CN1463935A - Environment-friendly water quality stabilizer - Google Patents

Environment-friendly water quality stabilizer Download PDF

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Publication number
CN1463935A
CN1463935A CN02113837A CN02113837A CN1463935A CN 1463935 A CN1463935 A CN 1463935A CN 02113837 A CN02113837 A CN 02113837A CN 02113837 A CN02113837 A CN 02113837A CN 1463935 A CN1463935 A CN 1463935A
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China
Prior art keywords
acid
water
water conditioner
described water
conditioner
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Granted
Application number
CN02113837A
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Chinese (zh)
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CN1289411C (en
Inventor
冯李文
刘政
李莉
袁秋礼
何玉涛
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CHUANHUA GROUP Co Ltd
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CHUANHUA GROUP Co Ltd
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Priority to CNB021138370A priority Critical patent/CN1289411C/en
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Publication of CN1289411C publication Critical patent/CN1289411C/en
Anticipated expiration legal-status Critical
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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F14/00—Inhibiting incrustation in apparatus for heating liquids for physical or chemical purposes
    • C23F14/02—Inhibiting incrustation in apparatus for heating liquids for physical or chemical purposes by chemical means

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

The environment protecting water quality stabilizer consists of scale inhibitor, corrosion inhibitor, assistant compounded together, and has the features of high efficiency, low toxicity and environment friendship. The water treating agent may be used in water system to produce corrosion inhibiting and scale inhibiting dispersion effect and may be used in the conditions of high hardness, high pH and high concentration multiple. The water treating agent may be used in circulating cooling water system with calcium hardness up to 750-1300 ppm, and in make-up water calcium hardness of 120 ppm, the concentration multiple may reach 10, being in zero-exhaust level.

