CN1493417A - Low carbon high aluminium integral composite plug rod - Google Patents
Low carbon high aluminium integral composite plug rod Download PDFInfo
- Publication number
- CN1493417A CN1493417A CNA031391257A CN03139125A CN1493417A CN 1493417 A CN1493417 A CN 1493417A CN A031391257 A CNA031391257 A CN A031391257A CN 03139125 A CN03139125 A CN 03139125A CN 1493417 A CN1493417 A CN 1493417A
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- phenolic resin
- alumina
- stopper
- metallic
- aluminium powder
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Abstract
An integrated composite low-carbon high-aluminium stopper for conticasting steel features that its rod head has the residual carbon content about 8-15%, and contains scale graphite (5-10 wt.%), electro-corundam (75-85), light-burnt alumina (2-5), metallic Si-Al powder (2.5-5), liquid phenolic resin (5-10) and solid phenolic resin (0.4-0.7%). Its advantage is long service life.
Description
Technical field
The present invention relates to a kind of novel inorganic non-metallic refractory product, especially relate to the low-carbon (LC) high alumina matter integral composite stopper rod that in continuous casting steel machine is produced, uses.
Background technology
The stopper that uses in continuous casting steel machine is produced both at home and abroad all is made up of two portions usually as aluminium carbon integrated filler rod or aluminium carbon integrated composite stopper rod at present, i.e. stopper rod body and caput.Stopper rod body generally adopts the lower raw materials of price such as brown corundum, and caput adopts white fused alumina.But the common AL of caput
2O
3Content is no more than 80%, and reason is caput and excellent body AL
2O
3It is bigger that content differs, and causes the thermal expansivity of material own to differ also bigger, in production and use, is easy to generate the phenomenon that turns around.Because caput AL
2O
3How much being directly proportional with the work-ing life of stopper of content, therefore, the prior art stopper is generally lower work-ing life.
Summary of the invention
The present invention is for solving above-mentioned stopper low problem in work-ing life, a kind of improved stopper is provided, this stopper caput adopts low-carbon (LC), high alumina refractories to be composited, and the remaining carbon of whole caput is 8-15%, caput material as low-carbon (LC) high alumina matter integral composite stopper rod, its component (weight percent, as follows) be: crystalline flake graphite 5-10%, fused white corundum or electric smelting compact alumina 75-85%, calcined alumina 2-5%, metallic silicon power and metallic aluminium powder 2.5-5%, liquid phenolic resin 5-10%, solid phenolic resin 4-7 ‰.
Wherein, crystalline flake graphite is 5%, fused white corundum or electric smelting compact alumina 78%, calcined alumina 2%, metallic silicon power and metallic aluminium powder 4.5%, liquid phenolic resin 10%, solid phenolic resin 5 ‰.
Wherein, crystalline flake graphite is 9%, fused white corundum or electric smelting compact alumina 78.5%, calcined alumina 2.5%, metallic silicon power and metallic aluminium powder 4.6%, liquid phenolic resin 5%, solid phenolic resin 4 ‰.
Wherein, crystalline flake graphite is 6%, fused white corundum or electric smelting compact alumina 82%, calcined alumina 2%, metallic silicon power and metallic aluminium powder 4.5%, liquid phenolic resin 5%, solid phenolic resin 5 ‰.
Along with caput material AL
2O
3The increase of content, caput and excellent body AL
2O
3It is bigger that content differs, and causes the thermal expansivity of material own to differ also bigger, in production and use, be easy to generate the phenomenon that turns around,, between excellent body and caput, add a transition section for overcoming this problem, it adopts the mixing raw material of excellent body and caput, and the proportioning of two kinds of material is 1 to 1.
Description of drawings
Below in conjunction with drawings and Examples the present invention is described in detail.
Accompanying drawing 1 is a front view of the present invention.
1 is excellent body among the figure; 2 is caput; 3 is transition section.
Embodiment
Stopper as shown in Figure 1, it comprises excellent body 1, caput 2, transition section 3, excellent body 1 adopts common aluminium carbon materials such as special alum or brown corundum.Caput 2 adopts the low-carbon (LC) high alumina refractories, its component (weight percent, as follows) be: crystalline flake graphite 5-10%, fused white corundum or electric smelting compact alumina 75-85%, calcined alumina 2-5%, metallic silicon power and metallic aluminium powder 2.5-5%, liquid phenolic resin 5-10%, solid phenolic resin 4-7 ‰.Transition section 3 adopts the mixing raw material of excellent body and caput, and the proportioning of two kinds of material is 1 to 1.
In the embodiment 1 caput material, crystalline flake graphite is 5%, fused white corundum or electric smelting compact alumina 78%, calcined alumina 2%, metallic silicon power and metallic aluminium powder 4.5%, liquid phenolic resin 10%, solid phenolic resin 5 ‰.
In the embodiment 2 caput material, crystalline flake graphite is 9%, fused white corundum or electric smelting compact alumina 78.5%, calcined alumina 2.5%, metallic silicon power and metallic aluminium powder 4.6%, liquid phenolic resin 5%, solid phenolic resin 4 ‰.
In the embodiment 3 caput material, crystalline flake graphite is 6%, fused white corundum or electric smelting compact alumina 82%, calcined alumina 2%, metallic silicon power and metallic aluminium powder 4.5%, liquid phenolic resin 5%, solid phenolic resin 5 ‰.
