CN1493417A - Low carbon high aluminium integral composite plug rod - Google Patents

Low carbon high aluminium integral composite plug rod Download PDF

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Publication number
CN1493417A
CN1493417A CNA031391257A CN03139125A CN1493417A CN 1493417 A CN1493417 A CN 1493417A CN A031391257 A CNA031391257 A CN A031391257A CN 03139125 A CN03139125 A CN 03139125A CN 1493417 A CN1493417 A CN 1493417A
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CN
China
Prior art keywords
phenolic resin
alumina
stopper
metallic
aluminium powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CNA031391257A
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Chinese (zh)
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CN1220566C (en
Inventor
董文全
徐文相
郑学杰
曹雪峰
吴春
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SHUANGYING REFRACTORY MATERIAL CO Ltd QINGDAO
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SHUANGYING REFRACTORY MATERIAL CO Ltd QINGDAO
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Priority to CN 03139125 priority Critical patent/CN1220566C/en
Publication of CN1493417A publication Critical patent/CN1493417A/en
Application granted granted Critical
Publication of CN1220566C publication Critical patent/CN1220566C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

An integrated composite low-carbon high-aluminium stopper for conticasting steel features that its rod head has the residual carbon content about 8-15%, and contains scale graphite (5-10 wt.%), electro-corundam (75-85), light-burnt alumina (2-5), metallic Si-Al powder (2.5-5), liquid phenolic resin (5-10) and solid phenolic resin (0.4-0.7%). Its advantage is long service life.

Description

Low-carbon (LC) high alumina matter integral composite stopper rod
Technical field
The present invention relates to a kind of novel inorganic non-metallic refractory product, especially relate to the low-carbon (LC) high alumina matter integral composite stopper rod that in continuous casting steel machine is produced, uses.
Background technology
The stopper that uses in continuous casting steel machine is produced both at home and abroad all is made up of two portions usually as aluminium carbon integrated filler rod or aluminium carbon integrated composite stopper rod at present, i.e. stopper rod body and caput.Stopper rod body generally adopts the lower raw materials of price such as brown corundum, and caput adopts white fused alumina.But the common AL of caput 2O 3Content is no more than 80%, and reason is caput and excellent body AL 2O 3It is bigger that content differs, and causes the thermal expansivity of material own to differ also bigger, in production and use, is easy to generate the phenomenon that turns around.Because caput AL 2O 3How much being directly proportional with the work-ing life of stopper of content, therefore, the prior art stopper is generally lower work-ing life.
Summary of the invention
The present invention is for solving above-mentioned stopper low problem in work-ing life, a kind of improved stopper is provided, this stopper caput adopts low-carbon (LC), high alumina refractories to be composited, and the remaining carbon of whole caput is 8-15%, caput material as low-carbon (LC) high alumina matter integral composite stopper rod, its component (weight percent, as follows) be: crystalline flake graphite 5-10%, fused white corundum or electric smelting compact alumina 75-85%, calcined alumina 2-5%, metallic silicon power and metallic aluminium powder 2.5-5%, liquid phenolic resin 5-10%, solid phenolic resin 4-7 ‰.
Wherein, crystalline flake graphite is 5%, fused white corundum or electric smelting compact alumina 78%, calcined alumina 2%, metallic silicon power and metallic aluminium powder 4.5%, liquid phenolic resin 10%, solid phenolic resin 5 ‰.
Wherein, crystalline flake graphite is 9%, fused white corundum or electric smelting compact alumina 78.5%, calcined alumina 2.5%, metallic silicon power and metallic aluminium powder 4.6%, liquid phenolic resin 5%, solid phenolic resin 4 ‰.
Wherein, crystalline flake graphite is 6%, fused white corundum or electric smelting compact alumina 82%, calcined alumina 2%, metallic silicon power and metallic aluminium powder 4.5%, liquid phenolic resin 5%, solid phenolic resin 5 ‰.
Along with caput material AL 2O 3The increase of content, caput and excellent body AL 2O 3It is bigger that content differs, and causes the thermal expansivity of material own to differ also bigger, in production and use, be easy to generate the phenomenon that turns around,, between excellent body and caput, add a transition section for overcoming this problem, it adopts the mixing raw material of excellent body and caput, and the proportioning of two kinds of material is 1 to 1.
Description of drawings
Below in conjunction with drawings and Examples the present invention is described in detail.
Accompanying drawing 1 is a front view of the present invention.
1 is excellent body among the figure; 2 is caput; 3 is transition section.
Embodiment
Stopper as shown in Figure 1, it comprises excellent body 1, caput 2, transition section 3, excellent body 1 adopts common aluminium carbon materials such as special alum or brown corundum.Caput 2 adopts the low-carbon (LC) high alumina refractories, its component (weight percent, as follows) be: crystalline flake graphite 5-10%, fused white corundum or electric smelting compact alumina 75-85%, calcined alumina 2-5%, metallic silicon power and metallic aluminium powder 2.5-5%, liquid phenolic resin 5-10%, solid phenolic resin 4-7 ‰.Transition section 3 adopts the mixing raw material of excellent body and caput, and the proportioning of two kinds of material is 1 to 1.
In the embodiment 1 caput material, crystalline flake graphite is 5%, fused white corundum or electric smelting compact alumina 78%, calcined alumina 2%, metallic silicon power and metallic aluminium powder 4.5%, liquid phenolic resin 10%, solid phenolic resin 5 ‰.
In the embodiment 2 caput material, crystalline flake graphite is 9%, fused white corundum or electric smelting compact alumina 78.5%, calcined alumina 2.5%, metallic silicon power and metallic aluminium powder 4.6%, liquid phenolic resin 5%, solid phenolic resin 4 ‰.
In the embodiment 3 caput material, crystalline flake graphite is 6%, fused white corundum or electric smelting compact alumina 82%, calcined alumina 2%, metallic silicon power and metallic aluminium powder 4.5%, liquid phenolic resin 5%, solid phenolic resin 5 ‰.

