CN1204222C - Multielement mixture workmedium throttle refrigerant suitable for deep cold tepmerature region - Google Patents
Multielement mixture workmedium throttle refrigerant suitable for deep cold tepmerature region Download PDFInfo
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- CN1204222C CN1204222C CN 03121423 CN03121423A CN1204222C CN 1204222 C CN1204222 C CN 1204222C CN 03121423 CN03121423 CN 03121423 CN 03121423 A CN03121423 A CN 03121423A CN 1204222 C CN1204222 C CN 1204222C
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- 239000000203 mixture Substances 0.000 title claims abstract description 106
- 239000003507 refrigerant Substances 0.000 title claims description 13
- 239000000463 material Substances 0.000 claims abstract description 253
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 60
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 53
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims abstract description 49
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims abstract description 42
- XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical compound FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 claims abstract description 33
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims abstract description 28
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 25
- 239000001294 propane Substances 0.000 claims abstract description 24
- QYSGYZVSCZSLHT-UHFFFAOYSA-N octafluoropropane Chemical compound FC(F)(F)C(F)(F)C(F)(F)F QYSGYZVSCZSLHT-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229960004065 perflutren Drugs 0.000 claims abstract description 23
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 claims abstract description 20
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 19
- AFABGHUZZDYHJO-UHFFFAOYSA-N 2-Methylpentane Chemical compound CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims abstract description 17
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052786 argon Inorganic materials 0.000 claims abstract description 13
- 229910052743 krypton Inorganic materials 0.000 claims abstract description 9
- DNNSSWSSYDEUBZ-UHFFFAOYSA-N krypton atom Chemical compound [Kr] DNNSSWSSYDEUBZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims abstract description 9
- QKCGXXHCELUCKW-UHFFFAOYSA-N n-[4-[4-(dinaphthalen-2-ylamino)phenyl]phenyl]-n-naphthalen-2-ylnaphthalen-2-amine Chemical compound C1=CC=CC2=CC(N(C=3C=CC(=CC=3)C=3C=CC(=CC=3)N(C=3C=C4C=CC=CC4=CC=3)C=3C=C4C=CC=CC4=CC=3)C3=CC4=CC=CC=C4C=C3)=CC=C21 QKCGXXHCELUCKW-UHFFFAOYSA-N 0.000 claims abstract description 6
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims description 37
- 238000001816 cooling Methods 0.000 claims description 19
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 12
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims description 12
- 239000007789 gas Substances 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 claims description 6
- 238000005057 refrigeration Methods 0.000 abstract description 61
- 239000003795 chemical substances by application Substances 0.000 abstract description 28
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 4
- 239000001282 iso-butane Substances 0.000 abstract 2
- 238000002156 mixing Methods 0.000 description 23
- 238000000034 method Methods 0.000 description 15
- 238000007906 compression Methods 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- 239000007788 liquid Substances 0.000 description 9
- 230000006835 compression Effects 0.000 description 8
- 239000000470 constituent Substances 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 239000006244 Medium Thermal Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- GVGCUCJTUSOZKP-UHFFFAOYSA-N nitrogen trifluoride Chemical class FN(F)F GVGCUCJTUSOZKP-UHFFFAOYSA-N 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- 241001076960 Argon Species 0.000 description 5
- 235000013876 argon Nutrition 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 238000011084 recovery Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 239000006200 vaporizer Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 3
- 239000013256 coordination polymer Substances 0.000 description 3
- 238000011835 investigation Methods 0.000 description 3
- 238000009835 boiling Methods 0.000 description 2
- 230000002427 irreversible effect Effects 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical group [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- QJGQUHMNIGDVPM-OUBTZVSYSA-N nitrogen-15 Chemical compound [15N] QJGQUHMNIGDVPM-OUBTZVSYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
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Abstract
The present invention relates to a multielement mixed actuating medium throttling refrigeration agent which is suitable for deep cold regions. The present invention comprises 6 groups of materials with the molarity sum of 100%, wherein the first group has the total molarity of 5% to 50% and comprises nitrogen or argon or a mixture of the nitrogen and the argon; the second group has the total molarity of 15% to 55% and comprises methane or krypton or a mixture of the methane and the krypton; the fourth group has the total molarity of 5% to 30% and comprises ethene or ethane or fluoroform or a mixture of the ethene, the ethane and the fluoroform; the fifth group has the total molarity of 5% to 30% and comprises propene or propane or perfluoropropane or a mixture of the propene, the propane and the perfluoropropane; the sixth group has the total molarity of 5% to 25% and comprises 1-butene or isobutane or 2-methybutane or 1-pentene or 3-methyl-1-butylene or 2-methylpentane or a mixture of the 1-butene, the isobutane, the 2-methybutane, the 1-pentene, the 3-methyl-1-butylene and the 2-methylpentane; the third group has the total molarity as the rest and comprises carbon tetrafluoride or nitrogen trifluoride or a mixture of the carbon tetrafluoride and the nitrogen trifluoride. Different elements exert the main functions in different temperature regions, so the multielement mixed actuating medium throttling refrigeration agent which is suitable for the temperature range from 100 to 150K is obtained.
Description
Invention field
The present invention relates to low-temperature refrigeration technology, particularly a kind of deep cooling warm area (multicomponent mixture working medium throttling refrigerant of 120～150K) that is applicable to.
Background technology
According to the low temperature thermodynamic theory, overlapping and backheat are to realize two possible methods of cryogenic refrigeration.Realize the necessary high generalized force of low temperature by utilizing overlapping or backheat to reduce.Mixing medium is applied in the circulation of back-heating type throttling refrigeration, can reduce operating pressure greatly, reduce throttling process and heat recovery process loss, improves system efficiency.The system schematic of mixing medium back-heating type j-t refrigerator is seen Fig. 1; mainly constitute by compressor CP, water cooler AC, counter flow back-heating interchanger HX, throttling element JT and cryogenic vaporizer EV; sometimes in order to consider measures such as oil return; can on the parts of bearing the backheat effect, do some variations; constitute interior overlapping circulation form, see Fig. 2 with vapour liquid separator.The composition of mixed work medium for throttling refrigeration agent is closely-related with the form of the construction system of realizing refrigerating hardware and these hardware, but shows through further investigation, and the mixing medium proper property is the basic factor of decision performance of refrigerant systems.After further research, the selection principle of mixing medium in various refrigeration systems all can be considered from the following aspects:
The one, guarantee that mixture can reach required low temperature in the operating pressure scope; the 2nd, guarantee that irreversible loss is reduced to minimum in the refrigeration cycle process; the 3rd, guarantee that mixing medium meets relevant environmental regulations; and have good physics, chemical stability, and other are such as the source and the consideration of economy etc.