Description

A kind of environment-friendly type water quality stablizer
One, technical field
The present invention be a kind of apply to rise in the water system scale inhibition disperses and efficient and environment-friendly type water conditioner, the especially high concentration multiple of corrosion inhibition, high rigidity, high pH value condition under the water conditioner used of recirculating cooling water system.
Two, technical background
Cooling water system comprises heat exchanger, cooling tower, pump and cooling water pipeline.In the cooling water system operational process, the metallic surface of the heat exchanger that contacts with water coolant, pipeline, pump etc. can produce problems such as burn into fouling, sludge blockage, thereby influences the heat exchange efficiency of heat exchanger and service life of equipment etc.
Dirt in the cooling water system can have different dirts because of different systems.Dirt in the cooling water system generally has carbonate, phosphoric acid salt, silicate scale, metal oxide dirt, foundry loam and organic deposition, particularly carbonate scale and the foundry loam of calcium magnesium.Be high phosphorated with the water conditioner major part now, improper use can produce the phosphoric acid salt dirt deposition; The sewage of discharging is because of phosphorous too high polluting the environment.Dirt deposition can reduce heat exchange efficiency in the metallic surface.
The electrochemical action of the free metal ion in the water coolant and the oxygenizement of free oxygen can cause corrosion of metal and form the corrosion product dirt.Dirt deposition can form underdeposit corrosion in the metallic surface.
In order to slow down problems such as burn into fouling, sludgd deposition, in water coolant, add water conditioner usually, play the effect of corrosion-mitigation scale-inhibition dispersive, make cooling water system can be effectively, operation stably.
In recirculating cooling water system, in order to reach the purpose of high-level efficiency, low consumption operation, require recirculated cooling water moving than under the high concentration multiple, promptly reach at least more than 3.0 times, even reach 6.0～10 times zero blowdown level.
The water quality stabilizer kind that is used for water system at present is more, when using single anti-incrustation corrosion inhibitor, cooling water system is difficult at high concentration multiple, moves under the condition of high pH value, do not reach the purpose of equipment corrosion in the Controlling System, fouling, sludgd deposition, thereby influence the normal operation of system; Use composite water disposal agent, because of the difference of filling a prescription, result of use is widely different.General composite water disposal agent can reach 3.0 times cycles of concentration in recirculating cooling water system, but can reach 6.0～10 times of cycles of concentration, and environment amenable water conditioner is few.
The poly aspartic acid (PASP) of U.S. Donlar company development; Poly-amino-polyether base methylenephosphonic acid (PAPEMP) (" process water and the waste water " 2000 of Cagon company exploitation, " recirculated cooling water is handled the progress of new chemical agent " in 31 (6)) water treatment agent monomer, have efficient, environment amenable feature, but do not see the composite water disposal agent report identical with the present invention.
Three, summary of the invention
The present invention will design a kind of efficient, low toxicity and environment amenable compound prescription type water conditioner.
Composition of the present invention is the water conditioner based on poly aspartic acid, polyamino polyether base methylenephosphonic acid, vinylformic acid-acrylate-phosphonic acids-sulfonic acid tetrapolymer; According to concrete utilization field or condition, add not other medicaments of same-action again, constitute the water conditioner that serves many purposes.
The present invention utilizes the water conditioner monomer, by the different separately mechanism of action, utilizes rational compounded technology, gives full play to the synergy between each monomer, designs compound prescription type anti-incrustation corrosion inhibitor.Selective water conditioner monomer have: poly aspartic acid (PASP), polyamino polyether base methylenephosphonic acid (PAPEMP), two hexamethylene triamine pentamethylene phosphonic acids (BHMT), phosphono-carboxylic acids (POCA), polyvalent alcohol phosphonic acid ester (PAPE), phosphine carboxylic acid (PBTCA), 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid (HEDP), Amino Trimethylene Phosphonic Acid (ATMP), 2-hydroxyl phosphino-acetate (HPA), polyacrylic acid (PAA), the phosphonate group polymers of carboxylic acid, the phosphino-polymaleic acid, vinylformic acid-methyl acrylate copolymer, vinylformic acid-Propylene glycol monoacrylate multipolymer, vinylformic acid-Propylene glycol monoacrylate terpolymer, vinylformic acid-sulfonic acid based terpolymers, vinylformic acid-Propylene glycol monoacrylate-sulfonic acid terpolymer, vinylformic acid-acrylate-phosphoric acid-sulfonic acid tetrapolymer, benzotriazole (BTA), mercaptobenzothiazole (MBT), Methylbenzotriazole (TTA), tripoly phosphate sodium STPP, Sodium hexametaphosphate 99, zinc sulfate, zinc chloride etc.; Auxiliary: water, sulfuric acid, hydrochloric acid, citric acid, dimethyl formamide, ethanol etc.
The poly aspartic acid that uses among the present invention have good to alkaline earth metal carbonate, vitriol restraining effect and to the corrosion inhibition of metal; And poly aspartic acid is not phosphorous, biodegradable, is a kind of environment amenable anti-incrustation corrosion inhibitor.
Vinylformic acid-the acrylate that uses among the present invention-phosphoric acid-sulfonic acid tetrapolymer is the multipolymer that contains groups such as carboxyl, hydroxyl, phosphono, sulfonic group.Prevent that carbonate, phosphatoptosis effect are good, can also stably dispersing zinc, metal ion such as iron, and be fit in extensive range.
The polyamino polyether base methylenephosphonic acid that uses among the present invention has good restraining effect to lime carbonate, calcium sulfate and silicon dirt; Can also stablize metal ions such as zinc, iron, manganese well.
