726 research institute of The Seventh Academy of China Shipbuilding Industry Corp.
The specific embodiment two: present embodiment adopts the equipment of the specific embodiment one, in resin transfer molding (RTM) process fiber in the mold cavity and resin is handled, and its parameters is as follows:
The ultrasonic wave electrical power that Vltrasonic device 7 is intrinsic: 0～400w is adjustable, ultrasonic frequency: 48 ± 1.5kHz.
Vibration Box size: 725 * 115 * 100mm
3
Cavity dimension: 100 * 110 * 2mm
3
Specimen size: 100 * 110 * 2, epoxy 711#, 2-ethyl 4-methylimidazole resin system, the T-300 carbon fibre fabric is for strengthening body.
When ultrasonic processing power was 300W, in the RTM forming process, resin improved maximum to the wellability of fibre reinforcement, and wet-out rate improves 50%; Power value during interface unsticking 50% improves 36% than untreated samples; Interlaminar shear strength improves 11% than untreated samples.
The specific embodiment three: present embodiment adopts the equipment of the specific embodiment one, in resin transfer molding (RTM) process fiber in the mold cavity and resin is handled, and its parameters is as follows:
The ultrasonic wave electrical power that Vltrasonic device 7 is intrinsic: 0～400w is adjustable, ultrasonic frequency: 48 ± 1.5kHz.
Vibration Box size: 725 * 115 * 100mm
3
Cavity dimension: 100 * 50 * 2mm
3
Specimen size: 100 * 50 * 2, epoxy 711#, 2-ethyl 4-methylimidazole resin system, carbon cloth is for strengthening body.
When ultrasonic processing power was 200W, in the RTM forming process, resin improved maximum to the wellability of fibre reinforcement, and wet-out rate improves 20%; Power value during interface unsticking 50% improves 30% than untreated samples; Interlaminar shear strength improves 15% than untreated samples.
The specific embodiment four: present embodiment adopts the equipment of the specific embodiment one, in resin transfer molding (RTM) process fiber in the mold cavity and resin is handled, and its parameters is as follows:
The ultrasonic wave electrical power that Vltrasonic device 7 is intrinsic: 0～500w is adjustable, ultrasonic frequency: 48 ± 1.5kHz.
Vibration Box size: 725 * 200 * 100mm
3
Cavity dimension: 160 * 150 * 2mm
3
Specimen size: 160 * 150 * 2mm
3
When ultrasonic processing power was 400W, in the RTM forming process, resin improved maximum to the wellability of fibre reinforcement, and wet-out rate improves 35%; Power value during interface unsticking 50% improves 40% than untreated samples; Interlaminar shear strength improves 13% than untreated samples.
The specific embodiment five: present embodiment adopts the device of the specific embodiment one, and the specific embodiment two, three or four method are produced glass fibre/epoxy composite material or Carbon Fiber, and shape of product is controlled by die cavity.
The specific embodiment six: present embodiment adopts the device of the specific embodiment one, and the specific embodiment two, three or four method are in process of production at first with nano-ZnO and epoxy 711
#Evenly mix, and then strengthen carbon fiber/epoxy 711 with this device fabrication nano-ZnO
#Composite, the comparable nano-ZnO that does not add ultrasonic RTM technological forming of its performance strengthens carbon fiber/epoxy 711
#The composite material interface performance improves can improve 10%.
Claims (6)
1, ultrasonic-processing resin transfer molding method is characterized in that in resin transfer molding (RTM) process fiber in the dies cavity and resin being carried out ultrasonic processing.
2, ultrasonic-processing resin transfer molding method according to claim 1 is characterized in that described ultrasonic frequency is 40～60KHz.
3, ultrasonic-processing resin transfer molding method according to claim 1 and 2 is characterized in that described ultrasonic frequency is 45～55KHz.
4, the used device of ultrasonic-processing resin transfer molding, it comprises air accumulator (1), storage glue jar (2), mould (3), collection glue jar (4) and vavuum pump (5), and be connected above each the device between glue conveying box, it is characterized in that it also includes ultrasonic unit (7), the ultrasonic wave that Vltrasonic device (7) produces is towards mould (3), Vltrasonic device (7) is arranged on the position near mould (3), and be positioned at mould (3) the side, above or below.
5, the used device of ultrasonic-processing resin transfer molding according to claim 4 is characterized in that described mould (3) is that the tool metal is made.
