CN1487119A - Making process of mirror interference color stainless steel pattern - Google Patents
Making process of mirror interference color stainless steel pattern Download PDFInfo
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- CN1487119A CN1487119A CNA031237517A CN03123751A CN1487119A CN 1487119 A CN1487119 A CN 1487119A CN A031237517 A CNA031237517 A CN A031237517A CN 03123751 A CN03123751 A CN 03123751A CN 1487119 A CN1487119 A CN 1487119A
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Abstract
The making process of mirror interference color stainless steel pattern includes the following steps: soaking bright mirror stainless steel product inside chemical coloring liquid to form ligh interference color oxide film; hardening the interference color oxide film in hardening electrolyte solution, enclosing and attaching and curing one layer of image and text protecting intermediate film; eliminating unprotected color oxide film; eliminating the said protecting intermediate film; washing, stoving, coating one layer of antifouling protection film of 5-80 nm thickness; and coating one or two layers of protecting film for packing. The process is simple, convenient, high in decoration effect, high in antifouling capacity and suitable for use in household appliance, kitchen apparatus, decoration, artistic work and other industry.
Description
Technical field
The present invention relates to a kind of making method of Color Stainless Steel goods floral designs.
Background technology
The making method of existing Color Stainless Steel goods floral designs, such as, the Color Stainless Steel convex-concave of using at elevator industry is corroded floral designs plate etc. at present, because Color Stainless Steel convex-concave corrosion floral designs plate has a shortcoming the most fatal: the surface that was corroded is very coarse, antifouling property is very poor, is easy to be made dirty; The surface that was not corroded simultaneously is very coarse, and its resistance to corrosion is also poor, is corroded easily in atmosphere; Therefore, limited its development greatly.
Summary of the invention
The purpose of this invention is to provide a kind of specular light light and interfere the making method of Color Stainless Steel floral designs, solve the problem of existing Color Stainless Steel floral designs dalle and goods antifouling property difference with good decorative effect.
The present invention adopts following two kinds of technical schemes based on same design to solve the problems referred to above:
The specular light light interferes the making method of Color Stainless Steel floral designs that two kinds of methods are arranged, and first method and step are as follows: step (1): the Stainless Steel Products of minute surface light is placed on CrO
3And H
2SO
4Chemical stain solution in, painted by chemical oxidation, on surface of stainless steel product, form interference of light colored oxide film;
Step (2): Stainless Steel Products is placed on contains CrO
3And H
2SO
4Electrolysis post bake solution in, above-mentioned interference of light colored oxide film is solidified firmly adding under the condition of galvanic current energising;
Step (3): the Color Stainless Steel goods that formed by step (1) (2) are put into Na
2SiO
3The aqueous solution in, carry out sealing treatment;
Step (4): above-mentioned interference of light Color Stainless Steel combination with decorative surfaces is cleaned, after the oven dry, enclosed the middle protective membrane of one deck image or literal, then it is cured;
Step (5): contain H putting into through the good Color Stainless Steel goods of above-mentioned four step process
2SO
4And H
3PO
4Solution in, adding under the galvanic condition, these Color Stainless Steel goods are anode, stereotype is a negative electrode, removes the colored oxide film of not protected by middle protective membrane;
Step (6): remove above-mentioned in the middle of protective membrane, clean then, oven dry, just manufactured the specular light light by above step and interfered Color Stainless Steel floral designs surface, its image be with above-mentioned in the middle of the visual opposite image of protective membrane;
Step (7): in order further to strengthen the ostentatious antifouling property of above-mentioned Color Stainless Steel, apply the very strong transparent anti-soil protective membrane of last layer bonding force again, the thickness of this protective membrane is about 5 nanometer to 80 nanometers;
Step (8): last again at one to two layer of protection glued membrane that is used for packed and transported of surface coverage of this anti-soil protective membrane.
The second method that the specular light light interferes the Color Stainless Steel floral designs to be made is characterized in that following steps are arranged:
Step a: the Stainless Steel Products of minute surface light is cleaned, after the oven dry, enclosed the middle protective membrane of one deck image or literal, then it is cured;
Step b: above-mentioned Stainless Steel Products is placed on contains CrO
3And H
2SO
4Chemical stain solution in, painted by chemical oxidation, on stainless steel surface, form colorama and interfere oxide film, its image be with above-mentioned in the middle of the visual opposite image of protective membrane;
Step c: containing CrO
3And H
2SO
4Electrolysis post bake solution in, switch on adding under the condition of galvanic current, make above-mentioned colorama interfere oxide film to solidify firmly;
Steps d: above-mentioned Color Stainless Steel goods are put into chemical ingredients is: Na
2SiO
3The aqueous solution in, carry out sealing treatment;
Step e: remove above-mentioned middle protective membrane, form the specular light light and interfere Color Stainless Steel floral designs surface;
Step f: in order to strengthen the ostentatious antifouling property of above-mentioned Color Stainless Steel, apply the very strong transparent anti-soil protective membrane of last layer bonding force again on above-mentioned interference of light Color Stainless Steel product surface, the thickness of this protective membrane is about 5 nanometer to 80 nanometers;
Step g: last again at one to two layer of protection glued membrane that is used for packed and transported of surface coverage of this anti-soil film.
