CN1511184A - Paint, and method of producing same - Google Patents
Paint, and method of producing same Download PDFInfo
- Publication number
- CN1511184A CN1511184A CNA028078276A CN02807827A CN1511184A CN 1511184 A CN1511184 A CN 1511184A CN A028078276 A CNA028078276 A CN A028078276A CN 02807827 A CN02807827 A CN 02807827A CN 1511184 A CN1511184 A CN 1511184A
- Authority
- CN
- China
- Prior art keywords
- agent
- flame retardant
- retardant compositions
- film
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003973 paint Substances 0.000 title claims abstract description 11
- 238000000034 method Methods 0.000 title abstract description 9
- 239000003063 flame retardant Substances 0.000 claims abstract description 62
- 239000011230 binding agent Substances 0.000 claims abstract description 41
- 239000000843 powder Substances 0.000 claims abstract description 14
- 239000011248 coating agent Substances 0.000 claims description 58
- 238000000576 coating method Methods 0.000 claims description 58
- 239000000203 mixture Substances 0.000 claims description 57
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 53
- 239000000654 additive Substances 0.000 claims description 48
- 239000003795 chemical substances by application Substances 0.000 claims description 48
- 230000000996 additive effect Effects 0.000 claims description 33
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 24
- 229920000877 Melamine resin Polymers 0.000 claims description 22
- 229920000388 Polyphosphate Polymers 0.000 claims description 22
- 239000000470 constituent Substances 0.000 claims description 22
- 239000001205 polyphosphate Substances 0.000 claims description 22
- 235000011176 polyphosphates Nutrition 0.000 claims description 22
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 20
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 20
- 229940059574 pentaerithrityl Drugs 0.000 claims description 19
- 239000006185 dispersion Substances 0.000 claims description 14
- 239000008204 material by function Substances 0.000 claims description 14
- 239000013008 thixotropic agent Substances 0.000 claims description 14
- 239000002904 solvent Substances 0.000 claims description 13
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
- 229920000742 Cotton Polymers 0.000 claims description 10
- 239000000049 pigment Substances 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 10
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 8
- 239000012463 white pigment Substances 0.000 claims description 8
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- NKFIBMOQAPEKNZ-UHFFFAOYSA-N 5-amino-1h-indole-2-carboxylic acid Chemical compound NC1=CC=C2NC(C(O)=O)=CC2=C1 NKFIBMOQAPEKNZ-UHFFFAOYSA-N 0.000 claims description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 claims description 4
- 241000779819 Syncarpia glomulifera Species 0.000 claims description 4
- 229960004217 benzyl alcohol Drugs 0.000 claims description 4
- 235000019445 benzyl alcohol Nutrition 0.000 claims description 4
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 4
- 239000004816 latex Substances 0.000 claims description 4
- 229920000126 latex Polymers 0.000 claims description 4
- 229940043265 methyl isobutyl ketone Drugs 0.000 claims description 4
- 239000011707 mineral Substances 0.000 claims description 4
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 claims description 4
- 150000003016 phosphoric acids Chemical class 0.000 claims description 4
- 239000001739 pinus spp. Substances 0.000 claims description 4
- 239000004014 plasticizer Substances 0.000 claims description 4
- 239000002562 thickening agent Substances 0.000 claims description 4
- 229940036248 turpentine Drugs 0.000 claims description 4
- 239000002966 varnish Substances 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 238000002485 combustion reaction Methods 0.000 claims description 3
- 235000019439 ethyl acetate Nutrition 0.000 claims description 3
- BFHKYHMIVDBCPC-UHFFFAOYSA-N 1,3,5,7-tetrahydro-[1,3]oxazolo[3,4-c][1,3]oxazol-7a-ylmethanol Chemical compound C1OCN2COCC21CO BFHKYHMIVDBCPC-UHFFFAOYSA-N 0.000 claims description 2
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
- 229920003270 Cymel® Polymers 0.000 claims description 2
- 102000002322 Egg Proteins Human genes 0.000 claims description 2
- 108010000912 Egg Proteins Proteins 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- 239000013543 active substance Substances 0.000 claims description 2
- 229920000180 alkyd Polymers 0.000 claims description 2
- 150000001408 amides Chemical class 0.000 claims description 2
