CN1490367A - Modified double layer epoxide powder paint and preparing method thereof - Google Patents
Modified double layer epoxide powder paint and preparing method thereof Download PDFInfo
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- CN1490367A CN1490367A CNA031496814A CN03149681A CN1490367A CN 1490367 A CN1490367 A CN 1490367A CN A031496814 A CNA031496814 A CN A031496814A CN 03149681 A CN03149681 A CN 03149681A CN 1490367 A CN1490367 A CN 1490367A
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Abstract
A modified dual-layer epoxy powder paint for the anticorrosion pipe is prepared from epoxy resin, modified acrylic resin, solidifying agent, levelling agent, defoaming agent, catalyst, calcium stearate, pigment, titanium white powder, barium sulfate and sericite through proportional mixing, stirring, extruding out, pressing, air cooling, crushing, grinding and sieving. Its advantages are low cost and high resistance to impact and scratching.
Description
Technical field:
The present invention relates to the used powder coating in protective system field, belong to a kind of modification dual-layer epoxy powder coating and preparation method thereof.
Background technology:
What the outer anti-corrosion pipe of present domestic steel pipe was commonly used has three kinds: the one, and PE structural anticorrosion pipe, this anti-corrosion pipe application quantity is big, and can reach 50 years work-ing life, but complex manufacturing, cost height, cathode screen is difficult to realize galvanic protection in the use, is not suitable for applying; The 2nd, single FBE anticorrosion with painting pipe, this anti-corrosion pipe application quantity is big, and favorable anti-corrosion effect, but shock resistance, anti-surface tear poor performance are subjected to heavily to clash into and crackle can occur, lose preservative effect; The 3rd, the dual-layer epoxy powder anti-corrosion pipe of Minnesota Mining and Manufacturing Company, E.I.Du Pont Company, solved the problem that exists in single FBE anticorrosion with painting, but it is two kinds of different powder, to spray respectively, need to increase by three cover powder-supply systems and three cover powder spraying systems, strengthen facility investment and application difficulty, improved production cost.
Summary of the invention:
In order to overcome the deficiency of existing anti-corrosion pipe production cost height, shock resistance, anti-surface tear poor performance, the invention provides a kind of modification dual-layer epoxy powder coating and preparation method thereof, this modification dual-layer epoxy powder coating has that cost is low, shock resistance and the good characteristics of anti-surface tear performance, and the simple cost of production technique is low.
The technical solution adopted in the present invention is: each component and proportioning thereof are as follows by weight percentage in this modification dual-layer epoxy powder coating: Resins, epoxy 40%～45%; Acrylic resin modified 8%～10%; Solidifying agent 9%～10%; Flow agent 8%～10%; Pore eliminator 0.5%～0.6%; Catalyzer 0.6%～0.7%; Calcium stearate 2%～4%; Pigment 0.9%～1.0%; Titanium dioxide 9%～12%; Barium sulfate 12%～14%; Sericite 2%～5%.
Above-mentioned Resins, epoxy is the solid-state bisphenol A epoxide resin of E-12; Acrylic resin modified its molecular weight is 1000～15000; Solidifying agent is a polymer phenol polymer solidifying agent, and its molecular weight is 2000～3000; Flow agent is a butyl polyacrylate, and its molecular weight is 4000～6000; Pore eliminator is a st-yrax; Pigment is phthalocyanine green and organic yellow and respectively accounts for 50%; Catalyzer is a glyoxal ethyline.
A kind of preparation has the method for the modification dual-layer epoxy powder coating of such scheme, each component in the such scheme is put in the mixing tank by its proportioning, high-speed mixing stirs twice under the normal temperature, each 2 minutes, emit after mixing, deliver to the thin slice that 1～2mm was extruded, was pressed into to forcing machine, the forcing machine body temperature is set to: 86 ℃ ± 3 ℃ in 1 district, 105 ℃ ± 5 ℃ in 2 districts, material through extrude, compressing tablet, air-cooled, be crushed to the finished product powder that small pieces, abrasive dust, sub-sieve are collected designated size.