In above-mentioned two methods, the basal surface of Stainless Steel Products and pattern plane all are minute surface, and vision and feel all are slick surfaces, do not have the sense of convex-concave.
The step of above-mentioned two methods (2), step (3), step c, steps d can be omitted.
Among the step of above-mentioned two methods (4), the step a; the method of enclosing the middle protective membrane of image or literal is image or the literal ink lay that the anti-corrosion of metal ink printing last layer with preservative property designs in advance, perhaps puts up image or literal glued membrane that one deck is carved by the computer carving lettering machine.
Among the step of above-mentioned two methods (4), the step a, be photocuring or thermofixation to the curing of middle protective membrane.
Among the step of above-mentioned two methods (5), the step e, the method for removing above-mentioned middle protective membrane is to wash above-mentioned printing ink off or directly tear above-mentioned glued membrane in basic solution, cleans then, dries.
Among the step of above-mentioned two methods (7), the step f, transparent anti-soil protective membrane is with the nanometer film coating fluid coating that contains macromolecular material, inorganic nanoparticles.
Beneficial effect of the present invention: use the specular light light interference Color Stainless Steel that the present invention makes, the floral designs surface is splendid, rich color, the advantage that has not only kept original color stainless steel finishing material, and floral designs change various, its surface is no matter be that pattern plane and basal surface all are minute surface (as: 8K minute surface), vision and feel are got up all just as a very slick surface, the sensation that does not have convex-concave, make it not only have stronger decorative effect, and because its smooth surface, be not easy the deposition dirt, its contamination resistance improves greatly than stainless steel convex-concave corrosion pattern technological method in the past.Scribble on its surface in addition a layer thickness about 5 nanometer to 80 nanometers, can not change the nanometer film coating fluid of Color Stainless Steel color, the same interference of light look that can radiate dazzling radiance of the sort of jewel seemingly of the oxide film that not only makes it keep the painted generation of stainless steel oxidation, make its maintenance and improved the original various superiority of Color Stainless Steel: its corrosion resisting property, weather resistance, UV resistant, irradiation performance and exterior decorative effect are much better than common stainless steel; The more important thing is that it has improved the antifouling property of Color Stainless Steel greatly, be suitable for the multiple industry that needs decoration such as household electrical appliance, galley equipment, decoration decoration, industrial art.
Embodiment
Embodiment 1: silvery white stainless steel materials or goods are as base material: carry out pre-treatment earlier: mirro finished, oil removing, cleaning; (1) containing chemical ingredients and concentration is respectively CrO
3: 250g/L and H
2SO
4: in the chemical stain solution of 490g/L, temperature of reaction is to carry out chemical treatment under 0～60 ℃ the condition, painted by chemical oxidation, (its color has: dark brown bronze-colored, purple, blueness, grey, golden yellow, red-purple, sky blue, grass green, yellow-green colour, black and their intermediate color etc. of crying again) to form oxide film with different interference of light looks on stainless steel surface; (2) containing chemical ingredients and concentration is respectively CrO
3: 250g/L and H
2SO
4: in the electrolysis post bake solution of 2.5g/L, be I=0.6A/dm adding galvanic current density
2Condition under the energising about ten minutes; (3) in chemical ingredients be: Na
2SiO
3, concentration is: in 10% the aqueous solution, temperature of reaction is to carry out sealing treatment under 65～85 ℃ the condition; (4) above-mentioned interference of light Color Stainless Steel combination with decorative surfaces is cleaned, after the oven dry, the image that designs in advance with anti-corrosion of metal ink printing last layer or the middle protective membrane of literal (erect image or negative-appearing image) carry out light or thermofixation according to the requirement of this printing ink to it then; (5) contain H putting into through above-mentioned four good Color Stainless Steels of step process
2SO
430% and H
3PO
4In 50% the solution, be V=6～36v at applying direct current, I=15～80A/dm
2Condition under, this colored stainless steel plate (or goods) is an anode, stereotype is a negative electrode, removes the colored oxide film of not protected by middle protective membrane.(6) remove above-mentioned in the middle of protective membrane, in 10% NaOH basic solution, wash above-mentioned printing ink off under 80 ℃.Clean then, dry.(7) be coated with and be covered with " WHR nanometer film coating fluid ", heating cure.(8) stick one to two layer of protection glued membrane that is used for packed and transported with laminator.