Still there is not at present the mixing medium patent that directly applies to this warm area.Existing technology such as U.S. Pat 5,441,658 and China patent CN97,115,295.0 all to be applied to liquid nitrogen temperature (80K) be main purpose.Wherein, United States Patent (USP) has provided fixedly melting concn component, is applied to liquid nitrogen temperature, finds through further investigation, and the given mixing medium thermo-efficiency of this patent is still not high enough.Therefore, we have proposed a kind of mixing medium refrigeration agent that is applicable to cold zone on the further investigation basis, patent CN97115295.0, its main purpose is further to improve the thermo-efficiency of mixed work medium for throttling refrigeration agent, and reduce the combustibility of refrigeration agent, obtain low-temperature mixed throttling refrigeration agent efficiently, this technology is an application target with the 80K warm area still.
Find out that thus the given mixing medium refrigerant applications target of prior art is the low temperature field, mainly at liquid nitrogen temperature (80K).If be applied in more than the liquid nitrogen temperature (80K), efficient will descend.Here need to mention a bit: at patent CN97, in the definition to refrigeration thermo-efficiency in 115,295.0, what the calculating of relevant compression process wasted work was adopted is isothermal compression, and for refrigerating industry totally-enclosed compressor commonly used, wherein the compression process of Fa Shenging in fact more approaches adiabatic compression.The adiabatic compression wasted work is bigger than isothermal compression wasted work, and has only considered the working medium natural characteristics among the embodiment that provides of this patent, and the pressure condition that provides is not suitable for single-stage compressor operation condition (pressure ratio is too high, has 25).For the working medium that becomes with a kind of known group, the thermo-efficiency that adopts the adiabatic compression wasted work to calculate is littler by 15%～25% than adopting the isothermal compression counting yield.
In sum, prior art mainly is the mixing medium that proposes at liquid nitrogen temperature, and current research shows, its effective temperature range of operation of frozen composition multicomponent mixture work medium is narrower, generally about 5～15K, exceed this scope then efficient sharply descend.Therefore, the mixture working medium of liquid nitrogen temperature can not operate in the above warm area of 100K efficiently, and prior art does not take into full account practical factors such as concrete compressor operating operating mode in addition.
Summary of the invention
The object of the present invention is to provide a kind of deep cooling warm area (efficient multicomponent mixture working medium throttling refrigerant of 120～150K) that is applicable to.Compared with the prior art, it is higher that the mixing medium that the present invention proposes is suitable for warm area, and taking into full account the suitable operation pressure ratio operating mode of single-stage compressor aspect the concrete concentration proportioning, and at providing its corresponding concentration range every 10K in 100～150K warm area.
The foundation of carrying out the warm area division is on the mixing medium inherent thermodynamic property, in the mixture of certain known concrete composition, each composition is brought into play not same-action at the refrigerator operation temperature area to different warm areas between the envrionment temperature in the mixture, but every kind of constituent element is only brought into play effective refrigeration at a relatively-stationary warm area, and bring into play less effect at other warm areas, thus, can be desirably in the mixture and form similar a kind of relay effect by the cooperation between each constituent element, realization to the efficient combination the required refrigeration temperature, is seen Fig. 3 from envrionment temperature.
The mixture throttling refrigerating machine building block is simple relatively, corresponding to different parts generations are different thermal processing, referring to Fig. 4, be included in the adiabatic compression of carrying out in the compressor, isobaric heat release in the water cooler, heat recovery process in the Recuperative heat exchanger, throttling expansion process in the throttling element, this is the process that realizes energy transformation, merit by the compressor input is converted to cold fire usefulness, in vaporizer, realize the utilization of cold fire usefulness, low-pressure low-temperature working medium enters Recuperative heat exchanger cooling high pressure incoming flow working medium, after self temperature returns to envrionment temperature, enters compressor and finishes a thermodynamic cycle.Therefore, mixing medium finally will be embodied in influence to above-mentioned several thermal processing to the refrigerator Effect on Performance.In addition, the status of different thermal processing in refrigerator is also not quite identical, wherein heat recovery process is to influence (when especially the adopting multicomponent mixture working medium) maximum of refrigerator, the effect of heat recovery process also has a significant impact throttling process simultaneously, be in particular in when backheat is improved, temperature reduces before causing throttling, and the loss of throttling process is also reduced greatly.Therefore mixture working medium being selected to take all factors into consideration influence to each thermal processing, is that the irreversible loss of each process is reduced for preferred working medium, and final system obtains optimum performance.
According to above-mentioned analysis, be the calculating principle of example explanation mixed work medium for throttling refrigeration cycle thermal performance with Fig. 1, working cycle shown in Figure 4:
Specific refrigerating effect: q
c=h
L2-h
L3
Unit power consumption: W
In=h
G01-h
L1(adiabatic compression)
Coefficient of refrigerating performance:
Thermo-efficiency:
In the above-mentioned formula: q
cBe specific refrigerating effect, h represents enthalpy, W
InBe wasted work, T
c, T
0Represent refrigeration temperature and envrionment temperature respectively, subscript is represented each state point, referring to marginal data.The condition that realizes above-mentioned thermal performance is: must satisfy the device constraints that each thermal processing is normally carried out, as not occurring " bearing " temperature difference phenomenon in the Recuperative heat exchanger.
Technical scheme of the present invention is as follows:
The multicomponent mixture working medium throttling refrigerant that is applicable to the deep cooling warm area provided by the invention comprises 6 groups of materials, and these 6 groups of materials are respectively:
The 1st group of material: nitrogen (N
2), argon gas (Ar) or the mixture of the two, mainly be to change the working medium characteristic that balances each other, guarantee that refrigeration temperature reaches below the 110K, especially when the circulation back pressure is higher than 0.1MPa (absolute pressure), this group material in the mixture that the present invention proposes the useful effect warm area between 80～120K;
The 2nd group of material: methane (CH
4), krypton (Kr) or the mixture of the two, effectively operation temperature area is 110～150K, is the groundwork material;
The 3rd group of material: tetrafluoromethane (CF
4), nitrogen trifluoride (F
3N) or the mixture of the two, the useful effect warm area is 145～180K;
The 4th group of material: ethene (C
2H
4), ethane (C
2H
6), trifluoromethane (CHF
3) or be somebody's turn to do the mixture of organizing wantonly two kinds of materials in the material, perhaps be mixture of three kinds of materials in this group material, effectively operation temperature area is 170～230K;
The 5th group of material: propylene (C
3H
6), propane (C
3H
8), perfluoropropane (C
3F
8) or be the mixture of wantonly two kinds of materials in this group material, perhaps organize mixture of three kinds of materials in material for this, effective operation temperature area is 230～270K;
The 6th group of material is: 1-butylene (1-C
4H
8), Trimethylmethane (C
4H
10), 2-methylbutane (C
5H
12), 1-amylene (1-C
5H
10), 3-methyl-1-butene (C
5H
10), 2-methylpentane (C
6H
14) or be the mixture of wantonly two kinds of materials, three kinds, multiple material or all substances in this group material, its effective operation temperature area 260～350K.