- 239000000908 ammonium hydroxide Substances 0.000 claims description 2
- 239000003125 aqueous solvent Substances 0.000 claims description 2
- ZCGHEBMEQXMRQL-UHFFFAOYSA-N benzyl 2-carbamoylpyrrolidine-1-carboxylate Chemical compound NC(=O)C1CCCN1C(=O)OCC1=CC=CC=C1 ZCGHEBMEQXMRQL-UHFFFAOYSA-N 0.000 claims description 2
- 230000003115 biocidal effect Effects 0.000 claims description 2
- 239000003139 biocide Substances 0.000 claims description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 229940096386 coconut alcohol Drugs 0.000 claims description 2
- 239000000084 colloidal system Substances 0.000 claims description 2
- 238000004132 cross linking Methods 0.000 claims description 2
- 239000013530 defoamer Substances 0.000 claims description 2
- FSEUPUDHEBLWJY-HWKANZROSA-N diacetylmonoxime Chemical compound CC(=O)C(\C)=N\O FSEUPUDHEBLWJY-HWKANZROSA-N 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 210000003278 egg shell Anatomy 0.000 claims description 2
- 229920006334 epoxy coating Polymers 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 239000011812 mixed powder Substances 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 239000001912 oat gum Substances 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 2
- 239000008347 soybean phospholipid Substances 0.000 claims description 2
- 239000003351 stiffener Substances 0.000 claims description 2
- 239000013589 supplement Substances 0.000 claims description 2
- FBWNMEQMRUMQSO-UHFFFAOYSA-N tergitol NP-9 Chemical compound CCCCCCCCCC1=CC=C(OCCOCCOCCOCCOCCOCCOCCOCCOCCO)C=C1 FBWNMEQMRUMQSO-UHFFFAOYSA-N 0.000 claims description 2
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000080 wetting agent Substances 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 229920002125 Sokalan® Polymers 0.000 claims 1
- 150000001912 cyanamides Chemical class 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 239000004584 polyacrylic acid Substances 0.000 claims 1
- 239000004114 Ammonium polyphosphate Substances 0.000 description 2
- XHRNCTXIGXAOEN-UHFFFAOYSA-N OP(O)(=O)OP(=O)(O)O.N#CN Chemical compound OP(O)(=O)OP(=O)(O)O.N#CN XHRNCTXIGXAOEN-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 2
- 229920001276 ammonium polyphosphate Polymers 0.000 description 2
- IUTYMBRQELGIRS-UHFFFAOYSA-N boric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OB(O)O.NC1=NC(N)=NC(N)=N1 IUTYMBRQELGIRS-UHFFFAOYSA-N 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 description 2
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 description 2
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 1
- -1 methyl ethyl Chemical group 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
Abstract
A paint has a film-forming binder component, a color-producing component, an d a fire-retardant component adapted to least substantially protect from fire a surface of which the paint is applied; and the paint is produced by a method including providing a film-forming binder component; providing a color- producing component; mixing the components with some of dried powder components missing; and adding a fire retardant component to replace the dry powder component.
Description
Invention field
The present invention relates generally to coating and preparation method thereof.
Background of invention
As everyone knows, coating can be applicable to industry, the other field of the family and the modern life.Known coating comprises the film-forming binder component usually, and this component can film forming, and adheres to the base material that scribbles coating, and described coating also comprises the colour developing component, such as pigment and other toners.
When known coating provides to a certain extent protection for the surface that scribbles coating, avoid atmospheric harmful effect, and when providing certain color for the surface that scribbles coating, coating can not prevent fully that substrate surface from meeting fire burns.Can think that it is desirable eliminating this shortcoming.
Summary of the invention
Therefore, the objective of the invention is to propose a kind of method that can avoid the coating of prior art defective and prepare this coating.
Consistent with these purposes of the present invention and other purposes that hereinafter will mention, one of the present invention is characterised in that, be set fourth as briefly, this coating comprises the film-forming binder component, colour developing component, and the flame retardant compositions that is suitable for fully preventing scribbling the surface combustion of coating at least.