Embodiment 2: silvery white stainless steel materials or goods are as base material: carry out pre-treatment earlier: mirro finished, oil removing, cleaning, after cleaning, drying, the image that designs in advance with anti-corrosion of metal ink printing last layer or the middle protective membrane of literal (erect image or negative-appearing image) carry out light or thermofixation according to the requirement of this printing ink to it then; Containing chemical ingredients and concentration is respectively CrO
3: 250g/L and H
2SO
4: in the chemical stain solution of 490g/L, temperature of reaction is to carry out chemical treatment under 0～60 ℃ the condition, painted by chemical oxidation, (its color has: dark brown bronze-colored, purple, blueness, grey, golden yellow, red-purple, sky blue, grass green, yellow-green colour, black and their intermediate color etc. of crying again) to form oxide film with different interference of light looks on stainless steel surface; Containing chemical ingredients and concentration is respectively CrO
3: 250g/L and H
2SO
4: in the electrolysis post bake solution of 2.5g/L, be I=0.6A/dm adding galvanic current density
2Condition under the energising about ten minutes.D, remove above-mentioned in the middle of protective membrane, in 10% NaOH basic solution, wash above-mentioned printing ink off under 80 ℃.Clean then, dry.Apply commercially available WHR nanometer film coating fluid, the heating cure of last layer; Stick one to two layer of protection glued membrane that is used for packed and transported with laminator.
Claims (8)
1, a kind of specular light light is interfered Color Stainless Steel floral designs making method, it is characterized in that following steps are arranged:
Step (1): the Stainless Steel Products of minute surface light is placed on CrO
3And H
2SO
4Chemical stain solution in, painted by chemical oxidation, on surface of stainless steel product, form interference of light colored oxide film;
Step (2): Stainless Steel Products is placed on contains CrO
3And H
2SO
4Electrolysis post bake solution in, above-mentioned interference of light colored oxide film is solidified firmly adding under the condition of galvanic current energising;
Step (3): the Color Stainless Steel goods that formed by step (1) (2) are put into Na
2SiO
3The aqueous solution in, carry out sealing treatment;
Step (4): above-mentioned interference of light Color Stainless Steel combination with decorative surfaces is cleaned, after the oven dry, enclosed the middle protective membrane of one deck image or literal, then it is cured;
Step (5): contain H putting into through the good Color Stainless Steel goods of above-mentioned four step process
2SO
4And H
3PO
4Solution in, adding under the galvanic condition, these Color Stainless Steel goods are anode, stereotype is a negative electrode, removes the colored oxide film of not protected by middle protective membrane;
Step (6): remove above-mentioned in the middle of protective membrane, clean then, oven dry, just manufactured the specular light light by above step and interfered Color Stainless Steel floral designs surface, its image be with above-mentioned in the middle of the visual opposite image of protective membrane;
Step (7): in order further to strengthen the ostentatious antifouling property of above-mentioned Color Stainless Steel, apply the very strong transparent anti-soil protective membrane of last layer bonding force again, the thickness of this protective membrane is about 5 nanometer to 80 nanometers;
Step (8): last again at one to two layer of protection glued membrane that is used for packed and transported of surface coverage of this anti-soil protective membrane.
2, a kind of specular light light is interfered Color Stainless Steel floral designs making method, it is characterized in that following steps are arranged:
Step a: the Stainless Steel Products of minute surface light is cleaned, after the oven dry, enclosed the middle protective membrane of one deck image or literal, then it is cured;
Step b: above-mentioned Stainless Steel Products is placed on contains CrO
3And H
2SO
4Chemical stain solution in, painted by chemical oxidation, on stainless steel surface, form colorama and interfere oxide film, its image be with above-mentioned in the middle of the visual opposite image of protective membrane;
Step c: containing CrO
3And H
2SO
4Electrolysis post bake solution in, switch on adding under the condition of galvanic current, make above-mentioned colorama interfere oxide film to solidify firmly;
Steps d: above-mentioned Color Stainless Steel goods are put into chemical ingredients is: Na
2SiO
3The aqueous solution in, carry out sealing treatment;
Step e: remove above-mentioned middle protective membrane, form the specular light light and interfere Color Stainless Steel floral designs surface;
Step f: in order to strengthen the ostentatious antifouling property of above-mentioned Color Stainless Steel, apply the very strong transparent anti-soil protective membrane of last layer bonding force again on above-mentioned interference of light Color Stainless Steel product surface, the thickness of this protective membrane is about 5 nanometer to 80 nanometers;
Step g: last again at one to two layer of protection glued membrane that is used for packed and transported of surface coverage of this anti-soil film.
