CN1500844A - Bi component paint used as priming lacquer, producing process and usage thereof - Google Patents
Bi component paint used as priming lacquer, producing process and usage thereof Download PDFInfo
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Abstract
The two-component primer includes component A and component B mixed in the weight ratio of 3-8. The component A includes epoxy resin liquid 25-40 (in weight portions, the same below), amino resin 1-5, stuffing 30-40; and the component B includes polyamide resin 35-50, xylene 28-36, cyclohexanone 20-28 and drier 1-5. The paint product of the present invention has great adhesion force, good toughness, good antifouling performance, high wear resistance, smoke resistance, gasoline resistance, acid and alkali resistance, high electric insulating performance, shock resistance, heat resistance, cold resistance and good fireproof performance. It is used as primer widely in different fields.
Description
Technical field
The present invention relates to a kind of two-pack painting and production method and usage, especially based on the painting that is used for priming paint of Resins, epoxy.
Background technology
Paint be meant be coated onto body surface can dry film forming, make object attractive in appearance and be protected, perhaps form a class filmogen with other specific function film at body surface.Therefore paint is a multicomponent system, is generally thick liquid, because the effect of paint is to different object planes, shields in different environment, needs mechanical strength, characteristics such as ageing-resistant, corrosion-resistant.
The filmogen of paint uses macromolecular compound more; be commonly referred to as coating resin; it should have following performance: solvability is good; compatibility is good; good film-forming properties and to the wettability of pigment and can give the certain protection and ornamental of filming; also want good stability simultaneously, certain quality guaranteed period is arranged.Coating resin divides with its source, and natural resin, artificial resin and synthetic resins three major types are arranged.Synthetic resins is to use maximum, the best filmogen of performance in the present paint industry, such as Resins, epoxy, urethane, polymeric amide, polyester, resol, aminoresin or the like, all is widely used in paint industry.
The paint that China produces is various in style, but all belongs to usual production, far can not adapt to the requirement of China's high-technology industry development, and is especially true in the anti-corrosion of metal field.Corrosion of metal is that metal is subjected to the chemistry of surrounding medium or electrochemical action and ruined phenomenon.Corrosion of metal spreads all over the national economy every field, has brought tremendous loss to national economy.For a long time, one of method that the hardware protection against corrosion is effective, the most the most frequently used is at metallic surface coating erosion shield, with isolated corrosive medium and metallic matrix.Its prescription is formed and is mainly comprised binder resin, pigment, filler and solvent.Binder resin is a filmogen, is its main component, and its molecular structure is determining the salient features of paint.Can be a lot of as the resin of coating resin, different resins has different separately characteristics, has outstanding advantage simultaneously, and unsurmountable shortcoming is also arranged, such as, urethane resin has excellent Corrosion Protection, strong adhesion, wear-resisting, physical and mechanical properties is good, but its poor water resistance.Resins, epoxy is a kind of good coating material, as the paint that base-material is produced, has good sticking power, chemical proof, hardness, snappiness and fastness with it.Shrinking percentage is minimum during curing, and the mechanical property and the electric property of cured article are good, but its weathering resistance is poor, the easy efflorescence of paint film, loss of gloss.Therefore, present industrial two-pack or the multi-component painting of occurring, purpose is that various coating resins are used, advantages is got up separately, can also overcome shortcoming each other simultaneously.In CN 1061674C, disclose first, second two components based on the two-component priming anticorrosive paint of Resins, epoxy, the first component comprises that molecular weight is that 190～600 Resins, epoxy, molecular weight are that 600～1700 Resins, epoxy, iron oxide red, zinc yellow, zinc phosphate, wilkinite, filler, solubility parameter are 8～17, and viscosity is the organic solvent of 0.5～30 centipoise in the time of 20 ℃; The second component comprises that phenol aldehyde modified polyamine, amine value are that 200～600 polymeric amide, softening agent, iron oxide red, solubility parameter are 8～17, and viscosity is the organic solvent of 0.5～30 centipoise in the time of 20 ℃.This coating improves corrosion resistance and work-ing life greatly.This patent is with Resins, epoxy and two kinds of resin-bonded of polymeric amide, synergy, though improved the Corrosion Protection of coating to a certain extent, but still can not satisfy the needs of high-technology industry development fully.How the multiple coating resin with different characteristics is used, and is still the problem that the present utmost point need solve.
