CN1454072A - Personal care composition comprising hydrophobic gel - Google Patents
Personal care composition comprising hydrophobic gel Download PDFInfo
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- CN1454072A CN1454072A CN00819916A CN00819916A CN1454072A CN 1454072 A CN1454072 A CN 1454072A CN 00819916 A CN00819916 A CN 00819916A CN 00819916 A CN00819916 A CN 00819916A CN 1454072 A CN1454072 A CN 1454072A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/042—Gels
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/63—Steroids; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/55—Phosphorus compounds
- A61K8/553—Phospholipids, e.g. lecithin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
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- Cosmetics (AREA)
Abstract
Disclosed is a personal care composition comprising by weight; (a) from about 5% to about 35% of hydrophobic gel comprising; (i) a cholesteryl derivative; (ii) an oil swelling clay material; (iii) a non-volatile liquid oil; and (iv) a polar solvent; and (b) a carrier which is substantially free of water, surfactant, and lecithin; which satisfies the need for a personal care composition having improved physical stability.
Description
Invention field
The present invention relates to comprise the personal care composition of organophilic gel.Said composition especially can be used for preparing lip pomade, foundation cream and cream.
Background of invention
Lip pomade is mainly made by lipotropy or hydrophobic material.Design is used for providing the lip pomade of humidification beneficial effect to comprise water, polar solvent or having more or less hydrophilic other humidification component to lip.Existing people advises the association structure, so that this humidification component is incorporated in the lipotropy substrate of lip pomade.Lip composition although it is so provides good humidification benefit to lip, but they are being not to be entirely satisfactory aspect physical stability, colour stability and the anti-antiperspirant.
Physical stability relates to the stability of lip pomade when duration of storage and use.For example, stable lip pomade can not be out of shape during room temperature storage, and can be not crooked under regular service conditions or break.Colour stability relate to color duration of storage and be applied on the lip after stability.Known, be applied on the lip after, As time goes on, the lip pomade that contains high-load humidification component tends to take place color change.Perspiration is the phenomenon that takes place on the lip pomade surface, it is believed that this is owing to oil and/or separated from solvent and due to leaking out from the lipotropy substrate of lip pomade.Perspiration has brought bad outward appearance to user.
Use the emulsion compositions of cholesteryl derivant and expansive clay material for example to be disclosed among the Japan publication A-8-20529.Can provide physical stability to compositions though it is believed that such emulsion, still need further improvement.
Based on the above, still need such lip composition, promptly said composition not only has the physical stability of improvement, the colour stability of improvement and the anti-antiperspirant of improvement, can also provide the humidification beneficial effect to lip simultaneously.The personal care composition that also need in wide viscosity and/or hardness range, have the physical stability of improvement.
Summary of the invention
The present invention relates to comprise the personal care composition of following component by weight:
(a) about 5% to about 35% hydrophobic gel, this gel comprises:
(i) cholesteryl derivant;
(ii) oily expansive clay material;
(iii) non-volatile liquid oil; With
(iv) polar solvent; With
(b) be substantially free of the carrier of water, surfactant and lecithin;
This personal care composition can satisfy the needs to the personal care composition of the physical stability with improvement.
The invention still further relates to the lip composition that satisfies following needs, promptly said composition not only has the physical stability of improvement, the colour stability of improvement and the anti-antiperspirant of improvement, can also provide the humidification beneficial effect to lip simultaneously.
The invention still further relates to the suitable method of preparation above-mentioned composition.
To those skilled in the art, by reading the disclosure of the specification and claims, these and other feature of the present invention, aspect and advantage will become apparent.
Detailed Description Of The Invention
List the definition of term used herein below.
" comprise " and be meant and add other step of not influencing final result and other composition.This term comprise " by ... form " and " basically by ... composition ".
Unless offer some clarification in addition, otherwise all percentage ratios all are by total composition weight meter.
The list of references of all references all is incorporated herein in full, for your guidance.Quoting of any document is not to recognize that the decision that it is used as the availability of prior art of the present invention.
Except as otherwise noted, otherwise all proportions all is a weight ratio.
Hereinafter describe product of the present invention and method in detail.
The cholesteryl derivant
The present composition comprises the cholesteryl derivant with high moisture holding capacity.Be used for cholesteryl derivant of the present invention and provide hydrophobic gel with oily expansive clay material, non-volatile liquid oil and polar solvent.Bound by theory not it is believed that the cholesteryl derivant keeps polar solvent, provides stabilizing gel thus.
Regulate the amount of the cholesteryl derivant that is comprised according to the amount of polar solvent.That is to say, when needs high-load polar solvent, then comprise high-load cholesteryl derivant, to keep polar solvent effectively.For lip composition is provided, the cholesteryl derivant accounts for about 2% to about 7%, preferred about 3% to about 6% of whole composition weight.
