CN1475544A - Multielement mixture workmedium throttle refrigerant suitable for deep cold tepmerature region - Google Patents
Multielement mixture workmedium throttle refrigerant suitable for deep cold tepmerature region Download PDFInfo
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- CN1475544A CN1475544A CNA031214231A CN03121423A CN1475544A CN 1475544 A CN1475544 A CN 1475544A CN A031214231 A CNA031214231 A CN A031214231A CN 03121423 A CN03121423 A CN 03121423A CN 1475544 A CN1475544 A CN 1475544A
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- 239000000203 mixture Substances 0.000 title claims abstract description 103
- 239000003507 refrigerant Substances 0.000 title claims abstract description 16
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 59
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 51
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims abstract description 47
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims abstract description 38
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims abstract description 33
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims abstract description 27
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000001294 propane Substances 0.000 claims abstract description 23
- QYSGYZVSCZSLHT-UHFFFAOYSA-N octafluoropropane Chemical compound FC(F)(F)C(F)(F)C(F)(F)F QYSGYZVSCZSLHT-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229960004065 perflutren Drugs 0.000 claims abstract description 22
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 claims abstract description 19
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 18
- AFABGHUZZDYHJO-UHFFFAOYSA-N 2-Methylpentane Chemical compound CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052786 argon Inorganic materials 0.000 claims abstract description 12
- 239000007789 gas Substances 0.000 claims abstract description 8
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 claims abstract description 7
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims abstract description 6
- QKCGXXHCELUCKW-UHFFFAOYSA-N n-[4-[4-(dinaphthalen-2-ylamino)phenyl]phenyl]-n-naphthalen-2-ylnaphthalen-2-amine Chemical compound C1=CC=CC2=CC(N(C=3C=CC(=CC=3)C=3C=CC(=CC=3)N(C=3C=C4C=CC=CC4=CC=3)C=3C=C4C=CC=CC4=CC=3)C3=CC4=CC=CC=C4C=C3)=CC=C21 QKCGXXHCELUCKW-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 249
- XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical compound FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 claims description 29
- 229910052757 nitrogen Inorganic materials 0.000 claims description 24
- 238000001816 cooling Methods 0.000 claims description 21
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims description 12
- 229910052743 krypton Inorganic materials 0.000 claims description 7
- DNNSSWSSYDEUBZ-UHFFFAOYSA-N krypton atom Chemical compound [Kr] DNNSSWSSYDEUBZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 2
- 229910001873 dinitrogen Inorganic materials 0.000 abstract 1
- 239000001282 iso-butane Substances 0.000 abstract 1
- 238000005057 refrigeration Methods 0.000 description 58
- 239000003795 chemical substances by application Substances 0.000 description 26
- 238000002156 mixing Methods 0.000 description 23
- 238000000034 method Methods 0.000 description 15
- 238000007906 compression Methods 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- 239000007788 liquid Substances 0.000 description 9
- 230000006835 compression Effects 0.000 description 8
- 239000000470 constituent Substances 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 239000006244 Medium Thermal Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- 241001076960 Argon Species 0.000 description 5
- 235000013876 argon Nutrition 0.000 description 5
