CN1468937A - Residual pesticide degrading agent - Google Patents
Residual pesticide degrading agent Download PDFInfo
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- CN1468937A CN1468937A CNA021353093A CN02135309A CN1468937A CN 1468937 A CN1468937 A CN 1468937A CN A021353093 A CNA021353093 A CN A021353093A CN 02135309 A CN02135309 A CN 02135309A CN 1468937 A CN1468937 A CN 1468937A
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- CN
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- Prior art keywords
- pesticides
- chlorophenol
- organophosphorus
- pyrethroid
- residual pesticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 11
- 230000000593 degrading effect Effects 0.000 title claims 2
- 239000000575 pesticide Substances 0.000 title abstract description 64
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 230000015556 catabolic process Effects 0.000 claims abstract description 13
- 238000006731 degradation reaction Methods 0.000 claims abstract description 13
- 239000000447 pesticide residue Substances 0.000 claims abstract description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000843 powder Substances 0.000 claims abstract description 5
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 5
- 229930006000 Sucrose Natural products 0.000 claims abstract description 4
- 239000005720 sucrose Substances 0.000 claims abstract description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 3
- 239000003513 alkali Substances 0.000 claims abstract description 3
- 239000002245 particle Substances 0.000 claims description 4
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 150000002632 lipids Chemical class 0.000 claims 1
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 11
- 235000013311 vegetables Nutrition 0.000 abstract description 10
- 239000002689 soil Substances 0.000 abstract description 5
- 239000002105 nanoparticle Substances 0.000 abstract description 4
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 3
- 239000000194 fatty acid Substances 0.000 abstract description 3
- 229930195729 fatty acid Natural products 0.000 abstract description 3
- -1 fatty acid sucrose lipid Chemical class 0.000 abstract description 3
- 150000002978 peroxides Chemical class 0.000 abstract description 2
- 239000002728 pyrethroid Substances 0.000 abstract 5
- 241000723353 Chrysanthemum Species 0.000 description 15
- 235000007516 Chrysanthemum Nutrition 0.000 description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 2
- 239000004343 Calcium peroxide Substances 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 239000001099 ammonium carbonate Substances 0.000 description 2
- 235000019402 calcium peroxide Nutrition 0.000 description 2
- LHJQIRIGXXHNLA-UHFFFAOYSA-N calcium peroxide Chemical compound [Ca+2].[O-][O-] LHJQIRIGXXHNLA-UHFFFAOYSA-N 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241001282315 Nemesis Species 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- NHDHVHZZCFYRSB-UHFFFAOYSA-N pyriproxyfen Chemical compound C=1C=CC=NC=1OC(C)COC(C=C1)=CC=C1OC1=CC=CC=C1 NHDHVHZZCFYRSB-UHFFFAOYSA-N 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
一种残留农药降解剂，其特征所述的降解剂是纳米粒径的二氧化钛粉体或纳米粒径的氧化锌粉体或过氧化物或脂肪酸蔗糖脂或碳酸盐或碱。本发明的残留农药降解剂能使有机磷农药、氯酚农药及菊酯农药容易降解，将它用在有机磷农药、氯酚农药及菊酯农药残留的土壤中，在有机磷农药、氯酚农药及菊酯农药残留的水质中，在有机磷农药、氯酚农药及菊酯农药喷洒后的农作物及蔬菜上，在较短时间内有机磷农药、氯酚农药及菊酯农药有较理想的降解效果。A residual pesticide degradation agent, characterized in that the degradation agent is nano-sized titanium dioxide powder or nano-sized zinc oxide powder or peroxide or fatty acid sucrose lipid or carbonate or alkali. The residual pesticide degradation agent of the present invention can make organophosphorus pesticides, chlorophenol pesticides and pyrethroid pesticides easy to degrade, and it is used in the soil where organophosphorus pesticides, chlorophenol pesticides and pyrethroid pesticides remain. In the water quality of pesticides and pyrethroid pesticide residues, on the crops and vegetables sprayed with organophosphorus pesticides, chlorophenol pesticides and pyrethroid pesticides, organophosphorus pesticides, chlorophenol pesticides and pyrethroid pesticides have a relatively ideal effect in a short period of time. degradation effect.
Description
本发明涉及一种残留农药降解剂。The invention relates to a residual pesticide degradation agent.
