CN1468890A - A carbon fiber reinforced friction material and its preparation method - Google Patents

A carbon fiber reinforced friction material and its preparation method Download PDF

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Publication number
CN1468890A
CN1468890A CNA031124216A CN03112421A CN1468890A CN 1468890 A CN1468890 A CN 1468890A CN A031124216 A CNA031124216 A CN A031124216A CN 03112421 A CN03112421 A CN 03112421A CN 1468890 A CN1468890 A CN 1468890A
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Prior art keywords
fiber
carbon fiber
fiber reinforced
preparation
fibre
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CNA031124216A
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王成国
王海庆
庄光山
孙毅
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Shandong University
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Shandong University
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Abstract

本发明属于新材料领域,特别是涉及一种适用于制作汽车和火车刹车片的碳纤维增强摩阻材料及其制备方法。本发明的碳纤维增强摩阻材料由增强纤维、基体树脂、摩擦性能调节剂组成,其特征是增强纤维为碳纤维、金属纤维和无机矿物纤维的混合物,基体树脂是水乳胶改性酚醛树脂,摩擦性能调节剂采用硫酸钡、三氧化二铁、四氧化三铁、三氯化铁、氧化镁、二氧化硅中的至少两种;制备方法包含混料工序、预烘工序、压制工序和后处理工序。该碳纤维增强摩阻材料摩阻性能良好而且制备过程无污染。The invention belongs to the field of new materials, in particular to a carbon fiber reinforced friction material suitable for making automobile and train brake pads and a preparation method thereof. The carbon fiber reinforced friction material of the present invention is made up of reinforcing fiber, matrix resin, friction performance regulator, is characterized in that reinforcing fiber is the mixture of carbon fiber, metal fiber and inorganic mineral fiber, matrix resin is water latex modified phenolic resin, friction performance The regulator uses at least two of barium sulfate, ferric oxide, ferric oxide, ferric chloride, magnesium oxide, and silicon dioxide; the preparation method includes a mixing process, a pre-baking process, a pressing process and a post-treatment process . The carbon fiber reinforced friction material has good friction performance and no pollution in the preparation process.