In the water system that carbon steel, stainless steel are arranged, the available water conditioner of forming by poly aspartic acid, polyamino polyether base methylenephosphonic acid, vinylformic acid-acrylate-phosphonic acids-sulfonic acid tetrapolymer, 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid, phosphine carboxylic acid and a kind of zinc salt.Zinc salt is selected from zinc sulfate, zinc chloride.In the circulating water system of high concentration multiple utilization, can not add zinc salt.
In the water system that carbon steel, stainless steel, copper material are arranged, the available water conditioner of forming by poly aspartic acid, polyamino polyether base methylenephosphonic acid, vinylformic acid-acrylate-phosphonic acids-sulfonic acid tetrapolymer, 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid, phosphine carboxylic acid, at least a copper inhibitor and a kind of zinc salt.Copper inhibitor is selected from Methylbenzotriazole, benzotriazole, mercaptobenzothiazole; Zinc salt is selected from zinc sulfate, zinc chloride.In the circulating water system of high concentration multiple utilization, can not add zinc salt.
When in water conditioner, copper inhibitor being arranged, need to add at least a organic solvent and solve copper inhibitor and the immiscible problem of other water conditioner monomers.Organic solvent is selected from dimethyl formamide, ethanol.
When in water conditioner, zinc salt being arranged, need to add at least a mineral acid or organic acid and solve water conditioner when depositing for a long time, the easy sedimentary problem of zinc salt.Mineral acid is selected from hydrochloric acid, sulfuric acid; Organic acid is selected from formic acid, oxalic acid, citric acid.
The water conditioner that applies to the different ingredients under the different condition among the present invention all contains poly aspartic acid, polyamino polyether base methylenephosphonic acid, vinylformic acid-acrylate-phosphonic acids-three kinds of materials of sulfonic acid tetrapolymer at least, and as the master.Several water conditioners of different ingredients all are low phosphorous among the present invention, low toxicity or nontoxic, environment amenable water conditioner, and all have performance that stops carbonate, phosphoric acid salt, silicate deposit and dispersion foundry loam, suspended substance and carbonate, phosphoric acid salt, silicate colony efficiently and the performance that efficiently suppresses metallic corrosion.
Water conditioner of the present invention applies to cooling water system, boiler water system, reverse osmosis water treatment system, oil-gas-water treating system.Can under the condition of high rigidity, high pH value, high concentration multiple, stablize utilization.
Water conditioner of the present invention is when applying to recirculating cooling water system, and the calcium hardness in the recirculated cooling water (in lime carbonate) can reach 750ppm～1300ppm.In make up water calcium hardness 120ppm, cycles of concentration can reach 10 times.When from theory and practice, obtaining the recirculating cooling water system cycles of concentration and reaching 8～10 times, be in the level of zero blowdown.
Four, embodiment
Embodiment 1:
Produce the 100g water conditioner
In reaction flask, add 10g vinylformic acid-acrylate-phosphoric acid-sulfonic acid tetrapolymer, 50g poly aspartic acid, 25g polyamino polyether base methylenephosphonic acid, 10g phosphine carboxylic acid, the 5g 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid, after certain temperature stirs certain hour, promptly make water conditioner 100g.
Embodiment 2:
Produce the 100g water conditioner
Add 5g solid zinc chloride and 5g hydrochloric acid in 10g water, stirring and dissolving adds 5g phosphine carboxylic acid then, 3g 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid, 10g vinylformic acid-acrylate-phosphoric acid-sulfonic acid tetrapolymer, 42g poly aspartic acid, 20g polyamino polyether base methylenephosphonic acid.After in reaction flask, stirring, promptly make water conditioner 100g.
Embodiment 3:
Produce the 1000kg water conditioner
In 60kg water, add 60kg ethanol and 10kg dimethyl formamide, mix the back and add the 10kg Methylbenzotriazole, stir, add 100kg vinylformic acid-acrylate-phosphoric acid-sulfonic acid tetrapolymer, 450kg poly aspartic acid, 250kg polyamino polyether base methylenephosphonic acid, 40kg phosphine carboxylic acid then, the 20kg 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid.After in reactor, stirring certain hour, promptly make water conditioner 1000kg.Embodiment 4:
Produce the 1000kg water conditioner
In 45kg water, add 45kg solid sulphuric acid zinc, stirring and dissolving; Add 45kg ethanol and 10kg dimethyl formamide then, mix the back and add the 10kg Methylbenzotriazole, stir, add 150kg vinylformic acid-acrylate-phosphoric acid-sulfonic acid tetrapolymer, 550kg poly aspartic acid, 100kg polyamino polyether base methylenephosphonic acid, 35kg phosphine carboxylic acid again, the 10kg 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid; After in reactor, stirring certain hour, promptly make water conditioner 1000kg.
Regulation in CNS GB50050-95 " Code for design of industrial recirculating cooling water treatment ": be less than or equal to 0.125mm/a at open type system medium carbon steel corrosion rate, stainless steel, red copper, brass corrosion rate are less than or equal to 0.005mm/a, and the fouling resistance value should be less than 1.72 * 10 -4～3.44 * 10 -4m 2K/W, the recirculating cooling water system cycles of concentration should be greater than 3.0 times.
The water conditioner of producing with embodiment 1 to embodiment 4 uses gained result such as following table:
Embodiment Corrosion of carbon steel rate (mm/a) Corrosion of Stainless Steel rate (mm/a) Copper corrosion rate (mm/a)
Embodiment 1 ??0.0312 ??0.0012 ??/
Embodiment 2 ??0.0129 ??0.0009 ??/
Embodiment 3 ??0.0058 ??0.0010 ??0.0001
Embodiment 4 ??0.0036 ??0.0006 ??0.0003
Water conditioner with embodiment 3 and embodiment 4 carries out dynamic analog test, its result such as following table according to the chemical industry standard HG/T2160-91 of the People's Republic of China (PRC):
Embodiment Hard (the CaCO of calcium 3Meter) mg/l ????pH Cycles of concentration (in calcium) Fouling resistance m 2·K/W
Embodiment 3 ????1200 ????9.00 ????10.0 ??1.21×10 -4
Embodiment 4 ????750 ????9.16 ????6.2 ??3.8×10 -5