By the coating of the present invention's design, except the normal attribute with coating, it can also fully prevent to scribble the substrate surface burning of coating at least, in many cases, can strengthen the working life of erosion resistance and prolongation coating.
According to another feature of the present invention, flame retardant compositions comprises at least a phosphoric acid salt or derivatives thereof, such as melamine polyphosphate, and ammonium polyphosphate.
According to another feature of the present invention, described flame retardant compositions comprises the trimeric cyanamide or derivatives thereof, as melamine cyanurate, melamine borate salt, melamine polyphosphate, trimeric cyanamide diphosphate, melamine pyrophosphate and melamine phosphate.
The present invention proposes to prepare the method for coating, and this method comprises the steps: to be prepared to the film adhesive component, prepares the colour developing component, said components and some is leaked fire (missing) dry powder component mix, and adds flame retardant compositions alternative dry powdery components.
Particularly in additional claims, illustrated its novel characteristic, this characteristic is decided to be feature of the present invention.Yet, among the present invention, no matter be its structure, or its working method, together with described other purposes and advantage, will give to explain fully in the specific below example.The explanation of preferred embodiment
Coating according to the present invention preparation comprises the film-forming binder component, and colour developing component and preventing at least substantially scribbles the flame retardant compositions of the surface combustion of coating.
Flame retardant compositions can comprise the phosphoric acid salt or derivatives thereof, such as melamine polyphosphate, and ammonium polyphosphate.
Equally, flame retardant compositions comprises the trimeric cyanamide or derivatives thereof, as melamine cyanurate, and melamine borate salt, melamine polyphosphate, trimeric cyanamide diphosphate, melamine pyrophosphate and melamine phosphate.
According to the present invention, in coating, flame retardant compositions may comprise carbonized agent, and as tetramethylolmethane, monopentaerythritol or dipentaerythritol, and comprise whipping agent are as trimeric cyanamide be selected from the additive that contains in the above reagent of enumerating.
Need to prove that film forming matter (matrix material and tenderizer) is one of main component of coating, can influence weather resistance, gloss, elasticity, bonding, snappiness and hardness, pigment is to be insoluble to binding agent and the colored powder that is dissolved in tinting material, to produce colour-change and padding ability, except that above-mentioned two class materials, coating also comprises volatile constituent, in most cases, volatile constituent and matrix material form solution or so-called basic varnish (varnish) together.The additive that also can comprise other in the coating, these additives help chemical substance to form the specified property of coating.
According to the present invention, coating can be prepared by the method that comprises the following steps: be prepared to the film adhesive component, prepare the colour developing component, said components and some are leaked fiery dry powder component mix, and add flame retardant compositions replacement dry powder component.
Particularly, filler as lime carbonate and titanium dioxide, is replaced by flame retardant compositions.Yet, also may replace a spot of film-forming components certainly.
By the following examples coating of the present invention will be described:
Embodiment 1
Two parts of formula epoxy coatings
A part
Functional materials weight %
Liquid-state epoxy resin Epotuf37-127 32.80 film-forming binder
Thinner phenylcarbinol 3.75 film-forming binder
Dispersant B YK P-104S 0.32 additive
Anti-depression agent BYK A-530 0.15 additive
Flowing additive BYK 501 0.16 additives
Primary coat pigment titanox 2,020 12.3 colour developing components
Supplement Microna7 18.99 dry powder components
Whipping agent trimeric cyanamide 5.25 flame retardant compositions
Catalyzer melamine polyphosphate 4.50 flame retardant compositions
Carbonized agent tetramethylolmethane 5.25 flame retardant compositions
B part
Polymeric amide stiffening agent Epotuf37-801 13.32 film-forming binder
Thinner phenylcarbinol 3.21 film-forming binder
100.00
A part is 4/1 with the mixed volume ratio of B part.