- GVGCUCJTUSOZKP-UHFFFAOYSA-N nitrogen trifluoride Chemical class FN(F)F GVGCUCJTUSOZKP-UHFFFAOYSA-N 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 238000011084 recovery Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 239000006200 vaporizer Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 3
- 239000001273 butane Substances 0.000 description 3
- 239000013256 coordination polymer Substances 0.000 description 3
- 238000011835 investigation Methods 0.000 description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 230000002427 irreversible effect Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical group [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N methyl pentane Natural products CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-OUBTZVSYSA-N nitrogen-15 Chemical compound [15N] QJGQUHMNIGDVPM-OUBTZVSYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000011218 segmentation Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
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Abstract
Description
Project | Mixture 1 volumetric molar concentration % | Mixture 2 volumetric molar concentration % | Mixture 3 volumetric molar concentration % |
The 1st group | 35 (argon Ar) | 40 (nitrogen 30, argons 10) | 50 (argon 15, nitrogen 35) |
The 2nd group | 30 (methane 20, kryptons 10) | 25 (methane) | 15 (kryptons) |
The 3rd group | 10 (tetrafluoromethanes) | 5 (three fluoridize fluorine) | 5 (tetrafluoromethane 3, nitrogen trifluorides 2) |
The 4th group | 10 (ethane 5, trifluoromethanes 5) | 5 (ethene) | 10 (ethane 5, trifluoromethanes 5) |
The 5th group | 5 (propane) | 20 (propane 10, the third rare 5, perfluoropropane 5) | 5 (perfluoropropane) |
The 6th group | 10 (3-methyl-1-butene 6,2-methylpentane 2,2-methylpentanes 2) | 5 (2-methylbutanes) | 15 (Trimethylmethanes) |
High voltage/low voltage | 1.8/0.2(MPa) | 2.0/0.4(MPa) | 2.4/0.6(MPa) |
COP | 0.08 | 0.116 | 0.24 |
CEF% | 16 | 23.2 | 48 |
Project | Mixture 1 volumetric molar concentration % | Mixture 2 volumetric molar concentration % | Mixture 3 volumetric molar concentration % |
The 1st group | 30 (nitrogen) | 34 (nitrogen 20, argons 14) | 40 (argon 15, nitrogen 25) |
The 2nd group | 25 (methane 15, kryptons 10) | 23 (methane) | 20 (kryptons) |
The 3rd group | 5 (tetrafluoromethanes) | 5 (nitrogen trifluorides) | 2 (tetrafluoromethanes) |
The 4th group | 22 (ethane 17, trifluoromethanes 5) | 10 (ethene) | 8 (ethane 3, trifluoromethane 3, ethene 2) |
The 5th group | 8 (propane) | 10 (propane 2, the third rare 3, perfluoropropane 5) | 22 (perfluoropropane) |
The 6th group | 10 (Trimethylmethane 5,2-methylpentanes 5) | 18 (1-butylene 12,2-methylbutane, 6) | 8 (Trimethylmethanes) |
High voltage/low voltage | 2.0/0.2(MPa) | 1.8/0.2(MPa) | 2.0/0.2(MPa) |
COP | 0.154 | 0.244 | 0.097 |
CEF% | 26.6 | 42.1 | 16.75 |
Project | Mixture 1 volumetric molar concentration % | Mixture 2 volumetric molar concentration % | Mixture 3 volumetric molar concentration % |
The 1st group | 20 (nitrogen) | 26 (nitrogen 20, argons 6) | 35 (argon 20, nitrogen 15) |
The 2nd group | 30 (methane 20, fluorine 10) | 28 (methane) | 25 (kryptons) |
The 3rd group | 6 (tetrafluoromethanes) | 2 (nitrogen trifluorides) | 4 (tetrafluoromethane 2, nitrogen trifluorides 2) |
The 4th group | 24 (ethane 14, trifluoromethanes 10) | 10 (ethene) | 12 (ethane 4, trifluoromethane 4, ethene 4) |
The 5th group | 10 (propane) | 24 (propane 14, the third rare 5, perfluoropropane 5) | 12 (perfluoropropane) |
The 6th group | 10 (Trimethylmethane 7,2-methylpentanes 3) | 10 (1-butylene 4,2-methylbutane, 6) | 12 (Trimethylmethanes) |
High voltage/low voltage | 2.0/0.2(MPa) | 1.8/0.2(MPa) | 2.0/0.2(MPa) |
COP | 0.116 | 0.248 | 0.096 |
CEF% | 17.4 | 37.2 | 14.4 |
Project | Mixture 1 volumetric molar concentration % | Mixture 2 volumetric molar concentration % | Mixture 3 volumetric molar concentration % |
The 1st group | 15 (nitrogen) | 18 (nitrogen 20, argons 6) | 15 (nitrogen) |
