CN1487121A - Al-F-Cl electrolyte system - Google Patents

Al-F-Cl electrolyte system Download PDF

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Publication number
CN1487121A
CN1487121A CNA031389449A CN03138944A CN1487121A CN 1487121 A CN1487121 A CN 1487121A CN A031389449 A CNA031389449 A CN A031389449A CN 03138944 A CN03138944 A CN 03138944A CN 1487121 A CN1487121 A CN 1487121A
Authority
CN
China
Prior art keywords
sodium
aluminum fluoride
electrolyte
bariumchloride
chlor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA031389449A
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Chinese (zh)
Inventor
党建平
杨光辉
宁建文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANXI GUANLU CO Ltd
Original Assignee
SHANXI GUANLU CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANXI GUANLU CO Ltd filed Critical SHANXI GUANLU CO Ltd
Priority to CNA031389449A priority Critical patent/CN1487121A/en
Publication of CN1487121A publication Critical patent/CN1487121A/en
Pending legal-status Critical Current

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Abstract

The present invention relates to electrolyte for producing refined aluminum, and is especially aluminum-refining F-Cl electrolyte system. The F-Cl electrolyte system consists of barium chloride 55-65 wt%, cryolite 19-23 wt%, aluminum fluoride 13-17 wt% and sodium chloride 3-5 wt%. The F-Cl electrolyte system has reasonable formulation and ideal use effect, and can be used to obtain reasonable initial crystallizing temperature and lower electrolyte loss and avoid firing, electrolyte overflow, etc.

Description

Refined aluminium fluorine chlorine system electrolyte
Technical field
The present invention relates to refined aluminium and produce used ionogen, be specially refined aluminium fluorine chlorine system electrolyte.
Background technology
Three layers of electrolytic process are adopted in refined aluminium production usually, and its middle layer is a dielectric substrate.Refined aluminium is produced used ionogen and is divided into two kinds of systems: fluorine chlorine system and pure fluorine system.The most of enterprise of China uses fluorine chlorine system electrolyte.Whether accurately, rationally used electrolytical prescription is directly connected to the quality of refined aluminium.The unreasonable meeting of ionogen proportioning causes phenomenons such as burning with anger, turn over ionogen.Existing refined aluminium production is all more not satisfactory than effect with electrolysis plasmogamy.
Summary of the invention
The present invention solves existing refined aluminium and produces the not satisfactory problem of used ionogen result of use, and a kind of reasonable ratio, result of use ideal refined aluminium fluorine chlorine system electrolyte are provided.
The present invention adopts following technical scheme to realize: refined aluminium fluorine chlorine system electrolyte, comprise bariumchloride, sodium aluminum fluoride (hexafluoro closes aluminium three sour sodium), aluminum fluoride, sodium-chlor, and the weight percent of above-mentioned component is:
Bariumchloride: 55-65% sodium aluminum fluoride: 19-23%
Aluminum fluoride: 13-17% sodium-chlor: 3-5%
All be powdery under the above-mentioned each component normality, get final product after they are mixed by above-mentioned proportioning.
The invention provides a kind of prescription rationally, effect comparatively the production of ideal refined aluminium with ionogen (prescription).Phenomenons such as ionogen can effectively be avoided burning with anger, be turned over to the ionogen of this kind prescription; Can obtain comparatively reasonably liquidus temperature; Can reduce refined aluminium liquid unit consumption.
Embodiment
Embodiment 1
Refined aluminium fluorine chlorine system electrolyte comprises bariumchloride, sodium aluminum fluoride (hexafluoro closes aluminium three sour sodium), aluminum fluoride, sodium-chlor, and the weight percent of above-mentioned component is:
Bariumchloride: 55% sodium aluminum fluoride: 23%
Aluminum fluoride: 17% sodium-chlor: 5%
Embodiment 2
Refined aluminium fluorine chlorine system electrolyte comprises bariumchloride, sodium aluminum fluoride (hexafluoro closes aluminium three sour sodium), aluminum fluoride, sodium-chlor, and the weight percent of above-mentioned component is:
Bariumchloride: 65% sodium aluminum fluoride: 19%
Aluminum fluoride: 13% sodium-chlor: 3%
Embodiment 3
Refined aluminium fluorine chlorine system electrolyte comprises bariumchloride, sodium aluminum fluoride (hexafluoro closes aluminium three sour sodium), aluminum fluoride, sodium-chlor, and the weight percent of above-mentioned component is:
Bariumchloride: 60% sodium aluminum fluoride: 21%
Aluminum fluoride: 15% sodium-chlor: 4%

Claims (1)

1, a kind of refined aluminium fluorine chlorine system electrolyte comprises bariumchloride, sodium aluminum fluoride, aluminum fluoride, sodium-chlor, and it is characterized by: the weight percent of above-mentioned component is:
Bariumchloride: 55-65% sodium aluminum fluoride: 19-23%
Aluminum fluoride: 13-17% sodium-chlor: 3-5%.
CNA031389449A 2003-07-31 2003-07-31 Al-F-Cl electrolyte system Pending CN1487121A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNA031389449A CN1487121A (en) 2003-07-31 2003-07-31 Al-F-Cl electrolyte system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNA031389449A CN1487121A (en) 2003-07-31 2003-07-31 Al-F-Cl electrolyte system

Publications (1)

Publication Number Publication Date
CN1487121A true CN1487121A (en) 2004-04-07

Family

ID=34154975

Family Applications (1)

Application Number Title Priority Date Filing Date
CNA031389449A Pending CN1487121A (en) 2003-07-31 2003-07-31 Al-F-Cl electrolyte system

Country Status (1)

Country Link
CN (1) CN1487121A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100453705C (en) * 2006-03-24 2009-01-21 中国铝业股份有限公司 Chloro fluoride electrolyte for electrorefining
CN105177631A (en) * 2015-09-11 2015-12-23 中南大学 Method for preparing high-purity aluminum through electrolytic refining and electrolytic bath

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100453705C (en) * 2006-03-24 2009-01-21 中国铝业股份有限公司 Chloro fluoride electrolyte for electrorefining
CN105177631A (en) * 2015-09-11 2015-12-23 中南大学 Method for preparing high-purity aluminum through electrolytic refining and electrolytic bath
CN105177631B (en) * 2015-09-11 2017-10-13 中南大学 Electrorefining prepares the method and electrolytic cell of rafifinal

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