Can be used for cholesteryl derivant of the present invention and comprise cholesterol and the fatty acid of 12 to 22 carbon atoms or the hydroxy fatty acid with high moisture holding capacity are arranged, preferred cholesterol 12-hydroxy stearic acid ester, cholesterol macadami nut acid esters, Cholesteryl stearate and composition thereof.Commercially available cholesteryl derivant comprises with trade name Salacos HS and derives from Nisshin Oil Mills, Ltd. cholesterol 12-hydroxy stearic acid ester, with derive from Nippon Fine Chemical Co. with trade name YOFCO MAC, the cholesterol macadami nut acid esters of Ltd..
Oil expansive clay material
The present composition comprises the oily expansive clay material with high oily swelliong power.Be used for oily expansive clay material of the present invention and provide hydrophobic gel with cholesteryl derivant, non-volatile liquid oil and polar solvent.At first oily expansive clay material is expanded, mix with other component of preparation hydrophobic gel then with non-volatile liquid oil.Bound by theory not it is believed that oily expansive clay material also keeps the closely combination in its structure of cholesteryl derivant and polar solvent when absorbing non-volatile liquid oil.
Oil expansive clay material plays the thickening agent of compositions.Therefore, the amount of regulating the oily expansive clay material that is comprised according to the viscosity and the hardness of required compositions.For lip composition is provided, oily expansive clay material accounts for about 0.1% to about 1%, preferred about 0.2% to about 0.5% of whole composition weight.
Be used for that oily expansive clay material of the present invention comprises modification so that hectorite, bentonite, Montmorillonitum and the Bentonite that holds with oil phase.Modification preferably with ammonium compounds carry out quaternized.Preferred oily expansive clay material comprises the hectorite of quaternary ammonium modification.Commercially available oily expansive clay material comprises the benzyl dimethyl stearyl ammonium hectorite that derives from Rheox.Inc. with trade name Bentone 38 CG OR.
Nonvolatile oil
The present composition comprises the nonvolatile oil that is suitable for individual's use.In order to be provided for the hydrophobic gel of lip composition, nonvolatile oil accounts for about 2% to about 10%, preferred about 4% to about 7% of whole composition weight.
According to required product feature, can be used for nonvolatile oil of the present invention can also use in carrier.In this case, preferably, the nonvolatile oil that will be used to prepare hydrophobic gel mixes independently with other component of preparation hydrophobic gel.Therefore, the nonvolatile oil that preferably will be used to prepare carrier mixes with other component (if present) that is used to prepare carrier; At last hydrophobic gel and carrier are mixed, with the preparation present composition.
Being used for nonvolatile oil of the present invention is for example different n-nonanoic acid tridecyl ester, isostearic acid iso stearyl ester, the different cetyl ester of isostearic acid, the isostearic acid isopropyl ester, different isodecyl pelargonate, cetyl octanoate, isononyl isononanoate, the myristic acid diisopropyl ester, the different cetyl ester of myristic acid, myristic acid isotridecyl ester, isopropyl myristate, the different stearyl ester of Palmic acid, the different cetyl ester of Palmic acid, Palmic acid isodecyl ester, isopropyl palmitate, octyl palmitate, caprylic/capric triglyceride, three-2 ethyl hexanoic acid glyceride, the diglycerol sebacate, neopentyl ethylene glycol bisthioglycolate (2-ethylhexanoate), the dimerized linoleic acid diisopropyl ester, tocopherol, tocopheryl acetate, American Avocado Tree oil, Camellia oil, turtle oil, macadimia nut oil, Semen Maydis oil, ermine oil, olive oil, rapeseed oil, egg oil, Oleum sesami, peach kernel oil, wheat germ oil, pasanqua oil, Oleum Ricini, Semen Lini oil, safflower oil, Oleum Gossypii semen, perilla oil, Oleum Glycines, Oleum Arachidis hypogaeae semen, Oleum Camelliae, Oleum Cocois, Testa oryzae oil, China's Paulownia oil, Japan's Paulownia oil, simmondsia oil, rice embryo oil, tricaprylin, glycerol three different cetylates, the trimethylolpropane tris isostearate, isopropyl myristate, glycerol three-2-ethylhexanoate, tetramethylolmethane four-2-ethylhexanoate, lanoline, liquid lanolin, liquid paraffin, squalane, vaseline and composition thereof.Commercially available oil comprises the different n-nonanoic acid tridecyl ester that for example derives from Croda with trade name CrodamolTN, derives from Nisshin Oil Mills, the carboxyl ester that contains isotope carbon 13 of Ltd. and the tocopheryl acetate that derives from Eisai.