6, the used device of ultrasonic-processing resin transfer molding according to claim 4, the floor space that it is characterized in that mould (3) inner chamber (3-1) goes up the area on plane less than the Vibration Box (7-1) that is positioned at the Vltrasonic device (7) under the mould (3).
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| Application Number | Priority Date | Filing Date | Title |
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| CN 03132430 CN1240534C (en) | 2003-06-11 | 2003-06-11 | Ultrasonic processing resin transfer moulding method and used apparatus |
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| CN 03132430 CN1240534C (en) | 2003-06-11 | 2003-06-11 | Ultrasonic processing resin transfer moulding method and used apparatus |
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| CN1513663A true CN1513663A (en) | 2004-07-21 |
| CN1240534C CN1240534C (en) | 2006-02-08 |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100368185C (en) * | 2005-12-07 | 2008-02-13 | 南京航空航天大学 | Quick RTM manufacturing process of resin based advanced composite material |
| CN100411853C (en) * | 2005-07-27 | 2008-08-20 | 南京航空航天大学 | Pressure shock wave air removing device of resin transfer moulding technology and its method |
| CN105346101A (en) * | 2015-12-02 | 2016-02-24 | 中国商用飞机有限责任公司北京民用飞机技术研究中心 | Fiber-reinforced thermoplastic resin matrix composite laminate mold pressing method and mold pressing device |
| CN105711113A (en) * | 2016-01-30 | 2016-06-29 | 西北工业大学 | Experiment-grade RTM (Resin Transfer Molding) constant-pressure injection system and constant-pressure injection method |
| CN106426985A (en) * | 2016-10-28 | 2017-02-22 | 河北大学 | Vacuum circulation pouring device with resin injected from bottom and pouring method |
| CN108501406A (en) * | 2017-02-28 | 2018-09-07 | 株式会社斯巴鲁 | The manufacturing method of fiber reinforced composite material |
| CN111649224A (en) * | 2020-05-26 | 2020-09-11 | 武汉理工大学 | Ultrasonic injection-bulging integrated molding method for plastic inner container of fiber fully-wound gas cylinder |
| US11065787B2 (en) | 2017-10-25 | 2021-07-20 | Subaru Corporation | Composite forming jig and composite forming method |
-
2003
- 2003-06-11 CN CN 03132430 patent/CN1240534C/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100411853C (en) * | 2005-07-27 | 2008-08-20 | 南京航空航天大学 | Pressure shock wave air removing device of resin transfer moulding technology and its method |
| CN100368185C (en) * | 2005-12-07 | 2008-02-13 | 南京航空航天大学 | Quick RTM manufacturing process of resin based advanced composite material |
| CN105346101A (en) * | 2015-12-02 | 2016-02-24 | 中国商用飞机有限责任公司北京民用飞机技术研究中心 | Fiber-reinforced thermoplastic resin matrix composite laminate mold pressing method and mold pressing device |
| CN105711113A (en) * | 2016-01-30 | 2016-06-29 | 西北工业大学 | Experiment-grade RTM (Resin Transfer Molding) constant-pressure injection system and constant-pressure injection method |
| CN105711113B (en) * | 2016-01-30 | 2017-10-10 | 西北工业大学 | A kind of method for testing level RTM constant pressures injecting systems and constant pressure injection |
| CN106426985A (en) * | 2016-10-28 | 2017-02-22 | 河北大学 | Vacuum circulation pouring device with resin injected from bottom and pouring method |
| CN108501406A (en) * | 2017-02-28 | 2018-09-07 | 株式会社斯巴鲁 | The manufacturing method of fiber reinforced composite material |
| US11065787B2 (en) | 2017-10-25 | 2021-07-20 | Subaru Corporation | Composite forming jig and composite forming method |
| CN111649224A (en) * | 2020-05-26 | 2020-09-11 | 武汉理工大学 | Ultrasonic injection-bulging integrated molding method for plastic inner container of fiber fully-wound gas cylinder |
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| CN1240534C (en) | 2006-02-08 |
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Assignee: Dongguan Jianguan Auto Parts Manufacturing Co.,Ltd. Assignor: Harbin Institute of Technology Contract record no.: 2010440001209 Denomination of invention: Ultrasonic processing resin transfer moulding method and used apparatus Granted publication date: 20060208 License type: Exclusive License Open date: 20040721 Record date: 20100819 |
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