Here effective operation temperature area of each constituent element of indication is to exist corresponding to working pressure range: high pressure is in 1.2～2.5MPa scope, and low pressure (is absolute pressure) in 0.1～0.7MPa scope.
Consider that from the angle of refrigeration cycle the above-mentioned material of respectively organizing is brought into play not same-action in circulation, the 1st group of material is to guarantee to realize required refrigeration temperature, especially when cycle operation low pressure is higher; The 2nd group of material is the groundwork material, and the 3rd group to the 6th group material mainly is the loss that reduces heat recovery process, throttling process, and increases the isothermal throttling effect, reduces compressor exhaust temperature, reduces the condensation process loss.The above-mentioned substance constituent element is ozone free and consumes working medium (ODP is zero).
The mixed work medium for throttling refrigeration agent that is applicable to the deep cooling warm area that the invention described above provides, the total mol concentration of each group material also can satisfy following requirement:
The total mol concentration of the 1st group of material: 5%～35%;
The total mol concentration of the 2nd group of material: 25%～55%;
The total mol concentration of the 4th group of material: 10%～30%;
The total mol concentration of the 5th group of material: 10%～30%;
The total mol concentration of the 6th group of material: 10%～25%;
The total mol concentration of the 3rd group of material: surplus;
And this concentration range can segmented and optimization in the temperature range more specifically, is specially:
1, at the 100K warm area (100K ± 5K):
The total mol concentration of the 1st group of material: 35%～50%;
The total mol concentration of the 2nd group of material: 15%～30%;
The total mol concentration of the 4th group of material: 5%～20%;
The total mol concentration of the 5th group of material: 5%～20%;
The total mol concentration of the 6th group of material: 5%～15%;
The total mol concentration of the 3rd group of material: surplus;
2, at the 110K warm area (110K ± 5K):
The total mol concentration of the 1st group of material: 30%～40%;
The total mol concentration of the 2nd group of material: 20%～35%;
The total mol concentration of the 4th group of material: 8%～22%;
The total mol concentration of the 5th group of material: 8%～22%;
The total mol concentration of the 6th group of material: 8%～18%;
The total mol concentration of the 3rd group of material: surplus;
3, at the 120K warm area (120K ± 5K):
The total mol concentration of the 1st group of material: 20%～35%;
The total mol concentration of the 2nd group of material: 25%～40%;
The total mol concentration of the 4th group of material: 10%～24%;
The total mol concentration of the 5th group of material: 10%～24%;
The total mol concentration of the 6th group of material: 10%～20%;
The total mol concentration of the 3rd group of material: surplus;
4, at the 130K warm area (130K ± 5K):
The total mol concentration of the 1st group of material: 15%～30%;
The total mol concentration of the 2nd group of material: 30%～45%;
The total mol concentration of the 4th group of material: 12%～25%;
The total mol concentration of the 5th group of material: 12%～25%;
The total mol concentration of the 6th group of material: 10%～22%;
The total mol concentration of the 3rd group of material: surplus;
5, at the 140K warm area (140K ± 5K):
The total mol concentration of the 1st group of material: 10%～25%;
The total mol concentration of the 2nd group of material: 35%～50%;
The total mol concentration of the 4th group of material: 14%～27%;
The total mol concentration of the 5th group of material: 14%～27%;
The total mol concentration of the 6th group of material: 10%～23%;
The total mol concentration of the 3rd group of material: surplus;
6, at the 150K warm area (150K ± 5K):
The total mol concentration of the 1st group of material: 5%～20%;
The total mol concentration of the 2nd group of material: 35%～55%;
The total mol concentration of the 4th group of material: 15%～30%;
The total mol concentration of the 5th group of material: 15%～30%;
The total mol concentration of the 6th group of material: 10%～25%;
The total mol concentration of the 3rd group of material: surplus;
Above-mentioned concentration range exists corresponding to working pressure range: high pressure is in 1.2～2.5MPa scope, and low pressure (is absolute pressure) in 0.1～0.7MPa scope, and pressure ratio is 3～10.Wherein change in concentration trend is to increase with low pressure, and lower boiling constituent element concentration increases, and corresponding middle high boiling point constituent element concentration reduces, and vice versa.
Description of drawings
Fig. 1 is the procedure information figure of a circulating with choke of mixing medium back-heating type.
Fig. 2 is the interior overlapping throttling refrigeration round-robin procedure information figure that mixing medium back-heating type band one-level vapour-liquid is separated.
Fig. 3 is the part working medium constituent element warm area figure that plays a role.
Fig. 4 is corresponding to round-robin enthalpy temperature synoptic diagram shown in Figure 1.
Wherein: CP is a compressor, and AC is a water cooler, and JT, JT1, JT2 are throttling element, and HX, HX1, HX2, HX3 are Recuperative heat exchanger, and SP is a phase separator, and EV is a vaporizer, and MIX is a mixing tank; L1～L7 wherein, G01, G0～G5 are each state point of working medium, R14 is tetrafluoromethane (CF
4), iC4H10 is a Trimethylmethane, and iC5H12 is the 2-methylbutane, claims iso-pentane again, and C3H8 is a propane, and C2H6 is an ethane, and CH4 is a methane, and N2 is a nitrogen, and T0 is an envrionment temperature, and Tc is a refrigeration temperature, and W is the compressor power consumption, q
cBe refrigerating duty.
Embodiment
Specifically illustrate the heating power working process of mixed work medium for throttling refrigeration agent proposed by the invention in conjunction with Fig. 1 and Fig. 4: mixed work medium for throttling refrigeration agent of the present invention enters compressor CP from state L1, is compressed into state G01; Enter water cooler AC then and be cooled to state G0; Enter Recuperative heat exchanger HX, be further cooled to G1; Then through becoming L3 after the throttling element JT throttling; Enter vaporizer EV, become L2 behind the extraction cold; Then enter Recuperative heat exchanger HX rewarming, return to state L1, finish a thermodynamic cycle.
