CN1511711A - Water display type hidden anti-fake method, ink and its product - Google Patents

Water display type hidden anti-fake method, ink and its product Download PDF

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Publication number
CN1511711A
CN1511711A CNA021589046A CN02158904A CN1511711A CN 1511711 A CN1511711 A CN 1511711A CN A021589046 A CNA021589046 A CN A021589046A CN 02158904 A CN02158904 A CN 02158904A CN 1511711 A CN1511711 A CN 1511711A
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China
Prior art keywords
water
film
coated interference
obtains
explicit
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Pending
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CNA021589046A
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Chinese (zh)
Inventor
东 徐
徐东
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ZHONGQI WORLD TRADE INTERNATIONAL INVESTMENT CO Ltd
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ZHONGQI WORLD TRADE INTERNATIONAL INVESTMENT CO Ltd
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Application filed by ZHONGQI WORLD TRADE INTERNATIONAL INVESTMENT CO Ltd filed Critical ZHONGQI WORLD TRADE INTERNATIONAL INVESTMENT CO Ltd
Priority to CNA021589046A priority Critical patent/CN1511711A/en
Publication of CN1511711A publication Critical patent/CN1511711A/en
Pending legal-status Critical Current

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  • Laminated Bodies (AREA)

Abstract

The water display type hidden anti-fake method includes computerized design of multilayer film, coating the multilayer film, separating the multilayer film, crushing the multilayer film, mixing with print ink, printing and other steps. The present invention features the combination between the multilayer color-changing film technology and the 'water film' technology to reach the effect of dropping one drop of water to some specific area of the anti-fake product to display specific anti-fake pattern. The pattern will disappear after the water evaporates and displays color change with the altering viewing angle. The present invention has both public anti-fake function and expert anti-fake function.