When the hardware surface applied is painted, generally need carry out high bake to the paint of coating, it can be solidified rapidly, this brings very big inconvenience with regard to the construction of giving paint, so easily construction also is a direction of paint industry development.
Summary of the invention
The object of the present invention is to provide a kind of two-pack painting that is used for priming paint, this invention has that strong adhesion, good toughness, stain resistance are good, wear-resisting, salt spray resistance, anti-gasoline, acid and alkali-resistance, electrical insulating property are good, shock-resistant, high temperature resistant, cold-resistant, the characteristics of good flame resistance, and energy spontaneous curing, be easy to construction, can be used as the priming paint of paint coating.
Another object of the present invention is to provide a kind of working method that is used for the two-pack painting of priming paint.
An also purpose of the present invention is to provide a kind of using method that is used for the two-pack painting of priming paint.
In order to realize the object of the invention, the invention provides a kind of two-pack paint that collects the polyploid organic resin, one group is mainly adopted hydroxyl (OH) bis-phenol base propane and epoxy chloropropane synthetic resin; (NCO) two amido toluene affixtures are with two mixed joining of component for isocyanic ester for another group.Utilize (OH) with (NCO) cross-linking reaction, leave standstill, solidify, it is good to generate a kind of function, natural, graceful and poised plentiful, bright-coloured paint film.
In order to realize the object of the invention, the invention provides a kind of two-pack painting that is used for priming paint, it is characterized in that by A, two kinds of components of B constitute, the composition of A component comprises by weight: 25 parts～40 parts of Resins, epoxy liquid, 1 part～5 parts in aminoresin, 30 parts～45 parts of fillers, described Resins, epoxy liquid comprises 20 parts～30 parts of Resins, epoxy, 2 parts～8 parts of linear epoxy resins, 5 parts～12 parts in butanols, 6 parts～15 parts of pimelinketone, 12 parts～20 parts of dimethylbenzene, the composition of B component comprises by weight: 35 parts～50 parts of polyamide resins, 28 parts～36 parts of dimethylbenzene, 20 parts～28 parts of pimelinketone, 1 part～5 parts of siccative mixed with the B component A component by 3: 1～8: 1 weight ratio.
The composition of A component of the present invention also may further be (by weight): 34 parts～36 parts of Resins, epoxy liquid, 1.5 parts～3 parts in aminoresin, filler: 35 parts～42 parts, described Resins, epoxy liquid comprises 26 parts～28 parts of Resins, epoxy, 3 parts～6 parts of linear epoxy resins, 6 parts～11 parts in butanols, 8 parts～11 parts of pimelinketone, 16 parts～18 parts of dimethylbenzene, the composition of B component comprises by weight: 46 parts～48 parts of polyamide resins, 28 parts～36 parts of dimethylbenzene, 24 parts～26 parts of pimelinketone, 1 part～2 parts of siccative mix with the B component A component by 4: 1～6: 1 weight ratio.
The molecular weight of Resins, epoxy of the present invention is 600～1400, such as: a kind of in the Resins, epoxy 6101,618,634,601,604 etc.
The molecular weight of described linear epoxy resin is 20000～31000, such as Resins, epoxy 621.
The amine value of described polyamide resin is 600～800, such as polymeric amide T-31 or polymeric amide T-31-1.
The tolerance of described aminoresin is 2～10, such as aminoresin 590-4.
Described filler is that zinc sulfide white, talcum powder, titanium dioxide, process white, wilkinite, lime carbonate etc. are wherein at least a.