For thermodynamic cycle shown in Figure 2, its groundwork process is identical, has only increased one-level vapor-liquid separation SP and intermediate stage throttling JT1 and mixing process MIX.
Below in conjunction with drawings and Examples the present invention is described in further detail.
Preparation is applicable to the polybasic mixture throttling refrigeration agent of deep cooling warm area, and this polybasic mixture throttling refrigeration agent comprises following 6 groups of materials, and these 6 groups of materials are respectively:
The 1st group of material: nitrogen (N
2), argon gas (Ar) or the mixture of the two;
The 2nd group of material: methane (CH
4), krypton (Kr) or the mixture of the two;
The 3rd group of material: tetrafluoromethane (CF
4), nitrogen trifluoride (F
3N) or the mixture of the two;
The 4th group of material: ethene (C
2H
4), ethane (C
2H
6), trifluoromethane (CHF
3) or should organize in the material
The mixture of wantonly 2 kinds of materials or be the mixture of all substances in this group material;
The 5th group of material: propylene (C
3H
6), propane (C
3H
8), perfluoropropane (C
3F
8) or be the mixture of wantonly 2 kinds of materials in this group material; Perhaps organize the mixture of all substances in material for this;
The 6th group of material is: 1-butylene (1-C
4H
8), Trimethylmethane (C
4H
10), 2-methylbutane (C
5H
12), 1-amylene (1-C
5H
10), 3-methyl-1-butene (C
5H
10), 2-methylpentane (C
6H
14) or be the mixture of wantonly 2 kinds of materials, multiple material or all substances in this group material.
Embodiment 1: prepare a kind of mixture working medium refrigeration agent (optimization concentration) that operates in the 100K warm area efficiently, this mixture working medium refrigeration agent comprises the 1st group to the 6th group material, each volumetric molar concentration sum of organizing material is 100%, and the total mol concentration of every group of material is as follows:
The 1st group of material: total mol concentration is 50%, wherein nitrogen (N
2) volumetric molar concentration is 50%, the volumetric molar concentration of all the other materials is 0%;
The 2nd group of material: total mol concentration is 15%, wherein methane (CH
4) volumetric molar concentration is 15%, the volumetric molar concentration of all the other materials is 0%;
The 4th group of material: total mol concentration is 10%, wherein ethane (C
2H
6) volumetric molar concentration is 10%, the volumetric molar concentration of all the other materials is 0%;
The 5th group of material: total mol concentration is 5%, wherein perfluoropropane (C
3F
8) volumetric molar concentration is 5%, the volumetric molar concentration of all the other materials is 0%;
The 6th group of material: total mol concentration is 15%, wherein 1-butylene (1-C
4H
8) volumetric molar concentration is 8%, 2-methylbutane (C
5H
12) volumetric molar concentration is 7%, the volumetric molar concentration of all the other materials is 0%;
The 3rd group of material: total mol concentration is 5%, wherein tetrafluoromethane (CF
4) volumetric molar concentration is 5%, the volumetric molar concentration of all the other materials is 0%.
Working parameter is: envrionment temperature is 300K, refrigeration temperature 100K; High pressure 2.0MPa, low pressure 0.3MPa, refrigeration cycle is shown in Figure 1, and working medium coefficient of refrigerating performance COP is 0.225, and thermo-efficiency CEF is 45%.
Embodiment 2: the deep cooling mixture working medium of preparation 100K warm area, and envrionment temperature is 300K; Mixture concentration proportioning, refrigerator working parameter and mixing medium thermal performance see the following form:
Produce partially mixed substrate concentration proportioning of 100K warm area and thermal parameter table among the embodiment 2
| Project | Mixture 1 volumetric molar concentration % | Mixture 2 volumetric molar concentration % | Mixture 3 volumetric molar concentration % |
| The 1st group | 35 (argon Ar) | 40 (nitrogen 30, argons 10) | 50 (argon 15, nitrogen 35) |
| The 2nd group | 30 (methane 20, kryptons 10) | 25 (methane) | 15 (kryptons) |
| The 3rd group | 10 (tetrafluoromethanes) | 5 (nitrogen trifluorides) | 5 (tetrafluoromethane 3, nitrogen trifluorides 2) |
| The 4th group | 10 (ethane 5, trifluoromethanes 5) | 5 (ethene) | 10 (ethane 5, trifluoromethanes 5) |
| The 5th group | 5 (propane) | 20 (propane 10, propylene 5, perfluoropropane 5) | 5 (perfluoropropane) |
| The 6th group | 10 (3-methyl-1-butene 6,2-methylpentane 2,2-methylpentanes 2) | 5 (2-methylbutanes) | 15 (Trimethylmethanes) |
| High voltage/low voltage | 1.8/0.2(MPa) | 2.0/0.4(MPa) | 2.4/0.6(MPa) |
| COP | 0.08 | 0.116 | 0.24 |
| CEF％ | 16 | 23.2 | 48 |
Embodiment 3: prepare a kind of deep cooling warm area mixture working medium that is applied in 110K, this mixture working medium refrigeration agent comprises the 1st group to the 6th group material, and each volumetric molar concentration sum of organizing material is 100%, and the total mol concentration of every group of material is as follows:
The 1st group of material: total mol concentration is 30%, wherein nitrogen (N
2) volumetric molar concentration is 20%, (Ar) volumetric molar concentration is 10%;
The 2nd group of material: total mol concentration is 35%, wherein methane (CH
4) volumetric molar concentration is 25%, krypton (Kr) volumetric molar concentration is 10%;
The 4th group of material: total mol concentration is 8%, therein ethylene (C
2H
4) volumetric molar concentration is 3%, ethane (C
2H
6) volumetric molar concentration is 3%, trifluoromethane (CHF
3) volumetric molar concentration is 2%;
The 5th group of material: total mol concentration is 8%, wherein propylene (C
3H
6) volumetric molar concentration is 2%, propane (C
3H
8) volumetric molar concentration is 2%, perfluoropropane (C
3F
8) volumetric molar concentration is 4%;
The 6th group: total mol concentration is 8%, wherein 1-butylene (1-C
4H
8) 3%, Trimethylmethane (C
4H
10), 2-methylbutane (C
5H
12), 1-amylene (1-C
5H
10), 3-methyl-1-butene (C
5H
10) and 2-methylpentane (C
6H
14) volumetric molar concentration respectively be 1%;
The 3rd group of material: total mol concentration is 11%, wherein tetrafluoromethane (CF
4) volumetric molar concentration is 7%, nitrogen trifluoride (F
3N) volumetric molar concentration is 4%.
