CN1461669A - Device for oxidating titanium particle modified liquid by photochemical catalyst - Google Patents

Abstract

The invention provides an apparatus for achieving the modification of a liquid by particles and a plate containing photocatalytic titanium oxide and the others as one of apparatuses for eliminating a substance harmful to a thing in a living space and to achieve the reduction of wastewater treatment cost by allowing good wastewater to flow by a water-using person. In this liquid modifying apparatus, a liquid brought into close contact with photocatalytic titanium oxide particles or the like is irradiated with solar rays, ultraviolet rays due to a light and aphotic particles due to electrons to be modified. The apparatus is changed by purpose or use.

Description

Device by photocatalyst oxidizes titanium particle modified liquid

Technical field

The present invention relates to the industry of environment, health, removal nuisance.

Prior art

In the past, the modification of oil, existing multiple technologies such as the running waterization of water, but adopt methods such as magnetic, electricity, active carbon more, oil also is so, seldom has to adopt photochemical catalyst.

Summary of the invention

The problem of the modification of liquid such as oil of the present invention, water is as follows:

1) fuel oil increases substantially fuel cost efficient more than 30%, and removes the toxicity in the waste gas.

2) anti-aging of driving oil, fried wet goods, oxidation slip are more than 15%.

3) remove worm, agricultural chemicals in the agricultural water, increase the root activity; Water for industrial use sterilization, anti-algae, antirust.Water for beverages, fungi-proofing, anion equilibrium water.Fish shellfish breeding water, the breed water of increase mineral matter.

In containers such as flat ware, pipeline, add the photocatalyst oxidizes titanium particle, ultraviolet ray irradiation, liquid flow.

During from peripheral irradiation ultraviolet radiation, use quartz glass, amorphous polyolefins class plastics etc.; When shining internally, adopt the shape of utilizing metallic reflection light.

In addition, flow through in the device of Titanium particles type, the condition of regulating throughput is set at the liquid of unnecessary light.Multiple the close matter liquid making body different in purposes such as industry, agriculturals is to change the surface treatment that adds multiple particle wherein, and corresponding, roughly it is divided into several types, in medicinal adding specialities.In addition, utilizing the endless form of sunshine, is important as the spontaneous current flowing mode.

Reforming apparatus as constituted above during the electron synchrotron that takes place in the time of with liquid flow, acts on mutually with the catalyst of particle surface, produces dechlorination at short notice, reduces the effect of the gathering of molecule.In addition, photochemical catalyst is had an effect by the ultraviolet ray of sunshine, the ultraviolet ray of black light lamp, and when the material of particle was high ultraviolet permeability, distance also can act in the pipeline of light even the inside, center is advanced.

The liquid of disposable stream will obtain the action effect pipeline distance of titan oxide particles and will grow, and in the time of the liquid circulation modification of container, even short also it doesn't matter, is applicable to that industry, agricultural, grocery trade, medical treatment etc. close the effect of matter.

Brief Description Of Drawings

Fig. 1, the device half-sectional view that has water pot of use black light lamp.

Fig. 2, the front elevation of the aggregation type device of use black light lamp.

Fig. 3 utilizes the oblique view of the multi-cartridge device of sunshine.

Fig. 4, the profile of the circulating device of use black light lamp.

Fig. 5, the front half-sectional view of portable water purifying device.

Fig. 6, the oblique view of wall jar.

Fig. 7, freshness keeps the front cross-sectional view of container.

Fig. 8, the profile of wound photo-thermal water device.

The front elevation of the portable water purifying device in Fig. 9, satchel.

Figure 10 utilizes the rain of sunshine to take the interior profile that installs.

Figure 11, the profile of photocatalyst oxidizes titanium particle etc.

Figure 12, the front elevation of mask.

Figure 13, the side view of sunlight, the circulating device of unglazed double-column vertical.

Figure 14, the profile of the device of 2 kinds of particles of adding in the pipe.

Figure 15, the outside drawing of device before the lavatory flushing water pot, before the bathtub pot.

