CN1462783A - Antibiotic type coating material of epoxy powder modified by inorganic nano composite antimicrobial, and its prepn. method - Google Patents
Antibiotic type coating material of epoxy powder modified by inorganic nano composite antimicrobial, and its prepn. method Download PDFInfo
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- CN1462783A CN1462783A CN 03117984 CN03117984A CN1462783A CN 1462783 A CN1462783 A CN 1462783A CN 03117984 CN03117984 CN 03117984 CN 03117984 A CN03117984 A CN 03117984A CN 1462783 A CN1462783 A CN 1462783A
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- germicide
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Abstract
A nano-class inorganic composite antibacterial agent modified antibacterial epoxy powder paint is prepared from the nano-class composite antibacterial agent (nano-class porous TiO2 carried Ce ions), epoxy resin, solidifying agent, pigment, plus filler, and assistant through premixing, fusing-extruding-mixing, cooling, pressing sheet, breaking, pulverizing and sieving. Its advantages are high bacteria-suppressing rate (99% or more), high adhesion, toughness, impact strength, and high hardness and chemical resistance.
Description
One, technical field
The present invention relates to antimicrobial form epoxide powder coating of a kind of inorganic nano combined antiseptic-germicide modification and preparation method thereof, belong to the preparation field of powder coating.
Two, background technology
Japanese Patent 10-330937, Formation of substantially flat coating, reported to prepare a kind of technology that is used for the ultra-smooth coating on the superconducting integrated circuit plate, added a small amount of nanometer oxide material in this coating, to improve the intensity and the slipperiness of coating; Chinese patent CN1228107A, the making method that germ resistance powder coating, the electric furnace that has used this coating and germ resistance are filmed, reported and had resinous principle and on silicon-dioxide, be loaded with the preparation method of the powder coating that possesses germ resistance that thiosulfate anion closes the antiseptic-germicide of silver complex, this technology mainly is when the formation of coating germ resistance powder coating is filmed, antiseptic-germicide is embedded in the inside of filming, even contacting seldom of antiseptic-germicide and bacterium, can suppress the breeding of bacterium, but this technology is not reported the variable color situation in this germ resistance powder coating use yet.Chinese patent CN1270193A, a kind of manufacture method of antibiotic paint, reported a kind of preparation method of antimicrobial form interior wall coating, by this technology prepare that antimicrbial power is strong, has a broad antifungal spectrum, washable long-acting, nonvolatil and the antibiotic paint that has no side effect with antibacterial, the cost that this patent is not pointed out to add behind the antimicrobial component increases situation.Open east, antibiotic concrete research, New Building Materials, 2002, (4): P13-14, after having compared the antibacterial ability of rare earth compound cerous nitrate and silver ion antimicrobial agent, choose cerous nitrate and mix its antibiotic level of test in the cellular concrete, the result shows: the antibacterial ability and the silver ion antimicrobial agent of cerous nitrate are similar; The antibiotic level that is mixed with the cellular concrete of cerous nitrate is improved largely; Li Bingchao, pair Tian Xia, the preparation and the anti-microbial activity thereof of Ce-norfloxicin title complex, Liaoning chemical industry, 2000, (6), P341-343, synthesized new Ce-norfloxicin title complex, measured title complex to causing the minimum inhibitory concentration of burn infection main bacteria seed with the double dilution method of test tube.The result shows that Ce-norfloxicin title complex is water-soluble, and is fat-soluble good.Ce-norfloxicin title complex will be better than norfloxicin slightly to the anti-microbial activity of Pseudomonas aeruginosa, and to intestinal bacteria, the anti-microbial activity of golden yellow staphylococcus is similar to norfloxicin; Yan Yurong, Zhao Yaoming, inorganic antibacterial material, chemical industry progress, 2001, (7), P5-9, point out limitation and the easy wash-out of organic antibacterial agent in order to overcome the inorganic antiseptic antimicrobial spectrum, the deficiency of resistance toheat can adopt mode organic and/or inorganic and that hydroaropic substance is composite.The intrinsic anti-microbial activity of organic and inorganic antiseptic-germicide etc. may strengthen significantly in compound system, obtains high anti-microbial property under the situation of few additive; Song Linyong, Xu Wanjun, nano antibacterial agent and the application in powder coating thereof, coatings industry, 2002, (3), P32-34 has studied at epoxy/polyester, add 1%～3% inorganic silver ion antimicrobial agent in polyester/TGIC powder systems after, adopt original powder manufacturing apparatus and electrostatic painting process, the coating that forms has the function of good kill bacteria, and coating itself is harmless, but does not provide the variable color situation after coating is used; Wang Yong, antibacterial powder paint, Chinese coating, 2001, (1), P29-31 has prepared and has contained the antibacterial powder paint that coats silver ion antimicrobial agent with inorganic oxide, but article does not have the cost increase situation after silver are used in analysis in a large number.