Described siccative is a metal organic acid soap class, a kind of such as in lead resinate, fatty acid aluminium, the resin acid cobalt etc.
Filler is added Resins, epoxy, can reduce the cost of paint and improve the paint performance, such as, can reduce resin flow, shrinkability and the temperature rise that causes because of heat release when solidifying, and can improve the acid resistance of paint in various degree, wear resistance, thermotolerance and thermal conductivity etc.Add zinc sulfide white and can reduce shrinking percentage, add talcum powder and can improve wear resisting property, or the like.
It is good that aminoresin has chemical resistant properties, and ventilation property is low, the characteristics of strong adhesion, and acting as of polyamide resin quickened curing reaction and can be shortened set time.
In order to realize another purpose of the present invention, the invention provides a kind of production method that collects the two-pack painting of polyploid organic resin.Wherein the production method of A component is:
1.) the various compositions of required Resins, epoxy liquid are joined the speed with 500 commentaries on classics/min～800 commentaries on classics/min stirs in the reactor, and be warmed up to 120 ℃～160 ℃ with the speed of 2 ℃/min～5 ℃/min, reaction 100min～150min stops heat supply, be cooled to 40 ℃～60 ℃, get Resins, epoxy liquid;
2.) then Resins, epoxy liquid is mixed with other various compositions of A component, grind after stirring 10min～45min with the speed of 800 commentaries on classics/min～1200 commentaries on classics/min, fineness to 20 micron～50 microns makes the A component.
The production method of B component: the various compositions of B component are mixed, make the B component behind the speed stirring 5min～20min with 800 commentaries on classics/min～1200 commentaries on classics/min.
The purpose that at first prepares Resins, epoxy liquid is to make Resins, epoxy fully dissolve, dewater, and removes impurity, act as the minimizing processing sequence, by decompose, concise, purifying obtains the Resins, epoxy liquid of excellent quality.
In order to realize the object of the invention, the present invention also provides the using method of the two-pack paint that is used for priming paint, when it is characterized in that using the A component is mixed by 3: 1～8: 1 weight ratio with the B component, stirs, and just can be used for the use of priming paint.
Wherein said A component and the preferred proportioning of B component are 4: 1～6: 1.
In order to solve construction product viscosity problem, can when using, priming paint, add thinner in A component and B component blended while, and its A component: B component: thinner is 3: 1: 0.1～8: 1: 0.3, preferably 4: 1: 0.1 5～6: 1: 0.25.Usually, thinner is a mixture, mostly is the mixture of butanols, pimelinketone, dimethylbenzene, oxytol acetate equal solvent, and the geometric ratio that is preferably butanols, pimelinketone, dimethylbenzene and oxytol acetate is mixed.Thinner can not only solve construction product viscosity problem, and for cleaning the indispensable varnish remover of service tool (spray gun, hairbrush, push roller, paintpot).
Main resin such as the linear epoxy resin of polyploid multipolymer, Resins, epoxy, aminoresin, polymeric amide is through dissolving, polymerization, and the ester bond long-chain joint of many excellent properties appears in molecular structure.The present invention's paint is two components of A, B, and crosslinked, thermalization is carried out in preparation by a certain percentage, reaches amine and solidifies, at normal temperatures can seasoning.The paint film that generates has shown good characteristics such as physical property, mechanicalness, chemical.Paint film is plentiful, bright in colour, hard, good toughness, strong adhesion, insulating property outstanding, resistance to chemical corrosion is excellent.
Painting of the present invention can be used as priming paint and uses, product performance surpass the requirement of national standard and industry standard, product can be in 3～5 hours surface dryings and spontaneous curing at normal temperatures, hardness is greater than 0.8 (pendulum-rocker hardness meter), glossiness is greater than 100 (photoelectricity glossometers), sticking power reaches 1 grade, snappiness reaches 1 grade, soak 24 hours no changes in salpeter solution 25% or 25% hydrochloric acid soln or 25% sulphuric acid soln or 30% caustic soda soln, in salt solution or water or gasoline, soak 3 months no changes, shock strength reaches 50kg/cm, does not ftracture at～30 ℃ of-+100 ℃ of paint films, not softening, not delamination, long service life.