农作物及蔬菜病虫害严重影响着它们的产量，为增产除用生物农药外，还广泛的应用有机磷农药、氯酚农药及菊脂农药，它们依然是农作物及蔬菜病虫害的克星，但有机磷农药、氯酚农药及菊脂农药容易在土壤中、水中、粮食中及蔬菜中残留，由于它们严重危害人体健康，严重影响农产品及蔬菜的出售尤其是外贸出口。Crop and vegetable diseases and insect pests seriously affect their output. In addition to biological pesticides for increasing production, organophosphorus pesticides, chlorophenol pesticides and chrysanthemum pesticides are also widely used. They are still the nemesis of crops and vegetable diseases and insect pests, but organophosphorus pesticides, Chlorophenol pesticides and chrysanthemum pesticides are likely to remain in soil, water, grain and vegetables. Because they seriously endanger human health, they seriously affect the sale of agricultural products and vegetables, especially foreign trade exports.
本发明的目的是提供一种残留农药降解剂，它能克服现在技术的上述缺点。The purpose of this invention is to provide a kind of residual pesticide degradation agent, it can overcome the above-mentioned shortcoming of prior art.
一种残留农药降解剂，其特征所述的降解剂是纳米粒径的二氧化钛粉体或纳米粒径的氧化锌粉体或过氧化物或脂肪酸蔗糖脂或碳酸盐或碱。A residual pesticide degradation agent, characterized in that the degradation agent is nano-sized titanium dioxide powder or nano-sized zinc oxide powder or peroxide or fatty acid sucrose lipid or carbonate or alkali.
本发明的残留农药降解剂能使有机磷农药、氯酚农药及菊脂农药容易降解，将它用在有机磷农药、氯酚农药及菊脂农药残留的土壤中，在有机磷农药、氯酚农药及菊脂农药残留的水质中，在有机磷农药、氯酚农药及菊脂农药喷洒后的农作物及蔬菜上，在较短时间内有机磷农药、氯酚农药及菊脂农药有较理想的降解效果。The residual pesticide degradation agent of the present invention can make organophosphorus pesticides, chlorophenol pesticides and chrysanthemum pesticides easy to degrade, and it is used in the soil where organophosphorus pesticides, chlorophenol pesticides and chrysanthemum pesticides remain. In the water quality of pesticides and chrysanthemum pesticide residues, on the crops and vegetables sprayed with organophosphorus pesticides, chlorophenol pesticides and chrysanthemum pesticides, organophosphorus pesticides, chlorophenol pesticides and chrysanthemum pesticides have a relatively ideal degradation effect.
下面通过实施例说明本发明。The present invention is illustrated by the following examples.
实施例1：将1000克30纳米粒径的二氧化钛粉体(包括金红石型或锐钛矿型或板钛矿型)或1000克碳酸钠[或碳酸氢钠]或1000克氢氧化钠[或氢氧化氨]或1000克50纳米粒径的氧化锌粉体或1000克过氧化钙分别加入到100KG纯水中搅动均匀。使用时用水稀释20倍加入到有机磷农药、氯酚农药及菊脂农药残留的土壤中或有机磷农药、氯酚农药及菊脂农药残留的水质中或有机磷农药、氯酚农药及菊脂农药喷洒后的农作物及蔬菜上，在24小时内有机磷农药、氯酚农药及菊脂农药有较理想的降解效果。Example 1: 1000 grams of titanium dioxide powder (comprising rutile or anatase or brookite) or 1000 grams of sodium carbonate [or sodium bicarbonate] or 1000 grams of sodium hydroxide [or hydrogen Ammonium oxide] or 1000 grams of zinc oxide powder with a particle size of 50 nanometers or 1000 grams of calcium peroxide were added to 100KG pure water and stirred evenly. Dilute 20 times with water and add to the soil with organophosphorus pesticides, chlorophenol pesticides and chrysanthemum pesticide residues or the water quality of organophosphorus pesticides, chlorophenol pesticides and chrysanthemum pesticide residues or organophosphorus pesticides, chlorophenol pesticides and chrysanthemum pesticides On crops and vegetables sprayed with pesticides, organophosphorus pesticides, chlorophenol pesticides and chrysanthemum pesticides have ideal degradation effects within 24 hours.