Claims (8)

1, a kind of low-carbon (LC) high alumina matter integral composite stopper rod, form by excellent body and caput, it is characterized in that caput adopts low-carbon (LC), high alumina refractories to be composited, its component (weight percent, as follows) is: crystalline flake graphite 5-10%, fused white corundum or electric smelting compact alumina 75-85%, calcined alumina 2-5%, metallic silicon power and metallic aluminium powder 2.5-5%, liquid phenolic resin 5-10%, solid phenolic resin 4-7 ‰.
2, stopper as claimed in claim 1 is characterized in that a transition section is arranged between excellent body and the caput, and it adopts the mixing raw material of excellent body and caput, and the proportioning of two kinds of material is 1 to 1.
3, require 1 described stopper as the right profit, it is characterized in that described crystalline flake graphite is 5%, fused white corundum or electric smelting compact alumina 78%, calcined alumina 2%, metallic silicon power and metallic aluminium powder 4.5%, liquid phenolic resin 10%, solid phenolic resin 5 ‰.
4, stopper as claimed in claim 1 is characterized in that described crystalline flake graphite is 9%, fused white corundum or electric smelting compact alumina 78.5%, calcined alumina 2.5%, metallic silicon power and metallic aluminium powder 4.6%, liquid phenolic resin 5%, solid phenolic resin 4 ‰.
5, stopper as claimed in claim 1 is characterized in that described crystalline flake graphite is 6%, fused white corundum or electric smelting compact alumina 82%, calcined alumina 2%, metallic silicon power and metallic aluminium powder 4.5%, liquid phenolic resin 5%, solid phenolic resin 5 ‰.
6, stopper as claimed in claim 2 is characterized in that described crystalline flake graphite is 5%, fused white corundum or electric smelting compact alumina 78%, calcined alumina 2%, metallic silicon power and metallic aluminium powder 4.5%, liquid phenolic resin 10%, solid phenolic resin 5 ‰.
7, stopper as claimed in claim 2 is characterized in that described crystalline flake graphite is 9%, fused white corundum or electric smelting compact alumina 78.5%, calcined alumina 2.5%, metallic silicon power and metallic aluminium powder 4.6%, liquid phenolic resin 5%, solid phenolic resin 4 ‰.
8, stopper as claimed in claim 2 is characterized in that described crystalline flake graphite is 6%, fused white corundum or electric smelting compact alumina 82%, calcined alumina 2%, metallic silicon power and metallic aluminium powder 4.5%, liquid phenolic resin 5%, solid phenolic resin 5 ‰.
CN 03139125 2003-08-16 2003-08-16 Low carbon high aluminium integral composite plug rod Expired - Fee Related CN1220566C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 03139125 CN1220566C (en) 2003-08-16 2003-08-16 Low carbon high aluminium integral composite plug rod

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 03139125 CN1220566C (en) 2003-08-16 2003-08-16 Low carbon high aluminium integral composite plug rod

Publications (2)

Publication Number Publication Date
CN1493417A true CN1493417A (en) 2004-05-05
CN1220566C CN1220566C (en) 2005-09-28

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CN 03139125 Expired - Fee Related CN1220566C (en) 2003-08-16 2003-08-16 Low carbon high aluminium integral composite plug rod

Country Status (1)

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CN (1) CN1220566C (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100398234C (en) * 2004-12-24 2008-07-02 中钢集团洛阳耐火材料研究院 Integral column of sagger in composite structure
CN100439279C (en) * 2007-04-30 2008-12-03 山东中齐耐火材料有限公司 Formula of caput of composition type stopper
CN102515798A (en) * 2011-12-12 2012-06-27 辽宁科大东方巨业高级陶瓷有限公司 High corrosion resistant integral stopper for continuous casting
CN108607980A (en) * 2018-08-21 2018-10-02 北京利尔高温材料股份有限公司 It is a kind of can efficiently blowing argon gas and with removal wadding stream function stopper
CN115368142A (en) * 2022-07-28 2022-11-22 杭州大和江东新材料科技有限公司 Low dielectric loss aluminum nitride ceramic material and preparation method thereof
CN116041080A (en) * 2023-02-10 2023-05-02 西峡县西保冶金材料有限公司 Scour-resistant low-carbon long-service-life stopper rod and preparation method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100398234C (en) * 2004-12-24 2008-07-02 中钢集团洛阳耐火材料研究院 Integral column of sagger in composite structure
CN100439279C (en) * 2007-04-30 2008-12-03 山东中齐耐火材料有限公司 Formula of caput of composition type stopper
CN102515798A (en) * 2011-12-12 2012-06-27 辽宁科大东方巨业高级陶瓷有限公司 High corrosion resistant integral stopper for continuous casting
CN102515798B (en) * 2011-12-12 2013-09-25 辽宁科技大学 High corrosion resistant integral stopper for continuous casting
CN108607980A (en) * 2018-08-21 2018-10-02 北京利尔高温材料股份有限公司 It is a kind of can efficiently blowing argon gas and with removal wadding stream function stopper
CN115368142A (en) * 2022-07-28 2022-11-22 杭州大和江东新材料科技有限公司 Low dielectric loss aluminum nitride ceramic material and preparation method thereof
CN116041080A (en) * 2023-02-10 2023-05-02 西峡县西保冶金材料有限公司 Scour-resistant low-carbon long-service-life stopper rod and preparation method thereof

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Publication number Publication date
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