CN1490120A - Welding flux for stainless steel non-consumable electrode argon arc welding - Google Patents
Welding flux for stainless steel non-consumable electrode argon arc welding Download PDFInfo
- Publication number
- CN1490120A CN1490120A CNA02130887XA CN02130887A CN1490120A CN 1490120 A CN1490120 A CN 1490120A CN A02130887X A CNA02130887X A CN A02130887XA CN 02130887 A CN02130887 A CN 02130887A CN 1490120 A CN1490120 A CN 1490120A
- Authority
- CN
- China
- Prior art keywords
- welding
- fluoride
- stainless steel
- argon arc
- electrode argon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000003466 welding Methods 0.000 title claims abstract description 49
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 230000004907 flux Effects 0.000 title claims abstract description 30
- 229910001220 stainless steel Inorganic materials 0.000 title claims abstract description 20
- 239000010935 stainless steel Substances 0.000 title claims abstract description 20
- 229910052786 argon Inorganic materials 0.000 title claims abstract description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 11
- 229910001512 metal fluoride Inorganic materials 0.000 claims abstract description 10
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical group FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 claims abstract description 9
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 5
- 229910000679 solder Inorganic materials 0.000 claims description 24
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims description 16
- 238000002844 melting Methods 0.000 claims description 12
- 230000008018 melting Effects 0.000 claims description 11
- 238000000034 method Methods 0.000 abstract description 7
- 230000004927 fusion Effects 0.000 abstract description 6
- 230000008569 process Effects 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 4
- 230000000704 physical effect Effects 0.000 abstract description 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 abstract 3
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 abstract 2
- 229910001634 calcium fluoride Inorganic materials 0.000 abstract 2
- 229910000423 chromium oxide Inorganic materials 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 238000005265 energy consumption Methods 0.000 abstract 1
- 238000000498 ball milling Methods 0.000 description 8
- 238000010891 electric arc Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 230000035515 penetration Effects 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000005476 soldering Methods 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910001338 liquidmetal Inorganic materials 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910000963 austenitic stainless steel Inorganic materials 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
Landscapes
- Nonmetallic Welding Materials (AREA)
- Arc Welding In General (AREA)
Abstract
The invention relates to a welding flux for stainless steel non-consumable electrode argon arc welding, which is a mixture formed by mixing chromic oxide, titanium dioxide and metal fluoride through physical action and is an active welding flux for the non-consumable electrode argon arc welding. The welding flux comprises, by weight, 50-60% of chromium oxide, 20-30% of titanium dioxide, and the balance of metal fluoride. The welding flux takes chromic oxide and titanium dioxide as main raw materials and metal fluoride as an auxiliary raw material. The metal fluoride is aluminum fluoride and calcium fluoride, wherein the weight ratio of the aluminum fluoride to the calcium fluoride is 1: 2. The flux of the invention simplifies the prior welding process, overcomes the defect of shallow fusion depth, and simultaneously realizes the aims of good effect, low energy consumption, high efficiency and low cost.
Description
The present invention is a kind of solder flux that is used for non-melting electrode argon arc welding of stainless steel, and it is through physical action, a kind of mixture that mixes with chrome green, titanium dioxide and metal fluoride.
Non-melting electrode argon arc welding occupies an important position in the industry in welding, it have protect, welding process is stable, the welding scope is wide, the smooth series of advantages such as smooth, specious of joint.But, when soldering stainless steel, because the reduction of sulphur, oxygen content in the stainless steel, in welding process, do not have sufficiently high [S], [O] in the reaction of welding chemical metallurgy with steel in alloying element (Fe, Mn etc.) and impurity element (Ca, Al etc.) be combined into dystectic oxide and sulfide and enter welding slag, on the contrary, the element of these low ionization energy can evaporate and enter into electric arc.And the mean temperature of electric arc and arc-plasma are formed direct relation are arranged in the welding process, in general, the electric arc mean temperature be Tg=1000Ui (℃), Ui is the ionization energy of various atoms in the arc atmosphere.
| K | Na | Ca | Si | Mg | Fe | Ti | C | O | F | |
| Ui(ev) | 4.3 | 5.1 | 6.1 | 8.7 | 7.61 | 7.83 | 6.1 | 11.2 | 13.5 | 17.4 |
It is as shown in the table, because the elements vaporization of these low ionization energy enters into electric arc, causes electric arc to be dispersed, and temperature reduces.So cause when the non-melting electrode argon arc welding soldering stainless steel, fusion penetration is superficial, welding efficiency is low.