Painting of the present invention and finish paint are used, can solve " hydrophilic and oleophobic " in aircraft, submarine, car, oceangoing vessel, extra large land oil and gas well drilling, transport pipeline engineering, having anticorrosion, drag reduction, dewaxing, lightning protection punctures, technical features such as electrical isolation can both be used widely aspect civilian, industry and aircraft industry, national defense industry, the conventional weapon as " covering lacquer ".
Description of drawings
Fig. 1 is the paint production process flow sheet
Number in the figure is: 1 Raw material pail, 2 feeding pumps, 3 header tanks, 4 mixing tanks, 5 mixing tanks, 6 volume pumps, 7 reactors, 8 work in-process buckets, 9 cranes, 10 basins, 11 condensers, 12 scale tanks, 13 condensers, 14 water-and-oil separators, 15 surge tanks, 16 reactors, 17 vacuum pumps, 18 dispersion machines, 19 shredders, 20 strainers, 21 finished product jars, 22 canning machines.
Embodiment
Below be specific embodiments of the invention, described embodiment is used to describe the present invention, rather than restriction the present invention.(umber among the embodiment is parts by weight)
Embodiment 1
The composition of A component epoxy liquid is: 5 parts in butanols, 6 parts of pimelinketone, 12 parts of dimethylbenzene, 20 parts of Resins, epoxy, 2 parts of linear epoxy resins.Wherein Resins, epoxy is Resins, epoxy 601, and linear epoxy resin is a Resins, epoxy 621, is produced by Wuxi resin processing plant.
The A component is: 2 parts in aminoresin, 28 parts in zinc sulfide white, 2 parts of talcum powder, 30 parts of 6 parts of process whites and Resins, epoxy liquid.Wherein aminoresin is aminoresin 590-4, is produced by Tianjin resin processing plant.
B composition: 35 parts of polyamide resin T-31,20 parts of pimelinketone, 28 parts of dimethylbenzene, 2 parts of fatty acid aluminiums.Wherein polyamide resin T-31 is produced by Tianjin Yan Hai chemistry company limited.
A component epoxy liquid making processes: at first butanols, pimelinketone, dimethylbenzene, Resins, epoxy, linear epoxy resin in the Raw material pail 1 are utilized feeding pump 2, by header tank 3 and volume pump 6, import reactor 7 according to the above ratio, start agitator in the still, with the speed stirring of 600 commentaries on classics/min; Closing valve is opened cap relief valve then, progressively heats up 120 ℃ with the speed of 5 ℃/min, stops air feed to 100min.Open water coolant, still temperature drop to 60 ℃ stops to stir.Again through cooling, filter, standby in the work in-process bucket 8 through reactor 7 discharging resin liquid.
A component finished product making processes: with 2 parts in aminoresin, 28 parts in zinc sulfide white, 2 parts of talcum powder, 30 parts of 6 parts of process whites and Resins, epoxy liquid load in mixture in the dispersion tank by metering, send high speed dispersor 18, after fully stirring 30min with the speed of 900 commentaries on classics/min, pump into shredder 19 and circulate and mill, through strainer 20, obtaining fineness is 25 microns A components, change finished product jar 21 over to, canned through canning machine 22 again, finally finished product is put in storage.
Finish paint B component finished product making processes: adopt 35 parts of polyamide resins, 20 parts of pimelinketone, 28 parts of dimethylbenzene, 2 parts of fatty acid aluminiums load in mixture in the dispersion tank by metering, send high speed dispersor 18, after disperseing to stir 10min with the speed of 900 commentaries on classics/min, change finished product jar 21 over to, canned through canning machine 22 again, finally finished product is put in storage.