Figure 16, the structure chart of water drain U-shaped devices such as kitchen tub

Symbol description

The solid carrier band charged particle of A photocatalyst oxidizes titanium ion etc.

B BLB black light lamp fluorescent lamp C electric switch D handles flow container

1 pipeline, 2 inlet tubes, 3 joints, 4 float switches

5 water pots 6 take out valve 7 tedges 8 interfaces

10 filters take out plate 11 concetrated pipes 12 containers 13 helix tubes

14 network capacity devices

The specific embodiment

Fig. 1 is the small-sized device as family expenses, is applicable to cleaning, the cooking, beverage, beauty treatment, agricultural and gardening, breeds fish, the lining mixing of anion room, coating, freshness keep multiple or oily a small amount of modifications such as container.In the container (5), the center of overflow pipe (1) is provided with Ultraluminescence lamp (B).Particle is for adapting to the particle of such use, place the space between pipeline and the lamp, in pipeline, emit, rise from the outlet of pipe (13) from the liquid that inlet (2) enters, rest in the container, drive the sensor (4) that floats, close magnetic valve (2), close light, open down conveying end (6), after emitting, flow once more, the liquid of modification is arranged through the flow container of being everlasting (D) lining.

Fig. 2 is the example of the device used of medium-sized building, hotel, dining room, cleaning, industry, agricultural, the fishery used when can not use sunshine.Perhaps also can be used for the modification of fuel oil, fried oil.From the liquid inlet (2), along rising in the chimney filter (7),, be assigned to successively black light lamp and the particle pipe (1) from distributing pipe (8) by the filter (F) that contains magnetite, enter collector pipe (9).The liquid measure of distributing pipe is carried out ON, OFF operation by float switch (4), and liquid takes out from pipe (5) and uses.Make agricultural with extract, agricultural except that operation such as anhydrate in, can inject distributing pipe, in fishery, can inject mineral matter.

Fig. 3 utilizes the double lamplight type that utilizes of sunshine, and more sunshine is accepted in superincumbent centre, in the time of not enough, is provided with light in the inboard, the particle pipe (10) that irradiation is most.Press water enters from inlet (2), by chimney filter (7), is entered in next root pipe by concetrated pipe (11).Then by discharging from outlet (6) behind all pipelines.When the endless form such as water by the cooling tower of water for industrial use, compressor obtain, add the particle of antirust, anti-algae, antibiotic property therein, obtain maintenance.In addition at big water gaging such as the breeding water of fish and shellfish, agricultural water, circulating etc. become high-quality liquid after by many, so also be applicable to the modification of oil.Transparent pipeline uses high quartz glass, the PMMA of ultraviolet ray transmissivity, and radical is 3～10.In addition in the nontransparent pipeline of Jin Chukouing by the electronic effect of unglazed particle, filter etc., join in the liquid of anion.

Fig. 4 is the product that the circulation modification of container uses such as fresh article transportation, fish and shellfish transportation, spat, fish, small-sized agricultural and gardening, industrial small size machinery is used.Liquid infiltrates pressure (hydraulic) water, oil from inlet (2), and the liquid that soaks between the particle between the black light lamp at center is gone out by outlet (6) by filter.Since be the most small-sized, simple to operate.For making water with also being suitable for.Circulating bathing pool, the swimming pool etc. of also being applicable to.Need not be to the cleaning of ceramic tile.

Fig. 5 is the embodiment of the pipe method of long distance as far as possible that can be used in the good modification liquid such as aproll of bath tube bottom, coagulating cement water, plant.The fluid under pressure that inlet (2) enters soaks in not needing the electronics particle of light and flows through, and discharges from outlet (6).Helix tube has added conjugative plasmid in (13), is housed in the container (12).Under the situation of long especially distance, resemble and make horizontal type the socket, the convenient type that resembles bobbin that works elongation is also passable.

Fig. 6 is a scheme of making jar on the wall.Utilize on the roof of sunshine again or rain take in design reforming apparatus (Figure 10), water pipe can not utilize wall yet.Also useful to fire.