Working parameter: envrionment temperature is 300K, refrigeration temperature 110K; High pressure 2.4MPa, low pressure 0.2MPa, refrigeration cycle is shown in Figure 1, and working medium coefficient of refrigerating performance COP is 0.128, and thermo-efficiency CEF is 22%.
Embodiment 4: the deep cooling mixture working medium of preparation 110K warm area, and envrionment temperature is 300K; Mixture concentration proportioning, refrigerator working parameter and mixing medium thermal performance see the following form:
Produce partially mixed substrate concentration proportioning of 110K warm area and thermal parameter table among the embodiment 4
| Project | Mixture 1 volumetric molar concentration % | Mixture 2 volumetric molar concentration % | Mixture 3 volumetric molar concentration % |
| The 1st group | 30 (nitrogen) | 34 (nitrogen 20, argons 14) | 40 (argon 15, nitrogen 25) |
| The 2nd group | 25 (methane 15, kryptons 10) | 23 (methane) | 20 (kryptons) |
| The 3rd group | 5 (tetrafluoromethanes) | 5 (nitrogen trifluorides) | 2 (tetrafluoromethanes) |
| The 4th group | 22 ( | 10 (ethene) | 8 (ethane 3, trifluoromethane 3, ethene 2) |
| The 5th group | 8 (propane) | 10 (propane 2, propylene 3, perfluoropropane 5) | 22 (perfluoropropane) |
| The 6th group | 10 (Trimethylmethane 5,2-methylpentanes 5) | 18 (1-butylene 12,2-methylbutane, 6) | 8 (Trimethylmethanes) |
| High voltage/low voltage | 2.0/0.2(MPa) | 1.8/0.2(MPa) | 2.0/0.2(MPa) |
| COP | 0.154 | 0.244 | 0.097 |
| CEF％ | 26.6 | 42.1 | 16.75 |
Embodiment 5: prepare a kind of mixture refrigerant that operates in the 120K warm area, this mixture working medium refrigeration agent comprises the 1st group to the 6th group material, and each volumetric molar concentration sum of organizing material is 100%, and the total mol concentration of every group of material is as follows:
The 1st group of material: total mol concentration is 20%, wherein nitrogen (N
2) volumetric molar concentration is 20%, the volumetric molar concentration of all the other materials is 0%;
The 2nd group of material: total mol concentration is 40%, wherein methane (CH
4) volumetric molar concentration is 40%, the volumetric molar concentration of all the other materials is 0%;
The 4th group of material: total mol concentration is 10%, wherein ethane (C
2H
6) volumetric molar concentration is 10%, the volumetric molar concentration of all the other materials is 0%;
The 5th group of material: total mol concentration is 10%, wherein propane (C
3H
8) volumetric molar concentration is 10%, the volumetric molar concentration of all the other materials is 0%;
The 6th group of material: total mol concentration is 20%, wherein 1-butylene (1-C
4H
8) volumetric molar concentration is 5%, Trimethylmethane (C
4H
10) volumetric molar concentration is 12%, 2-methylbutane (C
5H
12) volumetric molar concentration is 3%, the volumetric molar concentration of all the other materials is 0%;
The 3rd group of material: total mol concentration is 0%.
Working parameter is: envrionment temperature is 300K, refrigeration temperature 120K; High pressure 1.8MPa, low pressure 0.3MPa, refrigeration cycle is shown in Figure 1, and working medium coefficient of refrigerating performance COP is 0.138, and thermo-efficiency CEF is 20.7%.
Embodiment 6: the deep cooling mixture working medium of preparation 120K warm area, and envrionment temperature is 300K; Mixture concentration proportioning, refrigerator working parameter and mixing medium thermal performance see the following form:
Produce partially mixed substrate concentration proportioning of 120K warm area and thermal parameter table among the embodiment 6
| Project | Mixture 1 volumetric molar concentration % | Mixture 2 volumetric molar concentration % | Mixture 3 volumetric molar concentration % |
| The 1st group | 20 (nitrogen) | 26 (nitrogen 20, argons 6) | 35 (argon 20, nitrogen 15) |
| The 2nd group | 30 (methane 20, kryptons 10) | 28 (methane) | 25 (kryptons) |
| The 3rd group | 6 (tetrafluoromethanes) | 2 (nitrogen trifluorides) | 4 (tetrafluoromethane 2, nitrogen trifluorides 2) |
| The 4th group | 24 (ethane 14, trifluoromethanes 10) | 10 (ethene) | 12 (ethane 4, trifluoromethane 4, ethene 4) |
| The 5th group | 10 (propane) | 24 (propane 14, propylene 5, perfluoropropane 5) | 12 (perfluoropropane) |
| The 6th group | 10 (Trimethylmethane 7,2-methylpentanes 3) | 10 (1-butylene 4,2-methylbutane, 6) | 12 (Trimethylmethanes) |
| High voltage/low voltage | 2.0/0.2(MPa) | 1.8/0.2(MPa) | 2.0/0.2(MPa) |
| COP | 0.116 | 0.248 | 0.096 |
| CEF％ | 17.4 | 37.2 | 14.4 |
Embodiment 7: prepare a kind of mixture working medium refrigeration agent that operates in the 130K warm area efficiently, this mixture working medium refrigeration agent comprises the 1st group to the 6th group material, and each volumetric molar concentration sum of organizing material is 100%, and the total mol concentration of every group of material is as follows:
The 1st group of material: total mol concentration is 30%, and wherein argon gas (Ar) volumetric molar concentration is 30%, and the volumetric molar concentration of all the other materials is 0%;
The 2nd group of material: total mol concentration is 30%, wherein methane (CH
4) volumetric molar concentration is 30%, the volumetric molar concentration of all the other materials is 0%;
The 4th group of material: total mol concentration is 12%, wherein ethane (C
2H
6) volumetric molar concentration is 12%, the volumetric molar concentration of all the other materials is 0%;
The 5th group of material: total mol concentration is 12%, wherein propane (C
3H
8) volumetric molar concentration is 12%, the volumetric molar concentration of all the other materials is 0%;
The 6th group of material: total mol concentration is 10%, wherein 2-methylbutane (C
5H
12) volumetric molar concentration is 6%, Trimethylmethane (C
4H
10) volumetric molar concentration be 4%, all the other material volumetric molar concentrations are 0%;
The 3rd group of material: total mol concentration is 6%, wherein tetrafluoromethane (CF
4) volumetric molar concentration is 6%, the volumetric molar concentration of all the other materials is 0%.