Description

A kind of carbon fiber reinforced friction resistance material and preparation method thereof
Technical field
The invention belongs to field of new, particularly relate to a kind of carbon fiber reinforced friction resistance material that is applicable to making automobile and train braking sheet and preparation method thereof.
Background technology
Brake facing is the key part that is related to car brakeing security and stationarity.Wide-scale adoption at beginning of the eighties semi-metallic brake pad.The semi-metallic brake pad material can be adjusted frictional behaviour, thermal characteristics and the mechanical property of material within the specific limits by changing prescription and technology.But there are fatal " three heat " defectives such as heat fading, thermal expansion and thermal crack in semi-metallic brake pad in braking procedure, the braking of running at high speed down can produce very heavy spark, and its brake noise is big.Therefore the current micro-metal brake pad that progressively uses both at home and abroad, and pay much attention to the application of carbon fiber brake facing on heavy duty, the vehicle of running at high speed.The patent No. is the Chinese patent of CN1142024 disclosed " carbon fiber strengthens disk-type braking gland of automobile and preparation thereof ", the employing weight ratio is the disk-type braking gland of carbon fiber (5-15%)/glass fibre (15-20%)/steel fiber (0-5%) conjugated fibre hybrid systems preparation, goods have been overcome 300 ℃ of heat fading phenomenons that produced, but it adopts traditional heat-resistant fireproof resin to make tackiness agent, and there is the defective that fragility is bigger than normal, hardness is higher in the product of manufacturing; The patent No. is another Chinese patent of CN1209381 disclosed " rubber multi-component composite brake shoe and a manufacture method thereof ", adopted the composite brake shoe of metal primitive fiber and carbon fiber preparation, be to utilize rubber to be adhesive composition, its thermotolerance is poor slightly, and moulding process is also comparatively loaded down with trivial details.
Summary of the invention
The objective of the invention is to overcome above-mentioned the deficiencies in the prior art, provide the free of contamination novel carbon fiber of a kind of functional, preparation process to strengthen friction resistance material and preparation method thereof.
The present invention realizes in the following manner:
A kind of carbon fiber reinforced friction resistance material, form by fortifying fibre, matrix resin, frictional property regulator, it is characterized in that fortifying fibre is the mixture of carbon fiber, steel fiber and inorganic mineral fiber, matrix resin is the water emulsion modified phenolic resins, and frictional property regulator adopts at least two kinds in barium sulfate, ferric oxide, Z 250, iron trichloride, magnesium oxide, the silicon-dioxide; The weight percent of each component concentration is: matrix resin content 15-30%, reinforced fiber content 30-50%, frictional property regulator are 20-35%.
Above-mentioned carbon fiber reinforced friction resistance material, it is characterized in that steel fiber is at least a in steel fiber, copper fiber, aluminum fiber, cast fiber and the Stainless Steel Fibre, inorganic mineral fiber is at least a in sepiolite fibre, wollastonite fibre, rock wool, sillimanite fiber and the polygorskite fiber.
Above-mentioned carbon fiber reinforced friction resistance material, the weight percent that it is characterized in that each component in the fortifying fibre is carbon fiber 20-35%, steel fiber 20-35%, inorganic mineral fiber 30-50%.
The preparation method of above-mentioned carbon fiber reinforced friction resistance material is characterized in that may further comprise the steps:
(1) compounding process: earlier with water emulsion modified phenolic resins, carbon fiber, steel fiber, inorganic fibre uniform mixing, at least two kinds of compositions that gradation is afterwards added in frictional property regulator barium sulfate, ferric oxide, Z 250, iron trichloride, magnesium oxide, the silicon-dioxide are made molding compound;
(2) preliminary drying operation: with the shredding of molding compound elder generation, then low molecular fugitive constituent is wherein removed, bake out temperature is preferably 100 ± 5 ℃, and the preliminary drying time is 20-40 minute;
(3) suppression process: molding compound is added in the mould pressurized, heated until solidifying and take out product from mould, mold temperature 160-200 ℃, forming pressure 30-35 MPa, molding time 2.0-3.0 minute/millimeter;
(4) postprocessing working procedures: product put into baking oven or vulcanizing oven carry out after fixing or thermal stresses is eliminated in sulfuration, after warm treatment temp at 160-180 ℃, 10 minutes/millimeter aftertreatment time.
In the material prescription system of the present invention, enhancement component adopts carbon fiber and steel fiber and inorganic mineral fiber etc. to mix, carbon fiber antifriction light weight, steel fiber high-strength heat conduction, advantage that the heat-resisting valency of inorganic fibre is low have been given full play to, can form the random crossover network that fiber is barricaded as, guarantee that from microtexture the friction resistance material of making has good braking ability, mechanical property and thermal characteristics.
Resin system of the present invention adopts the water-emulsion-based modified phenolic resins, utilizes the crosslinking reaction between the polymer to realize phenolic resin curing.And when being tackiness agent with the modified phenolic purely, in brake(-holder) block compression moulding process, discharge micro-molecular gas because of phenolic aldehyde generation polycondensation meeting, thereby be easy to blebbing during fabrication and cause the scrap rate height, and aerogenesis such as further polycondensation and heat scission reaction in use can take place in it because of phenolic aldehyde, cause cracking, fall slag and produce yield and split.And not having pollutions such as dust and organism volatilization when adopting water-emulsion-based resin system batch mixing, the low discharge quantity of hot pressing can guarantee that the goods bubbling that do not ftracture, the low splitting gas of use discharge and can guarantee to fall piece, fall slag, yield splits etc.Therefore the material that is made by this method has good braking characteristic and life-time service good reliability.
Embodiment
Provide most preferred embodiment of the present invention below.
Embodiment 1: 30 kilograms water emulsion modified phenolics as matrix resin, are mixed mutually with the fortifying fibre of being made up of 12 kg of carbon fibers, 13 kilograms of metallic steel fibers, 15 kilograms of sepiolite fibres; Add frictional property regulator (8 kilograms in barium sulfate, 6 kilograms of ferric oxide, 4 kilograms of iron trichlorides, 2 kilograms of silica 1s) afterwards, and mix thoroughly; Put into teaser shredding molding compound again;
Preheating procedure adopts hot-air seasoning, with the shredding of molding compound elder generation, then low molecular fugitive constituent is wherein removed, and bake out temperature is 100 ± 5 ℃, and the preliminary drying time is 30 minutes.Mold temperature is grasped at 180 ℃, and forming pressure is grasped in 35 MPas, molding time 2.5 minutes/millimeter; At last product is put into that baking oven or vulcanizing oven carry out after fixing or thermal stresses is eliminated in sulfuration, after warm treatment temp at 160-180 ℃, 10 minutes/millimeter aftertreatment time.
Carbon fiber brake facing provided by the invention, Materials Company of process Ministry of Railways friction materials measuring station is at the TOYO of Japanese import DENKI SEII K.K.The test of 1: 1 brake power testing table (TYPE:G6032M-A), results such as its stopping distance, brake stopping time, surface temperature rise, watering test, ramp speed governing test, stiction test have reached the relevant technologies requirement of the disc brake sheet of vehicle office of the Ministry of Railways (No. the 88th, a skill 1997) files specify.
Embodiment 2: the water emulsion modified phenolic of getting 30 kilograms is as matrix resin, mix mutually with the fortifying fibre of forming by 12 kg of carbon fibers, 15 kilograms of metallic steel fibers, 15 kilograms of sepiolite fibres, add frictional property regulator (9 kilograms in barium sulfate, 9 kilograms of ferric oxide, 3 kilograms of iron trichlorides, 7 kilograms of silicon-dioxide) afterwards, and mix thoroughly, put into teaser shredding molding compound again;
The preheating procedure hot-air seasoning with the shredding of molding compound elder generation, is removed low molecular fugitive constituent wherein then, and bake out temperature is 100 ± 5 ℃, and the preliminary drying time is 40 minutes; Mold temperature is grasped at 175 ℃, and forming pressure is grasped in 30 MPas, molding time 2.5 minutes/millimeter; At last product is put into that baking oven or vulcanizing oven carry out after fixing or thermal stresses is eliminated in sulfuration, after warm treatment temp at 160-180 ℃, 10 minutes/millimeter aftertreatment time.
Carbon fiber brake facing provided by the invention reaches the requirement of GB5763-1998 fully through the D-MS constant speed experimental machine test at Xianyang country friction materials quality examination center in every indexs such as the frictional coefficient at each temperature of testing regulation, wear rate, permission frictional coefficient deviations.