The objective of the invention is provides a kind of solder flux that is used for non-melting electrode argon arc welding of stainless steel in order to overcome deficiency of the prior art, and it makes when the non-melting electrode argon arc welding soldering stainless steel, realize power consumption less, good result of use such as efficient height, cost be low.
The objective of the invention is to realize by following measure:
This kind is used for the solder flux of non-melting electrode argon arc welding of stainless steel, it is characterized in that the formula constituent of this solder flux, and the composition of this solder flux and proportioning be by weight percentage, chrome green 50%-60%, and titanium dioxide 20%-30%, all the other are metal fluoride.This kind solder flux is a primary raw material with chrome green, titanium dioxide, and metal fluoride is an auxiliary material.Metal fluoride is aluminum fluoride and calcirm-fluoride, and wherein the part by weight of aluminum fluoride and calcirm-fluoride is 1: 2.Add closed container together after above-mentioned kind raw material mixed in proportion, carry out ball milling then, the ball milling time is 24 hours.Be 300 purpose sieve by granularity then.Before welding work pieces, earlier that this solder flux and solvent is even, then with brush after place to be welded is coated with the very thin solder flux of last layer, weld again and get final product.
In welding process, oxide is (as TiO in the solder flux
2, Cr
2O
3Deng) under the welding arc high temperature action, at first with steel in element reactions such as C, Si, generate CO, SiO
2, CO, SiO
2Then decomposite oxygen, because entering of oxygen makes the surface tension of liquid metal bath reduce.Under the effect of liquid metal flow behavior, electric arc gos deep into the molten bath more, and penetration capacity increases greatly.On the other hand, oxide on the molten pool metal surface, around the electric arc and sulfide decompose, and O, S enter the arc column periphery, catch the electronics at a slow speed of arc column periphery, thereby compression arc has more improved arc current density, cause electric arc more concentrated, thereby improved fusion penetration.
The present invention has played beyond thought effect through using in the austenitic stainless steel welding, very strong raising fusion penetration effect is arranged.Under identical welding condition, compare with traditional non-consumable gas shielded arc welding, can improve fusion penetration 1-2 doubly, through test, the mechanical property of joint is not less than common non-melting electrode argon arc welding simultaneously.
Below with reference to embodiment the present invention is further described:
Embodiment 1 claims chrome green 50 grams, titanium dioxide 20 grams, aluminum fluoride 10 grams, calcirm-fluoride 20 grams, pours into after the mixing in the ball mill, carries out ball milling, and the ball milling time is 24 hours, takes out the back with 300 purpose sieve, both has been the solder flux product.150 amperes of welding currents, speed of welding 7m/h under the technological parameter that weldingvoltage is 10 volts, uses the stainless steel material that this kind solder flux can a through welding 8mm, and general T IG weldering with this technological parameter once can only through welding 3mm stainless steel material.
Embodiment 2 claims chrome green 60 grams, titanium dioxide 30 grams, aluminum fluoride 3 grams, and calcirm-fluoride 6 grams are poured into after the mixing in the ball mill, carry out ball milling, and the ball milling time is 24 hours, takes out the back with 300 purpose sieve, both has been the solder flux product.160 amperes of welding currents, speed of welding 7m/h under the technological parameter that weldingvoltage is 10 volts, uses the stainless steel material that this kind solder flux can a through welding 8mm, and general T IG weldering with this technological parameter once can only through welding 3mm stainless steel material.
Embodiment 3 claims chrome green 56 grams, titanium dioxide 26 grams, aluminum fluoride 6 grams, and calcirm-fluoride 12 grams are poured into after the mixing in the ball mill, carry out ball milling, and the ball milling time is 24 hours, takes out the back with 300 purpose sieve, both has been the solder flux product.150 amperes of welding currents, speed of welding 7m/h under the technological parameter that weldingvoltage is 10 volts, uses the stainless steel material that this kind solder flux can a through welding 10mm, and general T IG weldering with this technological parameter once can only through welding 3mm stainless steel material.