In use, the A component is mixed by 3: 1 weight ratio with the B component, promptly can be used for the use of finish paint.
This product can be in 3 hours surface dryings and spontaneous curing at normal temperatures, hardness is 0.8 (pendulum-rocker hardness meter), glossiness 100 (photoelectricity glossometer), sticking power reaches 1 grade, and snappiness reaches 1 grade, soaks 24 hours no changes in salpeter solution 25% or 25% hydrochloric acid soln or 25% sulphuric acid soln or 30% caustic soda soln, in salt solution or water or gasoline, soak 3 months no changes, shock strength reaches 50kg/cm, does not ftracture, softening, not delamination long service life at-30 ℃ of-+100 ℃ of paint films.
As different from Example 1, the proportioning raw materials of A component epoxy liquid is: 11 parts in butanols, and 10 parts of pimelinketone, 18 parts of dimethylbenzene, Resins, epoxy 604 is 28 parts, linear epoxy resin 621 is 8 parts.Wherein stirring velocity is 800 commentaries on classics/min, progressively heats up 160 ℃ with the speed of 2 ℃/min, stops air feed to 150min.
The proportioning raw materials of A component finished product is: aminoresin is 3 parts, 33 parts in zinc sulfide white, 2 parts of talcum powder, 36 parts of 5 parts of process whites and Resins, epoxy liquid.Stirring velocity is 1200 commentaries on classics/min, and churning time is 40min, and fineness is 35 microns.
The proportioning raw materials of B component finished product is: polyamide resin T-31-1 is 48 parts, 26 parts of pimelinketone, and 36 parts of dimethylbenzene, 4 parts of lead resinates, stirring velocity is 1200 commentaries on classics/min, churning time is 10min.
In use, in A component and B component blended while, add thinner, thinner is the balanced mix of butanols, pimelinketone, dimethylbenzene and oxytol acetate, and A component, B component and thinner mix by 6: 1: 0.15 weight ratio.
This product can be in 4 hours surface dryings and spontaneous curing at normal temperatures, hardness is 0.85 (pendulum-rocker hardness meter), glossiness 110 (photoelectricity glossometer), sticking power reaches 1 grade, and snappiness reaches 1 grade, soaks 24 hours no changes in nitric acid 25% or 25% hydrochloric acid or 25% sulfuric acid or 30% caustic soda, in salt solution or water or gasoline, soak 3 months no changes, shock strength reaches 52kg/cm, does not ftracture, softening, not delamination long service life at-30 ℃ of-+100 ℃ of paint films.
Embodiment 3
As different from Example 1, the proportioning raw materials of A component epoxy liquid is: 11 parts in butanols, and 8 parts of pimelinketone, 15 parts of dimethylbenzene, Resins, epoxy 6101 is 30 parts, linear epoxy resin 621 is 8 parts.Wherein stirring velocity is 800 commentaries on classics/min, progressively heats up 160 ℃ with the speed of 2 ℃/min, stops air feed to 130min.
The proportioning raw materials of A component finished product is: 5 parts in aminoresin, 30 parts in zinc sulfide white, 4 parts of talcum powder, 40 parts of 5 parts of process whites and Resins, epoxy liquid.Stirring velocity is 1200 commentaries on classics/min, and churning time is 40min, and fineness is 35 microns.
The proportioning raw materials of B component finished product is: 40 parts of polyamide resins, and 23 parts of pimelinketone, 30 parts of dimethylbenzene, 2 parts of fatty acid aluminiums, stirring velocity is 1150 commentaries on classics/min, churning time is 10min.
In use, in A component and B component blended while, add thinner, thinner is the balanced mix of butanols, pimelinketone and dimethylbenzene, and A component, B component and thinner mix by 8: 1: 0.2 weight ratio.