Can be used for nonvolatile oil of the present invention and also comprise poly-alkyl or poly-aryl siloxanes with following array structure (I)
Formula (I)
R wherein
93Be that alkyl or aryl, p are about 7 to about 8,000 integers.Z
8The group of representative sealing siloxane chain end.(R at the siloxanes chain substitution
93) or at the terminal Z that replaces of siloxane chain
8Alkyl or aryl can have any structure, as long as the gained siloxanes satisfies following condition: keeping in room temperature is liquid; Be dispersible; Nonirritant, nontoxic or harmless in the time of on being applied in skin; Other component compatibility with compositions; And under normal use and holding conditions is chemically stable.Suitable Z
8Group comprises hydroxyl, methyl, methoxyl group, ethyoxyl, propoxyl group and aryloxy group.Two R on silicon atom
93Group can be represented identical or different group.Preferably, these two R
93The group that the group representative is identical.Suitable R
93Group comprises methyl, ethyl, propyl group, phenyl, aminomethyl phenyl and phenyl methyl.Preferred polysiloxane compound is polydimethylsiloxane, poly-di-ethyl siloxane and PSI.The polydimethylsiloxane that also is called simethicone is especially preferred.Spendable poly-alkylsiloxane comprises for example polydimethylsiloxane.These silicone compounds can be for example with its Viscasil
With SF96 series available from General ElectricCompany and with its Dow Corning 200 series available from Dow Corning.
Can also use polyoxyethylene alkyl aryl radical siloxane fluid, and it comprises for example PSI.These siloxanes can be available from for example General Electric Company, SF1075 aminomethyl phenyl fluid, and perhaps available from Dow Corning, 556 cosmetics-stage fluids.
Also can be used for the mineral oil that nonvolatile oil of the present invention is a different brackets.Mineral oil is the liquid mixture of the hydrocarbon that obtains from oil.The instantiation of suitable hydrocarbon comprises paraffin oil, mineral oil, dodecane, Fancol ID, hexadecane, 2-Methylpentadecane, eicosylene, different eicosylene, tridecane, the tetradecane, polybutene, polyisobutylene, and composition thereof.
Polar solvent
The present composition comprises water-soluble polar solvent.Polar solvent provides the humidification beneficial effect to skin.Polar solvent also plays the solvent action of the molten water-soluble wetting agent of bag, otherwise these water-soluble wetting agents can not be compatible in lipophilic carriers substrate.Bound by theory not it is believed that polar solvent remains in the cholesteryl derivant, and further is trapped in the oily expansive clay material, so that stable hydrophobic gel to be provided.
For lip composition is provided, polar solvent accounts for about 0.01% to about 10%, preferred about 1% to about 8% of whole composition weight.
Be used for polar solvent of the present invention and comprise polyhydric alcohol for example glycerol, 1,3 butylene glycol, propylene glycol, hexanediol, propylene glycol, ethylene glycol, diethylene glycol, dipropylene glycol, diglycerol, sorbitol and be other sugar of liquid form in room temperature.Also can be used for of the present invention is water soluble alkoxylated non-ionic polymers, for example Polyethylene Glycol.
Can be used for commercially available polar solvent of the present invention comprises: the glycerol that derives from Asahi Denka; Derive from the propylene glycol of Inolex with trade name LEXOL PG-865/855; Derive from 1 of BASF, 2-propylene glycol USP; Derive from the 1,3 butylene glycol of Daisel Kagaku Kogyo; Derive from the dipropylene glycol of BASF with the identical goods name; Derive from the diglycerol of Solvay GmbH with trade name DIGLYCEROL; Derive from the hyaluronate sodium of ActiveOrganics with trade name ACTIMOIST; Derive from the AVIAN SODIUMHYALURONATE series of Intergen; Derive from the hyaluronate sodium of Ichimaru Pharcos.
Water-soluble wetting agent
The present composition can also comprise can be dissolved in above-mentioned polar solvent, preferred about 0.1% water-soluble wetting agent to about amount of 10%, more preferably from about 1% to about 5%.
Can be used for water-soluble wetting agent of the present invention and comprise nicotiamide, pantothenylol, bacteria culture media, allantoin, sodium lactate, PCA soda, aminoacid, carbamide, hyaluronate sodium, chondroitin sulfate, collagen, elastin laminin, pectin, carrageenin, sodium alginate, trehalose, Polianthes tuberosa L. sugar, chitin derivatives, chitosan derivative, and composition thereof.Nicotinamide and pantothenylol can be commercially available by for example Roche.