3, specular light light according to claim 1 and 2 is interfered the making method of Color Stainless Steel floral designs, it is characterized in that in above-mentioned two methods, the basal surface of Stainless Steel Products and pattern plane all are minute surface, and vision and feel all are slick surfaces, do not have the sense of convex-concave.
4, specular light light according to claim 1 and 2 is interfered the making method of Color Stainless Steel floral designs, it is characterized in that step (2), step (3), step c, the steps d of above-mentioned two methods can be omitted.
5, specular light light according to claim 1 is interfered the making method of Color Stainless Steel floral designs; it is characterized in that in the step (4), step a of above-mentioned two methods; the method of enclosing the middle protective membrane of image or literal is image or the literal ink lay that the anti-corrosion of metal ink printing last layer with preservative property designs in advance, perhaps puts up image or literal glued membrane that one deck is carved by the computer carving lettering machine.
6, specular light light according to claim 1 and 2 is interfered the making method of Color Stainless Steel floral designs, it is characterized in that in the step (4), step a of above-mentioned two methods, and be photocuring or thermofixation to the curing of middle protective membrane.
7, specular light light according to claim 1 and 2 is interfered the making method of Color Stainless Steel floral designs; it is characterized in that in the step (5), step e of above-mentioned two methods; the method of removing above-mentioned middle protective membrane is to wash above-mentioned printing ink off or directly tear above-mentioned glued membrane in basic solution, cleans then, dries.
8, specular light light according to claim 1 and 2 is interfered the making method of Color Stainless Steel floral designs; it is characterized in that in the step (7), step f of above-mentioned two methods that transparent anti-soil protective membrane is with the nanometer film coating fluid coating that contains macromolecular material, inorganic nanoparticles.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03123751 CN1218066C (en) | 2003-05-22 | 2003-05-22 | Making process of mirror interference color stainless steel pattern |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03123751 CN1218066C (en) | 2003-05-22 | 2003-05-22 | Making process of mirror interference color stainless steel pattern |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1487119A true CN1487119A (en) | 2004-04-07 |
| CN1218066C CN1218066C (en) | 2005-09-07 |
Family
ID=34152835
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 03123751 Expired - Fee Related CN1218066C (en) | 2003-05-22 | 2003-05-22 | Making process of mirror interference color stainless steel pattern |
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| Country | Link |
|---|---|
| CN (1) | CN1218066C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1304623C (en) * | 2005-01-31 | 2007-03-14 | 浙江佰耐钢带有限公司 | Steel belt surface colouring method |
| CN101914746A (en) * | 2010-08-31 | 2010-12-15 | 南京飞燕活塞环股份有限公司 | Heat tinting method of stainless steel spring |
| CN103173762A (en) * | 2013-03-27 | 2013-06-26 | 黄进花 | Preparation method for color stainless steel board or stainless steel product |
| CN105586585A (en) * | 2016-03-08 | 2016-05-18 | 东北大学 | Preparation technology of color anti-bacterial stainless steel |
| CN107297503A (en) * | 2017-06-21 | 2017-10-27 | 合肥市旺友门窗有限公司 | A kind of preparation method of high nitrogen colored stainless steel product |
-
2003
- 2003-05-22 CN CN 03123751 patent/CN1218066C/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1304623C (en) * | 2005-01-31 | 2007-03-14 | 浙江佰耐钢带有限公司 | Steel belt surface colouring method |
| CN101914746A (en) * | 2010-08-31 | 2010-12-15 | 南京飞燕活塞环股份有限公司 | Heat tinting method of stainless steel spring |
| CN103173762A (en) * | 2013-03-27 | 2013-06-26 | 黄进花 | Preparation method for color stainless steel board or stainless steel product |
| CN105586585A (en) * | 2016-03-08 | 2016-05-18 | 东北大学 | Preparation technology of color anti-bacterial stainless steel |
| CN107297503A (en) * | 2017-06-21 | 2017-10-27 | 合肥市旺友门窗有限公司 | A kind of preparation method of high nitrogen colored stainless steel product |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1218066C (en) | 2005-09-07 |
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