Fig. 7 more helps fresh-keeping container than freezer, refrigerator.The sky of container (12) is aboveground, in the net that has the hole (15) of precipitation, carries out water distribution from pipeline (6).Water soaks into particle or see through regular rainfall under black light lamp from following water pot, tank.Preserve fresh article such as meat, fish and shellfish, vegetables in the net canopy, the luminous water that illumination generates is to decompose ethylene gas, bactericidal properties height, incorrupt water, more helps the maintenance of freshness than refrigerator.Need not seal, cost is low.The container of this mode also is applicable to the factory of strawberry in addition.Vegetables etc. become no Pesticidal products.

Fig. 8 is the EGR of bathing pool hot water, from hot water osmotic flow mistake from the particle pipeline that suction inlet (2) sucks, by filter (F), gets back to the bathing pool in the following mode of letting out that is similar to waterfall from outlet (6).This mode becomes the generation source of anion for the water beyond the bathing pool time, is multiduty.Because have sterilizing power, so because the circulation bunch size can diminish.

Fig. 9 be go on business, travel, the portable unit when tourism etc. needs life water, can be modified as drinking water to the running water of scenery with hills and waters, river, locality.

Have lid at an upper portion thereof, add entry from 2, the photocatalyst oxidizes titanium particle (A) that is added in the container tube (1) contacts with water, shone by the ultraviolet ray of sunshine, forms harmless drinking water.Open outlet valve (6), water is emitted from the bottom by filter.Device is placed on the foot rest, is fixed in the ring, in the collection sack.

Figure 10 utilizes the rain of sunshine mode to take.Owing to have long distance, can effectively utilize the space, improve the quality of modification liquid.In addition, on the nigh wall water pot being set also can.

Figure 11 is the superficial layer figure of photocatalyst oxidizes titanium, and according to multi-purpose difference, the parent material is different, in addition 1 of its surface layer～top layer carry hold, material, thickness be also different.Parent is glass, pottery, sand, ore, charcoal etc., and in addition, titanium oxide and other materials are used in the 1st layer～top layer, can decompose various harmful organic substances, in addition, utilize the generation of sunshine, ultraviolet ray, far infrared, unglazed electronic and ionic, can

1) water is promoted in the beverage of animal, health care

2) interaction in vitro of anion water stimulates circulation, and improves vigour

3) efficient of raising fuel oil concerning oil prevents deterioration in addition, can serve many purposes by multiple particle.

Figure 12 is the long-time waist-mounted type anion sheet that stimulates circulation that adds in seat cloth that diseases prevention is used when stiff in the narrow and small vehicles.The driving fits such as face shield of powder granule of having enclosed photocatalyst oxidizes titanium+ト Le マ リ Application ionized water etc. are put in the time of sleep at facial area, can produce the effect of beauty treatment.In addition, the gas washing mask can also have anion, prevent the effect that pollen is invaded.In below not covering nose, add circular nostril therein.

Except that above figure, various embodiments can also be arranged.1) the processing chip of vegetables, fish shellfish, meat etc., when preserving before transporting to sewage treatment plant, the device that can use Fig. 3, Fig. 4 is as the water device that prevents stench.2) disposable modified in the device that the water of shower, bath in a tub etc. obtains, with the form of Fig. 5 hot water, cold water are soaked into and to flow through.The amount of can degerming, regulating anion.In addition, by filter is set, also can add the function of magnetic, carbon etc.

Figure 13 is that oil, shellfish preserve water, and modifications such as melt water, his water of industrial cleaning are used, and sunshine mixed type gravitation utilizes the product of mode.Water in the water pot rises with water pump, enters the distribution plate from feed pipe, and in the pipeline more than several (1), photocatalyst oxidizes titanium particle and do not have photochemical catalyst to soak into utilizes gravitation to fall back in the water pot.1 time suction effect is insufficient, by repeatedly above circulation, and also can modification at the post sunset that does not have photochemical catalyst.