Embodiment 2
The Synolac base paint
Functional materials weight %
Medium oil alkyd 80% Beckosol AA-203 31.48 film-forming binder
Solvent mineral turpentine 21.94 volatile constituents
Dispersion agent Soya Lecithin 0.13 additive
Thixotropic agent Thixatrol ST 0.32 thixotropic agent
Drop down Flow Control preparation Post 4 0.44 thixotropic agent
Cobalt siccative 12% cobalt naphthenate 0.08 additive
Calcium siccative 6% calcium naphthenate 0.78 additive
Anti Diacetylmonoxime (methyl ethyl ketoxine) 0.33 additive
Primary coat pigment Tipure 902 21.38 colour developing components
Replenish pigment Nicron 604 8.12 dry powder components
Whipping agent trimeric cyanamide 5.25 flame retardant compositions
Catalyzer melamine polyphosphate 4.50 flame retardant compositions
Carbonized agent tetramethylolmethane 5.25 flame retardant compositions
100.00
Embodiment 3
Polyurethane paint
Functional materials weight
Urethane Spenkel F47-M-60 50.10 film-forming binder of oil modification
Dispersion agent Nuosperes 657 0.46 additives
Thixotropic agent Bentone SD-1 0.95 thixotropic agent
Solvent mineral turpentine 6.18 volatile constituents
Primary coat pigment Tronox CR-828 23.95 colour developing components
Cobalt siccative 12% cobalt naphthenate 0.38 additive
Calcium siccative 6% calcium naphthenate 1.26 additives
Zirconium siccative 24% zirconium naphthenate 1.61 additives
Anti Exkin#2 0.11 additive
Whipping agent trimeric cyanamide 5.25 fire retardants
Catalyzer melamine polyphosphate 4.50 fire retardants
Carbonized agent tetramethylolmethane 5.25 fire retardants
100.00
Embodiment 4
Strippable vinyl coating
Functional materials weight %
High molecular weight ethylene base resin Ucar YVNS 7.38 film-forming binder
Low-molecular-weight ethylenic base resin Ucar VYHD 3.69 film-forming binder
Plasticizer phthalic acid dioctyl ester 2.88 film-forming binder
White pigment TiPure 902 6.50 colour developing components
Thinner toluene 22.20 volatile constituents
Ketone solvent methyl iso-butyl ketone (MIBK) 20.95 volatile constituents
Acetic ester solvent acetic acid butyl ester 21.40 volatile constituents
Whipping agent trimeric cyanamide 5.25 flame retardant compositions
Catalyzer melamine polyphosphate 4.50 flame retardant compositions
Carbonized agent tetramethylolmethane 5.25 flame retardant compositions
100.00
Embodiment 5
Soluble cotton satin weave varnish
Functional materials weight %
Lower molecular weight soluble cotton soluble cotton 1/4sec 6.75 film-forming binder
High molecular soluble cotton soluble cotton 1/2sec 0.10 film-forming binder
Thinner toluene 13.75 volatile constituents
Horizontal solvent (lateral solvent) isopropyl acetone 2.70 volatile constituents
Rapid-curing cutback solvent acetic acid butyl ester 27.60 volatile constituents
Slow curing solvent PM acetic ester 2.70 volatile constituents
Coconut alcohol acid resin 70% Bookosol91-470 12.78 film-forming binder among the BA
Plasticizer phthalic acid dioctyl ester 1.34 film-forming binder
White pigment Tipure 902 9.80 colour developing components
Linking agent Cymel 303 6.95 film-forming binder
Crosslinking catalyst butyl acid phosphoric acid salt 0.53 additive
Whipping agent trimeric cyanamide 5.25 flame retardant compositions
Catalyzer melamine polyphosphate 4.50 flame retardant compositions
Carbonized agent tetramethylolmethane 5.25 flame retardant compositions
100.00
Embodiment 6
The egg-shell glaze latex paint
Functional materials weight %
Aqueous solvent 25.3 volatile constituents
Dispersion agent Potassium tripolyphosphate 0.22 additive
Tensio-active agent Igepal CO-630 0.84 additive
Defoamer Colloid 643 0.23 additives
Wet limit control agent (wet edge control) propylene glycol 2.77 additives
Biocide Nuosept 95 0.38 additives
White pigment TiPure 902 18.11 colour developing components
Whipping agent trimeric cyanamide 5.25 flame retardant compositions
Catalyzer melamine polyphosphate 4.5 flame retardant compositions
Carbonized agent tetramethylolmethane 5.25 flame retardant compositions
Cellulose thickener Bernocol E411 FQ 0.32 thixotropic agent
Latex polymer 55% Rovace 9,100 34.88 film-forming binder
PH regulator agent 28% ammonium hydroxide 0.13 additive
Associative thickener acrylate water miscible liquid RM-5 1.82 thixotropic agent
100.00
The preparation method
Above-mentioned sample is prepared from by Cowles high speed dispersion device.The coating preparation technology of employing standard, in an amount of vehicle, vehicle comprises dispersion agent and wetting agent with the powder material high speed dispersion.
