CN107127478A - A kind of flux-cored wire - Google Patents

A kind of flux-cored wire Download PDF

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Publication number
CN107127478A
CN107127478A CN201710346765.4A CN201710346765A CN107127478A CN 107127478 A CN107127478 A CN 107127478A CN 201710346765 A CN201710346765 A CN 201710346765A CN 107127478 A CN107127478 A CN 107127478A
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China
Prior art keywords
powder
flux
cored wire
slag former
medicine core
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Application number
CN201710346765.4A
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Chinese (zh)
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CN107127478B (en
Inventor
卢齐元
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Anhui Welding Industry Ltd By Share Ltd
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Anhui Welding Industry Ltd By Share Ltd
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Priority to CN201710346765.4A priority Critical patent/CN107127478B/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3053Fe as the principal constituent
    • B23K35/308Fe as the principal constituent with Cr as next major constituent
    • B23K35/3086Fe as the principal constituent with Cr as next major constituent containing Ni or Mn
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/02Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
    • B23K35/0255Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in welding
    • B23K35/0261Rods, electrodes, wires
    • B23K35/0266Rods, electrodes, wires flux-cored
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/3601Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
    • B23K35/3602Carbonates, basic oxides or hydroxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/368Selection of non-metallic compositions of core materials either alone or conjoint with selection of soldering or welding materials

Abstract

The invention discloses a kind of flux-cored wire, including mild-carbon steel strip crust and medicine core, wherein, the raw materials by weight of the medicine core includes:Graphite 1 2%, chromium powder 15 17%, manganese powder 1 2%, nickel powder 4 6%, niobium powder 4 6%, 13 parts of vanadium powder, titanium dioxide 1 1.5%, silica 0.5 1%, rheium oxide 4 5%, cerium oxide 4 5%, slag former, Oxidizing and Reducing Agents, surplus is iron powder.The present invention is cooperated by each material, the problem of can substantially reducing spatter so that the welding coating porosity is low, and coating structure is fine and close, good toughness, and intensity is high.