Hydrophobic gel
In the time of in being included in lipophilic carriers, hydrophobic gel can remain on polarity and water-soluble material in the hydrophobic gel with stable manner.By changing the content and the type of carrier, can make and contain hydrophobic gel and have different viscosities and the compositions of hardness, the viscosity of compositions and hardness can not wait to thin cream from hard lip pomade.The personal care composition that contains hydrophobic gel provides the physical stability of improving, for example stability under the phase condition and viscosity.Bound by theory not it is believed that hydrophobic gel of the present invention has good heat stability, and is stable surpassing under the environment of room temperature thus.
Hydrophobic gel of the present invention preferably makes by the method that comprises the following step:
(a) with the mixture of cholesteryl derivant, oily expansive clay material and nonvolatile oil with about 1500 rev/mins to about 3000 rev/mins, preferred about 1500 rev/mins to about 2500 rev/mins speed and about 80 ℃ to about 95 ℃, preferred about 88 ℃ to about 92 ℃ temperature mixing; With
(b) with the mixture that obtains in polar solvent and the step (a) with at least about 4000 rev/mins, preferred about 4000 rev/mins to about 8000 rev/mins, more preferably from about 5000 rev/mins to about 7000 rev/mins speed and about 85 ℃ to about 95 ℃, preferably about 88 ℃ of extremely about 92 ℃ temperature are mixed.
The blender that mixing can use high-shear mixer known in the art, for example be called Homomixer or Disper carries out.Hydrophobic gel of the present invention is preferably by mixing to be higher than the rotating speed that the typical case is used to prepare personal care composition, and makes with 2 steps.Bound by theory not, it is believed that in step (a), the mixture of component is mixed with the rotating speed of controlling, so oily expansive clay material expands, to be provided for Cholesteryl hydroxystearate and the polar solvent that adds subsequently traps enough spaces in the oily expansive clay material, mixing simultaneously is not too violent, thereby does not destroy the structure of oily expansive clay material.Bound by theory not it is believed that in step (b), and the mixture of component is mixed with high rotating speed, and polar solvent is trapped in the oily expansive clay material effectively like this.It is believed that the stability that this provides hydrophobic gel.
Use conventional mixed media that thus obtained hydrophobic gel is mixed with carrier then.
Carrier
The present composition comprises the carrier that is substantially free of water, surfactant and lecithin that is suitable for required application.Owing to be substantially free of such component, it is believed that hydrophobic gel provides physical stability, colour stability and anti-antiperspirant to compositions.In addition, owing to be substantially free of surfactant, can obtain compositions to the skin gentleness.So-called " being substantially free of " is meant and do not comprise active water, surfactant or lecithin in the compositions.Yet the present invention does not get rid of water, surfactant or lecithin that use can the have non-significant quantity component as impurity or by-product.For example, known in the artly be the water of above-mentioned polar solvent portability small percentage.Such low amounts of water is acceptable in the present composition.In typical case, any water, surfactant or the content of lecithin in whole compositions should be lower than respectively about 1%, preferably be lower than about 0.5%.
Because do not comprise water, surfactant or lecithin basically, carrier of the present invention is lipophilic in nature.Any component that can be compatible with hydrophobic gel all can be used as carrier.Select carrier to prepare different personal care compositions, comprise lip pomade, foundation cream, pigment or unpigmented skin or Hair grooming cream, hidroschesis rod are arranged and send out rod.Solid wax, gellant, above-mentioned nonvolatile oil, powder, coloring pigment and other lipophilic active ingredients can be mixed in the carrier.Above-mentioned nonvolatile oil can be included in the carrier.The nonvolatile oil that is used for carrier can be identical or different with the nonvolatile oil that is used to prepare hydrophobic gel.
In order to prepare lip pomade, foundation cream and cream, carrier is selected from one or more solid wax, nonvolatile oil, powder and coloring pigment.The present composition is particularly suited for preparing the lip composition that contains solid wax and coloring pigment in carrier.
Solid wax
The present composition can comprise solid wax.For lip composition is provided, solid wax accounts for about 10% to about 20%, preferred 12% to about 15% of whole composition weight.The amount of control solid wax is to provide required hardness and intensity to product.
Can be used for solid wax of the present invention is paraffin, microwax, ceresine, ceresin, Brazil wax, candelilla wax, behenic acid eicosyl ester, and composition thereof.The preferred mixture that uses various waxes.
Can be used for commercially available solid wax of the present invention comprises: derive from Noda wax candelilla wax NC-1630, derive from Strahl﹠amp; The ceresine SP-1021 of Pitsh and the behenic acid eicosyl ester that derives from CasChemical.
Powder and coloring pigment
The present composition can comprise powder and coloring pigment.For lip composition is provided, powder and coloring pigment account for about 1% to about 30%, preferred 2% to about 20% of whole composition weight.The amount of powder and coloring pigment is that for example tone, covering, UV protection effect and different dermal sensations are selected according to required product feature with type.