Claims (7)

1 one kinds of water conditioners are made up of Scale inhibitors, inhibiter, auxiliary agent etc., it is characterized in that:
Contain poly aspartic acid (PASP), polyamino polyether base methylenephosphonic acid (PAPEMP) and vinylformic acid-acrylate-phosphonic acids-sulfonic acid tetrapolymer.
2 according to the described water conditioner of claim 1, it is characterized in that: also contain 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid (HEDP), phosphine carboxylic acid (PBTCA).
3 according to the described water conditioner of claim 1, it is characterized in that: also contain 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid (HEDP), phosphine carboxylic acid (PBTCA) and at least a zinc salt and at least a mineral acid or organic acid.
4 according to the described water conditioner of claim 3, and it is characterized in that: zinc salt is selected from zinc sulfate, zinc chloride; Mineral acid is selected from hydrochloric acid, sulfuric acid; Organic acid is selected from formic acid, oxalic acid, citric acid.
5 according to the described water conditioner of claim 1, it is characterized in that: also contain 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid (HEDP), phosphine carboxylic acid (PBTCA) and at least a copper inhibitor and at least a organic solvent.
6 according to the described water conditioner of claim 5, it is characterized in that: copper inhibitor is selected from Methylbenzotriazole (TTA), benzotriazole (BTA) and mercaptobenzothiazole (MBT).
7 according to the described water conditioner of claim 5, and it is characterized in that: organic solvent is selected from dimethyl formamide, ethanol.
CNB021138370A 2002-06-07 2002-06-07 Environment-friendly water quality stabilizer Expired - Fee Related CN1289411C (en)