Description

The explicit concealed anti-false method of water, printing ink and goods thereof
Technical field
The present invention relates to the explicit anti-counterfeiting technology of water, particularly based on the explicit invisible false proof technique of water of the colorless ink of multilayer optical film.
Background technology
Modern anti-counterfeiting technology mainly is divided into two big classes:
The one, the public is false proof, and is promptly so-called bright anti-, is characterized in the sign that the public is easy to discern in product powerful and influential place design, with the naked eye can distinguish the true from the false, and as various anti-false trademarks, sign, the watermark on the banknote, safety line, laser hologram trade mark, sign; Temperature induced color changing, photochromism anti-forging sign etc.The public is false proof will be by widely propaganda and teach knowledge and the method for distinguishing to the public socially, also simple and easy to do simultaneously, so just can reach and mobilize broad masses to contain the generation of fakement phenomena, but the false proof shortcoming of the public also is tangible, that is exactly: confidentiality is poor, and false proof intensity is low, the anti-counterfeiting technology characteristics has been exposed to the fake producer also meaning when the numerous common people propagate the anti-counterfeiting technology characteristics, therefore in some specific occasion, the public is false proof also false proof in conjunction with specialty.
The 2nd, professional false proof, promptly what is called is dark anti-, is characterized in: need by the secret mark on instrument, the recognition of devices product, password etc., as using ultraviolet lamp, infrared lamp, magnetic demoder, reaching computer picture, literal, password automatic recognition system etc.Specialty is false proof owing to adopt many secret marks of keeping secret, so in actual use except that fluoroscopic examination, major part is used for the professional false evaluation of distinguishing, often serve in judicial domain and the lawsuit activity, for example four kinds of secret marks of 100 yuans of new editions are also unexposed up till now, and its purpose is just in order finally to be judged the true and false of currency by the expert.
The principle that has interference effect between eighties of last century National Research Council of Canada in the latter stage eighties utilizes according to multilayer optical film has first been released the optically variable films anti-counterfeiting technology and at first adopted this technology on Canadian currency, it is reported that its antifalse effect is very desirable, there is the currency of many countries all to plan or adopted this technology now, China has applied for national patent (ZL931.12380.1) in 1993 by Shanghai Institute of Technical Physics of the Chinese Academy of Sciences, and present the 5th cover RMB has adopted the color shifting ink anti-counterfeiting technology based on multilayer optical film.
Summary of the invention
One of purpose of the present invention is to provide a kind of water explicit concealed anti-false method, and this method had both belonged to and is easy to popular the grasp and the false proof category of the public of operation, combines professional false proof characteristics again and is difficult to be copied by others.
Two of purpose of the present invention is to provide a kind of explicit hidden anti-fake print ink of water of utilizing the explicit concealed anti-false method preparation of water.
Three of purpose of the present invention is to provide a kind of explicit concealed anti-false goods of water that utilize the explicit concealed anti-false method preparation of water.
The fundamental difference of the color shifting ink anti-counterfeiting technology of the present invention and available technology adopting multilayer optical film has 2 points: the one, adopt to change the optical thin film number of plies (appearance of water film and evaporate) when reaching and when producing interference effect and do not produce interference effect, and then when realizing and visible interference light, the time and can not see the result of interference light.The 2nd, adopt the mode of adding colorless ink to reach the purpose of invisible printing ink.Be that anti-counterfeiting characteristic of the present invention is: can visible anti-counterfeiting mark after dripping; And the anti-counterfeiting characteristic of above-mentioned prior art is to distinguish the variation of pattern color by changing viewing angle, and then judges the true and false.