Finish after the dispersion, underspeed, the vehicle of equal amount with
All the other components in the prescription add together.
Embodiment 7
The acrylic acid or the like powder coating
Functional materials weight %
Vinylformic acid Racemic glycidol Fine-Clad A-207-SA 56.90 film-forming binder
Linking agent dodecanedioic acid 10.83 film-forming binder
Flowing additive Silwet L-7500 0.33 additive
White pigment Titanox 2,020 16.94 colour developing components
Whipping agent trimeric cyanamide 5.25 flame retardant compositions
Catalyzer melamine polyphosphate 4.50 flame retardant compositions
Carbonized agent tetramethylolmethane 5.25 flame retardant compositions
100.00
Stoving temperature: 150 ℃, 20 minutes
The preparation method
Use W﹠amp; P ZSK-30 stirrer mixed powder
60/80 ℃ of bucket temperature
Speed of rotation: 250rpm
Classification: 100% by 200 orders
By above-mentioned listed examples as can be seen, the fire retardant of coating of the present invention part is made up of three kinds of flame retardant compositions, trimeric cyanamide just, melamine polyphosphate, and tetramethylolmethane.These three kinds of flame retardant compositions account for 15% of coating weight altogether altogether.
Should be understood that each above-mentioned composition, and two or more compositions together, be applied to be different from other materials and the method for the above-mentioned type.
With coating and working method thereof the present invention has been described, but the restriction of details shown in not being subjected to because under the situation that does not depart from spirit of the present invention, can be carried out various changes and structural changes.
Do not having under the situation about further analyzing, above-mentionedly everyly will fully disclose main points of the present invention, by using existing knowledge, other people can easily use it for different application, and do not lose feature.From the angle of prior art, these features have been formed the essential characteristic of the general or particular aspects of the present invention.
Limit by appended claims as new scope with requiring patent protection.
Claims (11)
1. the surface is painted the coating of predetermined color, described coating comprises:
The film-forming binder component is used for forming from the teeth outwards paint film;
The colour developing component is used for the color that provides predetermined from the teeth outwards;
Flame retardant compositions is suitable for preventing surface combustion,
Wherein, described flame retardant compositions comprises trimeric cyanamide, tetramethylolmethane, and melamine polyphosphate,
Remaining component comprises filler and additive.
2. coating as claimed in claim 1 is characterized in that, % counts by weight, and described flame retardant compositions comprises: 35% trimeric cyanamide, 35% tetramethylolmethane and 30% melamine polyphosphate.
3. coating as claimed in claim 1 is characterized in that, in the gross weight of coating, described flame retardant compositions comprises 5.25 weight % trimeric cyanamides, 5.25 weight % tetramethylolmethanes, 4.50 weight % melamine polyphosphates.
4. coating as claimed in claim 1 is characterized in that described flame retardant compositions is no more than 15% of coating gross weight.
5. coating as claimed in claim 1 is characterized in that, described coating comprises following component:
Two parts of formula epoxy coatings
A part
Functional materials weight %
Liquid-state epoxy resin Epotuf37-127 32.80 film-forming binder
Thinner phenylcarbinol 3.75 film-forming binder
Dispersant B YK P-104S 0.32 additive
Anti-depression agent BYK A-530 0.15 additive
Flowing additive BYK 501 0.16 additives
Primary coat pigment titanox 2,020 12.3 colour developing components
Supplement Microna7 18.99 dry powder components
Whipping agent trimeric cyanamide 5.25 flame retardant compositions
Catalyzer melamine polyphosphate 4.50 flame retardant compositions
Carbonized agent tetramethylolmethane 5.25 flame retardant compositions
B part
Polymeric amide stiffening agent Epotuf37-801 13.32 film-forming binder
Thinner phenylcarbinol 3.21 film-forming binder
100.00
A part is 4/1 with the mixed volume ratio of B part.