Working parameter is: envrionment temperature is 300K, refrigeration temperature 120K; High pressure 2.0MPa, low pressure 0.4MPa, refrigeration cycle is flash trapping stage circulation shown in Figure 2, and working medium coefficient of refrigerating performance COP is 0.281, and thermo-efficiency CEF is 36.7%.
Embodiment 8: the deep cooling mixture working medium of preparation 130K warm area, and envrionment temperature is 300K; Mixture concentration proportioning, refrigerator working parameter and mixing medium thermal performance see the following form:
Produce partially mixed substrate concentration proportioning of 130K warm area and thermal parameter table among the embodiment 8
| Project | Mixture 1 volumetric molar concentration % | Mixture 2 volumetric molar concentration % | Mixture 3 volumetric molar concentration % |
| The 1st group | 15 (nitrogen) | 18 (nitrogen 20, argons 6) | 15 (nitrogen) |
| The 2nd group | 45 (methane 35, kryptons 10) | 32 (methane) | 30 (kryptons) |
| The 3rd group | 6 (tetrafluoromethanes) | 0 | 6 (tetrafluoromethane 4, nitrogen trifluorides 2) |
| The 4th group | 12 (ethane 7, trifluoromethanes 5) | 15 (ethene) | 12 (ethane 4, trifluoromethane 4, ethene 4) |
| The 5th group | 12 (propane) | 25 (propane 14, propylene 5, perfluoropropane 5) | 15 (perfluoropropane) |
| The 6th group | 10 (Trimethylmethane 7,2-methylpentanes 3) | 10 (1-butylene 4,2-methylbutane, 6) | 22 (Trimethylmethanes) |
| High voltage/low voltage | 2.0/0.2(MPa) | 1.8/0.2(MPa) | 1.8/0.2(MPa) |
| COP | 0.103 | 0.282 | 0.272 |
| CEF％ | 13.5 | 36.8 | 35.6 |
Embodiment 9: prepare a kind of mixture working medium refrigeration agent that is applied in the 130K warm area, this mixture working medium refrigeration agent comprises the 1st group to the 6th group material, and each volumetric molar concentration sum of organizing material is 100%, and the total mol concentration of every group of material is as follows:
The 1st group of material: total mol concentration is 18%, wherein nitrogen (N
2) volumetric molar concentration is 18%, the volumetric molar concentration of all the other materials is 0%;
The 2nd group of material: total mol concentration is 32%, wherein methane (CH
4) volumetric molar concentration is 32%, the volumetric molar concentration of all the other materials is 0%;
The 4th group of material: total mol concentration is 25%, wherein ethane (C
2H
6) volumetric molar concentration is 25%, the volumetric molar concentration of all the other materials is 0%;
The 5th group of material: total mol concentration is 15%, wherein propane (C
3H
8) volumetric molar concentration is 15%, the volumetric molar concentration of all the other materials is 0%;
The 6th group of material: total mol concentration is 10%, wherein 2-methylbutane (C
5H
12) volumetric molar concentration is 10%, the volumetric molar concentration of all the other materials is 0%;
The 3rd group of material: total mol concentration is 0%.
Working parameter is: envrionment temperature is 300K, refrigeration temperature 120K; High pressure 2.0MPa, low pressure 0.2MPa, refrigeration cycle is shown in Figure 1, and working medium coefficient of refrigerating performance COP is 0.277, and thermo-efficiency CEF is 36.2%.
Embodiment 10: prepare a kind of mixture working medium refrigeration agent that operates in the 140K warm area efficiently, this mixture working medium refrigeration agent comprises the 1st group to the 6th group material, and each volumetric molar concentration sum of organizing material is 100%, and the total mol concentration of every group of material is as follows:
The 1st group of material: total mol concentration is 25%, wherein nitrogen (N
2) volumetric molar concentration is 20%, argon gas (Ar) volumetric molar concentration is 5%;
The 2nd group of material: total mol concentration is 35%, and wherein krypton (Kr) volumetric molar concentration is 35%, and all the other material volumetric molar concentrations are 0%;
The 4th group of material: total mol concentration is 14%, wherein ethane (C
2H
6) volumetric molar concentration is 14%, all the other material volumetric molar concentrations are 0%;
The 5th group of material: total mol concentration is 14%, wherein perfluoropropane (C
3F
8) volumetric molar concentration is 14%, all the other material volumetric molar concentrations are 0%;
The 6th group of material: total mol concentration is 10%, wherein Trimethylmethane (C
4H
10) volumetric molar concentration is 5%, 2-methylbutane (C
5H
12) volumetric molar concentration is 5%, all the other material volumetric molar concentrations are 0%;
The 3rd group of material: total mol concentration is 2%, wherein tetrafluoromethane (CF
4) volumetric molar concentration is 2%, all the other material volumetric molar concentrations are 0%.
Working parameter is: envrionment temperature is 300K, refrigeration temperature 130K; High pressure 1.6MPa, low pressure 0.3MPa, refrigeration cycle is shown in Figure 1, and working medium coefficient of refrigerating performance COP is 0.129, and thermo-efficiency CEF is 14.7%.