The present invention has following beneficial effect: because this modification dual-layer epoxy powder coating has component and preparation method in the such scheme, with the steel pipe outside surface of this powder coated in heating, in the fusion gel, when solidifying, the heat curing-type powdered epoxy resin at high temperature solidifies and moves down, form preservative coat in steel tube surface, thermoplastic powder modification acrylic resin does not at high temperature solidify and upwards moves in surperficial levelling, form protective layer through cooling curing, thereby form the ideal double-layer structure coating, play good anticorrosion, protection effect; Only need a set of equipment cost low during spraying, and the simple cost of production technique is low.
Embodiment:
Below with the present invention is further illustrated:
Each component and proportioning thereof are as follows by weight percentage in this modification dual-layer epoxy powder coating: the solid-state bisphenol A epoxide resin of E-12 accounts for 40%～45%, its epoxy equivalent (weight) is that 900～1050g/eq, relative density are 1.17～1.20, softening temperature is 90 ℃～104 ℃, this Resins, epoxy is to form the corrosion prevention film essential substance, shrinking percentage is low, water-fast, resistance to chemical attack, organic solvent-resistant, with the steel material bonding firmly and the preferred weight percentage composition be 41.6%; Acrylic resin modifiedly account for 8%～10%, its molecular weight is 1000～15000, and its preparation method is that multiple esters of acrylic acid stirs under 80 ℃～90 ℃ temperature in reactor, after the polyreaction 2～3 hours, slowly add divinyl, repolymerization promptly obtains acrylic resin modified to terminal point, this is acrylic resin modified to be the base resin of protective film, and the preferred weight percentage composition is 8.3%; Polymer phenol polymer solidifying agent accounts for 9%～10%, and its molecular weight is 2000～3000, and this polymer phenols curing agent can impel powder at high temperature to solidify, and the preferred weight percentage composition is 10%; Butyl polyacrylate accounts for 8%～10%, and it can make powder levelling under molten state, and its preferred weight percentage composition is 10.5%, molecular weight is 4000～6000; St-yrax accounts for 0.5%～0.6%, and it can eliminate the issuable pin hole of filming, and the preferred weight percentage composition is 0.5%; Glyoxal ethyline accounts for 0.6%～0.7%, and it can help epoxy resin cure, and the preferred weight percentage composition is 0.6%; Calcium stearate accounts for 2%～4%, and it plays lubricated, increase plasticity, and the preferred weight percentage composition is 3.0%; Pigment accounts for 0.9%～1.0%, and it is made up of phthalocyanine green and organic yellow and respectively accounts for 50%, and it plays a part painted, and the preferred weight percentage composition is 0.7%; Titanium dioxide accounts for 9%～12%, and it is a filler, can increase coating strength, and the preferred weight percentage composition is 9.2%; Barium sulfate accounts for 12%～14%, and it is a filler, can increase coating strength, and the preferred weight percentage composition is 12.5%; Sericite accounts for 2%～5%, and it is a filler, can increase the water resisting property of filming, and the preferred weight percentage composition is 3.1%.