The present invention utilizes the interference effect of multilayer optical film on the optics can launch the principle of certain light of particular color, its core content is for to treat the water film as the special optical thin film of one deck, utilize the interference effect of water film and other multilayer optical thin film (one group of inteferometer coating) generation, calculate thickness and the required number of plies and the required material that forms each layer inteferometer coating of multi-coated interference film.When not adding the water film, because the inteferometer coating group lacks one deck inteferometer coating so do not form interference effect, promptly do not launch interference light, do not see pattern; After dripping, along with the evaporation of moisture, the attenuation gradually of water film forms interference effect with other inteferometer coating group after reaching specific thickness sometime, observes the specific pattern that can see color change this moment from different perspectives; As time goes on the water film continues the evaporation attenuation until withered, so the time interference disappear and no longer send interference light, pattern has not just been seen yet.
The explicit concealed anti-false method of water of the present invention, comprise that water, multicoating, plated film are peeled off, technology such as plated film pulverizing, plated film and colorless ink mixed processing, it is characterized in that the multi-layer colour-changing thin film technique is combined with " water film ", reach after water is dripped in the specific region, can demonstrate specific pattern, after water evaporates, this pattern Lock-out.It is finished by the following technical programs:
A, computer plural layers design, and utilize the principle of interference of optical thin film, design some ground floors by computer and are " water film ".Other several layers is the multi-coated interference film group that zirconia and silicon oxide film are alternately formed;
B, multicoating, the number of plies of the plural layers that design obtains according to computer and every layer thickness, physical vapor deposition methods such as utilization vacuum evaporation deposit needed multi-coated interference film group in the plastic sheeting substrate;
C, plated film separate, and the multi-coated interference film group that obtains is separated with the plastic sheeting substrate, obtain ultra-thin multi-coated interference diaphragm.
D, plated film are pulverized, and the multi-coated interference diaphragm that obtains is pulverized with size reduction machinery;
E, mixed ink mix the multi-coated interference film fractionlet that obtains with colorless ink, obtain a kind of colourless but drip the specialty inks that water can display pattern;
F, printing: adopt the explicit hidden anti-fake print ink of common printed technology water that security pattern is imprinted on the assigned address on blank printed medium surface.
The explicit hidden anti-fake print ink of water of the present invention prepares by following steps:
A. the computer plural layers design, and utilize the principle of interference of optical thin film, design some ground floors by computer and are " water film ".Other several layers is the multi-coated interference film group that zirconia and silicon oxide film are alternately formed;
B. multicoating, the number of plies of the plural layers that design obtains according to computer and every layer thickness, physical vapor deposition methods such as utilization vacuum evaporation deposit needed multi-coated interference film group in the plastic sheeting substrate;
C. plated film separates, and the multi-coated interference film group that obtains is separated with the plastic sheeting substrate, obtains ultra-thin multi-coated interference diaphragm;
D. plated film is pulverized, and the multi-coated interference diaphragm that obtains is pulverized with size reduction machinery;
E. mixed ink mixes the multi-coated interference film fractionlet that obtains with colorless ink, obtains a kind of colourless but drip the specialty inks that water can display pattern.
The explicit concealed anti-false goods of water of the present invention prepare by following steps:
A, computer plural layers design, and utilize the principle of interference of optical thin film, design some ground floors by computer and are " water film ".Other several layers is the multi-coated interference film group that zirconia and silicon oxide film are alternately formed;
B, multicoating, the number of plies of the plural layers that design obtains according to computer and every layer thickness, physical vapor deposition methods such as utilization vacuum evaporation deposit needed multi-coated interference film group in the plastic sheeting substrate;
C, plated film separate, and the multi-coated interference film group that obtains is separated with the plastic sheeting substrate, obtain ultra-thin multi-coated interference diaphragm;
D, plated film are pulverized, and the multi-coated interference diaphragm that obtains is pulverized with size reduction machinery;