Owing to use solder flux of the present invention, make existing welding procedure become simple and overcome the shallow shortcoming of its fusion penetration, realized simultaneously effective, power consumption less, efficient height, target that cost is low, become a kind of new welding method.
Claims (4)
1. solder flux that is used for non-melting electrode argon arc welding of stainless steel, it is characterized in that: the composition of solder flux and proportioning are by weight percentage: chrome green 50%-60%, titanium dioxide 20%-30%, all the other are metal fluoride.
2. the solder flux that is used for non-melting electrode argon arc welding of stainless steel according to claim 1 is characterized in that: metal fluoride is aluminum fluoride and calcirm-fluoride, and wherein the part by weight of aluminum fluoride and calcirm-fluoride is 1: 2.
3. the solder flux that is used for non-melting electrode argon arc welding of stainless steel according to claim 1 is characterized in that: the granularity of this solder flux each component is less than 300 orders.
4. the solder flux that is used for non-melting electrode argon arc welding of stainless steel according to claim 1, it is characterized in that the composition of this solder flux and proportioning are by weight percentage: chrome green is 55%-57%, and titanium dioxide is 25%-28%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02130887 CN1211182C (en) | 2002-10-15 | 2002-10-15 | Welding flux for stainless steel non-consumable electrode argon arc welding |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02130887 CN1211182C (en) | 2002-10-15 | 2002-10-15 | Welding flux for stainless steel non-consumable electrode argon arc welding |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1490120A true CN1490120A (en) | 2004-04-21 |
| CN1211182C CN1211182C (en) | 2005-07-20 |
Family
ID=34144674
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02130887 Expired - Lifetime CN1211182C (en) | 2002-10-15 | 2002-10-15 | Welding flux for stainless steel non-consumable electrode argon arc welding |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1211182C (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100357059C (en) * | 2005-09-28 | 2007-12-26 | 中国航空工业第一集团公司北京航空制造工程研究所 | Welding flux for stainless steel plasma arc welding |
| CN101138815B (en) * | 2006-09-07 | 2010-06-16 | 景航企业股份有限公司 | Active scaling powder for soldering stainless steel |
| CN101947703A (en) * | 2010-10-08 | 2011-01-19 | 中国航空工业集团公司北京航空制造工程研究所 | Active welding flux for high-temperature alloy fusion welding and preparation method thereof |
| CN102343489A (en) * | 2011-07-11 | 2012-02-08 | 重庆大学 | Novel active agent used for TIG (Tungsten Inert Gas) welding of magnesium alloy |
| CN102886625A (en) * | 2012-10-16 | 2013-01-23 | 重庆理工大学 | Efficient active agent used for aluminum alloy alternating current TIG (tungsten inert gas) welding |
| CN103418938A (en) * | 2013-09-02 | 2013-12-04 | 湖北鸿路钢结构有限公司 | Active solder for welding ferritic stainless steel with fined grains and preparation method of active solder |
| CN103962752A (en) * | 2013-05-14 | 2014-08-06 | 南车青岛四方机车车辆股份有限公司 | Active agent for MAG welding of weathering steel and using method |
| CN104708229A (en) * | 2013-06-05 | 2015-06-17 | 天津大学 | Application of low-melting-point flux to large-power TIG welding joint protection |
-
2002
- 2002-10-15 CN CN 02130887 patent/CN1211182C/en not_active Expired - Lifetime
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100357059C (en) * | 2005-09-28 | 2007-12-26 | 中国航空工业第一集团公司北京航空制造工程研究所 | Welding flux for stainless steel plasma arc welding |
| CN101138815B (en) * | 2006-09-07 | 2010-06-16 | 景航企业股份有限公司 | Active scaling powder for soldering stainless steel |
| CN101947703A (en) * | 2010-10-08 | 2011-01-19 | 中国航空工业集团公司北京航空制造工程研究所 | Active welding flux for high-temperature alloy fusion welding and preparation method thereof |
| CN101947703B (en) * | 2010-10-08 | 2012-07-04 | 中国航空工业集团公司北京航空制造工程研究所 | Active welding flux for high-temperature alloy fusion welding and preparation method thereof |