Can be used for material of the present invention is for example Talcum, Muscovitum, sericite, silicon dioxide, magnesium silicate, synthetic fluorophologopite, calcium silicates, aluminium silicate, bentonite and Montmorillonitum of clay inorganic material powders; Pearlescent pigment is the Muscovitum of aluminium oxide, barium sulfate, calcium hydrogen phosphate, calcium carbonate, titanium oxide, finely divided titanium oxide, zirconium oxide, zinc oxide, hydroxyapatite, ferrum oxide, iron titanate, ultramarine, Prussian blue, chromium oxide, chromic oxide gel, cobalt oxide, cobalt titanate, titanium oxide coating for example; Organic dust is polyester, polyethylene, polystyrene, isobutylene methyl resin, cellulose, 12-nylon, 6-nylon, styrene-propene acid copolymer, polypropylene, vinyl chloride-base polymer, tetrafluoro ethylene polymer, boron nitride, fish scale guanine, tar lake colours and natural lake colours for example.
Can use the spherical pigment of certain percentage.In preferred embodiments, this material is selected according to the oily absorbability of pigment.In a preferred embodiment, be used in combination pigment with high oily absorbability and pigment with low oily absorbability.
Can also use the pigment of handling through hydrophobicity.This pigment of handling through hydrophobicity can make by handling above-mentioned host material with the hydrophobicity inorganic agent, and described hydrophobicity inorganic agent comprises: siloxanes is methylsiloxane, polydimethylsiloxane and perfluoroalkyl silane for example; Fat material is stearic acid for example; Metallic soap is two aluminium myristates for example; The aluminum salt of h-tallow glutamic acid aluminum, hydrolecithin, lauroyl lysine, perfluoroalkyl phosphoric acid, and composition thereof.
Supplementary element
Compositions of the present invention can comprise other supplementary element, they can be selected by the person in the art according to the required feature of end product, and their suitable said compositions that makes are in beauty treatment or aestheticly more can be accepted or make them to have additional use beneficial effect.This class annexing ingredient uses with the content that is no more than composition weight about 5% separately usually.
The present composition can also comprise the non-volatile dispersive siloxanes that is commonly referred to siloxanes natural gum.Term used herein " siloxanes natural gum " is meant viscosity when 25 ℃ of temperature more than or equal to 1,000, the polysiloxane material of 000mPas.It is believed that siloxanes natural gum can improve for example lasting result of use of mar proof.The mass molecular weight typical case of " siloxanes natural gum " is about more than 200,000, usually about 200,000 to about 1,000, between 000.Concrete example comprises polydimethylsiloxane, poly-(dimethyl siloxane ethylene methacrylic radical siloxane) copolymer, poly-(dimethyl siloxane diphenyl siloxane ethylene methacrylic radical siloxane) copolymer and composition thereof.Commercially available siloxanes natural gum is described among the General Electric Silicone Rubber ProductData Sheets as SE 30, SE 33, SE54 and SE 76.
It is the silicone resin of highly cross-linked polysiloxanes system that the present composition can also comprise.It is believed that silicone resin can improve spreading ability and the sensation of improving skin.Described crosslinkedly introduce by trifunctional and four functional silanes being mixed with simple function or difunctional silane or the two at the polyorganosiloxane resin production period.As well known in the art, will change according to the specific silane moiety that mixes in the silicone resin in order to obtain the required crosslinking degree of polyorganosiloxane resin.Generally speaking, have the trifunctional of enough content and four functional silane monomeric units, and therefore have the crosslinked of enough levels, thereby make they can form hard or firm film when becoming dry silicone compositions can be considered silicone resin.The ratio of oxygen atom and silicon atom is the indication of the crosslinked level of concrete silicone material.Each silicon atom has at least about the polysiloxanes material of 1.1 oxygen atoms silicone resin normally of the present invention.Preferably, the ratio of oxygen and silicon atom was at least about 1.2: 1.0.The silane that is used for preparing silicone resin comprise monomethyl-, dimethyl-, trimethyl-, a phenyl-, diphenyl-, aminomethyl phenyl-, a vinyl-and methyl chloride vinyl silanes and tetrachloro silicane, wherein methyl substituted silane is the most frequently used.Preferably commodity are called the crosslinking silicone powder of Trefil E-505C, Trefil E-506C and 9506 Powder (powder); The suspended substance of the silicone elastomer of commodity BY29-119 by name and BY29-122; Silicone compounds latex with commodity SH5500, SC5570 by name and SM 5571; All these all derive from Dow Corning.