6. coating as claimed in claim 1, described coating comprises following component:
The Synolac base paint
Functional materials weight %
Medium oil alkyd 80% Beckosol AA-203 31.48 film-forming binder
Solvent mineral turpentine 21.94 volatile constituents
Dispersion agent Soya Lecithin 0.13 additive
Thixotropic agent Thixatrol ST 0.32 thixotropic agent
Drop down Flow Control preparation Post 4 0.44 thixotropic agent
Cobalt siccative 12% cobalt naphthenate 0.08 additive
Calcium siccative 6% calcium naphthenate 0.78 additive
Anti Diacetylmonoxime 0.33 additive
Primary coat pigment Tipure902 21.38 colour developing components
Replenish pigment Nicron604 8.12 dry powder components
Whipping agent trimeric cyanamide 5.25 flame retardant compositions
Catalyzer melamine polyphosphate 4.50 flame retardant compositions
Carbonized agent tetramethylolmethane 5.25 flame retardant compositions
100.00
7. coating as claimed in claim 1, described coating comprises following component:
Polyurethane paint
Functional materials weight
Urethane Spenkel F47-M-60 50.10 film-forming binder of oil modification
Dispersion agent Nuosperes 657 0.46 additives
Thixotropic agent Bentone SD-1 0.95 thixotropic agent
Solvent mineral turpentine 6.18 volatile constituents
Primary coat pigment Tronox CR-828 23.95 colour developing components
Cobalt siccative 12% cobalt naphthenate 0.38 additive
Calcium siccative 6% calcium naphthenate 1.26 additives
Zirconium siccative 24% zirconium naphthenate 1.61 additives
Anti Exkin#2 0.11 additive
Whipping agent trimeric cyanamide 5.25 fire retardants
Catalyzer melamine polyphosphate 4.50 fire retardants
Carbonized agent tetramethylolmethane 5.25 fire retardants
100.00
8. coating as claimed in claim 1, described coating comprises following component:
Strippable vinyl coating
Functional materials weight %
High molecular weight ethylene base resin Ucar YVNS 7.38 film-forming binder
Low-molecular-weight ethylenic base resin Ucar VYHD 3.69 film-forming binder
Plasticizer phthalic acid dioctyl ester 2.88 film-forming binder
White pigment TiPure 902 6.50 colour developing components
Thinner toluene 22.20 volatile constituents
Ketone solvent methyl iso-butyl ketone (MIBK) 20.95 volatile constituents
Acetic ester solvent acetic acid butyl ester 21.40 volatile constituents
Whipping agent trimeric cyanamide 5.25 flame retardant compositions
Catalyzer melamine polyphosphate 4.50 flame retardant compositions
Carbonized agent tetramethylolmethane 5.25 flame retardant compositions
100.00
9. coating as claimed in claim 1, described coating comprises following component:
Soluble cotton satin weave varnish
Functional materials weight %
Lower molecular weight soluble cotton soluble cotton 1/4sec 6.75 film-forming binder
High molecular soluble cotton soluble cotton 1/2sec 0.10 film-forming binder
Thinner toluene 13.75 volatile constituents
Horizontal solvent isopropyl acetone 2.70 volatile constituents
Rapid-curing cutback solvent acetic acid butyl ester 27.60 volatile constituents
Slow curing solvent PM acid esters 2.70 volatile constituents
Coconut alcohol acid resin 70% Bookosol 91-470 12.78 film-forming binder among the BA
Plasticizer phthalic acid dioctyl ester 1.34 film-forming binder
White pigment Tipure 902 9.80 colour developing components
Linking agent Cymel 303 6.95 film-forming binder
Crosslinking catalyst butyl acid phosphoric acid salt 0.53 additive
Whipping agent trimeric cyanamide 5.25 flame retardant compositions
Catalyzer melamine polyphosphate 4.50 flame retardant compositions
Carbonized agent tetramethylolmethane 5.25 flame retardant compositions
100.00
10. coating as claimed in claim 1, described coating comprises following component:
The egg-shell glaze latex paint
Functional materials weight %
Aqueous solvent 25.3 volatile constituents
Dispersion agent Potassium tripolyphosphate 0.22 additive
Tensio-active agent Igepal CO-630 0.84 additive
Defoamer Colloid 643 0.23 additives
Wet limit control agent propylene glycol 2.77 additives
Biocide Nuosept 95 0.38 additives
White pigment TiPure 902 18.11 colour developing components
Whipping agent trimeric cyanamide 5.25 flame retardant compositions
Catalyzer melamine polyphosphate 4.5 flame retardant compositions
Carbonized agent tetramethylolmethane 5.25 flame retardant compositions
Cellulose thickener Bemocol E411 FQ 0.32 thixotropic agent
Latex polymer 55% Rovace 9,100 34.88 film-forming binder
PH regulator agent 28% ammonium hydroxide 0.13 additive
Associative thickener acrylate water miscible liquid RM-5 1.82 thixotropic agent
100.00
The preparation method
Above-mentioned sample is prepared from by Cowles high speed dispersion instrument.The coating complete processing of employing standard, in an amount of vehicle, vehicle comprises dispersion agent and wetting agent with the powder material high speed dispersion.