| CN102343489A (en) * | 2011-07-11 | 2012-02-08 | 重庆大学 | Novel active agent used for TIG (Tungsten Inert Gas) welding of magnesium alloy |
| CN102886625A (en) * | 2012-10-16 | 2013-01-23 | 重庆理工大学 | Efficient active agent used for aluminum alloy alternating current TIG (tungsten inert gas) welding |
| CN102886625B (en) * | 2012-10-16 | 2015-06-17 | 重庆理工大学 | Efficient active agent used for aluminum alloy alternating current TIG (tungsten inert gas) welding |
| CN103962752A (en) * | 2013-05-14 | 2014-08-06 | 南车青岛四方机车车辆股份有限公司 | Active agent for MAG welding of weathering steel and using method |
| CN103962752B (en) * | 2013-05-14 | 2017-04-05 | 中车青岛四方机车车辆股份有限公司 | A kind of activating agent and using method for weathering steel MAG welding |
| CN104708229A (en) * | 2013-06-05 | 2015-06-17 | 天津大学 | Application of low-melting-point flux to large-power TIG welding joint protection |
| CN103418938A (en) * | 2013-09-02 | 2013-12-04 | 湖北鸿路钢结构有限公司 | Active solder for welding ferritic stainless steel with fined grains and preparation method of active solder |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1211182C (en) | 2005-07-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2009255164A (en) | METAL-BASED FLUX CORED WIRE FOR Ar-CO2 MIXED GAS SHIELDED ARC WELDING | |
| CN105689918A (en) | Welding core and coating of rare earth treated 830 MPa grade low-alloy, high-strength and high-toughness basic electrode and preparation method thereof | |
| CN1211182C (en) | Welding flux for stainless steel non-consumable electrode argon arc welding | |
| CN103008923A (en) | Low-hydrogen basic welding rod for welding 1Ni9 steel and preparation method thereof | |
| CN109570812A (en) | Welding electrode containing aluminium | |
| KR100508399B1 (en) | Large heat input submerged arc welding joint, method for producing the joint, steel wire for the submerged arc welding joint, and flux for the submerged arc welding joint | |
| CN101804525A (en) | Sintered flux for submerged arc welding of FCW with martensitic stainless steel hard surface | |
| CN101596657B (en) | Ultra-low-carbon heat-resistant steel flux-cored wire capable of carrying out all-position welding | |
| CN101653875A (en) | Flux-cored hard facing welding electrode | |
| CN103551761A (en) | Soldering flux, application and soldering method thereof | |
| CN108838581A (en) | A kind of sintered flux for stainless steel and preparation method thereof | |
| CN103302416A (en) | Flux-cored wire for gas protection of arc welding | |
| JP2003225792A (en) | Wire for carbon dioxide gas shielded arc welding | |
| CN109514126A (en) | A kind of molybdenum stainless steel welding and preparation method thereof, sintered flux and preparation method thereof and a kind of single layer strip electrode electroslag surfacing method | |
| CN109483083A (en) | The method of nuclear power stainless steel band pole submerged arc overlay welding welding, sintered flux and nuclear power stainless steel band pole submerged arc overlay welding | |
| CN108788538A (en) | One kind middle high fluorine-type sintered flux of titanium peculiar to vessel and preparation method thereof | |
| CN110877169B (en) | Electrodeposition nickel-tungsten-rare earth surfacing electrode and preparation process thereof | |
| CN1850420B (en) | Surface clad consumable electrode gas-shielded welding wire | |
| JP2004188428A (en) | Steel wire for carbon dioxide gas-shielded arc welding, and welding method using the same | |
| CN107127478A (en) | A kind of flux-cored wire | |
| EP1714728B1 (en) | High strength steel welding | |
| CN103347646A (en) | Titanium oxide raw material for welding material | |
| CN109128579A (en) | A kind of multipurpose steel alloy submerged arc sintered flux and preparation method thereof | |
| JPH0521677B2 (en) | ||
| JP3969322B2 (en) | Steel wire for carbon dioxide shielded arc welding and welding method using the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20050720 |