Spendable other silicone resin is the silicone resin powder, and for example the CTFA name is called the material of polymethylsilsequioxane, and this material is by the commercially available Tospearl of ToshibaSilicones
TM
The abbreviation naming system that is called " MDTQ " nomenclature principle according to those skilled in the art are well-known can be discerned silicone compositions, especially silicone resin easily.Under this naming system, polysiloxanes is described according to the various siloxanyl monomers of the formation polysiloxanes that exists.In brief, symbol M is meant a functional unit (CH
3)
3SiO
0.5D is meant difunctionality unit (CH
3)
2SiO; T is meant trifunctional units (CH
3) SiO
1.5Q is meant four functional unit SiO2.Unit symbol for example " ' " of M ', D ', T ' and Q ' is meant substituent group except that methyl, and must concrete definition when occurring at every turn.Typical other substituent group comprises the group such as vinyl, phenyl, amino, hydroxyl etc.Under the MDTQ system, according to the symbol subscript of various unitary total numbers in the expression polysiloxanes, or according to its meansigma methods, or as represent with molecular weight concrete shown in the mol ratio of different units of ratio finished the description of silicone materials.In polyorganosiloxane resin, with respect to D, D ', M and/or M ', the T of higher molar amounts, Q, T ' and/or Q ' mean the crosslinked of higher level.Yet as mentioned above, total crosslinked level can also be represented by the ratio of oxygen and silicon.
Can be used for preferred silicone resin of the present invention is MQ, MT, MTQ, MQ and MDTQ resin.Therefore, preferred siloxanes substituent group is a methyl.Particularly preferably be wherein M: the Q ratio is that the mean molecule quantity of about 0.5: 1.0 to about 1.5: 1.0 and resin is about 1000 to about 10,000 MQ resin.Commercially available MQ resin is the trimethylsiloxy silicate that for example derives from Dow Corning with trade name BY11-018.
The present composition can also comprise water-soluble polymer.It is believed that water-soluble polymer provides lasting effect.Spendable water-soluble polymer comprises sodium carboxymethyl cellulose, polyvinylpyrrolidone, polyvinyl alcohol, xanthan gum, agar, pulleran, bentonite and composition thereof.Commercially available water-soluble polymer comprises Carbopol series that derives from B.F.Goodrich Company and the PVP K-30 that derives from G.A.F.Chemicals.
Other component that can be formulated in the present composition is: antiseptic is benzyl alcohol, methyl parahydroxybenzoate, propyl p-hydroxybenzoate, imidazolidinyl urea and EDTA and salt thereof for example, spice, ultraviolet and infrared shielding agent and absorbent, for example ethylhexyl methoxy cinnamate and other.
Embodiment
The following example has further described and has proved the preferred embodiment in the scope of the invention.Provide these embodiment and only be for the present invention is described, but not be construed as limiting the invention,, can carry out multiple change it because under the condition that does not deviate from spirit and scope of the invention.
Embodiment 1 to 5
Following make-up composition is by being made by following component with preparation method described herein:
| Numbering | Component | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| ????1 | Quaternary ammonium-18 hectorite *1 | ????0.2 | ????0.2 | ????0.2 | ????0.2 | ????0.3 |
| ????2 | Cholesteryl hydroxystearate *2 | ????3 | ????6 | ????5 | ????5 | |
| ????3 | Cholesteryl?Macadamiate *3 | ????3 | ||||
| ????4 | Phenyl gathers trimethicone *4 | ????5 | ????5 | ????7 | ||
| ????5 | Liquid paraffin *5 | ????2 | ????5 | |||
| ????6 | Nicotiamide *6 | ????2 | ????2 | ????3.3 | ||
| ????7 | Carbamide *7 | ????2 | ||||
| ????8 | Glycerol *8 | ????6 | ????6 | ????8 | ????8 | ????10 |
| ????9 | Ceresine *9 | ????4 | ????4 | ????4 | ????4 | ????4 |
| ????10 | Microwax *10 | ????1.5 | ????1.5 | ????1.5 | ????1.5 | ????1.5 |
| ????11 | Candelilla wax *11 | ????5 | ????5 | ????5 | ????5 | ????5 |
| ????12 | Paraffin *12 | ????3 | ????3 | ????3 | ????3 | ????2 |
| ????13 | Diglycerol sebacate/different cetylate *13 | ????22.3 | ????22.3 | ????22.3 | ????22.3 | |
| ????14 | Absorb purified lanoline *14 | ????2.5 | ????2.5 | ????2.5 | ????2.5 | ????2.5 |
| ????15 | Lanolin oil *15 | ????20 | ????20 | ????20 | ||
| ????16 | The carboxylate that contains isotope carbon 13 *16 | ????7 | ????7 | ????7 | ????16 | ????20.2 |
| ????17 | Different n-nonanoic acid isotridecyl ester *17 | ????3 | ????3 | ????3 | ????5 | ????10 |
| ????18 | Ethylhexyl methoxy cinnamate | ????3.5 | ||||
| ????19 | Antiseptic | ????0.5 | ????0.5 | ????0.5 | ????0.5 | ????0.5 |
| ????20 | Powder pigment | ????15 | ????15 | ????15 | ????20 | ????30 |
The definition of component
*1 quaternary ammonium-18 hectorite: the Bentone 38 that derives from Rheox.Inc.