Claims (8)
1, a kind of low-carbon (LC) high alumina matter integral composite stopper rod, form by excellent body and caput, it is characterized in that caput adopts low-carbon (LC), high alumina refractories to be composited, its component (weight percent, as follows) is: crystalline flake graphite 5-10%, fused white corundum or electric smelting compact alumina 75-85%, calcined alumina 2-5%, metallic silicon power and metallic aluminium powder 2.5-5%, liquid phenolic resin 5-10%, solid phenolic resin 4-7 ‰.
2, stopper as claimed in claim 1 is characterized in that a transition section is arranged between excellent body and the caput, and it adopts the mixing raw material of excellent body and caput, and the proportioning of two kinds of material is 1 to 1.
3, require 1 described stopper as the right profit, it is characterized in that described crystalline flake graphite is 5%, fused white corundum or electric smelting compact alumina 78%, calcined alumina 2%, metallic silicon power and metallic aluminium powder 4.5%, liquid phenolic resin 10%, solid phenolic resin 5 ‰.
4, stopper as claimed in claim 1 is characterized in that described crystalline flake graphite is 9%, fused white corundum or electric smelting compact alumina 78.5%, calcined alumina 2.5%, metallic silicon power and metallic aluminium powder 4.6%, liquid phenolic resin 5%, solid phenolic resin 4 ‰.
5, stopper as claimed in claim 1 is characterized in that described crystalline flake graphite is 6%, fused white corundum or electric smelting compact alumina 82%, calcined alumina 2%, metallic silicon power and metallic aluminium powder 4.5%, liquid phenolic resin 5%, solid phenolic resin 5 ‰.
6, stopper as claimed in claim 2 is characterized in that described crystalline flake graphite is 5%, fused white corundum or electric smelting compact alumina 78%, calcined alumina 2%, metallic silicon power and metallic aluminium powder 4.5%, liquid phenolic resin 10%, solid phenolic resin 5 ‰.
7, stopper as claimed in claim 2 is characterized in that described crystalline flake graphite is 9%, fused white corundum or electric smelting compact alumina 78.5%, calcined alumina 2.5%, metallic silicon power and metallic aluminium powder 4.6%, liquid phenolic resin 5%, solid phenolic resin 4 ‰.
8, stopper as claimed in claim 2 is characterized in that described crystalline flake graphite is 6%, fused white corundum or electric smelting compact alumina 82%, calcined alumina 2%, metallic silicon power and metallic aluminium powder 4.5%, liquid phenolic resin 5%, solid phenolic resin 5 ‰.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 03139125 CN1220566C (en) | 2003-08-16 | 2003-08-16 | Low carbon high aluminium integral composite plug rod |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 03139125 CN1220566C (en) | 2003-08-16 | 2003-08-16 | Low carbon high aluminium integral composite plug rod |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1493417A true CN1493417A (en) | 2004-05-05 |
CN1220566C CN1220566C (en) | 2005-09-28 |
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ID=34240160
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 03139125 Expired - Fee Related CN1220566C (en) | 2003-08-16 | 2003-08-16 | Low carbon high aluminium integral composite plug rod |
Country Status (1)
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CN (1) | CN1220566C (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100398234C (en) * | 2004-12-24 | 2008-07-02 | 中钢集团洛阳耐火材料研究院 | Integral column of sagger in composite structure |
CN100439279C (en) * | 2007-04-30 | 2008-12-03 | 山东中齐耐火材料有限公司 | Formula of caput of composition type stopper |
CN102515798A (en) * | 2011-12-12 | 2012-06-27 | 辽宁科大东方巨业高级陶瓷有限公司 | High corrosion resistant integral stopper for continuous casting |
CN108607980A (en) * | 2018-08-21 | 2018-10-02 | 北京利尔高温材料股份有限公司 | It is a kind of can efficiently blowing argon gas and with removal wadding stream function stopper |
CN115368142A (en) * | 2022-07-28 | 2022-11-22 | 杭州大和江东新材料科技有限公司 | Low dielectric loss aluminum nitride ceramic material and preparation method thereof |
CN116041080A (en) * | 2023-02-10 | 2023-05-02 | 西峡县西保冶金材料有限公司 | Scour-resistant low-carbon long-service-life stopper rod and preparation method thereof |
-
2003
- 2003-08-16 CN CN 03139125 patent/CN1220566C/en not_active Expired - Fee Related
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100398234C (en) * | 2004-12-24 | 2008-07-02 | 中钢集团洛阳耐火材料研究院 | Integral column of sagger in composite structure |
CN100439279C (en) * | 2007-04-30 | 2008-12-03 | 山东中齐耐火材料有限公司 | Formula of caput of composition type stopper |
CN102515798A (en) * | 2011-12-12 | 2012-06-27 | 辽宁科大东方巨业高级陶瓷有限公司 | High corrosion resistant integral stopper for continuous casting |
CN102515798B (en) * | 2011-12-12 | 2013-09-25 | 辽宁科技大学 | High corrosion resistant integral stopper for continuous casting |
CN108607980A (en) * | 2018-08-21 | 2018-10-02 | 北京利尔高温材料股份有限公司 | It is a kind of can efficiently blowing argon gas and with removal wadding stream function stopper |
CN115368142A (en) * | 2022-07-28 | 2022-11-22 | 杭州大和江东新材料科技有限公司 | Low dielectric loss aluminum nitride ceramic material and preparation method thereof |
CN116041080A (en) * | 2023-02-10 | 2023-05-02 | 西峡县西保冶金材料有限公司 | Scour-resistant low-carbon long-service-life stopper rod and preparation method thereof |
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Publication number | Publication date |
---|---|
CN1220566C (en) | 2005-09-28 |
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