The 2nd group | 45 (methane 35, kryptons 10) | 32 (methane) | 30 (kryptons) |
The 3rd group | 6 (tetrafluoromethanes) | 0 | 6 (tetrafluoromethane 4, nitrogen trifluorides 2) |
The 4th group | 12 (ethane 7, trifluoromethanes 5) | 15 (ethene) | 12 (ethane 4, trifluoromethane 4, ethene 4) |
The 5th group | 12 (propane) | 25 (propane 14, the third rare 5, perfluoropropane 5) | 15 (perfluoropropane) |
The 6th group | 10 (Trimethylmethane 7,2-methylpentanes 3) | 10 (1-butylene 4,2-methylbutane, 6) | 22 (Trimethylmethanes) |
High voltage/low voltage | 2.0/0.2(MPa) | 1.8/0.2(MPa) | 1.8/0.2(MPa) |
COP | 0.103 | 0.282 | 0.272 |
CEF% | 13.5 | 36.8 | 35.6 |
Project | Mixture 1 volumetric molar concentration % | Mixture 2 volumetric molar concentration % | Mixture 3 volumetric molar concentration % |
The 1st group | 10 (nitrogen) | 12 (nitrogen) | 11 (nitrogen) |
The 2nd group | 50 (methane 40, kryptons 10) | 36 (methane) | 37 (kryptons) |
The 3rd group | 2 (tetrafluoromethanes) | 0 | ?0 |
The 4th group | 14 (ethane 7, trifluoromethanes 7) | 15 (ethene) | 27 (ethane 14, trifluoromethane 10, ethene 3) |
The 5th group | 14 (propane) | 27 (propane 17, the third rare 5, perfluoropropane 5) | 15 (perfluoropropane) |
The 6th group | 10 (Trimethylmethane 7,2-methylpentanes 3) | 10 (1-butylene 4,2-methylbutane, 6) | 10 (Trimethylmethanes) |
High voltage/low voltage | 1.8/0.2(MPa) | 2.0/0.2(MPa) | 2.2/0.3(MPa) |
COP | 0.123 | 0.332 | 0.142 |
CEF% | 15.3 | 41.5 | 17.8 |
Project | Mixture 1 volumetric molar concentration % | Mixture 2 volumetric molar concentration % | Mixture 3 volumetric molar concentration % |
The 1st group | 5 (nitrogen) | 7 (nitrogen) | 8 (argons) |
The 2nd group | 55 (methane) | 38 (methane) | 37 (kryptons) |
The 3rd group | 0 | ?0 | 0 |
The 4th group | 15 (ethane 7, trifluoromethanes 7) | 15 (ethene) | 30 (ethane 14, trifluoromethane 10, ethene 3) |
The 5th group | 15 (propane) | 30 (propane 20, the third rare 5, perfluoropropane 5) | 15 (perfluoropropane) |
The 6th group | 10 (Trimethylmethane 7,2-methylpentanes 3) | 10 (1-butylene 4,2-methylbutane, 6) | 10 (Trimethylmethanes) |
High voltage/low voltage | 2.0/0.5(MPa) | 2.0/0.4(MPa) | 2.2/0.5(MPa) |
COP | 0.323 | 0.39 | 0.342 |
CEF% | 32.3 | 39 | 34.2 |
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 03121423 CN1204222C (en) | 2002-05-14 | 2003-03-28 | Multielement mixture workmedium throttle refrigerant suitable for deep cold tepmerature region |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN02117656 | 2002-05-14 | ||
CN02117656.6 | 2002-05-14 | ||
CN 03121423 CN1204222C (en) | 2002-05-14 | 2003-03-28 | Multielement mixture workmedium throttle refrigerant suitable for deep cold tepmerature region |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1475544A true CN1475544A (en) | 2004-02-18 |
CN1204222C CN1204222C (en) | 2005-06-01 |
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Application Number | Title | Priority Date | Filing Date |
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CN 03121423 Expired - Lifetime CN1204222C (en) | 2002-05-14 | 2003-03-28 | Multielement mixture workmedium throttle refrigerant suitable for deep cold tepmerature region |
Country Status (1)
Country | Link |
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CN (1) | CN1204222C (en) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1977023A (en) * | 2004-04-16 | 2007-06-06 | 霍尼韦尔国际公司 | Azeotrope-like compositions of tetrafluoropropene and pentafluoropropene |
CN101922850A (en) * | 2010-09-15 | 2010-12-22 | 煤炭科学研究总院重庆研究院 | Method for utilizing coalbed methane containing oxygen to prepare liquefied natural gas |
CN101929788A (en) * | 2010-09-15 | 2010-12-29 | 中国科学院理化技术研究所 | Device for preparing liquefied natural gas by oxygen-bearing coal mine methane |
CN101608860B (en) * | 2008-06-17 | 2011-08-17 | 北京安瑞科新能能源科技有限公司 | Gas liquefying process for mixed refrigerant and mixed refrigerant |