*2 Cholesteryl hydroxystearates: derive from Nisshin Oil Mills, the Salacos HS of Ltd.
*3Cholesteryl Macadamiate: the Yofco MAC that derives from Nippon Fine Chemical
*4 phenyl gather trimethicone: the silicone oil KF-56 that derives from Shinetsu Silicone
*5 liquid paraffin: the liquid paraffin that derives from Witco Chemicla
*6 nicotiamide: the nicotiamide that derives from Roche
*7 carbamide: the carbamide that derives from Taisei Chemical
*8 glycerol: the glycerol USP that derives from Asahi Denka
*9 ceresine: derive from Strahl﹠amp; The ceresine SP-1021 of Pitsh
*10 microwaxes: the Multiwax 180-M Yellow that derives from Witco Chemical
*11 candelilla wax: the Candelilla wax NC-1630 that derives from Noda wax
*12 paraffin: the Paraffin wax FT-150 that derives from Sazole
*13 diglycerol sebacates/different cetylate: the Salacos DGS-16 that derives from Nisshin Oil Mills
*14 absorb purified lanoline: the Crodalan SWL that derives from Croda
*15 lanolin oils: the lanolin oil that derives from Croda
*16Trioctanoin: derive from Nisshin Oil Mills, the Hexalan of Ltd
*17 different n-nonanoic acid isotridecyl esters: the Crodamol TN that derives from Croda
Preparation method
The make-up composition of embodiment 1 to 5 is as described below suitably to be made: at first, use the Homomixer heating that the mixture of component numbering 1 to 5 is disperseed with 1500 rev/mins to 2500 rev/mins speed in the hermetically sealed can of 90 ℃ of temperature.Mixture with component numbering 6 to 8 dissolves 90 ℃ of temperature separately.This solution (component numbering 6 to 8) is added in the dispersion liquid (component numbering 1 to 5), and uses Homomixer that this mixture is further disperseed to form hydrophobic gel with 5000 rev/mins to 7000 rev/mins speed.Next, component as implied above numbering 9 to 19 is heated to dissolving in the jar of the sealing of 80 ℃ of temperature, adds above-mentioned hydrophobic gel and component numbering 20 then, use disperser with this mixture 80 ℃ of temperature dispersion to make the lipotropy dispersion liquid.Thermoregulation to 80 ℃ temperature with the gained dispersion liquid.At last, this dispersion liquid is filled in the gas-tight container, and is cooled to room temperature.
These embodiments of the foregoing description representative have lot of advantages.For example, embodiment 1 to 3 provides lip pomade, and this lip pomade provides lip flexibility, the wettability improved, and has reduced observable cheilogramma and wrinkle around lip.Embodiment 4 provides the bar powder.Embodiment 5 provides loose powder.The foundation cream of embodiment 4 to 5 provides flexibility, the wettability improved, and has reduced observable lines and wrinkle on skin, particularly skin of face.The make-up composition of embodiment 1 to 5 also has the stability of the improvement aspect physical hardness, color and anti-antiperspirant.
Should be appreciated that embodiment of the present invention and specific embodiments only are illustrative, under the condition that does not deviate from spirit and scope of the invention, this area professional can carry out various changes or variation to it.
Claims (6)
1. personal care composition, said composition comprises by weight:
(a) about 5% to about 35% hydrophobic gel, this gel comprises:
(i) cholesteryl derivant;
(ii) oily expansive clay material;
(iii) non-volatile liquid oil; With
(iv) polar solvent; With
(b) be substantially free of the carrier of water, surfactant and lecithin.
2. as the personal care composition of lip pomade, foundation cream or cream, said composition comprises by weight:
(a) about 5% to about 35% hydrophobic gel, this gel comprises:
(i) cholesteryl derivant;
(ii) oily expansive clay material;
(iii) non-volatile liquid oil; With
(iv) polar solvent; With
(b) be substantially free of the carrier of water, surfactant and lecithin, this carrier comprises one or more solid wax and powder or coloring pigment.
3. be used as the compositions of the claim 1 of lip pomade, said composition comprises by weight:
(a) about 10% to about 20% hydrophobic gel, and this gel comprises by whole composition weight meter:
(i) about 2% to about 7% cholesteryl derivant;
(ii) about 0.1% to 1% oily expansive clay material;
(iii) about 2% to about 10% non-volatile liquid oil; With
(iv) about 0.01% to about 10% polar solvent; With
(b) be substantially free of the carrier of water, surfactant and lecithin, this carrier comprises solid wax and powder or coloring pigment.