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Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100357331C (en) * 2005-06-15 2007-12-26 北京博泰盛合科技有限公司 Copolymer and its preparation method and reverse osmosis membrane protective agent comprising the copolymer and its uses
CN100509654C (en) * 2004-08-31 2009-07-08 中国石化北京燕化石油化工股份有限公司 Low-phosphorus composite antiincrustation corrosion inhibitor and use for water treatment
CN101172719B (en) * 2006-10-31 2010-12-08 中国石油化工股份有限公司 Dirty blocking inhibitor and application in water treatment thereof
CN102079584A (en) * 2010-12-14 2011-06-01 成都齐达水处理工程股份有限公司 Non-phosphorus scale and corrosion inhibitor, and preparation method and applications thereof
CN101913712B (en) * 2009-07-22 2011-10-05 乌鲁木齐市科发展精细化工有限公司 Low-phosphorous environment-friendly scale inhibitor adapting to 'three-high' water quality and preparation thereof
CN102363538A (en) * 2010-12-07 2012-02-29 新疆德蓝股份有限公司 Preparation of composite corrosion and scale inhibitor for low-hardness circulating cooling water
CN102432112A (en) * 2011-11-01 2012-05-02 中冶建筑研究总院有限公司 Complexing agent
CN101554565B (en) * 2009-04-21 2012-05-02 李洪社 Phosphorus-free reverse osmosis membrane antisludging agent and preparation method thereof
CN102863090A (en) * 2011-07-08 2013-01-09 爱环吴世(苏州)环保有限公司 Corrosion and scale inhibitor for low-hardness water and preparation method thereof
CN103787518A (en) * 2014-01-21 2014-05-14 山东省泰和水处理有限公司 Low-temperature multi-effect sea water desalination scale and corrosion inhibitor
CN103803728A (en) * 2014-02-25 2014-05-21 江苏紫石化工科技有限公司 Dimethyl formamide compound scale inhibitor
CN104355384A (en) * 2014-10-24 2015-02-18 无锡伊佩克科技有限公司 Sewage treatment agent
CN104556427A (en) * 2015-01-15 2015-04-29 鞍钢贝克吉利尼水处理有限公司 Composite efficient corrosion and scale inhibitor for ammonia still water treatment
CN104556420A (en) * 2013-10-12 2015-04-29 中国石油化工股份有限公司 Non-phosphorus composite corrosion and scale inhibitor and preparation method thereof, as well as corrosion and scale inhibition method of circulating cooling water
CN104861948A (en) * 2014-02-21 2015-08-26 中国石油化工股份有限公司 Composition used for increasing polymer solution viscosity, and applications thereof
CN105130019A (en) * 2015-07-13 2015-12-09 鞍钢贝克吉利尼水处理有限公司 High-effective composite corrosion and scale inhibitor being suitable for high-calcium and -alkali water and preparation method thereof
CN105217806A (en) * 2015-10-13 2016-01-06 武汉钢铁(集团)公司 Circulating water corrosion inhibitor and application thereof
CN106495248A (en) * 2016-11-26 2017-03-15 王晓东 A kind of water process zero-emission controlling agent and method for treating water
CN107720984A (en) * 2017-10-17 2018-02-23 高产明 A kind of preparation method of the low-phosphorous water quality stabilizer of efficient scale corrosion inhibition type
CN108483686A (en) * 2018-04-09 2018-09-04 翟琳 A kind of corrosion inhibition type antisludging agent
CN110104805A (en) * 2019-03-25 2019-08-09 大唐双鸭山热电有限公司 A method of reducing thermal power plant recirculated cooling water utilization rate
CN110127870A (en) * 2019-03-25 2019-08-16 大唐双鸭山热电有限公司 A kind of thermal power plant circulating water cooling treatment composite drug
CN112094633A (en) * 2020-10-29 2020-12-18 四川中汇安达石油化工有限公司 Chelating type blocking remover and preparation method and application thereof