Embodiment 11: the deep cooling mixture working medium of preparation 140K warm area, and envrionment temperature is 300K; Mixture concentration proportioning, refrigerator working parameter and mixing medium thermal performance see the following form:
Produce partially mixed substrate concentration proportioning of 140K warm area and thermal parameter table among the embodiment 11
| Project | Mixture 1 volumetric molar concentration % | Mixture 2 volumetric molar concentration % | Mixture 3 volumetric molar concentration % |
| The 1st group | 10 (nitrogen) | 12 (nitrogen) | 11 (nitrogen) |
| The 2nd group | 50 (methane 40, kryptons 10) | 36 (methane) | 37 (kryptons) |
| The 3rd group | 2 (tetrafluoromethanes) | 0 | 0 |
| The 4th group | 14 (ethane 7, trifluoromethanes 7) | 15 (ethene) | 27 (ethane 14, trifluoromethane 10, ethene 3) |
| The 5th group | 14 (propane) | 27 ( | 15 (perfluoropropane) |
| The 6th group | 10 (Trimethylmethane 7,2-methylpentanes 3) | 10 (1-butylene 4,2-methylbutane, 6) | 10 (Trimethylmethanes) |
| High voltage/low voltage | 1.8/0.2(MPa) | 2.0/0.2(MPa) | 2.2/0.3(MPa) |
| COP | 0.123 | 0.332 | 0.142 |
| CEF％ | 15.3 | 41.5 | 17.8 |
Embodiment 12: prepare a kind of mixture working medium refrigeration agent that is applied to the 140K warm area, this mixture working medium refrigeration agent comprises the 1st group to the 6th group material, and each volumetric molar concentration sum of organizing material is 100%, and the total mol concentration of every group of material is as follows:
The 1st group of material: total mol concentration is 13%, wherein nitrogen (N
2) volumetric molar concentration is 10%, the argon gas volumetric molar concentration is 4%;
The 2nd group of material: total mol concentration is 36%, wherein methane (CH
4) volumetric molar concentration is 38%, the volumetric molar concentration of all the other materials is 0%;
The 4th group of material: total mol concentration is 14%, wherein ethane (C
2H
6) volumetric molar concentration is 14%, the volumetric molar concentration of all the other materials is 0%;
The 5th group of material: total mol concentration is 14%, wherein perfluoropropane (C
3F
8) volumetric molar concentration is 14%, the volumetric molar concentration of all the other materials is 0%;
The 6th group of material: total mol concentration is 23%, wherein Trimethylmethane (C
4H
10) volumetric molar concentration is 5%, 1-amylene (1-C
5H
10) volumetric molar concentration is 10%, 3-methyl-1-butene (C
5H
10) volumetric molar concentration is 5%, 2-methylbutane (C
5H
12) volumetric molar concentration is 3%, the volumetric molar concentration of all the other materials is 0%;
The 3rd group of material: total mol concentration is 0%.
Working parameter is: envrionment temperature is 300K, refrigeration temperature 140K; High pressure 1.8MPa, low pressure 0.2MPa, refrigeration cycle is shown in Figure 1, and working medium coefficient of refrigerating performance COP is 0.337, and thermo-efficiency CEF is 42.1%.
Embodiment 13: prepare a kind of mixture working medium refrigeration agent that is applied to the 150K warm area, this mixture working medium refrigeration agent comprises the 1st group to the 6th group material, and each volumetric molar concentration sum of organizing material is 100%, and the total mol concentration of every group of material is as follows:
The 1st group of material: total mol concentration is 20%, wherein nitrogen (N
2) volumetric molar concentration is 10%, argon gas (Ar) volumetric molar concentration is 10%;
The 2nd group of material: total mol concentration is 35%, wherein methane (CH
4) volumetric molar concentration is 25%, krypton (Kr) volumetric molar concentration is 10%;
The 4th group of material: total mol concentration is 15%, therein ethylene (C
2H
4) volumetric molar concentration is 5%, ethane (C
2H
6) volumetric molar concentration is 5%, trifluoromethane (CHF
3) 5%;
The 5th group of material: total mol concentration is 15%, wherein propylene (C
3H
6) volumetric molar concentration is 5%, propane (C
3H
8) volumetric molar concentration is 5%, perfluoropropane (C
3F
8) volumetric molar concentration is 5%;
The 6th group of material: total mol concentration is 12%, wherein Trimethylmethane (C
4H
10) volumetric molar concentration is 10%, 2-methylbutane (C
5H
12) volumetric molar concentration is 2%;
The 3rd group of material: total mol concentration is 3%, wherein tetrafluoromethane (CF
4) volumetric molar concentration is 3%.
Working parameter is: envrionment temperature is 300K, refrigeration temperature 150K; High pressure 2.4MPa, low pressure 0.6MPa, refrigeration cycle is shown in Figure 1, and working medium coefficient of refrigerating performance COP is 0.458, and thermo-efficiency CEF is 45.8%.
Embodiment 14: prepare a kind of mixture working medium refrigeration agent that is applied to the 150K warm area, this mixture working medium refrigeration agent comprises the 1st group to the 6th group material, and each volumetric molar concentration sum of organizing material is 100%, and the total mol concentration of every group of material is as follows:
The 1st group of material: total mol concentration is 5%, wherein nitrogen (N
2) volumetric molar concentration is 5%;
The 2nd group of material: total mol concentration is 35%, wherein methane (CH
4) volumetric molar concentration is 25%, krypton (Kr) volumetric molar concentration is 10%;
The 4th group of material: total mol concentration is 17%, therein ethylene (C
2H
4) volumetric molar concentration is 7%, ethane (C
2H
6) volumetric molar concentration is 5%, trifluoromethane (CHF
3) 5%;
The 5th group of material: total mol concentration is 18%, wherein propylene (C
3H
6) volumetric molar concentration is 8%, propane (C
3H
8) volumetric molar concentration is 5%, perfluoropropane (C
3F
8) volumetric molar concentration is 5%;
The 6th group of material: total mol concentration is 25%, wherein the 1-butylene volumetric molar concentration be 10%, Trimethylmethane (C
4H
10) volumetric molar concentration is 13%, 2-methylpentane (C
6H
14) volumetric molar concentration is 2%;
The 3rd group of material: total mol concentration is 0%.
Working parameter is: envrionment temperature is 300K, refrigeration temperature 150K; High pressure 2.0MPa, low pressure 0.4MPa, refrigeration cycle is shown in Figure 1, and working medium coefficient of refrigerating performance COP is 0.303, and thermo-efficiency CEF is 30.3%.