Description

A kind of flux-cored wire
Technical field
The present invention relates to welding wire technology field, more particularly to a kind of flux-cored wire.
Background technology
Bead weld repair is carried out to damaging metal parts using flux-cored wire, can damage metal parts to recycle, reduce The waste of part, but in weld deposit process, easily produce splashing so that there is stomata in welding coating, coating easily ftractures.
The content of the invention
The technical problem existed based on background technology, the present invention proposes a kind of flux-cored wire, and the present invention passes through each material Cooperate, the problem of can substantially reducing spatter so that the welding coating porosity is low, coating structure is fine and close, good toughness, by force Degree is high.
A kind of flux-cored wire proposed by the present invention, including mild-carbon steel strip crust and medicine core, wherein, the raw material of the medicine core is pressed Percentage by weight includes:Graphite 1-2%, chromium powder 15-17%, manganese powder 1-2%, nickel powder 4-6%, niobium powder 4-6%, 1-3 parts of vanadium powder, Titanium dioxide 1-1.5%, silica 0.5-1%, rheium oxide 4-5%, cerium oxide 4-5%, slag former, oxidant and reduction Agent, surplus is iron powder.
Preferably, cerium oxide, slag former, the weight ratio of Oxidizing and Reducing Agents are 4-5:6-7:13-15:2-4.
Preferably, slag former is calcirm-fluoride, sodium fluozirconate.
Preferably, calcirm-fluoride, the weight ratio of sodium fluozirconate are 7-8:1.
Preferably, reducing agent is magnesia, wherein, the content of magnesia is 95-98wt%.
Preferably, oxidant is lithium carbonate and di-iron trioxide.
Preferably, the weight ratio of lithium carbonate and di-iron trioxide is 4-6:1.
Flux-cored wire of the present invention is prepared according to the conventional flux-cored wire preparation technology in this area, and each raw material is put into Mixer is well mixed, crust mild-carbon steel strip, using flux-cored wire production equipment, is obtained through curling, drawing.
The present invention is cooperated from calcirm-fluoride and sodium fluozirconate, gasifies to form a floor dynamic gas cage in welding arc area Wire segment portion is covered on, it is mobile with the movement of electric arc to play a part of air-isolation, and molten drop surface tension can be reduced, promote molten Drop refinement, so as to substantially reduce the porosity of welding coating;On the one hand magnesia can reduce molten drop surface tension with air-isolation, On the other hand the oxygen content in final welding coating can be controlled by the precipitation desoxydation of precedent desoxydation, molten drop and molten bath stage, Reduce the fragility of coating;Lithium carbonate and di-iron trioxide cooperate, and on the one hand can be heated release gas, improve electric arc and blow Power, so as to avoid the problem of undue deoxidation of magnesia causes insufficient (incomplete) penetration, increases fusion penetration;On the other hand molten drop surface can be reduced Power, promotes molten drop refinement, makes the droplet transfer more steady, it is possible to play nitrogen fixation;Above-mentioned slag former, oxidant and reduction Agent is cooperated with proper ratio can substantially reduce spatter, reduce the porosity, and reduce coating fragility;Graphite and chromium powder Carbide can be formed, and perpendicular to the bond strength of matrix surface growth, the intensity of increase coating, and coating and matrix;Manganese Powder, nickel powder, niobium powder, vanadium powder, titanium dioxide, silica, rheium oxide, cerium oxide cooperate, and can form small and dispersed phase With new solution strengthening phase so that welding coating tissue fine uniform, greatly increases the intensity and toughness of coating;And magnesium Sand, rheium oxide, cerium oxide cooperate, and can purify welding coating, substantially reduce objectionable impurities in steel, so as to further increase The toughness and intensity of the present invention;Above-mentioned each material cooperates, the problem of can substantially reducing spatter so that welding coating gas Porosity is low, and coating structure is fine and close, good toughness, and intensity is high.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of flux-cored wire, including mild-carbon steel strip crust and medicine core, wherein, the raw materials by weight bag of the medicine core Include:Graphite 1.5%, chromium powder 16%, manganese powder 1.5%, nickel powder 5%, niobium powder 5%, 2 parts of vanadium powder, titanium dioxide 1.2%, titanium dioxide Silicon 0.7%, rheium oxide 4.5%, cerium oxide 4.5%, slag former, Oxidizing and Reducing Agents, surplus is iron powder.
Embodiment 2
A kind of flux-cored wire, including mild-carbon steel strip crust and medicine core, wherein, the raw materials by weight bag of the medicine core Include:Graphite 1%, chromium powder 17%, manganese powder 1%, nickel powder 6%, niobium powder 4%, 3 parts of vanadium powder, titanium dioxide 1%, silica 1 %, Rheium oxide 4%, cerium oxide 5%, slag former, Oxidizing and Reducing Agents, surplus is iron powder;
Wherein, cerium oxide, slag former, the weight ratio of Oxidizing and Reducing Agents are 5:6:15:2;
Slag former be calcirm-fluoride, sodium fluozirconate, wherein, calcirm-fluoride, sodium fluozirconate weight ratio be 8:1;
Reducing agent is magnesia, wherein, the content of magnesia is 95wt%;
Oxidant is lithium carbonate and di-iron trioxide;The weight ratio of lithium carbonate and di-iron trioxide is 6:1.
Embodiment 3
A kind of flux-cored wire, including mild-carbon steel strip crust and medicine core, wherein, the raw materials by weight bag of the medicine core Include:Graphite 2%, chromium powder 15%, manganese powder 2%, nickel powder 4%, niobium powder 6%, 1 part of vanadium powder, titanium dioxide 1.5%, silica 0.5%, rheium oxide 5%, cerium oxide 4%, slag former, Oxidizing and Reducing Agents, surplus is iron powder;
Wherein, cerium oxide, slag former, the weight ratio of Oxidizing and Reducing Agents are 4:7:13:4;
Slag former be calcirm-fluoride, sodium fluozirconate, wherein, calcirm-fluoride, sodium fluozirconate weight ratio be 7:1;
Reducing agent is magnesia, wherein, the content of magnesia is 98wt%;
Oxidant is lithium carbonate and di-iron trioxide;The weight ratio of lithium carbonate and di-iron trioxide is 4:1.
Embodiment 4
A kind of flux-cored wire, including mild-carbon steel strip crust and medicine core, wherein, the raw materials by weight bag of the medicine core Include:Graphite 1.2%, chromium powder 16.5%, manganese powder 1.3%, nickel powder 5.5%, niobium powder 4.5%, 2.5 parts of vanadium powder, titanium dioxide 1.1%, silica 0.8%, rheium oxide 4.3%, cerium oxide 4.7%, slag former, Oxidizing and Reducing Agents, surplus is iron powder;
Wherein, cerium oxide, slag former, the weight ratio of Oxidizing and Reducing Agents are 4.7:6.2:14.5:2.5;
Slag former be calcirm-fluoride, sodium fluozirconate, wherein, calcirm-fluoride, sodium fluozirconate weight ratio be 7.8:1;
Reducing agent is magnesia, wherein, the content of magnesia is 96wt%;
Oxidant is lithium carbonate and di-iron trioxide;The weight ratio of lithium carbonate and di-iron trioxide is 5.5:1.
Embodiment 5
A kind of flux-cored wire, including mild-carbon steel strip crust and medicine core, wherein, the raw materials by weight bag of the medicine core Include:Graphite 1.8%, chromium powder 15.5%, manganese powder 1.7%, nickel powder 4.5%, niobium powder 5.5%, 1.5 parts of vanadium powder, titanium dioxide 1.3%, silica 0.6%, rheium oxide 4.7%, cerium oxide 4.3%, slag former, Oxidizing and Reducing Agents, surplus is iron powder;
Wherein, cerium oxide, slag former, the weight ratio of Oxidizing and Reducing Agents are 4.3:6.8:13.5:3.5;
Slag former be calcirm-fluoride, sodium fluozirconate, wherein, calcirm-fluoride, sodium fluozirconate weight ratio be 7.2:1;
Reducing agent is magnesia, wherein, the content of magnesia is 97wt%;
Oxidant is lithium carbonate and di-iron trioxide;The weight ratio of lithium carbonate and di-iron trioxide is 4.5:1.
Example 1-5, carries out built-up welding to Q235 steel plates, obtains the coating of same thickness, and carries out performance test to it, As a result it is as follows:
The present invention splashes small in welding as can be seen from the above table, the welding coating good toughness of formation.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.