Finish after the dispersion, underspeed, the vehicle of equal amount all the other components in prescription add.
11. coating as claimed in claim 1, described coating comprises following component
The acrylic acid or the like powder coating
Functional materials weight %
Polyacrylic acid Racemic glycidol Fine-Clad A-207-SA 56.90 film-forming binder
Linking agent dodecanedioic acid 10.83 film-forming binder
Flowing additive Silwet L-7500 0.33 additive
White pigment Titanox 2,020 16.94 colour developing components
Whipping agent trimeric cyanamide 5.25 flame retardant compositions
Catalyzer melamine polyphosphate 4.50 flame retardant compositions
Carbonized agent tetramethylolmethane 5.25 flame retardant compositions
100.00
Stoving temperature: 150 ℃, 20 minutes
The preparation method
Use W﹠amp; P ZSK-30 stirrer mixed powder
60/80 ℃ of bucket temperature
Speed of rotation: 250rpm
Classification: 100% by 200 orders
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US28078901P | 2001-04-02 | 2001-04-02 | |
| CA2,342,662 | 2001-04-02 | ||
| CA 2342662 CA2342662A1 (en) | 2001-04-02 | 2001-04-02 | Fire retardant and coatings compositions |
| US60/280,789 | 2001-04-02 | ||
| US10/023,949 | 2001-12-21 | ||
| US10/023,949 US6686403B2 (en) | 2001-04-02 | 2001-12-21 | Paint, and method of producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1511184A true CN1511184A (en) | 2004-07-07 |
| CN1274771C CN1274771C (en) | 2006-09-13 |
Family
ID=27171498
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB028078276A Expired - Fee Related CN1274771C (en) | 2001-04-02 | 2002-04-02 | Paint, and method of producing same |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP1401965A2 (en) |
| JP (1) | JP4274799B2 (en) |
| CN (1) | CN1274771C (en) |
| AU (1) | AU2002250748A1 (en) |
| BG (1) | BG108305A (en) |
| CZ (1) | CZ305026B6 (en) |
| EA (1) | EA006144B1 (en) |
| HK (1) | HK1065059A1 (en) |
| HU (1) | HUP0402272A3 (en) |
| PL (1) | PL207152B1 (en) |
| SK (1) | SK285850B6 (en) |
| UA (1) | UA76747C2 (en) |
| WO (1) | WO2002079329A2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194633A (en) * | 2014-08-27 | 2014-12-10 | 苏州诚晟信息技术有限公司 | Ultraviolet-resistant fire-resistant paint and preparation method thereof |
| CN105295681A (en) * | 2014-06-29 | 2016-02-03 | 江苏飞翔涂料实业总公司 | Fast drying paint |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103937229A (en) * | 2013-01-17 | 2014-07-23 | 上海杰事杰新材料(集团)股份有限公司 | Fire retardant glass fiber reinforced nylon composite material, and preparation method thereof |
| WO2018087315A1 (en) * | 2016-11-10 | 2018-05-17 | Ppg Coatings Europe B.V. | Surfactants for intumescent foam stabilization |
| CN106638121B (en) * | 2016-12-30 | 2018-11-13 | 北京蓝海黑石科技有限公司 | A kind of paper is containing immersion liquid and preparation method thereof |