This product can be in 3 hours surface dryings and spontaneous curing at normal temperatures, hardness is 0.87 (pendulum-rocker hardness meter), glossiness 115 (photoelectricity glossometer), sticking power reaches 1 grade, and snappiness reaches 1 grade, soaks 24 hours no changes in salpeter solution 25% or 25% hydrochloric acid soln or 25% sulphuric acid soln or 30% caustic soda soln, in salt solution or water or gasoline, soak 3 months no changes, shock strength reaches 50kg/cm, does not ftracture, softening, not delamination long service life at-30 ℃ of-+100 ℃ of paint films.
Claims (10)
1. two-pack painting that is used for priming paint, it is characterized in that by A, two kinds of components of B constitute, the composition of A component comprises by weight: 25 parts～40 parts of Resins, epoxy liquid, 1 part～5 parts in aminoresin, 30 parts～45 parts of fillers, described Resins, epoxy liquid comprises 20 parts～30 parts of Resins, epoxy, 2 parts～8 parts of linear epoxy resins, 5 parts～12 parts in butanols, 6 parts～15 parts of pimelinketone, 12 parts～20 parts of dimethylbenzene, the composition of B component comprises by weight: 35 parts～50 parts of polyamide resins, 28 parts～36 parts of dimethylbenzene, 20 parts～28 parts of pimelinketone, 1 part～5 parts of siccative.
2. two-pack painting according to claim 1, it is characterized in that the composition of A component comprises by weight: 34 parts～36 parts of Resins, epoxy liquid, 1.5 parts～3 parts in aminoresin, 35 parts～42 parts of fillers, described Resins, epoxy liquid comprises 26 parts～28 parts of Resins, epoxy, 3 parts～6 parts of linear epoxy resins, 6 parts～11 parts in butanols, 8 parts～11 parts of pimelinketone, 16 parts～18 parts of dimethylbenzene, the composition of B component comprises by weight: 46 parts～48 parts of polyamide resins, 28 parts～36 parts of dimethylbenzene, 24 parts～26 parts of pimelinketone, 1 part～2 parts of siccative.
3. two-pack painting according to claim 1, the molecular weight that it is characterized in that described Resins, epoxy is 600～1400, the molecular weight of described linear epoxy resin is 20000～31000, the amine value of described polyamide resin is 600～800, and the tolerance of described aminoresin is 2～10.
4. two-pack painting according to claim 3, it is characterized in that described Resins, epoxy is a kind of in the Resins, epoxy 6101,618,634,601,604, described linear epoxy resin is a Resins, epoxy 621, and described polymeric amide is polymeric amide T-31 or polymeric amide T-31-1.
5. two-pack painting according to claim 1 is characterized in that described filler is at least a in zinc sulfide white, talcum powder, titanium dioxide, process white, wilkinite, the lime carbonate.
6. two-pack painting according to claim 1 is characterized in that described siccative is a metal organic acid soap class, a kind of in lead resinate, fatty acid aluminium or the resin acid cobalt.
7. production method that is used for the two-pack painting of priming paint, wherein the production method of A component is:
1.) the various compositions of required Resins, epoxy liquid are joined the speed with 500 commentaries on classics/min～800 commentaries on classics/min stirs in the reactor, and be warmed up to 120 ℃～160 ℃ with the speed of 2 ℃/min～5 ℃/min, reaction 100min～150min stops heat supply, be cooled to 40 ℃～60 ℃, get Resins, epoxy liquid;
2.) then Resins, epoxy liquid is mixed with other various compositions of A component, grind after stirring 10min～45min with the speed of 800 commentaries on classics/min～1200 commentaries on classics/min, fineness to 20 micron～50 microns makes the A component;
The production method of B component: the various compositions of B component are mixed, make the B component behind the speed stirring 5min～20min with 800 commentaries on classics/min～1200 commentaries on classics/min.
8. the usage of the described two-pack painting of claim 1 was mixed with the B component A component when it is characterized in that using by 3: 1～8: 1 weight ratio, stirred, and made priming paint and painted product.
9. the usage of two-pack painting according to claim 8 is characterized in that the A component mixes by 4: 1～6: 1 weight ratio with the B component.