Three, summary of the invention
Antimicrobial form epoxide powder coating of a kind of inorganic nano combined antiseptic-germicide modification that provides at the deficiencies in the prior art and preparation method thereof is provided, be characterized in existing epoxide powder coating, introducing inorganic nano combined antiseptic-germicide, give the epoxide powder coating antibacterial, do not reduce performances such as epoxide powder coating sticking power, snappiness, shock strength, slickness, hardness and chemical resistant properties simultaneously.
The present inventor finds that nano titanium oxide has certain effect to the raising of coating antibiosis, but the existence that needs UV-irradiation, oxygen or water just can be played bacteriostatic action, but can not obtain satisfied antibacterial effect; And common inorganic antiseptic majority contains silver ions, easily oxidizedly be transformed into brown silver suboxide or be reduced into black simple substance silver through ultraviolet catalyzed, the variable color of silver has not only reduced its germ resistance, be applied in white or the light-coloured coating and go but also limited it, and use silver-colored cost height in a large number, restricted it in wider application.Therefore, it be carrier by loading cheap cerium is the composite nano germicide that obtains behind the ion that the present invention adopts the multi-hole type nano titanium oxide, add in the epoxide powder coating with suitable amount, can increase substantially the anti-microbial property and the integrated performance index of epoxide powder coating.
Purpose of the present invention is realized that by following technical measures wherein said raw material umber is parts by weight except that specified otherwise.
The recipe ingredient of the antimicrobial form epoxide powder coating raw material of inorganic nano combined antiseptic-germicide modification is:
55～65 parts of Resins, epoxy
0.5～5 part in solidifying agent
30～40 parts of color stuffings
0.5～6 part of auxiliary agent
Inorganic nano combined antiseptic-germicide, particle diameter are 0.5～10 part of 10～100nm
Inorganic nano combined antiseptic-germicide is that carrier loading cerium is the composite nano germicide that ion obtains for the multi-hole type nano titanium oxide.
Solidifying agent is at least a in dicarboxyl acid dihydrazide, acid anhydrides, Dyhard RU 100 and/or the imidazoles.
Color stuffing is at least a in titanium dioxide, lime carbonate, process white and/or the zinc sulfide white.
Auxiliary agent comprises flow agent, corner hiding power properties-correcting agent, decorative pattern auxiliary agent, powder fluffy powder, pigment dyestuff and curing catalyst etc., these all are this those skilled in the art's technique known, can be used, to be these auxiliary agents do not have a negative impact to the realization and the obtaining of excellent results of the present invention of purpose of the present invention its precondition.
The preparation method of the antimicrobial form epoxy powder coating of inorganic nano combined antiseptic-germicide modification:
1, takes by weighing 0.5～10 part of the multi-hole type nano TiO 2 carrying cerium antiseptic-germicide that particle diameter is 10～100nm; Take by weighing 3～6 parts of 50～65 parts of Resins, epoxy, 0.5～5 part in solidifying agent, 30～40 parts of color stuffings and auxiliary agents, it is even to join in the mixing machine pre-mixing.
2, through the said mixture material, be transported to feeder and carry out melting mixing in the screw extrusion press, by tabletting machine be pressed into thin slice, cooling, after crusher in crushing, be transported to that to carry out fine powder in the air classifying mill (ACM) broken, capture most of pulverized work in-process by cyclonic separator, after powder shifter is removed foreign material and coarse meal, can make the antimicrobial form epoxide powder coating finished product of composite nano germicide modification again, and pack.
The epoxy powder coating of the prepared inorganic nano combined antiseptic-germicide modification that goes out, its bacteriostasis rate index is greater than 99%.