实施例2：将1000克10纳米粒径的二氧化钛粉体(包括金红石型或锐钛矿型或板钛矿型)或1000克碳酸铵[或碳酸氢铵或碳酸钠]或氢氧化钠[或氢氧化氨]或1000克50纳米粒径的氧化锌粉体或1000克双氧水或有机过氧化物如过氧化苯甲酰或过氧化甲乙酮分别加入到20KG纯水中，搅动均匀，使用时用水稀释50倍，加入到有机磷农药、氯酚农药及菊脂农药残留的土壤中、有机磷农药、氯酚农药及菊脂农药残留的水质中或有机磷农药、氯酚农药及菊脂农药喷洒后的农作物及蔬菜上，在较短时间内有机磷农药、氯酚农药及菊脂农药有较理想的降解效果。将脂肪酸蔗糖脂水溶液用于洗涤残留在农作物及蔬菜上的农药，也有明显的效果。Embodiment 2: the titanium dioxide powder (comprising rutile type or anatase type or brookite type) or 1000 gram ammonium carbonate [or ammonium bicarbonate or sodium carbonate] or sodium hydroxide [or Ammonium hydroxide] or 1000 grams of zinc oxide powder with a particle size of 50 nanometers or 1000 grams of hydrogen peroxide or organic peroxides such as benzoyl peroxide or methyl ethyl ketone peroxide were added to 20KG pure water, stirred evenly, and diluted with water when used 50 times, added to the soil with organophosphorus pesticides, chlorophenol pesticides and chrysanthemum pesticide residues, in the water quality of organophosphorus pesticides, chlorophenol pesticides and chrysanthemum pesticide residues, or after spraying with organophosphorus pesticides, chlorophenol pesticides and chrysanthemum pesticides On crops and vegetables, organophosphorus pesticides, chlorophenol pesticides and chrysanthemum pesticides have ideal degradation effects in a short period of time. The fatty acid sucrose lipid aqueous solution is used to wash the pesticides remaining on the crops and vegetables, which also has obvious effects.
实施例3：使用臭氧发生器按每分钟0.1-0.5G的量向农药污染的水质和蔬菜的洗涤水中加入臭氧，上述残留农药能在更短的时间内降解。Embodiment 3: Use an ozone generator to add ozone to the water quality polluted by pesticides and the washing water of vegetables in an amount of 0.1-0.5G per minute, and the above-mentioned residual pesticides can be degraded in a shorter time.
本实施例中过氧化钙可改用金属或碱土金属过氧化物。Calcium peroxide can use metal or alkaline earth metal peroxide instead in the present embodiment.
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Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA021353093A CN1468937A (en) | 2002-07-18 | 2002-07-18 | Residual pesticide degrading agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA021353093A CN1468937A (en) | 2002-07-18 | 2002-07-18 | Residual pesticide degrading agent |
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| Publication Number | Publication Date |
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| CN1468937A true CN1468937A (en) | 2004-01-21 |
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Cited By (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1312050C (en) * | 2004-10-28 | 2007-04-25 | 上海交通大学 | Method for light catalytic degrading carbamate pesticide in water |
| CN101948886A (en) * | 2010-07-27 | 2011-01-19 | 华东理工大学 | Pesticide residue degradation agent, vitamin PP homologue and vitamin B derivative |
| CN102499335A (en) * | 2011-11-15 | 2012-06-20 | 湖南农业大学 | Method for degrading organophosphorus pesticide in fruits and vegetables with nanometer degradation agent |
| CN103081898A (en) * | 2012-10-17 | 2013-05-08 | 王浅肃 | Pesticide residue remover for agricultural products |
| CN103081905A (en) * | 2012-10-17 | 2013-05-08 | 王浅肃 | Preparation method of pesticide residue toxinicide for agricultural products |
| CN103081904A (en) * | 2012-10-17 | 2013-05-08 | 王浅肃 | Pesticide residue toxinicide for agricultural products |
| CN103081902A (en) * | 2012-10-17 | 2013-05-08 | 王浅肃 | Method for detoxicating pesticide residue |
| CN103081903A (en) * | 2012-10-17 | 2013-05-08 | 王浅肃 | Pesticide residue remover for agricultural products |
| CN103081734A (en) * | 2012-10-17 | 2013-05-08 | 王浅肃 | Method for removing pesticide residues |
| CN103081897A (en) * | 2012-10-17 | 2013-05-08 | 王浅肃 | Preparation method of pesticide residue remover |
| CN103081901A (en) * | 2012-10-17 | 2013-05-08 | 王浅肃 | Preparation method of pesticide residue degrading agent |
| CN103081733A (en) * | 2012-10-17 | 2013-05-08 | 王浅肃 | Method for eliminating pesticide residues |
| CN103081899A (en) * | 2012-10-17 | 2013-05-08 | 王浅肃 | Preparation method of pesticide residue remover |
| CN103141449A (en) * | 2013-02-26 | 2013-06-12 | 苏州大学 | Method for improving organophosphorus pesticide resistance of silkworms |