Claims (4)

1, a kind of carbon fiber reinforced friction resistance material, form by fortifying fibre, matrix resin, frictional property regulator, it is characterized in that fortifying fibre is the mixture of carbon fiber, steel fiber and inorganic mineral fiber, matrix resin is the water emulsion modified phenolic resins, and frictional property regulator adopts at least two kinds in barium sulfate, ferric oxide, Z 250, iron trichloride, magnesium oxide, the silicon-dioxide; The weight percent of each component concentration is: matrix resin content 15-30%, reinforced fiber content 30-50%, frictional property regulator are 20-35%.
2, claim 1 described carbon fiber reinforced friction resistance material, it is characterized in that steel fiber is at least a in steel fiber, copper fiber, aluminum fiber, cast fiber and the Stainless Steel Fibre, inorganic mineral fiber is at least a in sepiolite fibre, wollastonite fibre, rock wool, sillimanite fiber and the polygorskite fiber.
3, according to claim 1 or 2 described carbon fiber reinforced friction resistance material, the weight percent that it is characterized in that each component in the fortifying fibre is carbon fiber 20-35%, steel fiber 20-35%, inorganic mineral fiber 30-50%.
4,, it is characterized in that may further comprise the steps according to the preparation method of the described carbon fiber reinforced friction resistance material of claim 1-3:
(1) compounding process: earlier with water emulsion modified phenolic resins, carbon fiber, steel fiber, inorganic mineral fiber uniform mixing, at least two kinds of compositions that gradation is afterwards added in frictional property regulator barium sulfate, ferric oxide, Z 250, iron trichloride, magnesium oxide, the silicon-dioxide are made molding compound;
(2) preliminary drying operation: with the shredding of molding compound elder generation, then low molecular fugitive constituent is wherein removed, bake out temperature is 100 ± 5 ℃, and the preliminary drying time is 20-40 minute;
(3) suppression process: molding compound is added in the mould pressurized, heated until solidifying and take out product from mould, mold temperature 160-200 ℃, forming pressure 30-35 MPa, molding time 2.0-3.0 minute/millimeter;
(4) postprocessing working procedures: product put into baking oven or vulcanizing oven carry out after fixing or thermal stresses is eliminated in sulfuration, after warm treatment temp at 160-180 ℃, 10 minutes/millimeter aftertreatment time.
CNA031124216A 2003-06-12 2003-06-12 A carbon fiber reinforced friction material and its preparation method Pending CN1468890A (en)