Cited By (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100509654C (en) * 2004-08-31 2009-07-08 中国石化北京燕化石油化工股份有限公司 Low-phosphorus composite antiincrustation corrosion inhibitor and use for water treatment
CN100357331C (en) * 2005-06-15 2007-12-26 北京博泰盛合科技有限公司 Copolymer and its preparation method and reverse osmosis membrane protective agent comprising the copolymer and its uses
CN101172719B (en) * 2006-10-31 2010-12-08 中国石油化工股份有限公司 Dirty blocking inhibitor and application in water treatment thereof
CN101554565B (en) * 2009-04-21 2012-05-02 李洪社 Phosphorus-free reverse osmosis membrane antisludging agent and preparation method thereof
CN101913712B (en) * 2009-07-22 2011-10-05 乌鲁木齐市科发展精细化工有限公司 Low-phosphorous environment-friendly scale inhibitor adapting to 'three-high' water quality and preparation thereof
CN102363538B (en) * 2010-12-07 2013-04-03 新疆德蓝股份有限公司 Preparation of composite corrosion and scale inhibitor for low-hardness circulating cooling water
CN102363538A (en) * 2010-12-07 2012-02-29 新疆德蓝股份有限公司 Preparation of composite corrosion and scale inhibitor for low-hardness circulating cooling water
CN102079584A (en) * 2010-12-14 2011-06-01 成都齐达水处理工程股份有限公司 Non-phosphorus scale and corrosion inhibitor, and preparation method and applications thereof
CN102863090A (en) * 2011-07-08 2013-01-09 爱环吴世(苏州)环保有限公司 Corrosion and scale inhibitor for low-hardness water and preparation method thereof
CN102432112B (en) * 2011-11-01 2014-06-11 中冶建筑研究总院有限公司 Complexing agent
CN102432112A (en) * 2011-11-01 2012-05-02 中冶建筑研究总院有限公司 Complexing agent
CN104556420A (en) * 2013-10-12 2015-04-29 中国石油化工股份有限公司 Non-phosphorus composite corrosion and scale inhibitor and preparation method thereof, as well as corrosion and scale inhibition method of circulating cooling water
CN104556420B (en) * 2013-10-12 2016-06-29 中国石油化工股份有限公司 The corrosion-proofing and antisludging method of without phosphorus composite slow-corrosion scale resistor and preparation method thereof and recirculated cooling water
CN103787518A (en) * 2014-01-21 2014-05-14 山东省泰和水处理有限公司 Low-temperature multi-effect sea water desalination scale and corrosion inhibitor
CN104861948B (en) * 2014-02-21 2018-09-11 中国石油化工股份有限公司 It is a kind of improve polymer solution viscosity composition and its application
CN104861948A (en) * 2014-02-21 2015-08-26 中国石油化工股份有限公司 Composition used for increasing polymer solution viscosity, and applications thereof
CN103803728A (en) * 2014-02-25 2014-05-21 江苏紫石化工科技有限公司 Dimethyl formamide compound scale inhibitor
CN104355384A (en) * 2014-10-24 2015-02-18 无锡伊佩克科技有限公司 Sewage treatment agent
CN104556427A (en) * 2015-01-15 2015-04-29 鞍钢贝克吉利尼水处理有限公司 Composite efficient corrosion and scale inhibitor for ammonia still water treatment
CN105130019A (en) * 2015-07-13 2015-12-09 鞍钢贝克吉利尼水处理有限公司 High-effective composite corrosion and scale inhibitor being suitable for high-calcium and -alkali water and preparation method thereof
CN105217806A (en) * 2015-10-13 2016-01-06 武汉钢铁(集团)公司 Circulating water corrosion inhibitor and application thereof
CN106495248A (en) * 2016-11-26 2017-03-15 王晓东 A kind of water process zero-emission controlling agent and method for treating water
CN107720984A (en) * 2017-10-17 2018-02-23 高产明 A kind of preparation method of the low-phosphorous water quality stabilizer of efficient scale corrosion inhibition type
CN108483686A (en) * 2018-04-09 2018-09-04 翟琳 A kind of corrosion inhibition type antisludging agent
CN110104805A (en) * 2019-03-25 2019-08-09 大唐双鸭山热电有限公司 A method of reducing thermal power plant recirculated cooling water utilization rate
CN110127870A (en) * 2019-03-25 2019-08-16 大唐双鸭山热电有限公司 A kind of thermal power plant circulating water cooling treatment composite drug
CN112094633A (en) * 2020-10-29 2020-12-18 四川中汇安达石油化工有限公司 Chelating type blocking remover and preparation method and application thereof

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