| CN103155915A (en) * | 2013-02-04 | 2013-06-19 | 中国科学院合肥物质科学研究院 | Novel high-efficiency method for controlling flow-away and degradation of pesticides |
| CN104531157A (en) * | 2014-12-09 | 2015-04-22 | 江苏盖亚环境工程有限公司 | Soil remediation agent for removing organic phosphorus pollution, preparation method and applications thereof |
| CN105815330A (en) * | 2016-04-27 | 2016-08-03 | 贺州学院 | Nanometer titanium dioxide composite cypermethrin pesticide and preparation method thereof |
| CN105851001A (en) * | 2016-04-27 | 2016-08-17 | 贺州学院 | Nano titanium dioxide compound chlorpyrifos pesticide and preparation method thereof |
| CN105851000A (en) * | 2016-04-27 | 2016-08-17 | 贺州学院 | Nano titanium dioxide compound abamectin pesticide and preparation method thereof |
| CN105994344A (en) * | 2016-06-06 | 2016-10-12 | 佛山市聚成生化技术研发有限公司 | Preparation method of pyrethroid degradable pesticide insecticide and pesticide insecticide prepared by method |
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2002
- 2002-07-18 CN CNA021353093A patent/CN1468937A/en active Pending
Cited By (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1312050C (en) * | 2004-10-28 | 2007-04-25 | 上海交通大学 | Method for light catalytic degrading carbamate pesticide in water |
| CN101948886A (en) * | 2010-07-27 | 2011-01-19 | 华东理工大学 | Pesticide residue degradation agent, vitamin PP homologue and vitamin B derivative |
| CN101948886B (en) * | 2010-07-27 | 2013-10-30 | 华东理工大学 | Pesticide residue degradation agent, vitamin PP homologue and vitamin B derivative |
| CN102499335A (en) * | 2011-11-15 | 2012-06-20 | 湖南农业大学 | Method for degrading organophosphorus pesticide in fruits and vegetables with nanometer degradation agent |
| CN103081902A (en) * | 2012-10-17 | 2013-05-08 | 王浅肃 | Method for detoxicating pesticide residue |
| CN103081904A (en) * | 2012-10-17 | 2013-05-08 | 王浅肃 | Pesticide residue toxinicide for agricultural products |
| CN103081905A (en) * | 2012-10-17 | 2013-05-08 | 王浅肃 | Preparation method of pesticide residue toxinicide for agricultural products |
| CN103081903A (en) * | 2012-10-17 | 2013-05-08 | 王浅肃 | Pesticide residue remover for agricultural products |
| CN103081734A (en) * | 2012-10-17 | 2013-05-08 | 王浅肃 | Method for removing pesticide residues |
| CN103081897A (en) * | 2012-10-17 | 2013-05-08 | 王浅肃 | Preparation method of pesticide residue remover |
| CN103081901A (en) * | 2012-10-17 | 2013-05-08 | 王浅肃 | Preparation method of pesticide residue degrading agent |
| CN103081733A (en) * | 2012-10-17 | 2013-05-08 | 王浅肃 | Method for eliminating pesticide residues |
| CN103081899A (en) * | 2012-10-17 | 2013-05-08 | 王浅肃 | Preparation method of pesticide residue remover |
| CN103081898A (en) * | 2012-10-17 | 2013-05-08 | 王浅肃 | Pesticide residue remover for agricultural products |
| CN103155915A (en) * | 2013-02-04 | 2013-06-19 | 中国科学院合肥物质科学研究院 | Novel high-efficiency method for controlling flow-away and degradation of pesticides |
| CN103155915B (en) * | 2013-02-04 | 2014-06-04 | 中国科学院合肥物质科学研究院 | Novel high-efficiency method for controlling flow-away and degradation of pesticides |
| CN103141449A (en) * | 2013-02-26 | 2013-06-12 | 苏州大学 | Method for improving organophosphorus pesticide resistance of silkworms |
| CN103141449B (en) * | 2013-02-26 | 2014-07-16 | 苏州大学 | Method for improving organophosphorus pesticide resistance of silkworms |
| CN104531157A (en) * | 2014-12-09 | 2015-04-22 | 江苏盖亚环境工程有限公司 | Soil remediation agent for removing organic phosphorus pollution, preparation method and applications thereof |
| CN105851000A (en) * | 2016-04-27 | 2016-08-17 | 贺州学院 | Nano titanium dioxide compound abamectin pesticide and preparation method thereof |
| CN105851001A (en) * | 2016-04-27 | 2016-08-17 | 贺州学院 | Nano titanium dioxide compound chlorpyrifos pesticide and preparation method thereof |
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| CN105994344A (en) * | 2016-06-06 | 2016-10-12 | 佛山市聚成生化技术研发有限公司 | Preparation method of pyrethroid degradable pesticide insecticide and pesticide insecticide prepared by method |
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