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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100340592C (en) * 2004-11-11 2007-10-03 西安交通大学 Doublelayer paper base friction material and friction plate making method
CN100389093C (en) * 2006-08-31 2008-05-21 杜亮 Metal-free ceramic-type brake plate and processing method
CN100463949C (en) * 2007-02-14 2009-02-25 西北工业大学 Flexible paper-based friction material
CN100465135C (en) * 2004-04-23 2009-03-04 丰田自动车株式会社 Carbon composite material comprising metal carbide particles dispersed therein and method of making the same
CN101982427A (en) * 2010-10-25 2011-03-02 四川城际轨道交通材料有限责任公司 Method for modifying composite surface of carbon fiber
CN102796268A (en) * 2012-08-24 2012-11-28 缪卫巍 Preparation method of friction material with good running-in performance
CN102796269A (en) * 2012-08-24 2012-11-28 缪卫巍 Preparation method of friction material less wearing mating plate
CN102807844A (en) * 2012-08-24 2012-12-05 缪卫巍 Friction material slightly wearing mating plate
CN104592709A (en) * 2014-10-13 2015-05-06 杭州桑拉科技有限公司 Novel composite fiber-reinforced damping friction-resistant material and preparation method thereof
CN105546002A (en) * 2016-02-29 2016-05-04 天长市天航摩擦材料有限公司 Manufacturing method for environment-friendly high-performance brake pad
CN105605131A (en) * 2016-02-29 2016-05-25 天长市天航摩擦材料有限公司 Manufacturing method of brake pad for heavy machine
CN106151331A (en) * 2016-06-27 2016-11-23 杭州桑拉科技有限公司 A kind of electric car automatic speed transmission Wet-type friction slice and preparation method thereof
CN106188623A (en) * 2016-07-12 2016-12-07 江苏瑞科高新材料有限公司 A kind of composite reinforcing fiber and preparation technology thereof
CN109608821A (en) * 2018-12-25 2019-04-12 邱华英 A kind of preparation method of high tenacity transmission brake material
CN114196159A (en) * 2021-11-15 2022-03-18 泰山体育产业集团有限公司 Layered carbon fiber reinforced friction material and preparation process thereof
CN115678202A (en) * 2022-12-29 2023-02-03 沈阳远程摩擦密封材料有限公司 Composite brake shoe and preparation method thereof

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100465135C (en) * 2004-04-23 2009-03-04 丰田自动车株式会社 Carbon composite material comprising metal carbide particles dispersed therein and method of making the same
CN100340592C (en) * 2004-11-11 2007-10-03 西安交通大学 Doublelayer paper base friction material and friction plate making method
CN100389093C (en) * 2006-08-31 2008-05-21 杜亮 Metal-free ceramic-type brake plate and processing method
CN100463949C (en) * 2007-02-14 2009-02-25 西北工业大学 Flexible paper-based friction material
CN101982427A (en) * 2010-10-25 2011-03-02 四川城际轨道交通材料有限责任公司 Method for modifying composite surface of carbon fiber
CN102796268B (en) * 2012-08-24 2015-03-11 朱育盼 Preparation method of friction material with good running-in performance
CN102796269A (en) * 2012-08-24 2012-11-28 缪卫巍 Preparation method of friction material less wearing mating plate
CN102807844A (en) * 2012-08-24 2012-12-05 缪卫巍 Friction material slightly wearing mating plate
CN102796268A (en) * 2012-08-24 2012-11-28 缪卫巍 Preparation method of friction material with good running-in performance
CN102796269B (en) * 2012-08-24 2015-07-15 李露青 Preparation method of friction material less wearing mating plate
CN104592709A (en) * 2014-10-13 2015-05-06 杭州桑拉科技有限公司 Novel composite fiber-reinforced damping friction-resistant material and preparation method thereof
CN105546002A (en) * 2016-02-29 2016-05-04 天长市天航摩擦材料有限公司 Manufacturing method for environment-friendly high-performance brake pad
CN105605131A (en) * 2016-02-29 2016-05-25 天长市天航摩擦材料有限公司 Manufacturing method of brake pad for heavy machine
CN106151331A (en) * 2016-06-27 2016-11-23 杭州桑拉科技有限公司 A kind of electric car automatic speed transmission Wet-type friction slice and preparation method thereof
CN106188623A (en) * 2016-07-12 2016-12-07 江苏瑞科高新材料有限公司 A kind of composite reinforcing fiber and preparation technology thereof
CN109608821A (en) * 2018-12-25 2019-04-12 邱华英 A kind of preparation method of high tenacity transmission brake material
CN114196159A (en) * 2021-11-15 2022-03-18 泰山体育产业集团有限公司 Layered carbon fiber reinforced friction material and preparation process thereof
CN115678202A (en) * 2022-12-29 2023-02-03 沈阳远程摩擦密封材料有限公司 Composite brake shoe and preparation method thereof

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