Figure 14 is antibiotic, the reforming apparatus that do not make biological self reproducing in the water in preserving.For obtaining not have the water of bacterium, protist, use ship or other modes.The unglazed photocatalyst oxidizes titanium particle (2～3 φ) of about wherein granule more than 500 millimeters is provided with little net in the water pipe of the porch of water.The space of 2 times of L is set in the pipeline of little net back, big net and bulky grain more than 500 millimeters are set then, flow through pressure (hydraulic) water, bacterium, other biological just have been killed.Because be that pressurised stream is crossed granule, improve inapplicable general tape carrier type, the special device that uses the particle appearance to be fenced up for making the photocatalyst surface durability by plastics etc.Bacteriums after killing etc. are owing to the cause of pressure reduction is stayed in the position, space.

Figure 15 is the anterior device that is provided with of water tank in the front portion (bathing pool, shower dual-purpose feedwater portion) and the lavatory of hot-water supply.The water that enters from below soaks into the no photocatalyst oxidizes titanium particle in the pipeline, produces antifouling, antibiotic, mildew-resistant, the smelly effect that disappears, and water obtains modification.Add the interior particle of pipeline because of the different difference of purposes, but container is common.

Figure 16 is the variation of the U type pipe at draining positions, flowing water place such as culinary art place, the room that washes one's face.Make special U type pipe, wherein add anhydrous photochemical catalyst.The water of being crossed by catalyst treatment enters drainpipe like this, does not remain in the drainpipe, and also reduces at the purification run cost of draining factory.

For improving the fresh keeping time of flower arrangement, be ready that water adopts Fig. 1, Fig. 3, Fig. 5, Figure 13 to make a large amount of water according to amount of application, when using in a small amount, adopt Fig. 5 and Figure 13 device to make water, can improve the durability of flower arrangement.

In addition, mask with and the water of daily life clothes etc., water that must be especially in a small amount, it is good making water by Figure 13.

Water, wet goods liquid, life is different with the photochemical catalyst of the device of, industrial, agriculture usefulness and content.Generally, detect less than nuisance chloroform below 1.7 milligrams of residual chlorine, organic matter, two bromochloromethanes, bromofom, chloroform etc. and decompose by redox.Help domestic water, water for industrial use, the purification of waste water treatment plant simultaneously.

1) healthy, improve looks, return to young effect, this water also have in addition clean, antifouling, mildew-proof function.

2) concrete water, inapplicable intermixture can overcome durability, intensity, uniformity, watertightness 4 large projects.Chlorine is removed in the lubricity of aggregate, filling, crosslinked little in addition, reduces oxidation-reduction potential, reduces the size of hydrone.Shrinkage factor reduces by 13%, and pin hole reduces by 10%, and cement consumption reduces by 13%.

3) limit of plant, fish, meat, shellfish improves the root activity of crops, removes by the decomposition of agricultural chemicals, decomposes ethylene gas.It is smelly, antibiotic to disappear, and crop has proliferative ability in addition.

4) oil time, be divided into fuel oil, frying oils, lubricating oil 3 big classes.Improve efficiency of combustion 15% and reduce exhaust 12%.Frying oils, lubricant oil regeneration and fresh oil are same.The industry oil life-span improves 8%.

5) invention of no photocatalyst oxidizes titanium particle can all have very big effect simultaneously, separately with sunshine.In the room, can not have black light lamp.In addition, catalyst granules when being granulation, buries the invention of particle at surperficial carrier band, even pressure (hydraulic) water can improve durability.Energy-conservation, conserve space, effect is big.

6) sunshine utilizes in the type device circulating pump is set, and the number of times time improves, can a large amount of water of modification.Midget plant is saved cost.The disposable mode of bathing pool, shower etc.The mode that has concurrently of flower arrangement, agriculture water etc.The dual-purpose modes of after shave lotion etc. can freely make things convenient for.

Claims (1)

1. the liquid modifying device is added with in the container or plate vessel side by side of most titan oxide particles, with the irradiation of sunshine or black light lamp, makes liquid-immersedly, obtains modification liquid; Perhaps, will not want ultraviolet particle and add container, and in the many particle space of quantity, modification liquid will be flow through under the unglazed state, obtain modification liquid by electricity.

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