The invention will be further described can to take following three kinds of schemes:
With modification dual-layer epoxy powder coating 20kg case dress is example, and each component adds as table 1 by its weight percent metering:
Table 1
| Material name | Prescription (kg) | |||
| Scheme 1 | Scheme 2 | Scheme 3 | ||
| Resins, epoxy | ????8.32 | ????8.32 | ????8.37 | |
| Acrylic resin modified | ????1.97 | ????1.66 | ????1.53 | |
| The polymer phenols curing agent | ????2.00 | ????2.00 | ????2.00 | |
| The butyl polyacrylate flow agent | ????1.80 | ????2.10 | ????1.86 | |
| Glyoxal ethyline | ????0.12 | ????0.12 | ????0.15 | |
| St-yrax | ????0.10 | ????0.10 | ????0.12 | |
| Titanium dioxide | ????1.84 | ????1.84 | ????1.91 | |
| Barium sulfate | ????2.50 | ????2.50 | ????2.60 | |
| Sericite | ????0.65 | ????0.61 | ????0.66 | |
| Calcium stearate | ????0.55 | ????0.60 | ????0.65 | |
| Pigment | Organic yellow | ????0.075 | ????0.075 | ????0.075 |
| Phthalocyanine green | ????0.075 | ????0.075 | ????0.075 | |
Resins, epoxy in the last table, solidifying agent, organic yellow are put in the mixing tank as the bottom anticorrosive powder after by its proportioning and titanium dioxide, flow agent, barium sulfate, pore eliminator, the meromict of calcium stearate by its proportioning, high-speed mixing stirs twice under the normal temperature, each 2 minutes, emit after mixing, deliver to forcing machine and extrude, be pressed into the thin slice of 1～2mm, the forcing machine body temperature is set to: 86 ℃ ± 3 ℃ in 1 district, 105 ℃ ± 5 ℃ in 2 districts, material through extrude, compressing tablet, air-cooled, be crushed to yellow small pieces; Acrylic resin modified, sericite in the last table, phthalocyanine green are put in the mixing tank as the surface layer protective powder after by its proportioning and titanium dioxide, flow agent, barium sulfate, pore eliminator, the meromict of calcium stearate by its proportioning, high-speed mixing stirs twice under the normal temperature, each 2 minutes, emit after mixing, deliver to forcing machine and extrude, be pressed into the thin slice of 1～2mm, the forcing machine body temperature is set to: 86 ℃ ± 3 ℃ in 1 district, 105 ℃ ± 5 ℃ in 2 districts, material through extrude, compressing tablet, air-cooled, be crushed to green small pieces; Above-mentioned two kinds of little sheet stocks are mixed the finished product powder that back abrasive dust, sub-sieve are collected designated size, and this production technique is simple, and cost is low.
According to SY/T0315-97 and Q/CNPC38-2002 standard sampling and testing granularity, gel time, set time, and spraying sample testing sticking power and resistance to impact shock, test result such as following table 2:
Table 2
| Project | Assay | |||
| Scheme 1 | Scheme 2 | Scheme 3 | ||
| Size-grade distribution | 150 μ m oversize powder≤4% | ????3.6 | ????3.6 | ????3.6 |
| 250 μ m oversize powder≤0.2% | ????0 | ????0 | ????0 | |
| Gel time (205 ℃ ± 3 ℃, 〉=12s) | ????16 | ????15 | ????13 | |
| Set time (230 ℃ ± 3 ℃ ,≤3min) | ????2.6 | ????2.6 | ????2.6 | |
| Outward appearance | Surfacing is smooth, no shrinkage cavity, pin hole | Surfacing is smooth, no shrinkage cavity, pin hole | Surfacing is smooth, no shrinkage cavity, pin hole | |
| Sticking power (95 ± 2 ℃, 24h) | 1 grade | 1 grade | 1 grade | |
| Resistance to impact shock (being coated with thickness 〉=600 μ m, shock height 50) | Flawless | Flawless | Flawless | |
| The 24h cathodic disbonding | ??2.5mm | ??2.0mm | ??4.0mm | |
As seen from the above table: this modification dual-layer epoxy powder coating test result is all qualified, and scheme 2 effects are preferably screening formulation; Simultaneously can learn that this powder coating shock resistance is good.
Powder coating is coated on the steel pipe outside surface of heating, in the fusion gel, during curing, heat curing-type powdered epoxy resin epoxide group generation at high temperature cross linking reaction and solidification moves down, form preservative coat in steel tube surface, thermoplastic powder modification acrylic resin does not at high temperature solidify and upwards moves in surperficial levelling, form protective layer through cooling curing, thereby form the ideal double-layer structure coating, play good anticorrosion, protection effect, and this powder only needs one group of spray equipment can finish the outer corrosion prevention operation of steel pipe, and with the yellow preservative coat that can obviously see after this double-layer structure coating partly cut-away under the green protective layer.Applying the outer corrosion prevention operation of steel pipe than the end of using Minnesota Mining and Manufacturing Company, flour end needs three groups of spray equipments will economize expense, easy, easy to operate, and production cost is low, and adaptability is strong.