10. the usage of two-pack painting according to claim 8, it is characterized in that to add thinner in use, A component wherein: the B component: the weight ratio of thinner is 3: 1: 0.1～8: 1: 0.3, preferred weight ratio is 4: 1: 0.1 5～6: 1: 0.25, described thinner was the mixture of butanols, pimelinketone, dimethylbenzene or oxytol acetate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02146497 CN1229457C (en) | 2002-11-12 | 2002-11-12 | Bi component paint used as priming lacquer, producing process and usage thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN 02146497 CN1229457C (en) | 2002-11-12 | 2002-11-12 | Bi component paint used as priming lacquer, producing process and usage thereof |
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| CN1500844A true CN1500844A (en) | 2004-06-02 |
| CN1229457C CN1229457C (en) | 2005-11-30 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 02146497 Expired - Fee Related CN1229457C (en) | 2002-11-12 | 2002-11-12 | Bi component paint used as priming lacquer, producing process and usage thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100410340C (en) * | 2005-07-01 | 2008-08-13 | 上海市涂料研究所 | Aircraft skin coating |
| CN102604535A (en) * | 2012-03-02 | 2012-07-25 | 中国航空工业集团公司北京航空材料研究院 | High-temperature-resisting aluminum paint used on steel surface, and preparation method thereof |
| CN103194110A (en) * | 2012-01-09 | 2013-07-10 | 江苏格桑花涂料有限公司 | High-temperature and corrosion resistant coating production apparatus |
| CN103194111A (en) * | 2012-01-09 | 2013-07-10 | 江苏格桑花涂料有限公司 | Wear-resistant clean floor coating production apparatus |
| CN104449209A (en) * | 2014-11-05 | 2015-03-25 | 德阳森华涂料化工有限公司 | Epoxy baking varnish |
| CN105086610A (en) * | 2015-10-08 | 2015-11-25 | 苏州市永津彩印包装有限公司 | High-quality anti-gelling printing ink |
| CN106349865A (en) * | 2016-08-26 | 2017-01-25 | 袁华 | Environment-friendly flame-retardant acid- and alkali-resistant treating coating for building materials |
| CN114958145A (en) * | 2022-06-14 | 2022-08-30 | 湖北省林业科学研究院 | Composite coating and application thereof |
-
2002
- 2002-11-12 CN CN 02146497 patent/CN1229457C/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100410340C (en) * | 2005-07-01 | 2008-08-13 | 上海市涂料研究所 | Aircraft skin coating |
| CN103194110A (en) * | 2012-01-09 | 2013-07-10 | 江苏格桑花涂料有限公司 | High-temperature and corrosion resistant coating production apparatus |
| CN103194111A (en) * | 2012-01-09 | 2013-07-10 | 江苏格桑花涂料有限公司 | Wear-resistant clean floor coating production apparatus |
| CN103194111B (en) * | 2012-01-09 | 2014-12-10 | 江苏格桑花涂料有限公司 | Wear-resistant clean floor coating production apparatus |
| CN102604535A (en) * | 2012-03-02 | 2012-07-25 | 中国航空工业集团公司北京航空材料研究院 | High-temperature-resisting aluminum paint used on steel surface, and preparation method thereof |
| CN104449209A (en) * | 2014-11-05 | 2015-03-25 | 德阳森华涂料化工有限公司 | Epoxy baking varnish |
| CN105086610A (en) * | 2015-10-08 | 2015-11-25 | 苏州市永津彩印包装有限公司 | High-quality anti-gelling printing ink |
| CN106349865A (en) * | 2016-08-26 | 2017-01-25 | 袁华 | Environment-friendly flame-retardant acid- and alkali-resistant treating coating for building materials |
| CN114958145A (en) * | 2022-06-14 | 2022-08-30 | 湖北省林业科学研究院 | Composite coating and application thereof |
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| Publication number | Publication date |
|---|---|
| CN1229457C (en) | 2005-11-30 |
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