4. the lip composition of claim 3, said composition also comprises the water-soluble wetting agent that exists with the amount that can be dissolved in polar solvent.
5. the lip composition of claim 4, wherein this water-soluble wetting agent is about 1% to about 5% nicotiamide, this polar solvent is a glycerol, and the content of glycerol be niacinamide content at least about 3 times.
6. the preparation of compositions method of claim 1, this method comprises the following step:
(a) with the mixture of cholesteryl derivant, oily expansive clay material and non-volatile liquid oil, mix with about 1500 rev/mins of extremely about 3000 rev/mins speed with in about 85 ℃ of extremely about 95 ℃ temperature;
(b) with the mixture that obtains in polar solvent and the step (a) to mix to about 92 ℃ temperature at least about 4000 rev/mins speed with at about 85 ℃; With
(c) carrier is mixed with the mixture of acquisition in the step (b).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US2000/026492 WO2002026198A1 (en) | 2000-09-26 | 2000-09-26 | Personal care composition comprising hydrophobic gel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1454072A true CN1454072A (en) | 2003-11-05 |
Family
ID=21741809
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN00819916A Pending CN1454072A (en) | 2000-09-26 | 2000-09-26 | Personal care composition comprising hydrophobic gel |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP1320352A1 (en) |
| JP (1) | JP2004509911A (en) |
| KR (1) | KR20030036817A (en) |
| CN (1) | CN1454072A (en) |
| AU (2) | AU7834100A (en) |
| CA (1) | CA2422453A1 (en) |
| CZ (1) | CZ2003789A3 (en) |
| MX (1) | MXPA03002695A (en) |
| WO (1) | WO2002026198A1 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4421831B2 (en) * | 2003-03-27 | 2010-02-24 | 株式会社コーセー | Oily cosmetics |
| JP4596449B2 (en) * | 2004-02-19 | 2010-12-08 | 株式会社資生堂 | Sunscreen cosmetics |
| JP2007269763A (en) * | 2006-03-31 | 2007-10-18 | Kose Corp | Oily cosmetic |
| JP5506442B2 (en) * | 2010-02-09 | 2014-05-28 | 株式会社ブリヂストン | Tire manufacturing bladder and method for manufacturing the tire manufacturing bladder |
| CA2813345C (en) | 2010-11-12 | 2019-03-12 | Unilever Plc | Antiperspirant compositions containing triethylhexanoin |
| JP7203641B2 (en) * | 2018-03-29 | 2023-01-13 | 株式会社コーセー | oily solid cosmetics |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1581663A (en) * | 1968-07-11 | 1969-09-19 | ||
| AU697809B2 (en) * | 1993-10-18 | 1998-10-15 | Procter & Gamble Company, The | Non-sweating lipsticks |
| KR100453448B1 (en) * | 1995-06-29 | 2005-01-13 | 가부시키가이샤 시세이도 | Cholesterol ester clathrate, water-holding composition, hydrous compositions, cosmetics containing the same, and process for the preparation thereof |
| CN1344151A (en) * | 1999-02-12 | 2002-04-10 | 宝洁公司 | Cosmetic compsns. contg. vitamin Be compounds |
-
2000
- 2000-09-26 KR KR10-2003-7004152A patent/KR20030036817A/en not_active Application Discontinuation
- 2000-09-26 CZ CZ2003789A patent/CZ2003789A3/en unknown
- 2000-09-26 EP EP00968424A patent/EP1320352A1/en not_active Ceased
- 2000-09-26 CA CA002422453A patent/CA2422453A1/en not_active Abandoned
- 2000-09-26 JP JP2002530029A patent/JP2004509911A/en active Pending
- 2000-09-26 WO PCT/US2000/026492 patent/WO2002026198A1/en not_active Application Discontinuation
- 2000-09-26 AU AU7834100A patent/AU7834100A/en active Pending
- 2000-09-26 MX MXPA03002695A patent/MXPA03002695A/en unknown
- 2000-09-26 CN CN00819916A patent/CN1454072A/en active Pending
- 2000-09-26 AU AU2000278341A patent/AU2000278341B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| KR20030036817A (en) | 2003-05-09 |
| CA2422453A1 (en) | 2002-04-04 |
| EP1320352A1 (en) | 2003-06-25 |
| WO2002026198A1 (en) | 2002-04-04 |
| JP2004509911A (en) | 2004-04-02 |
| AU2000278341B2 (en) | 2005-01-13 |
| CZ2003789A3 (en) | 2003-06-18 |
| MXPA03002695A (en) | 2003-06-24 |
| AU7834100A (en) | 2002-04-08 |
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