This shows that the simple cost of this modification dual-layer epoxy powder coating producing process is low, spraying is once finished, and it is low need not to increase equipment cost, can adapt to the anti-paint line operation of existing FBE outward, can apply.
Claims (10)
1, a kind of modification dual-layer epoxy powder coating is characterized in that: be made up of following each component:
Weight percentages (%)
Resins, epoxy 40～45
Acrylic resin modified 8～10
Solidifying agent 9～10
Flow agent 8～10
Pore eliminator 0.5～0.6
Catalyzer 0.6～0.7
Calcium stearate 2～4
Pigment 0.7～1.0
Titanium dioxide 9～12
Barium sulfate 12～14
Sericite 2～5
2, modification dual-layer epoxy powder coating according to claim 1 is characterized in that: Resins, epoxy is the solid-state bisphenol A epoxide resin of E-12.
3, modification dual-layer epoxy powder coating according to claim 1, it is characterized in that: acrylic resin modified its molecular weight is 1000～15000.
4, modification dual-layer epoxy powder coating according to claim 1 is characterized in that: solidifying agent is a polymer phenol polymer solidifying agent, and its molecular weight is 2000～3000.
5, modification dual-layer epoxy powder coating according to claim 1, it is characterized in that: flow agent is a butyl polyacrylate, its molecular weight is 4000～6000.
6, modification dual-layer epoxy powder coating according to claim 1, it is characterized in that: pore eliminator is a st-yrax.
7, modification dual-layer epoxy powder coating according to claim 1 is characterized in that: pigment is phthalocyanine green and organic yellow and respectively accounts for 50%.
8, modification dual-layer epoxy powder coating according to claim 1, it is characterized in that: catalyzer is a glyoxal ethyline.
9, modification dual-layer epoxy powder coating according to claim 1, it is characterized in that: the weight percentage of each component is preferably: Resins, epoxy 41.6%; Acrylic resin modified 8.3%; Solidifying agent 10%; Flow agent 10.5%; Pore eliminator 0.5%; Catalyzer 0.6%; Calcium stearate 3.0%; Pigment 0.7%; Titanium dioxide 9.2%; Barium sulfate 12.5%; Sericite 3.1%.
10, a kind of method for preparing the described modification dual-layer epoxy powder of claim 1 coating, it is characterized in that: the component in the claim 1 is put in the mixing tank by its proportioning, high-speed mixing stirs twice under the normal temperature, each 2 minutes, emit after mixing, deliver to forcing machine and extrude, be pressed into the thin slice of 1～2mm, the forcing machine body temperature is set to: 86 ℃ ± 3 ℃ in 1 district, 105 ℃ ± 5 ℃ in 2 districts, material through extrude, compressing tablet, air-cooled, be crushed to the finished product powder that small pieces, abrasive dust, sub-sieve are collected designated size.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03149681 CN1205288C (en) | 2003-08-06 | 2003-08-06 | Modified double layer epoxide powder paint and preparing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03149681 CN1205288C (en) | 2003-08-06 | 2003-08-06 | Modified double layer epoxide powder paint and preparing method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN1490367A true CN1490367A (en) | 2004-04-21 |
| CN1205288C CN1205288C (en) | 2005-06-08 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 03149681 Expired - Fee Related CN1205288C (en) | 2003-08-06 | 2003-08-06 | Modified double layer epoxide powder paint and preparing method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102382546A (en) * | 2010-09-06 | 2012-03-21 | 张子鹏 | Special modified solvent-free epoxy paint for glass reinforced plastic |