E, mixed ink mix the multi-coated interference film fractionlet that obtains with colorless ink, obtain a kind of colourless but drip the specialty inks that water can display pattern;
F, the explicit hidden anti-fake print ink of the common printed technology water of employing are imprinted on security pattern on the assigned address on blank printed medium surface.
The present invention has following beneficial effect:
1, the more convenient public uses, and water on appointment place is dripped sees that pattern promptly is a genuine piece, and this conception of species is easy to be grasped by masses and accept;
2, good confidentiality, owing to adopt the colorless ink printing, the anti-false trademark of enterprise is difficult for could being occurred at short notice after only dripping by perusal, so transreplication, imitation do not identify profile;
3, false proof intensity height owing to can add the additive of specific wavelength in colorless ink, identifies to reach the purpose of integrated anti-counterfeit so can be printed as the special secret mark that only certain light wave is reflected;
4, because the thickness of inteferometer coating group involved in the present invention has only several microns, need with special installation and craftwork manufacture, and the material of optical thin film and the thickness of every layer of inteferometer coating are through tight calculating, so copy product of the present invention is very difficult, thereby can effectively play anti-fake effect.
Description of drawings
Fig. 1 is the techniqueflow chart of the embodiment of the invention;
Fig. 2 is the trade mark schematic diagram (actual naked eyes be cannot see) that utilizes the explicit invisible printing ink printing of water;
Fig. 3 is for dripping the schematic diagram of water;
The schematic diagram that Fig. 4 stretches out and evaporates for water;
Fig. 5 exposes the schematic diagram of anti-fake mark for interference effect occurs
After Fig. 6 water evaporates is done, the schematic diagram that anti-fake mark disappears
The specific embodiment
Embodiment
With reference to the techniqueflow chart of Fig. 1, the explicit concealed anti-false goods of water are finished by following process:
1. selection fexible film: thin-film material: polyester plastics;
2. be coated with separating layer: the separating layer material: the silicone oil of 200 nano thickness;
3. plating multi-coated interference film group: the thickness and the materials of each layer inteferometer coating that calculates according to computer, adopt physical vapor deposition methods such as vacuum evaporation, plate the multi-coated interference film at the bottom of the fexible film, the materials of inteferometer coating are zirconium dioxide and silica, and inteferometer coating is four layers; Be respectively silica (sio 2) layer 400 nanometer; Zirconium dioxide (z ro 2) layer 310 nanometer; Silica (sio 2) layer 400 nanometer; Zirconium dioxide (z ro 2) layer 310 nanometer;
4. demoulding: adopt heating to wait physical method will plate the interference thin film group of getting well and strip down from the polyester plastics substrate;
5. pulverize: adopt sodium meter level size reduction machinery, the multi-coated interference film group that strips down is broken into fragment about 2 microns.
6. mix: the multi-coated interference film group that crushes is added colourless additive and links agent (adding proportion is about 3: 7), form the explicit hidden anti-fake print ink of water after the mixed processing;
7. printing: adopt the explicit hidden anti-fake print ink of common printed technology water security pattern to be imprinted on the assigned address on surface of blank paper, pottery, metal, plastics, rubber, fabric, the answering of printed patterns
Assorted degree is decided by the requirement of common printed technology, and the general and explicit hidden anti-fake print ink of water has nothing to do.
Actual mechanical process of the present invention is as follows, sees also Fig. 2, and 3,4, shown in 5,6:
1. the paper or the article that will be printed on the pattern that utilizes the explicit invisible printing ink printing of water lie on the desk.
2. drip a water at the assigned address of hidden pattern.
3. along with the evaporation of moisture content, water film and inteferometer coating group interfere effect.(can adopt hair dryer to dry up mode) in order to see pattern as early as possible.
4. from watching less than the position of 90 degree, can find out the pattern that invisible printing ink prints with the angle of desktop.
5. along with the evaporation of moisture content, this pattern disappeared after tens seconds.
6. this pattern can drip repeatedly, occur repeatedly, and along with the difference of viewing angle, pattern color changes to some extent.