Claims (7)

1. a kind of flux-cored wire, it is characterised in that including mild-carbon steel strip crust and medicine core, wherein, the raw material of the medicine core is by weight Amount percentage includes:Graphite 1-2%, chromium powder 15-17%, manganese powder 1-2%, nickel powder 4-6%, niobium powder 4-6%, 1-3 parts of vanadium powder, two Titanium oxide 1-1.5%, silica 0.5-1%, rheium oxide 4-5%, cerium oxide 4-5%, slag former, Oxidizing and Reducing Agents, Surplus is iron powder.
2. flux-cored wire according to claim 1, it is characterised in that cerium oxide, slag former, the weight of Oxidizing and Reducing Agents Than for 4-5:6-7:13-15:2-4.
3. flux-cored wire according to claim 1 or claim 2, it is characterised in that slag former is calcirm-fluoride, sodium fluozirconate.
4. flux-cored wire according to claim 3, it is characterised in that calcirm-fluoride, the weight ratio of sodium fluozirconate are 7-8:1.
5. according to any one of the claim 1-4 flux-cored wires, it is characterised in that reducing agent is magnesia, wherein, magnesia contains Measure as 95-98wt%.
6. according to any one of the claim 1-5 flux-cored wires, it is characterised in that oxidant is lithium carbonate and three oxidations two Iron.
7. flux-cored wire according to claim 6, it is characterised in that the weight ratio of lithium carbonate and di-iron trioxide is 4-6:1.
CN201710346765.4A 2017-05-17 2017-05-17 Flux-cored wire Active CN107127478B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710346765.4A CN107127478B (en) 2017-05-17 2017-05-17 Flux-cored wire

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Application Number Priority Date Filing Date Title
CN201710346765.4A CN107127478B (en) 2017-05-17 2017-05-17 Flux-cored wire

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CN107127478B CN107127478B (en) 2020-10-13

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107570910A (en) * 2017-10-18 2018-01-12 柳州凯通新材料科技有限公司 A kind of highly wear-resisting alloy steel welding wire medicine core
CN110026708A (en) * 2019-05-16 2019-07-19 江苏师范大学 One kind O containing nano Ce2, Nb welding wire and its application method

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1799755A (en) * 2005-01-03 2006-07-12 林肯环球公司 Cored electrode for reducing diffusible hydrogen
CN1846928A (en) * 2005-04-05 2006-10-18 林肯环球公司 Flux cored electrode with fluorine
CN104551437A (en) * 2014-11-13 2015-04-29 上海施威重工成套有限公司 Manufacture technology of submerged-arc welding tubular flux-cored wire
CN106112311A (en) * 2016-08-05 2016-11-16 天长市通联焊业有限公司 A kind of flux-cored wire with excellent toughness
CN106141485A (en) * 2016-07-29 2016-11-23 安徽飞狐焊业股份有限公司 A kind of high-performance flux-cored wire
CN106514047A (en) * 2016-12-09 2017-03-22 天长市通联焊业有限公司 Wear-resistant flux-cored wire for stainless steel

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1799755A (en) * 2005-01-03 2006-07-12 林肯环球公司 Cored electrode for reducing diffusible hydrogen
CN1846928A (en) * 2005-04-05 2006-10-18 林肯环球公司 Flux cored electrode with fluorine
CN104551437A (en) * 2014-11-13 2015-04-29 上海施威重工成套有限公司 Manufacture technology of submerged-arc welding tubular flux-cored wire
CN106141485A (en) * 2016-07-29 2016-11-23 安徽飞狐焊业股份有限公司 A kind of high-performance flux-cored wire
CN106112311A (en) * 2016-08-05 2016-11-16 天长市通联焊业有限公司 A kind of flux-cored wire with excellent toughness
CN106514047A (en) * 2016-12-09 2017-03-22 天长市通联焊业有限公司 Wear-resistant flux-cored wire for stainless steel

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107570910A (en) * 2017-10-18 2018-01-12 柳州凯通新材料科技有限公司 A kind of highly wear-resisting alloy steel welding wire medicine core
CN110026708A (en) * 2019-05-16 2019-07-19 江苏师范大学 One kind O containing nano Ce2, Nb welding wire and its application method
CN110026708B (en) * 2019-05-16 2021-06-11 江苏师范大学 Welding method of dual-phase steel

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