Embodiment 15: the deep cooling mixture working medium of preparation 150K warm area, and envrionment temperature is 300K; Mixture concentration proportioning, refrigerator working parameter and mixing medium thermal performance see the following form:
Produce partially mixed substrate concentration proportioning of 150K warm area and thermal parameter table among the embodiment 15
| Project | Mixture 1 volumetric molar concentration % | Mixture 2 volumetric molar concentration % | Mixture 3 volumetric molar concentration % |
| The 1st group | 5 (nitrogen) | 7 (nitrogen) | 8 (argons) |
| The 2nd group | 55 (methane) | 38 (methane) | 37 (kryptons) |
| The 3rd group | 0 | 0 | 0 |
| The 4th group | 15 (ethane 7, trifluoromethanes 7) | 15 (ethene) | 30 (ethane 14, trifluoromethane 10, ethene 3) |
| The 5th group | 15 (propane) | 30 (propane 20, propylene 5, perfluoropropane 5) | 15 (perfluoropropane) |
| The 6th group | 10 (Trimethylmethane 7,2-methylpentanes 3) | 10 (1-butylene 4,2-methylbutane, 6) | 10 (Trimethylmethanes) |
| High voltage/low voltage | 2.0/0.5(MPa) | 2.0/0.4(MPa) | 2.2/0.5(MPa) |
| COP | 0.323 | 0.39 | 0.342 |
| CEF％ | 32.3 | 39 | 34.2 |
Claims (5)
1. a multicomponent mixture working medium throttling refrigerant that is applicable to the deep cooling warm area is characterized in that, comprises 6 groups of materials, and these 6 groups of materials are respectively:
The 1st group of material: nitrogen, argon gas or the mixture of the two;
The 2nd group of material: methane, krypton or the mixture of the two;
The 3rd group of material: tetrafluoromethane, nitrogen trifluoride or the mixture of the two;
The 4th group of material: ethene, ethane, trifluoromethane or should the group material in the mixture of wantonly two kinds of materials, perhaps organize the mixture of three kinds of materials in material for this;
The 5th group of material: propylene, propane, perfluoropropane or be the mixture of wantonly two kinds of materials in this group material, perhaps organize the mixture of three kinds of materials in material for this;
The 6th group of material is: 1-butylene, Trimethylmethane, 2-methylbutane, 1-amylene, 3-methyl-1-butene, 2-methylpentane or be the mixture of wantonly two kinds of materials in this group material, three kinds, multiple material or all substances;
Each volumetric molar concentration sum of organizing material is 100%, requires below wherein the total mol concentration of each group material satisfies:
The total mol concentration of the 1st group of material: 5%～35%;
The total mol concentration of the 2nd group of material: 25%～55%;
The total mol concentration of the 4th group of material: 10%～30%;
The total mol concentration of the 5th group of material: 10%～30%;
The total mol concentration of the 6th group of material: 10%～25%;
The total mol concentration of the 3rd group of material: surplus.
2. by the described multicomponent mixture working medium throttling refrigerant that is applicable to the deep cooling warm area of claim 1, it is characterized in that, require below the total mol concentration of described each group material satisfies:
The total mol concentration of the 1st group of material: 20%～35%;
The total mol concentration of the 2nd group of material: 25%～40%;
The total mol concentration of the 4th group of material: 10%～24%;
The total mol concentration of the 5th group of material: 10%～24%;
The total mol concentration of the 6th group of material: 10%～20%;
The total mol concentration of the 3rd group of material: surplus.
3. by the described multicomponent mixture working medium throttling refrigerant that is applicable to the deep cooling warm area of claim 1, it is characterized in that, require below the total mol concentration of described each group material satisfies:
The total mol concentration of the 1st group of material: 15%～30%;
The total mol concentration of the 2nd group of material: 30%～45%;
The total mol concentration of the 4th group of material: 12%～25%;
The total mol concentration of the 5th group of material: 12%～25%;
The total mol concentration of the 6th group of material: 10%～22%;
The total mol concentration of the 3rd group of material: surplus.
4. by the described multicomponent mixture working medium throttling refrigerant that is applicable to the deep cooling warm area of claim 1, it is characterized in that, require below the total mol concentration of described each group material satisfies:
The total mol concentration of the 1st group of material: 10%～25%;
The total mol concentration of the 2nd group of material: 35%～50%;
The total mol concentration of the 4th group of material: 14%～27%;
The total mol concentration of the 5th group of material: 14%～27%;
The total mol concentration of the 6th group of material: 10%～23%;
The total mol concentration of the 3rd group of material: surplus.
5. by the described multicomponent mixture working medium throttling refrigerant that is applicable to the deep cooling warm area of claim 1, it is characterized in that, require below the total mol concentration of described each group material satisfies:
The total mol concentration of the 1st group of material: 5%～20%;
The total mol concentration of the 2nd group of material: 35%～55%;
The total mol concentration of the 4th group of material: 15%～30%;
The total mol concentration of the 5th group of material: 15%～30%;
The total mol concentration of the 6th group of material: 10%～25%;
The total mol concentration of the 3rd group of material: surplus.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03121423 CN1204222C (en) | 2002-05-14 | 2003-03-28 | Multielement mixture workmedium throttle refrigerant suitable for deep cold tepmerature region |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN02117656.6 | 2002-05-14 | ||
| CN02117656 | 2002-05-14 | ||
| CN 03121423 CN1204222C (en) | 2002-05-14 | 2003-03-28 | Multielement mixture workmedium throttle refrigerant suitable for deep cold tepmerature region |
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| CN1475544A CN1475544A (en) | 2004-02-18 |
| CN1204222C true CN1204222C (en) | 2005-06-01 |
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Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7074751B2 (en) * | 2004-04-16 | 2006-07-11 | Honeywell International Inc. | Azeotrope-like compositions of tetrafluoropropene and trifluoroiodomethane |
| CN101608860B (en) * | 2008-06-17 | 2011-08-17 | 北京安瑞科新能能源科技有限公司 | Gas liquefying process for mixed refrigerant and mixed refrigerant |
| CN101922850B (en) * | 2010-09-15 | 2012-01-04 | 煤炭科学研究总院重庆研究院 | Method for utilizing coalbed methane containing oxygen to prepare liquefied natural gas |
| CN101929788B (en) * | 2010-09-15 | 2012-01-04 | 中国科学院理化技术研究所 | Device for preparing liquefied natural gas by oxygen-bearing coal mine methane |
| CN102618220B (en) * | 2011-01-26 | 2016-06-15 | 龙志刚 | A kind of mix refrigerant being applicable to 120K～150K Shen Lengwen district |
| CN108531135B (en) * | 2018-04-10 | 2021-05-07 | 龙志刚 | Mixed refrigerant suitable for cryogenic temperature zone and preparation method and application method thereof |
| CN109920581B (en) * | 2019-03-08 | 2020-12-15 | 中国科学院电工研究所 | Mixed insulating medium of liquid nitrogen and liquefied carbon tetrafluoride and preparation method thereof |
| CN110511726B (en) * | 2019-09-23 | 2021-06-11 | 杨文海 | Formula of mixed refrigerant with minimum temperature of-150 DEG C |
| CN113251711B (en) * | 2020-02-12 | 2022-06-07 | 合肥华凌股份有限公司 | Method, device, equipment and storage medium for judging filling state of mixed refrigerant |
| CN112442336A (en) * | 2020-12-02 | 2021-03-05 | 苏州博威科制冷科技有限公司 | Ultralow-temperature mixed refrigerant |
| CN112778976A (en) * | 2020-12-24 | 2021-05-11 | 青岛营上电器有限公司 | Low-temperature refrigerant and preparation method and application thereof |
| CN116606632B (en) * | 2023-07-19 | 2023-10-20 | 中科美菱低温科技股份有限公司 | Refrigerant and method for producing the same |
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