The present invention has the following advantages:
1, under the prerequisite that does not change original epoxide powder coating production technique, by adding a spot of inorganic nano combined antiseptic-germicide, prepare epoxide powder coating with high anti-microbial property, the prepared modified epoxy powder coating that goes out, its bacteriostasis rate index is greater than 99%;
2, other performance of coating such as aspects such as sticking power, snappiness, shock strength, slickness, hardness and chemical resistant properties all meet country and industry standard;
3, use the inorganic nano combined antiseptic-germicide contain Ce elements to replace original silver ion antimicrobial agent, reduced the discolouration after the coating film forming, reduced product cost, thereby had the stronger market competitiveness.
Four, embodiment
Below by embodiment the present invention is specifically described; be necessary to be pointed out that at this present embodiment only is used for the present invention is further specified; can not be interpreted as limiting the scope of the invention, the person skilled in the art in this field can make some nonessential improvement and adjustment according to the content of the invention described above.
Embodiment 1:
Antimicrobial form epoxide powder coating prescription is:
| Composition | Resins, epoxy | The 2-benzylimidazoline | Titanium dioxide | Multi-hole type nano TiO 2 carrying cerium antiseptic-germicide |
| Weight (kilogram) | ????55.5 | ????4 | ????38.5 | ????2.0 |
Embodiment 2:
Antimicrobial form epoxide powder coating formulation for coating material is:
| Composition | Resins, epoxy | Dyhard RU 100 | The 2-benzylimidazoline | Titanium dioxide | Multi-hole type nano TiO 2 carrying cerium antiseptic-germicide |
| Weight (kilogram) | ??54.5 | 1.3 | ??2.2 | ??40 | ????1.5 |
Embodiment 3:
Antimicrobial form epoxide powder coating formulation for coating material is:
| Composition | Resins, epoxy | Dyhard RU 100 | The 2-benzylimidazoline | Titanium dioxide | Multi-hole type nano TiO 2 carrying cerium antiseptic-germicide |
| Weight (kilogram) | ???57.2 | 2.3 | ??0.3 | ??37.2 | ????3.0 |
The preparation method of the antimicrobial form epoxy powder coating of inorganic nano combined antiseptic-germicide modification:
1, take by weighing multi-hole type nano TiO 2 carrying cerium antiseptic-germicide, Resins, epoxy, solidifying agent, color stuffing, the auxiliary agent that median size is 10～100nm, it is even to join in the mixing machine pre-mixing together.
2, through above-mentioned mixed material, be transported to feeder and carry out melting mixing in the screw extrusion press, by tabletting machine be pressed into thin slice, cooling, after crusher in crushing, be transported to that to carry out fine powder in the air classifying mill (ACM) broken, capture most of pulverized work in-process by cyclonic separator, after powder shifter is removed foreign material and coarse meal, can make the antimicrobial form epoxide powder coating finished product of composite nano germicide modification again, and pack.
Claims (4)
1, the antimicrobial form epoxide powder coating of inorganic nano combined antiseptic-germicide modification is characterized in that the recipe ingredient (by weight) of this epoxide powder coating is:
55～65 parts of Resins, epoxy
0.5～5 part in solidifying agent
30～40 parts of color stuffings
0.5～6 part of auxiliary agent
Inorganic nano combined antiseptic-germicide, particle diameter are 0.5～10 part of 10～100nm
Wherein inorganic nano combined antiseptic-germicide be with the multi-hole type nano titanium oxide be carrier to load cerium be the composite nano germicide that ion obtains, the epoxy powder coating of the prepared inorganic nano combined antiseptic-germicide modification that goes out, its bacteriostasis rate index is greater than 99%.
2,, it is characterized in that solidifying agent is at least a in dicarboxyl acid dihydrazide, Dyhard RU 100 and/or the imidazoles according to the antimicrobial form epoxide powder coating of the described inorganic nano combined antiseptic-germicide modification of claim 1.
3,, it is characterized in that color stuffing is at least a in titanium dioxide, lime carbonate, process white and/or the zinc sulfide white according to the antimicrobial form epoxide powder coating of the described inorganic nano combined antiseptic-germicide modification of claim 1.