| WO2020027175A1 (en) * | 2018-08-01 | 2020-02-06 | 関西ペイント株式会社 | Expandable coating composition |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3635970A (en) * | 1969-04-17 | 1972-01-18 | American Cyanamid Co | Crystalline melamine pyrophosphate |
| US3654190A (en) * | 1970-05-28 | 1972-04-04 | Us Navy | Fire retardant intumescent paint |
| DE3009104C2 (en) * | 1980-03-10 | 1990-10-04 | Odenwald-Chemie GmbH, 6901 Schönau | Use of an epoxy resin for the production of fire-retardant layers or coatings and processes for the production of the same |
| US4965296A (en) * | 1989-03-15 | 1990-10-23 | No Fire Engineering, Inc. | Intumescent fire-retardant and electrically-conductive coating material |
| GB2246136A (en) * | 1990-07-18 | 1992-01-22 | Prometheus Developments Ltd | Intumescent coating compositions |
-
2002
- 2002-02-04 UA UA2003109815A patent/UA76747C2/en unknown
- 2002-04-02 CZ CZ2003-2967A patent/CZ305026B6/en not_active IP Right Cessation
- 2002-04-02 HU HU0402272A patent/HUP0402272A3/en unknown
- 2002-04-02 AU AU2002250748A patent/AU2002250748A1/en not_active Abandoned
- 2002-04-02 EA EA200301085A patent/EA006144B1/en not_active IP Right Cessation
- 2002-04-02 EP EP02719578A patent/EP1401965A2/en not_active Withdrawn
- 2002-04-02 CN CNB028078276A patent/CN1274771C/en not_active Expired - Fee Related
- 2002-04-02 PL PL365338A patent/PL207152B1/en unknown
- 2002-04-02 SK SK1357-2003A patent/SK285850B6/en not_active IP Right Cessation
- 2002-04-02 JP JP2002578338A patent/JP4274799B2/en not_active Expired - Fee Related
- 2002-04-02 WO PCT/CA2002/000467 patent/WO2002079329A2/en active Application Filing
-
2003
- 2003-10-30 BG BG108305A patent/BG108305A/en unknown
-
2004
- 2004-10-15 HK HK04107977A patent/HK1065059A1/en not_active IP Right Cessation
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105295681A (en) * | 2014-06-29 | 2016-02-03 | 江苏飞翔涂料实业总公司 | Fast drying paint |
| CN104194633A (en) * | 2014-08-27 | 2014-12-10 | 苏州诚晟信息技术有限公司 | Ultraviolet-resistant fire-resistant paint and preparation method thereof |
| CN104194633B (en) * | 2014-08-27 | 2016-08-24 | 苏州诚晟信息技术有限公司 | A kind of uvioresistant fireproof coating and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| HUP0402272A2 (en) | 2005-02-28 |
| AU2002250748A1 (en) | 2002-10-15 |
| UA76747C2 (en) | 2006-09-15 |
| HK1065059A1 (en) | 2005-02-08 |
| SK285850B6 (en) | 2007-09-06 |
| PL365338A1 (en) | 2004-12-27 |
| EA200301085A1 (en) | 2004-04-29 |
| BG108305A (en) | 2004-09-30 |
| JP4274799B2 (en) | 2009-06-10 |
| CZ20032967A3 (en) | 2004-04-14 |
| WO2002079329A3 (en) | 2002-12-05 |
| SK13572003A3 (en) | 2004-02-03 |
| PL207152B1 (en) | 2010-11-30 |
| CN1274771C (en) | 2006-09-13 |
| EA006144B1 (en) | 2005-10-27 |
| HUP0402272A3 (en) | 2011-01-28 |
| EP1401965A2 (en) | 2004-03-31 |
| CZ305026B6 (en) | 2015-04-01 |
| JP2004532914A (en) | 2004-10-28 |
| WO2002079329A2 (en) | 2002-10-10 |
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