CN102618220A (en) * | 2011-01-26 | 2012-08-01 | 龙志刚 | Mixed refrigerant suitable for 120-150K cryogenic temperature region |
CN108531135A (en) * | 2018-04-10 | 2018-09-14 | 龙志刚 | Mix refrigerant suitable for deep cooling warm area and preparation method thereof, application process |
CN109920581A (en) * | 2019-03-08 | 2019-06-21 | 中国科学院电工研究所 | A kind of the mix insulation medium and its preparation method of liquid nitrogen and liquefaction carbon tetrafluoride |
CN110511726A (en) * | 2019-09-23 | 2019-11-29 | 杨文海 | A kind of reachable -150 DEG C of minimum temperature of hybrid refrigeration agent prescription |
CN112442336A (en) * | 2020-12-02 | 2021-03-05 | 苏州博威科制冷科技有限公司 | Ultralow-temperature mixed refrigerant |
CN112778976A (en) * | 2020-12-24 | 2021-05-11 | 青岛营上电器有限公司 | Low-temperature refrigerant and preparation method and application thereof |
CN113251711A (en) * | 2020-02-12 | 2021-08-13 | 合肥华凌股份有限公司 | Method, device, equipment and storage medium for judging filling state of mixed refrigerant |
CN116606632A (en) * | 2023-07-19 | 2023-08-18 | 中科美菱低温科技股份有限公司 | Refrigerant and method for producing the same |
-
2003
- 2003-03-28 CN CN 03121423 patent/CN1204222C/en not_active Expired - Lifetime
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1977023A (en) * | 2004-04-16 | 2007-06-06 | 霍尼韦尔国际公司 | Azeotrope-like compositions of tetrafluoropropene and pentafluoropropene |
CN1977023B (en) * | 2004-04-16 | 2015-05-06 | 霍尼韦尔国际公司 | Azeotrope-like compositions of tetrafluoropropene and pentafluoropropene |
CN101608860B (en) * | 2008-06-17 | 2011-08-17 | 北京安瑞科新能能源科技有限公司 | Gas liquefying process for mixed refrigerant and mixed refrigerant |
CN101922850A (en) * | 2010-09-15 | 2010-12-22 | 煤炭科学研究总院重庆研究院 | Method for utilizing coalbed methane containing oxygen to prepare liquefied natural gas |
CN101929788A (en) * | 2010-09-15 | 2010-12-29 | 中国科学院理化技术研究所 | Device for preparing liquefied natural gas by oxygen-bearing coal mine methane |
CN101922850B (en) * | 2010-09-15 | 2012-01-04 | 煤炭科学研究总院重庆研究院 | Method for utilizing coalbed methane containing oxygen to prepare liquefied natural gas |
CN102618220A (en) * | 2011-01-26 | 2012-08-01 | 龙志刚 | Mixed refrigerant suitable for 120-150K cryogenic temperature region |
CN102618220B (en) * | 2011-01-26 | 2016-06-15 | 龙志刚 | A kind of mix refrigerant being applicable to 120K~150K Shen Lengwen district |
CN108531135A (en) * | 2018-04-10 | 2018-09-14 | 龙志刚 | Mix refrigerant suitable for deep cooling warm area and preparation method thereof, application process |
CN108531135B (en) * | 2018-04-10 | 2021-05-07 | 龙志刚 | Mixed refrigerant suitable for cryogenic temperature zone and preparation method and application method thereof |
US11072733B2 (en) | 2018-04-10 | 2021-07-27 | Zhigang LONG | Mixed refrigerant for a cryogenic temperature range, and methods for preparing and applying the same |
CN109920581A (en) * | 2019-03-08 | 2019-06-21 | 中国科学院电工研究所 | A kind of the mix insulation medium and its preparation method of liquid nitrogen and liquefaction carbon tetrafluoride |
CN110511726A (en) * | 2019-09-23 | 2019-11-29 | 杨文海 | A kind of reachable -150 DEG C of minimum temperature of hybrid refrigeration agent prescription |
CN113251711A (en) * | 2020-02-12 | 2021-08-13 | 合肥华凌股份有限公司 | Method, device, equipment and storage medium for judging filling state of mixed refrigerant |
CN112442336A (en) * | 2020-12-02 | 2021-03-05 | 苏州博威科制冷科技有限公司 | Ultralow-temperature mixed refrigerant |
CN112778976A (en) * | 2020-12-24 | 2021-05-11 | 青岛营上电器有限公司 | Low-temperature refrigerant and preparation method and application thereof |
CN116606632A (en) * | 2023-07-19 | 2023-08-18 | 中科美菱低温科技股份有限公司 | Refrigerant and method for producing the same |
CN116606632B (en) * | 2023-07-19 | 2023-10-20 | 中科美菱低温科技股份有限公司 | Refrigerant and method for producing the same |
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