Claims (10)

1, the explicit method for anti-counterfeit of water comprises the steps:
A. the computer plural layers design, and utilize the principle of interference of optical thin film, design some ground floors by computer and are " water film ".Other several layers is the multi-coated interference film group that zirconia and silicon oxide film are alternately formed;
B. multicoating, the number of plies of the plural layers that design obtains according to computer and every layer thickness, physical vapor deposition methods such as utilization vacuum evaporation deposit needed multi-coated interference film group in the plastic sheeting substrate;
C. plated film separates, and the multi-coated interference film group that obtains is separated with the plastic sheeting substrate, obtains ultra-thin multi-coated interference diaphragm;
D. plated film is pulverized, and the multi-coated interference diaphragm that obtains is pulverized with size reduction machinery;
E. mixed ink mixes the multi-coated interference film fragment that obtains with colorless ink, obtains a kind of colourless but drip the specialty inks that water can display pattern;
F. adopt the explicit hidden anti-fake print ink of common printed technology water that security pattern is imprinted on the assigned address on blank printed medium surface.
2, the explicit method for anti-counterfeit of water according to claim 1 is characterized in that described plated film pulverizing is ground into the nanoscale fragment with the multi-coated interference diaphragm.
3, the explicit method for anti-counterfeit of water according to claim 1 and 2 is characterized in that described multi-coated interference film group is four layers, and it specifically is arranged as: silica (sio 2) layer 400 nanometer; Zirconium dioxide (z ro 2) layer 310 nanometer; Silica (sio 2) layer 400 nanometer; Zirconium dioxide (z ro 2) layer 310 nanometer.
4, the explicit hidden anti-fake print ink of water is characterized in that the explicit hidden anti-fake print ink of described water prepares by following steps:
A. the computer plural layers design, and utilize the principle of interference of optical thin film, design some ground floors by computer and are " water film ".Other several layers is the multi-coated interference film group that zirconia and silicon oxide film are alternately formed;
B. multicoating, the number of plies of the plural layers that design obtains according to computer and every layer thickness, physical vapor deposition methods such as utilization vacuum evaporation deposit needed multi-coated interference film group in the plastic sheeting substrate;
C. plated film separates, and the multi-coated interference film group that obtains is separated with the plastic sheeting substrate, obtains ultra-thin multi-coated interference diaphragm;
D. plated film is pulverized, and the multi-coated interference diaphragm that obtains is pulverized with size reduction machinery;
E. mixed ink mixes the multi-coated interference film fragment that obtains with colorless ink, obtains a kind of colourless but drip the specialty inks that water can display pattern;
5, the explicit hidden anti-fake print ink of water according to claim 4 is characterized in that described plated film pulverizing is ground into the nanoscale fragment with the multi-coated interference diaphragm.
6, according to claim 4, the explicit hidden anti-fake print ink of 5 described water is characterized in that described multi-coated interference film group is four layers, and it specifically is arranged as: silica (sio 2) layer 400 nanometer; Zirconium dioxide (z ro 2) layer 310 nanometer; Silica (sio 2) layer 400 nanometer; Zirconium dioxide (z ro 2) layer 310 nanometer.
7, the explicit concealed anti-false goods of water is characterized in that the explicit concealed anti-false goods of described water prepare by following steps:
A. the computer plural layers design, and utilize the principle of interference of optical thin film, design some ground floors by computer and are " water film ".Other several layers is the multi-coated interference film group that zirconia and silicon oxide film are alternately formed;
B. multicoating, the number of plies of the plural layers that design obtains according to computer and every layer thickness, physical vapor deposition methods such as utilization vacuum evaporation deposit needed multi-coated interference film group in the plastic sheeting substrate;
C. plated film separates, and the multi-coated interference film group that obtains is separated with the plastic sheeting substrate, obtains ultra-thin multi-coated interference diaphragm;
D. plated film is pulverized, and the multi-coated interference diaphragm that obtains is pulverized with size reduction machinery;
E. mixed ink mixes the multi-coated interference film fragment that obtains with colorless ink, obtains a kind of colourless but drip the specialty inks that water can display pattern;
F. adopt the explicit hidden anti-fake print ink of common printed technology water that security pattern is imprinted on the assigned address on blank printed medium surface.
8, the explicit concealed anti-false goods of water according to claim 7 is characterized in that can demonstrating described security pattern after dripping in the surface of the explicit concealed anti-false goods of described water, and with the difference of viewing angle, pattern color changes.
9, the explicit concealed anti-false goods of water according to claim 8 is characterized in that described plated film pulverizing is ground into the nanoscale fragment with the multi-coated interference diaphragm.
10, according to the explicit concealed anti-false goods of the described water of claim 7,8 or 9, it is characterized in that described multi-coated interference film group is four layers, it specifically is arranged as: silica (sio 2) layer 400 nanometer; Zirconium dioxide (z ro 2) layer 310 nanometer; Silica (sio 2) layer 400 nanometer; Zirconium dioxide (z ro 2) layer 310 nanometer.
CNA021589046A 2002-12-26 2002-12-26 Water display type hidden anti-fake method, ink and its product Pending CN1511711A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7704753B2 (en) 2005-03-03 2010-04-27 Inverness Medical Switzerland Gmbh Devices and methods for analyte assays with built-in result reporting using recognizable symbols
CN103236004A (en) * 2013-03-29 2013-08-07 李家栋 Anti-counterfeiting method implemented by collotype printed matters for products
CN103303015A (en) * 2013-06-26 2013-09-18 常熟印刷厂有限公司 Method for printing publication hidden content
CN104464505A (en) * 2014-11-28 2015-03-25 中国科学院深圳先进技术研究院 Novel anti-counterfeit mark and manufacturing method thereof
CN104464506A (en) * 2014-11-28 2015-03-25 中国科学院深圳先进技术研究院 Anti-counterfeiting mark used for information storage and preparing method thereof
CN110509681A (en) * 2019-08-15 2019-11-29 彭永贵 A kind of false proof process of printed decoration paper

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7704753B2 (en) 2005-03-03 2010-04-27 Inverness Medical Switzerland Gmbh Devices and methods for analyte assays with built-in result reporting using recognizable symbols
CN103236004A (en) * 2013-03-29 2013-08-07 李家栋 Anti-counterfeiting method implemented by collotype printed matters for products
CN103303015A (en) * 2013-06-26 2013-09-18 常熟印刷厂有限公司 Method for printing publication hidden content
CN104464505A (en) * 2014-11-28 2015-03-25 中国科学院深圳先进技术研究院 Novel anti-counterfeit mark and manufacturing method thereof
CN104464506A (en) * 2014-11-28 2015-03-25 中国科学院深圳先进技术研究院 Anti-counterfeiting mark used for information storage and preparing method thereof
CN104464505B (en) * 2014-11-28 2017-06-06 中国科学院深圳先进技术研究院 A kind of antifalse mark and preparation method thereof
CN104464506B (en) * 2014-11-28 2017-09-29 深圳先进技术研究院 A kind of anti-counterfeiting mark stored available for information and preparation method thereof
CN110509681A (en) * 2019-08-15 2019-11-29 彭永贵 A kind of false proof process of printed decoration paper

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