4, according to the preparation method of the antimicrobial form epoxide powder coating of the described inorganic nano combined antiseptic-germicide modification of claim 1～3, it is characterized in that:
(1) takes by weighing 0.5～10 part of the multi-hole type nano TiO 2 carrying cerium antiseptic-germicide that particle diameter is 10～100nm; Take by weighing 0.5～6 part of 50～65 parts of Resins, epoxy, 0.5～5 part in solidifying agent, 30～40 parts of color stuffings and auxiliary agent, it is even to join in the mixing machine pre-mixing,
(2) through above-mentioned mixed material, be transported to feeder and carry out melting mixing in the screw extrusion press, by tabletting machine be pressed into thin slice, cooling, after crusher in crushing, be transported to that to carry out fine powder in the air classifying mill (ACM) broken, capture most of pulverized work in-process by cyclonic separator, after powder shifter is removed foreign material and coarse meal, can make the antimicrobial form epoxide powder coating finished product of inorganic nano combined antiseptic-germicide modification again, and pack.
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| Application Number | Priority Date | Filing Date | Title |
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| CNB031179843A CN1177007C (en) | 2003-06-02 | 2003-06-02 | Antibiotic type coating material of epoxy powder modified by inorganic nano composite antimicrobial, and its prepn. method |
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| CNB031179843A CN1177007C (en) | 2003-06-02 | 2003-06-02 | Antibiotic type coating material of epoxy powder modified by inorganic nano composite antimicrobial, and its prepn. method |
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| CN1462783A true CN1462783A (en) | 2003-12-24 |
| CN1177007C CN1177007C (en) | 2004-11-24 |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100352872C (en) * | 2005-11-30 | 2007-12-05 | 深圳清华大学研究院 | Antibacterial, mildew-proof, algae-resistant and anticorrosive paint and application thereof |
| CN103387789A (en) * | 2013-07-08 | 2013-11-13 | 吴江市物华五金制品有限公司 | Antibiotic powdery paint for washing machines and preparation method thereof |
| CN103937391A (en) * | 2014-03-21 | 2014-07-23 | 安徽蓝柯复合材料有限公司 | Antibacterial self-dry paint and preparation method thereof |
| CN104745048A (en) * | 2013-12-31 | 2015-07-01 | 天津市凯华绝缘材料有限公司 | Halogen-free flame retardant epoxy resin powder coating used for coating magnetic ring |
| CN104845000A (en) * | 2015-06-02 | 2015-08-19 | 金海新源电气江苏有限公司 | Preparation process of insulating resin for completely sealed bus duct |
| CN110981999A (en) * | 2019-06-19 | 2020-04-10 | 张元泽 | Novel antibacterial polymer and preparation method thereof |
| CN112048227A (en) * | 2020-08-24 | 2020-12-08 | 廊坊艾格玛新立材料科技有限公司 | Powder coating with antibacterial function and preparation method thereof |
| CN112126100A (en) * | 2020-10-13 | 2020-12-25 | 绍兴高卓新材料科技有限公司 | Long-acting nano antibacterial composite material and preparation method thereof |
-
2003
- 2003-06-02 CN CNB031179843A patent/CN1177007C/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100352872C (en) * | 2005-11-30 | 2007-12-05 | 深圳清华大学研究院 | Antibacterial, mildew-proof, algae-resistant and anticorrosive paint and application thereof |
| CN103387789A (en) * | 2013-07-08 | 2013-11-13 | 吴江市物华五金制品有限公司 | Antibiotic powdery paint for washing machines and preparation method thereof |
| CN104745048A (en) * | 2013-12-31 | 2015-07-01 | 天津市凯华绝缘材料有限公司 | Halogen-free flame retardant epoxy resin powder coating used for coating magnetic ring |
| CN103937391A (en) * | 2014-03-21 | 2014-07-23 | 安徽蓝柯复合材料有限公司 | Antibacterial self-dry paint and preparation method thereof |
| CN104845000A (en) * | 2015-06-02 | 2015-08-19 | 金海新源电气江苏有限公司 | Preparation process of insulating resin for completely sealed bus duct |
| CN110981999A (en) * | 2019-06-19 | 2020-04-10 | 张元泽 | Novel antibacterial polymer and preparation method thereof |
| CN112048227A (en) * | 2020-08-24 | 2020-12-08 | 廊坊艾格玛新立材料科技有限公司 | Powder coating with antibacterial function and preparation method thereof |
| CN112126100A (en) * | 2020-10-13 | 2020-12-25 | 绍兴高卓新材料科技有限公司 | Long-acting nano antibacterial composite material and preparation method thereof |
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|---|---|
| CN1177007C (en) | 2004-11-24 |
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