| CN103589292A (en) * | 2013-11-28 | 2014-02-19 | 郎溪县鑫泽涂料有限公司 | Quick-drying epoxy powder anti-corrosive coating and manufacture method |
| CN103773182A (en) * | 2014-01-23 | 2014-05-07 | 安徽师范大学 | Powdery coating material with high surface hardness and high leveling property |
| CN104327566A (en) * | 2014-11-03 | 2015-02-04 | 江苏凯力高分子科技有限公司 | Modified epoxy powder coating applied to corrosion prevention of pipes and preparation method of modified epoxy powder coating |
| CN105623426A (en) * | 2014-11-03 | 2016-06-01 | 中泰致远(天津)涂料有限公司 | Composition of thermosetting powder coating material |
| CN106584029A (en) * | 2016-12-09 | 2017-04-26 | 李如武 | Production method of high-performance wardrobe |
| CN106670741A (en) * | 2016-12-09 | 2017-05-17 | 李如武 | Manufacturing method of environment-friendly wardrobe |
| CN106670742A (en) * | 2016-12-09 | 2017-05-17 | 李如武 | Manufacturing method of environment-friendly durable wardrobe |
| CN113956698A (en) * | 2021-09-18 | 2022-01-21 | 安徽华辉塑业科技股份有限公司 | Pipeline anticorrosion powder coating |
-
2003
- 2003-08-06 CN CN 03149681 patent/CN1205288C/en not_active Expired - Fee Related
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102382546A (en) * | 2010-09-06 | 2012-03-21 | 张子鹏 | Special modified solvent-free epoxy paint for glass reinforced plastic |
| CN103589292A (en) * | 2013-11-28 | 2014-02-19 | 郎溪县鑫泽涂料有限公司 | Quick-drying epoxy powder anti-corrosive coating and manufacture method |
| CN103773182A (en) * | 2014-01-23 | 2014-05-07 | 安徽师范大学 | Powdery coating material with high surface hardness and high leveling property |
| CN103773182B (en) * | 2014-01-23 | 2016-09-14 | 安徽师范大学 | A kind of powdery paints with high surface hardness and levelability |
| CN104327566A (en) * | 2014-11-03 | 2015-02-04 | 江苏凯力高分子科技有限公司 | Modified epoxy powder coating applied to corrosion prevention of pipes and preparation method of modified epoxy powder coating |
| CN105623426A (en) * | 2014-11-03 | 2016-06-01 | 中泰致远(天津)涂料有限公司 | Composition of thermosetting powder coating material |
| CN106584029A (en) * | 2016-12-09 | 2017-04-26 | 李如武 | Production method of high-performance wardrobe |
| CN106670741A (en) * | 2016-12-09 | 2017-05-17 | 李如武 | Manufacturing method of environment-friendly wardrobe |
| CN106670742A (en) * | 2016-12-09 | 2017-05-17 | 李如武 | Manufacturing method of environment-friendly durable wardrobe |
| CN113956698A (en) * | 2021-09-18 | 2022-01-21 | 安徽华辉塑业科技股份有限公司 | Pipeline anticorrosion powder coating |
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| Publication number | Publication date |
|---|---|
| CN1205288C (en) | 2005-06-08 |
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| Date | Code | Title | Description |
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: DAQING OIL SHINCO RENQING JOINT ANTI-CORROSION CO Free format text: FORMER OWNER: QINGLIAN ANTISEPTIC SCIENCE + TECHNOLOGY CO., LTD., DAQING OIL FIELD Effective date: 20041022 |
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| C41 | Transfer of patent application or patent right or utility model | ||
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Effective date of registration: 20041022 Address after: 163453 Heilongjiang Province, Daqing City Ranghulu District Xi Xiao Jie Applicant after: Xinke Qinglian Anti-Corrosion Co., Ltd., Daqing Oil Field Address before: 163453 Heilongjiang Province, Daqing City Ranghulu District Yuanwang post office box 6-6 Applicant before: Qinglian Antiseptic Science & Technology Co., Ltd., Daqing Oil Field |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20050608 Termination date: 20130806 |